#------------------------------------------------------------------------------
#$Date: 2016-03-23 20:15:11 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179404 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/01/4330151.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4330151
loop_
_publ_author_name
'Md Hosnay Mobarok'
'Robert McDonald'
'Michael J. Ferguson'
'Martin Cowie'
_publ_section_title
;
 Mixed Bis(μ-silylene) and (μ-Silylene)/(μ-Germylene) Complexes
 Involving the Rh/Ir Metal Combination: Nature of the Si...Si Interactions
 in the Bis(μ-silylene) Species
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              9249
_journal_page_last               9258
_journal_paper_doi               10.1021/ic300720y
_journal_volume                  51
_journal_year                    2012
_chemical_formula_moiety         'C65 H58 Ir O2 P4 Rh Si2, 2.5(C6 H6)'
_chemical_formula_sum            'C80 H73 Ir O2 P4 Rh Si2'
_chemical_formula_weight         1541.55
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 96.4988(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   20.1338(8)
_cell_length_b                   22.4680(9)
_cell_length_c                   30.3133(12)
_cell_measurement_reflns_used    9015
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      2.26
_cell_volume                     13624.6(9)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0248
_diffrn_reflns_av_sigmaI/netI    0.0198
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_l_max       39
_diffrn_reflns_limit_l_min       -39
_diffrn_reflns_number            59862
_diffrn_reflns_theta_full        27.52
_diffrn_reflns_theta_max         27.52
_diffrn_reflns_theta_min         1.47
_exptl_absorpt_coefficient_mu    2.371
_exptl_absorpt_correction_T_max  0.5864
_exptl_absorpt_correction_T_min  0.4613
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2008)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.503
_exptl_crystal_description       prism
_exptl_crystal_F_000             6232
_exptl_crystal_size_max          0.39
_exptl_crystal_size_mid          0.31
_exptl_crystal_size_min          0.25
_refine_diff_density_max         0.974
_refine_diff_density_min         -0.360
_refine_diff_density_rms         0.063
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.039
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     817
_refine_ls_number_reflns         15662
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.039
_refine_ls_R_factor_all          0.0264
_refine_ls_R_factor_gt           0.0216
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0264P)²+12.9241P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0512
_refine_ls_wR_factor_ref         0.0530
_reflns_number_gt                14009
_reflns_number_total             15662
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ic300720y_si_002_5.cif
_cod_data_source_block           cow1135
_cod_database_code               4330151
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
IrA Ir 0.762923(5) 0.029345(4) 0.146085(3) 0.02007(3) Uani 0.50 1 d P A 1
RhA Rh 0.643919(5) 0.014017(4) 0.089791(3) 0.01935(3) Uani 0.50 1 d P A 1
IrB Ir 0.643919(5) 0.014017(4) 0.089791(3) 0.01935(3) Uani 0.50 1 d P A 2
RhB Rh 0.762923(5) 0.029345(4) 0.146085(3) 0.02007(3) Uani 0.50 1 d P A 2
P1 P 0.78099(2) 0.12872(2) 0.126516(17) 0.02201(10) Uani 1 1 d . . .
P2 P 0.64526(2) 0.11407(2) 0.063775(16) 0.02067(10) Uani 1 1 d . . .
P3 P 0.70259(2) 0.04732(2) 0.207262(17) 0.02257(10) Uani 1 1 d . . .
P4 P 0.57066(2) 0.01632(2) 0.144451(17) 0.02149(10) Uani 1 1 d . . .
Si1 Si 0.75358(3) 0.01344(2) 0.068681(18) 0.02198(11) Uani 1 1 d . . .
H1 H 0.7680(12) 0.0641(11) 0.0453(8) 0.038(6) Uiso 1 1 d . . .
Si2 Si 0.70387(3) -0.06207(2) 0.134158(18) 0.02269(11) Uani 1 1 d . . .
O1 O 0.90411(10) -0.00975(11) 0.17468(8) 0.0707(7) Uani 1 1 d . A .
O2 O 0.57158(10) -0.05106(8) 0.01184(6) 0.0507(5) Uani 1 1 d . A .
C1 C 0.84926(11) 0.00454(11) 0.16507(8) 0.0376(5) Uani 1 1 d . . .
C2 C 0.59806(11) -0.02608(9) 0.04202(7) 0.0292(4) Uani 1 1 d . . .
C3 C 0.70417(9) 0.16266(8) 0.09829(7) 0.0235(4) Uani 1 1 d . A .
