#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/72/4317246.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4317246
loop_
_publ_author_name
'Brandon Kilduff'
'Dmitry Pogozhev'
'Stéphane A. Baudron'
'Mir Wais Hosseini'
_publ_contact_author
; Prof Mir Wais Hosseini
  Laboratoire de Chimie de Coordination Organique, 
  UMR CNRS 7140, Université de Strasbourg,
  CS 90032
  F-67081 Strasbourg Cedex, France 
;
_publ_contact_author_email       hosseini@unistra.fr
_publ_contact_author_fax         '33 3 68 85 13 23'
_publ_contact_author_phone       '33 3 68 85 13 25'
_publ_section_title
;
 Heterometallic Architectures Based on the Combination of Heteroleptic
 Copper and Cobalt Complexes with Silver Salts
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              11231
_journal_page_last               11239
_journal_paper_doi               10.1021/ic1019235
_journal_volume                  49
_journal_year                    2010
_chemical_formula_moiety         'C35 H26 Ag Co F3 N7 O5 S, C2 H3 N '
_chemical_formula_sum            'C37 H29 Ag Co F3 N8 O5 S'
_chemical_formula_weight         921.54
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 109.0160(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.4601(2)
_cell_length_b                   25.0292(6)
_cell_length_c                   13.8946(3)
_cell_measurement_reflns_used    8471
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.35
_cell_measurement_theta_min      2.49
_cell_volume                     3767.99(14)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0352
_diffrn_reflns_av_sigmaI/netI    0.0462
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       31
_diffrn_reflns_limit_k_min       -32
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            27714
_diffrn_reflns_theta_full        27.53
_diffrn_reflns_theta_max         27.53
_diffrn_reflns_theta_min         1.63
_exptl_absorpt_coefficient_mu    1.085
_exptl_absorpt_correction_T_max  0.9478
_exptl_absorpt_correction_T_min  0.8808
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.624
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       platelet
_exptl_crystal_F_000             1856
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.05
_refine_diff_density_max         2.220
_refine_diff_density_min         -1.056
_refine_diff_density_rms         0.130
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.111
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     508
_refine_ls_number_reflns         8608
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.111
_refine_ls_R_factor_all          0.0736
_refine_ls_R_factor_gt           0.0579
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0720P)²+7.6807P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1453
_refine_ls_wR_factor_ref         0.1630
_reflns_number_gt                7093
_reflns_number_total             8608
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic1019235_si_001_09.cif
_cod_data_source_block           compound10
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_Hall     '-P 2yn '
_cod_original_sg_symbol_H-M      'P 1 21/n 1 '
_cod_database_code               4317246
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.5321(4) 0.10350(18) 0.3285(3) 0.0330(10) Uani 1 1 d . . .
H1 H 0.4738 0.1255 0.3419 0.040 Uiso 1 1 calc R . .
C2 C 0.5035(4) 0.0597(2) 0.2613(4) 0.0375(11) Uani 1 1 d . . .
H2 H 0.4251 0.0478 0.2235 0.045 Uiso 1 1 calc R . .
C3 C 0.6127(4) 0.03821(19) 0.2626(4) 0.0361(10) Uani 1 1 d . . .
H3 H 0.6231 0.0088 0.2253 0.043 Uiso 1 1 calc R . .
C4 C 0.7084(4) 0.06883(17) 0.3313(3) 0.0280(9) Uani 1 1 d . . .
C5 C 0.8356(4) 0.06349(17) 0.3538(3) 0.0269(9) Uani 1 1 d . . .
C6 C 0.9246(4) 0.09696(17) 0.4195(3) 0.0262(8) Uani 1 1 d . . .
C7 C 1.0543(4) 0.09488(19) 0.4426(3) 0.0328(10) Uani 1 1 d . . .
H7 H 1.0984 0.0698 0.4189 0.039 Uiso 1 1 calc R . .
C8 C 1.1024(4) 0.1367(2) 0.5063(4) 0.0364(11) Uani 1 1 d . . .
H8 H 1.1854 0.1457 0.5341 0.044 Uiso 1 1 calc R . .
C9 C 1.0031(4) 0.16350(19) 0.5217(3) 0.0326(10) Uani 1 1 d . . .
H9 H 1.0104 0.1939 0.5618 0.039 Uiso 1 1 calc R . .
C10 C 0.8820(4) 0.02068(17) 0.3018(3) 0.0273(9) Uani 1 1 d . . .
C11 C 0.8686(4) -0.03331(18) 0.3189(4) 0.0350(10) Uani 1 1 d . . .
H11 H 0.8240 -0.0443 0.3605 0.042 Uiso 1 1 calc R . .
C12 C 0.9224(4) -0.07047(19) 0.2731(4) 0.0356(10) Uani 1 1 d . . .
H12 H 0.9159 -0.1068 0.2847 0.043 Uiso 1 1 calc R . .
C13 C 0.9856(4) -0.05323(18) 0.2101(3) 0.0326(10) Uani 1 1 d . . .
H13 H 1.0228 -0.0785 0.1805 0.039 Uiso 1 1 calc R . .
C14 C 0.9446(4) 0.03474(17) 0.2356(3) 0.0299(9) Uani 1 1 d . . .
H14 H 0.9517 0.0708 0.2220 0.036 Uiso 1 1 calc R . .
C15 C 0.8569(4) 0.20258(19) 0.6765(3) 0.0327(10) Uani 1 1 d . . .
H15 H 0.8622 0.1687 0.7051 0.039 Uiso 1 1 calc R . .
C16 C 0.8994(4) 0.24914(19) 0.7324(3) 0.0366(10) Uani 1 1 d . . .
H16 H 0.9379 0.2517 0.8024 0.044 Uiso 1 1 calc R . .
C17 C 0.8732(4) 0.29015(19) 0.6638(3) 0.0350(10) Uani 1 1 d . . .
H17 H 0.8896 0.3262 0.6786 0.042 Uiso 1 1 calc R . .
C18 C 0.8161(4) 0.26775(17) 0.5657(3) 0.0290(9) Uani 1 1 d . . .
C19 C 0.7841(4) 0.29326(17) 0.4713(3) 0.0275(9) Uani 1 1 d . . .
C20 C 0.7510(4) 0.26756(17) 0.3779(3) 0.0274(9) Uani 1 1 d . . .
C21 C 0.7376(4) 0.28985(19) 0.2800(3) 0.0353(10) Uani 1 1 d . . .
H21 H 0.7417 0.3259 0.2649 0.042 Uiso 1 1 calc R . .
C22 C 0.7174(5) 0.2482(2) 0.2130(4) 0.0378(11) Uani 1 1 d . . .
H22 H 0.7070 0.2504 0.1439 0.045 Uiso 1 1 calc R . .
C23 C 0.7154(4) 0.20143(19) 0.2682(3) 0.0323(10) Uani 1 1 d . . .
H23 H 0.7023 0.1673 0.2403 0.039 Uiso 1 1 calc R . .
C24 C 0.7913(4) 0.35262(17) 0.4740(3) 0.0299(9) Uani 1 1 d . . .
C25 C 0.8709(4) 0.3813(2) 0.4376(4) 0.0371(10) Uani 1 1 d . . .
H25 H 0.9225 0.3639 0.4081 0.044 Uiso 1 1 calc R . .
C26 C 0.8728(5) 0.4364(2) 0.4458(4) 0.0408(11) Uani 1 1 d . . .
H26 H 0.9258 0.4565 0.4218 0.049 Uiso 1 1 calc R . .
C27 C 0.7962(4) 0.46103(19) 0.4891(4) 0.0360(10) Uani 1 1 d . . .
H27 H 0.7994 0.4981 0.4950 0.043 Uiso 1 1 calc R . .