H3A H 0.7176 0.1952 0.0792 0.028 Uiso 1 1 calc R . .
H3B H 0.6796 0.1811 0.1213 0.028 Uiso 1 1 calc R . .
C4 C 0.61283(10) 0.02442(9) 0.20162(7) 0.0245(4) Uani 1 1 d . A .
H4A H 0.6097 -0.0141 0.2171 0.029 Uiso 1 1 calc R . .
H4B H 0.5878 0.0541 0.2173 0.029 Uiso 1 1 calc R . .
C11 C 0.84765(9) 0.14626(9) 0.09149(6) 0.0247(4) Uani 1 1 d . A .
C12 C 0.85531(10) 0.20429(10) 0.07697(7) 0.0305(4) Uani 1 1 d . . .
H12 H 0.8258 0.2343 0.0850 0.037 Uiso 1 1 calc R A .
C13 C 0.90503(11) 0.21916(11) 0.05103(8) 0.0360(5) Uani 1 1 d . A .
H13 H 0.9086 0.2588 0.0406 0.043 Uiso 1 1 calc R . .
C14 C 0.94961(12) 0.17599(12) 0.04032(8) 0.0404(6) Uani 1 1 d . . .
H14 H 0.9839 0.1859 0.0225 0.048 Uiso 1 1 calc R A .
C15 C 0.94420(11) 0.11874(11) 0.05549(8) 0.0394(5) Uani 1 1 d . A .
H15 H 0.9753 0.0893 0.0485 0.047 Uiso 1 1 calc R . .
C16 C 0.89343(10) 0.10360(10) 0.08098(7) 0.0311(5) Uani 1 1 d . . .
H16 H 0.8900 0.0639 0.0913 0.037 Uiso 1 1 calc R A .
C21 C 0.80719(10) 0.18352(9) 0.17026(7) 0.0265(4) Uani 1 1 d . A .
C22 C 0.78220(11) 0.24112(9) 0.17204(7) 0.0323(5) Uani 1 1 d . . .
H22 H 0.7466 0.2537 0.1508 0.039 Uiso 1 1 calc R A .
C23 C 0.80925(13) 0.28044(11) 0.20479(8) 0.0405(6) Uani 1 1 d . A .
H23 H 0.7914 0.3195 0.2060 0.049 Uiso 1 1 calc R . .
C24 C 0.86128(13) 0.26342(12) 0.23520(8) 0.0442(6) Uani 1 1 d . . .
H24 H 0.8797 0.2906 0.2573 0.053 Uiso 1 1 calc R A .
C25 C 0.88675(13) 0.20654(12) 0.23355(8) 0.0444(6) Uani 1 1 d . A .
H25 H 0.9231 0.1947 0.2545 0.053 Uiso 1 1 calc R . .
C26 C 0.85967(11) 0.16657(11) 0.20158(7) 0.0352(5) Uani 1 1 d . . .
H26 H 0.8771 0.1273 0.2011 0.042 Uiso 1 1 calc R A .
C31 C 0.56981(9) 0.16179(8) 0.05793(7) 0.0232(4) Uani 1 1 d . A .
C32 C 0.55271(11) 0.19891(10) 0.09151(8) 0.0353(5) Uani 1 1 d . . .
H32 H 0.5809 0.2008 0.1188 0.042 Uiso 1 1 calc R A .
C33 C 0.49521(12) 0.23331(11) 0.08597(9) 0.0420(6) Uani 1 1 d . A .
H33 H 0.4844 0.2582 0.1095 0.050 Uiso 1 1 calc R . .
C34 C 0.45350(11) 0.23171(10) 0.04661(9) 0.0381(5) Uani 1 1 d . . .
H34 H 0.4148 0.2561 0.0425 0.046 Uiso 1 1 calc R A .
C35 C 0.46877(11) 0.19445(11) 0.01351(8) 0.0382(5) Uani 1 1 d . A .
H35 H 0.4398 0.1924 -0.0135 0.046 Uiso 1 1 calc R . .
C36 C 0.52603(10) 0.15963(10) 0.01882(7) 0.0318(5) Uani 1 1 d . . .
H36 H 0.5356 0.1339 -0.0045 0.038 Uiso 1 1 calc R A .
C41 C 0.66870(10) 0.12201(9) 0.00724(7) 0.0254(4) Uani 1 1 d . A .
C42 C 0.71442(11) 0.16384(10) -0.00455(7) 0.0317(5) Uani 1 1 d . . .
H42 H 0.7348 0.1906 0.0172 0.038 Uiso 1 1 calc R A .
C43 C 0.73048(12) 0.16685(11) -0.04771(8) 0.0410(6) Uani 1 1 d . A .
H43 H 0.7630 0.1947 -0.0550 0.049 Uiso 1 1 calc R . .
C44 C 0.69991(13) 0.12988(12) -0.08026(8) 0.0444(6) Uani 1 1 d . . .
H44 H 0.7102 0.1331 -0.1100 0.053 Uiso 1 1 calc R A .
C45 C 0.65418(13) 0.08817(11) -0.06921(8) 0.0413(6) Uani 1 1 d . A .
H45 H 0.6328 0.0625 -0.0914 0.050 Uiso 1 1 calc R . .
C46 C 0.63957(11) 0.08380(10) -0.02575(7) 0.0326(5) Uani 1 1 d . . .
H46 H 0.6091 0.0542 -0.0182 0.039 Uiso 1 1 calc R A .
C51 C 0.73209(10) 0.01074(9) 0.26005(7) 0.0272(4) Uani 1 1 d . A .
C52 C 0.78774(12) -0.02589(11) 0.26305(8) 0.0382(5) Uani 1 1 d . . .
H52 H 0.8099 -0.0326 0.2375 0.046 Uiso 1 1 calc R A .
C53 C 0.81159(13) -0.05301(13) 0.30286(9) 0.0483(6) Uani 1 1 d . A .
H53 H 0.8497 -0.0782 0.3044 0.058 Uiso 1 1 calc R . .
C54 C 0.77987(14) -0.04327(13) 0.34019(9) 0.0484(7) Uani 1 1 d . . .
H54 H 0.7966 -0.0610 0.3677 0.058 Uiso 1 1 calc R A .
C55 C 0.72398(14) -0.00780(12) 0.33757(8) 0.0461(6) Uani 1 1 d . A .
H55 H 0.7018 -0.0016 0.3632 0.055 Uiso 1 1 calc R . .
C56 C 0.69979(12) 0.01900(10) 0.29784(8) 0.0363(5) Uani 1 1 d . . .
H56 H 0.6609 0.0432 0.2964 0.044 Uiso 1 1 calc R A .
C61 C 0.69214(10) 0.12413(9) 0.22585(7) 0.0271(4) Uani 1 1 d . A .
C62 C 0.73366(11) 0.14920(10) 0.26079(7) 0.0327(5) Uani 1 1 d . . .
H62 H 0.7690 0.1264 0.2757 0.039 Uiso 1 1 calc R A .
C63 C 0.72358(13) 0.20753(11) 0.27392(8) 0.0406(6) Uani 1 1 d . A .
H63 H 0.7517 0.2241 0.2981 0.049 Uiso 1 1 calc R . .
C64 C 0.67355(14) 0.24124(11) 0.25228(9) 0.0473(6) Uani 1 1 d . . .
H64 H 0.6667 0.2809 0.2616 0.057 Uiso 1 1 calc R A .
C65 C 0.63295(13) 0.21749(10) 0.21688(9) 0.0431(6) Uani 1 1 d . A .
H65 H 0.5990 0.2412 0.2013 0.052 Uiso 1 1 calc R . .
C66 C 0.64161(11) 0.15891(9) 0.20406(8) 0.0324(5) Uani 1 1 d . . .
H66 H 0.6127 0.1425 0.1802 0.039 Uiso 1 1 calc R A .
C71 C 0.49916(9) 0.06801(9) 0.14114(7) 0.0245(4) Uani 1 1 d . A .
C72 C 0.45952(10) 0.06938(9) 0.10041(7) 0.0298(4) Uani 1 1 d . . .
H72 H 0.4737 0.0487 0.0758 0.036 Uiso 1 1 calc R A .
C73 C 0.39983(11) 0.10037(10) 0.09528(8) 0.0359(5) Uani 1 1 d . A .
H73 H 0.3729 0.1002 0.0674 0.043 Uiso 1 1 calc R . .
C74 C 0.37919(11) 0.13171(10) 0.13079(9) 0.0391(5) Uani 1 1 d . . .
H74 H 0.3379 0.1526 0.1274 0.047 Uiso 1 1 calc R A .
C75 C 0.41870(11) 0.13251(10) 0.17092(8) 0.0370(5) Uani 1 1 d . A .