C28 C 0.7153(4) 0.38105(17) 0.5159(3) 0.0297(9) Uani 1 1 d . . .
H28 H 0.6607 0.3620 0.5399 0.036 Uiso 1 1 calc R . .
C29 C 0.4102(4) 0.2098(2) 0.5185(4) 0.0424(12) Uani 1 1 d . . .
H29A H 0.4228 0.2454 0.4983 0.064 Uiso 1 1 calc R . .
H29B H 0.3968 0.2109 0.5832 0.064 Uiso 1 1 calc R . .
H29C H 0.3395 0.1944 0.4686 0.064 Uiso 1 1 calc R . .
C30 C 0.5218(4) 0.17657(18) 0.5272(3) 0.0296(9) Uani 1 1 d . . .
C31 C 0.5519(4) 0.13214(18) 0.5930(3) 0.0318(9) Uani 1 1 d . . .
C32 C 0.6574(4) 0.09933(18) 0.6084(3) 0.0311(9) Uani 1 1 d . . .
C33 C 0.6759(5) 0.0507(2) 0.6750(5) 0.0506(14) Uani 1 1 d . . .
H33A H 0.7360 0.0278 0.6618 0.076 Uiso 1 1 calc R . .
H33B H 0.5991 0.0319 0.6607 0.076 Uiso 1 1 calc R . .
H33C H 0.7044 0.0614 0.7452 0.076 Uiso 1 1 calc R . .
C34 C 0.4678(5) 0.1187(2) 0.6468(4) 0.0420(12) Uani 1 1 d . . .
N1 N 0.6542(3) 0.10932(14) 0.3704(3) 0.0262(7) Uani 1 1 d . . .
N2 N 0.8962(3) 0.13980(14) 0.4715(3) 0.0258(7) Uani 1 1 d . . .
N3 N 0.9958(3) -0.00154(15) 0.1898(3) 0.0291(8) Uani 1 1 d . . .
N4 N 0.8078(3) 0.21269(14) 0.5770(3) 0.0272(7) Uani 1 1 d . . .
N5 N 0.7349(3) 0.21245(14) 0.3661(3) 0.0272(7) Uani 1 1 d . . .
N6 N 0.7168(3) 0.43438(14) 0.5235(3) 0.0301(8) Uani 1 1 d . . .
N7 N 0.4008(4) 0.1073(2) 0.6894(4) 0.0551(12) Uani 1 1 d . . .
O1 O 0.5818(3) 0.19075(12) 0.4694(2) 0.0291(6) Uani 1 1 d . . .
O2 O 0.7400(3) 0.10836(12) 0.5686(2) 0.0294(6) Uani 1 1 d . . .
Co1 Co 0.73631(5) 0.16223(2) 0.47026(4) 0.02397(15) Uani 1 1 d . . .
Ag1 Ag 1.09928(3) 0.028225(14) 0.09657(3) 0.03684(13) Uani 1 1 d . . .
C35 C 1.2878(6) -0.1422(4) 0.0253(6) 0.077(2) Uani 1 1 d . . .
O3 O 1.1402(5) -0.06827(16) 0.0331(4) 0.0770(15) Uani 1 1 d . . .
O4 O 1.1225(5) -0.1524(2) 0.1078(4) 0.0782(15) Uani 1 1 d . . .
O5 O 1.0608(4) -0.1429(2) -0.0734(3) 0.0768(14) Uani 1 1 d . . .
F1 F 1.3048(5) -0.1941(2) 0.0217(4) 0.1144(19) Uani 1 1 d . . .
F2 F 1.3122(5) -0.1178(3) -0.0540(4) 0.119(2) Uani 1 1 d . . .
F3 F 1.3701(4) -0.1235(4) 0.1103(5) 0.171(4) Uani 1 1 d . . .
S3 S 1.13584(12) -0.12416(5) 0.02285(11) 0.0437(3) Uani 1 1 d . . .
C36 C 0.1636(6) 0.1539(3) 0.2675(5) 0.0586(16) Uani 1 1 d . . .