H75 H 0.4053 0.1549 0.1950 0.044 Uiso 1 1 calc R . .
C76 C 0.47830(11) 0.10048(9) 0.17620(7) 0.0306(4) Uani 1 1 d . . .
H76 H 0.5051 0.1008 0.2041 0.037 Uiso 1 1 calc R A .
C81 C 0.52148(10) -0.05212(9) 0.14999(7) 0.0260(4) Uani 1 1 d . A .
C82 C 0.52318(11) -0.09863(10) 0.12002(8) 0.0317(5) Uani 1 1 d . . .
H82 H 0.5499 -0.0952 0.0963 0.038 Uiso 1 1 calc R A .
C83 C 0.48613(12) -0.15018(10) 0.12435(8) 0.0384(5) Uani 1 1 d . A .
H83 H 0.4876 -0.1816 0.1035 0.046 Uiso 1 1 calc R . .
C84 C 0.44759(12) -0.15574(11) 0.15856(9) 0.0434(6) Uani 1 1 d . . .
H84 H 0.4225 -0.1910 0.1616 0.052 Uiso 1 1 calc R A .
C85 C 0.44526(13) -0.10974(12) 0.18867(9) 0.0477(6) Uani 1 1 d . A .
H85 H 0.4189 -0.1137 0.2126 0.057 Uiso 1 1 calc R . .
C86 C 0.48120(12) -0.05789(11) 0.18412(8) 0.0386(5) Uani 1 1 d . . .
H86 H 0.4783 -0.0261 0.2045 0.046 Uiso 1 1 calc R A .
C91 C 0.79513(10) -0.04465(9) 0.03642(7) 0.0276(4) Uani 1 1 d . A .
C92 C 0.85762(11) -0.06868(10) 0.05036(8) 0.0343(5) Uani 1 1 d . . .
H92 H 0.8789 -0.0591 0.0791 0.041 Uiso 1 1 calc R A .
C93 C 0.88961(13) -0.10636(11) 0.02335(9) 0.0449(6) Uani 1 1 d . A .
H93 H 0.9325 -0.1219 0.0336 0.054 Uiso 1 1 calc R . .
C94 C 0.85981(14) -0.12133(12) -0.01796(10) 0.0510(7) Uani 1 1 d . . .
H94 H 0.8816 -0.1475 -0.0363 0.061 Uiso 1 1 calc R A .
C95 C 0.79763(14) -0.09808(13) -0.03296(9) 0.0527(7) Uani 1 1 d . A .
H95 H 0.7766 -0.1084 -0.0616 0.063 Uiso 1 1 calc R . .
C96 C 0.76602(12) -0.05968(12) -0.00613(8) 0.0422(6) Uani 1 1 d . . .
H96 H 0.7238 -0.0433 -0.0169 0.051 Uiso 1 1 calc R A .
C100 C 0.67646(11) -0.10718(10) 0.18238(7) 0.0323(5) Uani 1 1 d . A .
H10A H 0.7144 -0.1303 0.1964 0.039 Uiso 1 1 calc R . .
H10B H 0.6403 -0.1343 0.1712 0.039 Uiso 1 1 calc R . .
H10C H 0.6606 -0.0801 0.2043 0.039 Uiso 1 1 calc R . .
C101 C 0.73672(10) -0.12983(8) 0.10589(7) 0.0258(4) Uani 1 1 d . A .
C102 C 0.79285(11) -0.15986(9) 0.12595(8) 0.0348(5) Uani 1 1 d . . .
H102 H 0.8176 -0.1431 0.1515 0.042 Uiso 1 1 calc R A .
C103 C 0.81345(12) -0.21350(10) 0.10948(9) 0.0418(6) Uani 1 1 d . A .
H103 H 0.8521 -0.2329 0.1236 0.050 Uiso 1 1 calc R . .
C104 C 0.77819(13) -0.23868(10) 0.07276(9) 0.0440(6) Uani 1 1 d . . .
H104 H 0.7922 -0.2755 0.0616 0.053 Uiso 1 1 calc R A .
C105 C 0.72265(13) -0.21038(11) 0.05232(9) 0.0456(6) Uani 1 1 d . A .
H105 H 0.6980 -0.2277 0.0270 0.055 Uiso 1 1 calc R . .
C106 C 0.70234(12) -0.15616(10) 0.06873(8) 0.0363(5) Uani 1 1 d . . .
H106 H 0.6640 -0.1368 0.0541 0.044 Uiso 1 1 calc R A .
C11S C 1.0565(3) -0.0193(2) 0.08479(18) 0.1064(19) Uani 1 1 d . . .
H11S H 1.0419 0.0208 0.0865 0.128 Uiso 1 1 calc R . .
C12S C 1.03833(17) -0.0610(3) 0.11446(15) 0.0925(15) Uani 1 1 d . . .
H12S H 1.0105 -0.0501 0.1364 0.111 Uiso 1 1 calc R . .
C13S C 1.06089(18) -0.11868(18) 0.11206(13) 0.0777(11) Uani 1 1 d . . .
H13S H 1.0499 -0.1476 0.1329 0.093 Uiso 1 1 calc R . .
C14S C 1.09865(18) -0.13372(15) 0.07983(12) 0.0693(9) Uani 1 1 d . . .
H14S H 1.1130 -0.1738 0.0776 0.083 Uiso 1 1 calc R . .
C15S C 1.11645(15) -0.09311(16) 0.05076(11) 0.0618(8) Uani 1 1 d . . .
H15S H 1.1438 -0.1047 0.0287 0.074 Uiso 1 1 calc R . .
C16S C 1.0958(2) -0.03611(18) 0.05269(14) 0.0861(13) Uani 1 1 d . . .
H16S H 1.1084 -0.0077 0.0320 0.103 Uiso 1 1 calc R . .
C21S C 0.9664(2) 0.1283(2) 0.33345(14) 0.0891(12) Uani 1 1 d . . .
H21S H 1.0043 0.1109 0.3225 0.107 Uiso 1 1 calc R . .
C22S C 0.96845(19) 0.18539(19) 0.34703(12) 0.0761(11) Uani 1 1 d . . .
H22S H 1.0079 0.2082 0.3457 0.091 Uiso 1 1 calc R . .
C23S C 0.9139(2) 0.2107(2) 0.36278(12) 0.0816(11) Uani 1 1 d . . .
H23S H 0.9149 0.2512 0.3719 0.098 Uiso 1 1 calc R . .
C24S C 0.8574(2) 0.1764(3) 0.36519(13) 0.0988(16) Uani 1 1 d . . .
H24S H 0.8193 0.1932 0.3763 0.119 Uiso 1 1 calc R . .
C25S C 0.8565(3) 0.1187(3) 0.35169(15) 0.110(2) Uani 1 1 d . . .
H25S H 0.8181 0.0948 0.3538 0.133 Uiso 1 1 calc R . .
C26S C 0.9103(3) 0.0955(2) 0.33535(16) 0.1061(17) Uani 1 1 d . . .
H26S H 0.9089 0.0556 0.3250 0.127 Uiso 1 1 calc R . .
C31S C 0.5000 0.2745(2) 0.2500 0.0773(15) Uani 1 2 d S . .
H31S H 0.5000 0.2323 0.2500 0.093 Uiso 1 2 calc SR . .
C32S C 0.53212(19) 0.3047(2) 0.28492(14) 0.0835(11) Uani 1 1 d . . .
H32S H 0.5543 0.2838 0.3095 0.100 Uiso 1 1 calc R . .
C33S C 0.5323(2) 0.3653(3) 0.28433(19) 0.1176(19) Uani 1 1 d . . .
H33S H 0.5557 0.3860 0.3086 0.141 Uiso 1 1 calc R . .
C34S C 0.5000 0.3977(4) 0.2500 0.130(3) Uani 1 2 d S . .
H34S H 0.5000 0.4400 0.2500 0.156 Uiso 1 2 calc SR . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ir Ir -1.4442 7.9887 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 IrA P1 101.40(8) . .
C1 IrA Si1 103.27(8) . .
P1 IrA Si1 83.686(18) . .
C1 IrA P3 110.78(8) . .
P1 IrA P3 98.265(18) . .
Si1 IrA P3 144.658(18) . .
C1 IrA Si2 102.85(8) . .
P1 IrA Si2 150.546(18) . .
Si1 IrA Si2 74.696(19) . .
P3 IrA Si2 88.532(18) . .
C1 IrA RhA 149.26(8) . .
P1 IrA RhA 96.270(13) . .
Si1 IrA RhA 53.784(13) . .
P3 IrA RhA 91.082(13) . .
Si2 IrA RhA 54.777(13) . .
C2 RhA P4 105.36(7) . .
C2 RhA Si1 100.53(7) . .
P4 RhA Si1 150.849(19) . .
C2 RhA P2 102.85(6) . .