C37 C 0.0989(8) 0.2043(3) 0.2666(6) 0.081(2) Uani 1 1 d . . .
H37A H 0.0631 0.2041 0.3202 0.122 Uiso 1 1 calc R . .
H37B H 0.0349 0.2085 0.2022 0.122 Uiso 1 1 calc R . .
H37C H 0.1561 0.2335 0.2769 0.122 Uiso 1 1 calc R . .
N8 N 0.2146(6) 0.1146(3) 0.2696(5) 0.0730(16) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 C2 111.0(4) . . ?
N1 C1 H1 124.5 . . ?
C2 C1 H1 124.5 . . ?
C3 C2 C1 106.6(4) . . ?
C3 C2 H2 126.7 . . ?
C1 C2 H2 126.7 . . ?
C2 C3 C4 107.6(4) . . ?
C2 C3 H3 126.2 . . ?
C4 C3 H3 126.2 . . ?
N1 C4 C5 123.4(4) . . ?
N1 C4 C3 108.1(4) . . ?
C5 C4 C3 128.4(4) . . ?
C4 C5 C6 125.0(4) . . ?
C4 C5 C10 118.3(4) . . ?
C6 C5 C10 116.6(4) . . ?
N2 C6 C5 123.8(4) . . ?
N2 C6 C7 108.4(4) . . ?
C5 C6 C7 127.8(4) . . ?
C8 C7 C6 106.9(4) . . ?
C8 C7 H7 126.6 . . ?
C6 C7 H7 126.6 . . ?
C7 C8 C9 106.9(4) . . ?
C7 C8 H8 126.6 . . ?
C9 C8 H8 126.6 . . ?
N2 C9 C8 111.2(4) . . ?
N2 C9 H9 124.4 . . ?
C8 C9 H9 124.4 . . ?
C14 C10 C11 118.1(4) . . ?
C14 C10 C5 119.0(4) . . ?
C11 C10 C5 122.9(4) . . ?
C12 C11 C10 119.1(4) . . ?
C12 C11 H11 120.4 . . ?
C10 C11 H11 120.4 . . ?
C13 C12 C11 119.3(4) . . ?
C13 C12 H12 120.4 . . ?
C11 C12 H12 120.4 . . ?
N3 C13 C12 122.6(4) . . ?
N3 C13 H13 118.7 . . ?
C12 C13 H13 118.7 . . ?
N3 C14 C10 122.8(4) . . ?
N3 C14 H14 118.6 . . ?
C10 C14 H14 118.6 . . ?
N4 C15 C16 111.7(4) . . ?
N4 C15 H15 124.1 . . ?
C16 C15 H15 124.1 . . ?
C17 C16 C15 106.4(4) . . ?
C17 C16 H16 126.8 . . ?
C15 C16 H16 126.8 . . ?
C16 C17 C18 107.5(4) . . ?
C16 C17 H17 126.2 . . ?
C18 C17 H17 126.2 . . ?
N4 C18 C19 123.5(4) . . ?
N4 C18 C17 108.0(4) . . ?
C19 C18 C17 128.2(4) . . ?
C20 C19 C18 125.1(4) . . ?
C20 C19 C24 118.9(4) . . ?
C18 C19 C24 115.9(4) . . ?
C19 C20 N5 123.7(4) . . ?
C19 C20 C21 128.4(4) . . ?
N5 C20 C21 107.7(4) . . ?
C22 C21 C20 107.0(4) . . ?
C22 C21 H21 126.5 . . ?
C20 C21 H21 126.5 . . ?
C21 C22 C23 107.0(4) . . ?
C21 C22 H22 126.5 . . ?
C23 C22 H22 126.5 . . ?
N5 C23 C22 111.0(4) . . ?
N5 C23 H23 124.5 . . ?
C22 C23 H23 124.5 . . ?
C25 C24 C28 117.8(4) . . ?
C25 C24 C19 123.3(4) . . ?