P4 RhA P2 104.184(17) . .
Si1 RhA P2 82.523(17) . .
C2 RhA Si2 105.30(6) . .
P4 RhA Si2 86.369(18) . .
Si1 RhA Si2 73.962(18) . .
P2 RhA Si2 145.998(18) . .
C2 RhA IrA 148.10(7) . .
P4 RhA IrA 97.478(13) . .
Si1 RhA IrA 53.539(14) . .
P2 RhA IrA 92.560(12) . .
Si2 RhA IrA 53.699(13) . .
C21 P1 C3 102.37(9) . .
C21 P1 C11 95.95(9) . .
C3 P1 C11 105.72(9) . .
C21 P1 IrA 119.56(7) . .
C3 P1 IrA 111.36(6) . .
C11 P1 IrA 119.45(7) . .
C41 P2 C3 104.76(9) . .
C41 P2 C31 98.58(9) . .
C3 P2 C31 100.33(9) . .
C41 P2 RhA 114.45(6) . .
C3 P2 RhA 113.61(6) . .
C31 P2 RhA 122.54(6) . .
C61 P3 C51 100.97(10) . .
C61 P3 C4 98.26(9) . .
C51 P3 C4 99.83(9) . .
C61 P3 IrA 119.25(7) . .
C51 P3 IrA 117.57(7) . .
C4 P3 IrA 117.31(7) . .
C71 P4 C81 96.09(9) . .
C71 P4 C4 105.18(9) . .
C81 P4 C4 100.99(9) . .
C71 P4 RhA 121.75(7) . .
C81 P4 RhA 115.68(7) . .
C4 P4 RhA 113.96(6) . .
C91 Si1 IrA 129.15(7) . .
C91 Si1 RhA 128.83(7) . .
IrA Si1 RhA 72.677(16) . .
C101 Si2 C100 93.74(9) . .
C101 Si2 IrA 124.47(7) . .
C100 Si2 IrA 121.60(7) . .
C101 Si2 RhA 119.57(7) . .
C100 Si2 RhA 129.25(7) . .
IrA Si2 RhA 71.523(15) . .
O1 C1 IrA 176.2(2) . .
O2 C2 RhA 177.8(2) . .
P1 C3 P2 117.98(10) . .
P4 C4 P3 116.71(10) . .
C12 C11 C16 118.26(19) . .
C12 C11 P1 119.76(16) . .
C16 C11 P1 121.89(16) . .
C13 C12 C11 121.3(2) . .
C12 C13 C14 119.6(2) . .
C15 C14 C13 119.9(2) . .
C14 C15 C16 120.4(2) . .
C15 C16 C11 120.4(2) . .
C26 C21 C22 118.6(2) . .
C26 C21 P1 116.22(16) . .
C22 C21 P1 125.03(16) . .
C21 C22 C23 120.2(2) . .
C24 C23 C22 120.7(2) . .
C23 C24 C25 119.6(2) . .
C24 C25 C26 120.4(2) . .
C25 C26 C21 120.5(2) . .
C32 C31 C36 117.27(19) . .
C32 C31 P2 123.11(16) . .
C36 C31 P2 119.59(15) . .
C33 C32 C31 121.2(2) . .
C34 C33 C32 120.6(2) . .
C35 C34 C33 119.0(2) . .
C34 C35 C36 120.8(2) . .
C35 C36 C31 121.0(2) . .
C42 C41 C46 117.92(19) . .
C42 C41 P2 123.57(17) . .
C46 C41 P2 118.51(16) . .
C43 C42 C41 120.5(2) . .
C44 C43 C42 120.9(2) . .
C43 C44 C45 119.4(2) . .
C44 C45 C46 119.8(2) . .
C45 C46 C41 121.4(2) . .
C52 C51 C56 118.4(2) . .
C52 C51 P3 120.17(17) . .
C56 C51 P3 121.47(17) . .
C51 C52 C53 121.0(2) . .
C54 C53 C52 119.8(3) . .
C55 C54 C53 119.8(2) . .
C54 C55 C56 120.5(2) . .
C55 C56 C51 120.4(2) . .
C66 C61 C62 118.6(2) . .
C66 C61 P3 119.10(16) . .
C62 C61 P3 122.30(17) . .
C63 C62 C61 120.3(2) . .
C64 C63 C62 120.5(2) . .
C63 C64 C65 119.9(2) . .
C64 C65 C66 120.1(2) . .
C65 C66 C61 120.6(2) . .
C72 C71 C76 118.24(19) . .
C72 C71 P4 115.33(15) . .
C76 C71 P4 126.12(16) . .
C73 C72 C71 121.0(2) . .
C72 C73 C74 120.1(2) . .
C75 C74 C73 119.9(2) . .
C74 C75 C76 119.9(2) . .
C71 C76 C75 120.9(2) . .
C82 C81 C86 118.45(19) . .
C82 C81 P4 120.95(16) . .
C86 C81 P4 120.60(16) . .
C81 C82 C83 120.8(2) . .
C84 C83 C82 120.2(2) . .
C83 C84 C85 119.7(2) . .
C84 C85 C86 120.3(2) . .
C85 C86 C81 120.5(2) . .
C92 C91 C96 117.2(2) . .
C92 C91 Si1 123.46(17) . .
C96 C91 Si1 118.86(16) . .
C93 C92 C91 121.5(2) . .
C94 C93 C92 120.4(2) . .
C93 C94 C95 119.6(2) . .
C94 C95 C96 120.0(3) . .
C95 C96 C91 121.3(2) . .
C106 C101 C102 116.94(19) . .
C106 C101 Si2 122.73(15) . .
C102 C101 Si2 119.77(16) . .
C103 C102 C101 121.6(2) . .
C104 C103 C102 120.1(2) . .
C105 C104 C103 119.7(2) . .
C104 C105 C106 120.1(2) . .
C101 C106 C105 121.5(2) . .
C16S C11S C12S 119.5(4) . .
C11S C12S C13S 119.5(4) . .
C14S C13S C12S 119.4(4) . .
C15S C14S C13S 121.3(4) . .
C14S C15S C16S 120.6(4) . .
C15S C16S C11S 119.7(4) . .
C22S C21S C26S 120.1(5) . .
C21S C22S C23S 120.3(4) . .
C22S C23S C24S 119.0(4) . .
C25S C24S C23S 119.9(5) . .
C26S C25S C24S 119.8(4) . .
C25S C26S C21S 121.0(5) . .
C32S C31S C32S 120.0(6) . 2_655
C31S C32S C33S 119.4(5) . .
C32S C33S C34S 122.6(5) . .
C33S C34S C33S 115.9(7) 2_655 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
IrA C1 1.854(2) .
IrA P1 2.3491(5) .
IrA Si1 2.3598(6) .
IrA P3 2.3637(5) .
IrA Si2 2.3801(5) .
IrA RhA 2.80107(16) .
RhA C2 1.860(2) .
RhA P4 2.3403(5) .
RhA Si1 2.3673(5) .
RhA P2 2.3835(5) .
RhA Si2 2.4126(5) .
P1 C21 1.842(2) .
P1 C3 1.8455(19) .
P1 C11 1.846(2) .
P2 C41 1.837(2) .
P2 C3 1.847(2) .
P2 C31 1.8514(19) .
P3 C61 1.835(2) .
P3 C51 1.837(2) .
P3 C4 1.868(2) .
P4 C71 1.844(2) .
P4 C81 1.847(2) .
P4 C4 1.850(2) .
Si1 C91 1.883(2) .
Si2 C101 1.902(2) .
Si2 C100 1.911(2) .
O1 C1 1.155(3) .
O2 C2 1.151(3) .
C11 C12 1.390(3) .
C11 C16 1.392(3) .
C12 C13 1.382(3) .
C13 C14 1.385(3) .
C14 C15 1.374(3) .
C15 C16 1.392(3) .
C21 C26 1.391(3) .
C21 C22 1.392(3) .
C22 C23 1.393(3) .
C23 C24 1.369(4) .
C24 C25 1.380(4) .
C25 C26 1.387(3) .
C31 C32 1.389(3) .
C31 C36 1.396(3) .
C32 C33 1.386(3) .
C33 C34 1.380(4) .
C34 C35 1.368(3) .
C35 C36 1.387(3) .
C41 C42 1.390(3) .
C41 C46 1.396(3) .
C42 C43 1.384(3) .
C43 C44 1.380(4) .
C44 C45 1.381(4) .
C45 C46 1.385(3) .
C51 C52 1.385(3) .
C51 C56 1.392(3) .
C52 C53 1.388(3) .
C53 C54 1.378(4) .
C54 C55 1.374(4) .
C55 C56 1.384(3) .
C61 C66 1.389(3) .
C61 C62 1.392(3) .
C62 C63 1.391(3) .