C28 C24 C19 119.0(4) . . ?
C24 C25 C26 118.9(4) . . ?
C24 C25 H25 120.6 . . ?
C26 C25 H25 120.6 . . ?
C27 C26 C25 119.5(5) . . ?
C27 C26 H26 120.3 . . ?
C25 C26 H26 120.3 . . ?
N6 C27 C26 123.0(4) . . ?
N6 C27 H27 118.5 . . ?
C26 C27 H27 118.5 . . ?
N6 C28 C24 123.3(4) . . ?
N6 C28 H28 118.3 . . ?
C24 C28 H28 118.3 . . ?
C30 C29 H29A 109.5 . . ?
C30 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C30 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
O1 C30 C31 124.3(4) . . ?
O1 C30 C29 114.8(4) . . ?
C31 C30 C29 120.8(4) . . ?
C30 C31 C32 124.8(4) . . ?
C30 C31 C34 117.3(4) . . ?
C32 C31 C34 118.0(4) . . ?
O2 C32 C31 123.7(4) . . ?
O2 C32 C33 116.1(4) . . ?
C31 C32 C33 120.2(4) . . ?
C32 C33 H33A 109.5 . . ?
C32 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C32 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
N7 C34 C31 179.2(6) . . ?
C1 N1 C4 106.7(4) . . ?
C1 N1 Co1 125.8(3) . . ?
C4 N1 Co1 127.4(3) . . ?
C9 N2 C6 106.6(4) . . ?
C9 N2 Co1 126.0(3) . . ?
C6 N2 Co1 127.4(3) . . ?
C13 N3 C14 118.1(4) . . ?
C13 N3 Ag1 124.4(3) . . ?
C14 N3 Ag1 117.4(3) . . ?
C15 N4 C18 106.4(4) . . ?
C15 N4 Co1 127.3(3) . . ?
C18 N4 Co1 126.3(3) . . ?
C23 N5 C20 107.2(4) . . ?
C23 N5 Co1 126.4(3) . . ?
C20 N5 Co1 126.4(3) . . ?
C27 N6 C28 117.5(4) . . ?
C27 N6 Ag1 123.8(3) . 4_566 ?
C28 N6 Ag1 118.5(3) . 4_566 ?
C30 O1 Co1 125.9(3) . . ?
C32 O2 Co1 126.5(3) . . ?
O1 Co1 O2 94.17(13) . . ?
O1 Co1 N2 175.08(14) . . ?
O2 Co1 N2 89.34(14) . . ?
O1 Co1 N5 88.29(14) . . ?
O2 Co1 N5 176.12(14) . . ?
N2 Co1 N5 88.38(15) . . ?
O1 Co1 N4 85.41(14) . . ?
O2 Co1 N4 90.42(14) . . ?
N2 Co1 N4 91.12(15) . . ?
N5 Co1 N4 92.77(15) . . ?
O1 Co1 N1 91.03(14) . . ?
O2 Co1 N1 85.50(14) . . ?
N2 Co1 N1 92.68(15) . . ?
N5 Co1 N1 91.46(15) . . ?
N4 Co1 N1 174.39(15) . . ?
N6 Ag1 N3 171.09(14) 4_665 . ?
N6 Ag1 Ag1 100.29(10) 4_665 3_755 ?
N3 Ag1 Ag1 88.38(10) . 3_755 ?
F1 C35 F3 108.0(8) . . ?
F1 C35 F2 109.8(6) . . ?
F3 C35 F2 106.7(7) . . ?
F1 C35 S3 113.7(6) . . ?
F3 C35 S3 109.4(5) . . ?
F2 C35 S3 109.0(6) . . ?
O3 S3 O5 114.6(3) . . ?
O3 S3 O4 114.8(3) . . ?
O5 S3 O4 115.0(3) . . ?
O3 S3 C35 104.3(4) . . ?
O5 S3 C35 102.9(3) . . ?
O4 S3 C35 103.0(4) . . ?
N8 C36 C37 179.1(7) . . ?
C36 C37 H37A 109.5 . . ?
C36 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C36 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N1 1.337(5) . ?
C1 C2 1.408(7) . ?
C1 H1 0.9300 . ?
C2 C3 1.357(7) . ?
C2 H2 0.9300 . ?
C3 C4 1.421(6) . ?
C3 H3 0.9300 . ?
C4 N1 1.389(6) . ?
C4 C5 1.394(6) . ?
C5 C6 1.403(6) . ?
C5 C10 1.484(6) . ?
C6 N2 1.389(5) . ?
C6 C7 1.416(6) . ?
C7 C8 1.366(7) . ?
C7 H7 0.9300 . ?
C8 C9 1.396(7) . ?
C8 H8 0.9300 . ?
C9 N2 1.335(5) . ?
C9 H9 0.9300 . ?
C10 C14 1.385(6) . ?
C10 C11 1.389(6) . ?
C11 C12 1.380(7) . ?
C11 H11 0.9300 . ?
C12 C13 1.375(7) . ?
C12 H12 0.9300 . ?
C13 N3 1.337(6) . ?
C13 H13 0.9300 . ?
C14 N3 1.347(6) . ?
C14 H14 0.9300 . ?
C15 N4 1.337(5) . ?
C15 C16 1.397(7) . ?
C15 H15 0.9300 . ?
C16 C17 1.366(7) . ?
C16 H16 0.9300 . ?
C17 C18 1.421(6) . ?
C17 H17 0.9300 . ?
C18 N4 1.394(5) . ?
C18 C19 1.396(6) . ?
C19 C20 1.386(6) . ?
C19 C24 1.488(6) . ?
C20 N5 1.394(5) . ?
C20 C21 1.432(6) . ?
C21 C22 1.366(7) . ?
C21 H21 0.9300 . ?
C22 C23 1.404(7) . ?
C22 H22 0.9300 . ?
C23 N5 1.334(6) . ?
C23 H23 0.9300 . ?
C24 C25 1.381(6) . ?
C24 C28 1.391(6) . ?
C25 C26 1.383(7) . ?
C25 H25 0.9300 . ?
C26 C27 1.362(7) . ?
C26 H26 0.9300 . ?
C27 N6 1.336(6) . ?
C27 H27 0.9300 . ?
C28 N6 1.339(5) . ?
C28 H28 0.9300 . ?
C29 C30 1.497(6) . ?
C29 H29A 0.9600 . ?
C29 H29B 0.9600 . ?
C29 H29C 0.9600 . ?
C30 O1 1.267(5) . ?
C30 C31 1.409(6) . ?
C31 C32 1.419(6) . ?
C31 C34 1.438(7) . ?
C32 O2 1.262(5) . ?
C32 C33 1.502(7) . ?
C33 H33A 0.9600 . ?
C33 H33B 0.9600 . ?
C33 H33C 0.9600 . ?
C34 N7 1.148(7) . ?
N1 Co1 1.927(3) . ?
N2 Co1 1.912(3) . ?
N3 Ag1 2.154(4) . ?
N4 Co1 1.916(4) . ?
N5 Co1 1.912(4) . ?
N6 Ag1 2.148(4) 4_566 ?
O1 Co1 1.905(3) . ?
O2 Co1 1.911(3) . ?
Ag1 N6 2.148(4) 4_665 ?
Ag1 Ag1 3.2244(8) 3_755 ?
C35 F1 1.318(10) . ?
C35 F3 1.333(8) . ?
C35 F2 1.365(10) . ?
C35 S3 1.789(7) . ?
O3 S3 1.405(4) . ?
O4 S3 1.426(4) . ?
O5 S3 1.414(5) . ?
C36 N8 1.139(9) . ?
C36 C37 1.461(11) . ?
C37 H37A 0.9600 . ?
C37 H37B 0.9600 . ?
C37 H37C 0.9600 . ?