C63 C64 1.367(4) .
C64 C65 1.381(4) .
C65 C66 1.389(3) .
C71 C72 1.392(3) .
C71 C76 1.392(3) .
C72 C73 1.382(3) .
C73 C74 1.389(3) .
C74 C75 1.376(3) .
C75 C76 1.393(3) .
C81 C82 1.388(3) .
C81 C86 1.391(3) .
C82 C83 1.392(3) .
C83 C84 1.369(3) .
C84 C85 1.383(4) .
C85 C86 1.386(3) .
C91 C92 1.390(3) .
C91 C96 1.396(3) .
C92 C93 1.386(3) .
C93 C94 1.368(4) .
C94 C95 1.385(4) .
C95 C96 1.389(3) .
C101 C106 1.386(3) .
C101 C102 1.395(3) .
C102 C103 1.386(3) .
C103 C104 1.373(4) .
C104 C105 1.372(4) .
C105 C106 1.394(3) .
C11S C16S 1.375(7) .
C11S C12S 1.377(7) .
C12S C13S 1.378(6) .
C13S C14S 1.347(5) .
C14S C15S 1.345(5) .
C15S C16S 1.350(5) .
C21S C22S 1.347(6) .
C21S C26S 1.355(6) .
C22S C23S 1.370(6) .
C23S C24S 1.382(6) .
C24S C25S 1.360(7) .
C25S C26S 1.345(7) .
C31S C32S 1.358(5) .
C31S C32S 1.358(5) 2_655
C32S C33S 1.361(7) .
C33S C34S 1.372(7) .
C34S C33S 1.372(7) 2_655
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C1 IrA RhA C2 -6.77(18) . .
P1 IrA RhA C2 118.23(12) . .
Si1 IrA RhA C2 40.80(12) . .
P3 IrA RhA C2 -143.33(12) . .
Si2 IrA RhA C2 -55.89(12) . .
C1 IrA RhA P4 129.00(14) . .
P1 IrA RhA P4 -105.993(17) . .
Si1 IrA RhA P4 176.58(2) . .
P3 IrA RhA P4 -7.556(17) . .
Si2 IrA RhA P4 79.88(2) . .
C1 IrA RhA Si1 -47.57(14) . .
P1 IrA RhA Si1 77.43(2) . .
P3 IrA RhA Si1 175.87(2) . .
Si2 IrA RhA Si1 -96.69(2) . .
C1 IrA RhA P2 -126.33(14) . .
P1 IrA RhA P2 -1.323(17) . .
Si1 IrA RhA P2 -78.76(2) . .
P3 IrA RhA P2 97.114(17) . .
Si2 IrA RhA P2 -175.45(2) . .
C1 IrA RhA Si2 49.12(14) . .
P1 IrA RhA Si2 174.13(2) . .
Si1 IrA RhA Si2 96.69(2) . .
P3 IrA RhA Si2 -87.44(2) . .
C1 IrA P1 C21 -69.25(11) . .
Si1 IrA P1 C21 -171.57(8) . .
P3 IrA P1 C21 44.02(8) . .
Si2 IrA P1 C21 145.82(8) . .
RhA IrA P1 C21 136.03(8) . .
C1 IrA P1 C3 171.65(10) . .
Si1 IrA P1 C3 69.33(7) . .
P3 IrA P1 C3 -75.08(7) . .
Si2 IrA P1 C3 26.72(8) . .
RhA IrA P1 C3 16.93(7) . .
C1 IrA P1 C11 47.95(11) . .
Si1 IrA P1 C11 -54.37(7) . .
P3 IrA P1 C11 161.22(7) . .
Si2 IrA P1 C11 -96.98(8) . .
RhA IrA P1 C11 -106.77(7) . .
C2 RhA P2 C41 -46.20(10) . .
P4 RhA P2 C41 -155.96(7) . .
Si1 RhA P2 C41 52.96(7) . .
Si2 RhA P2 C41 99.10(8) . .
IrA RhA P2 C41 105.67(7) . .
C2 RhA P2 C3 -166.48(10) . .
P4 RhA P2 C3 83.76(7) . .
Si1 RhA P2 C3 -67.32(7) . .
Si2 RhA P2 C3 -21.18(8) . .
IrA RhA P2 C3 -14.61(7) . .
C2 RhA P2 C31 72.78(11) . .
P4 RhA P2 C31 -36.98(8) . .
Si1 RhA P2 C31 171.94(8) . .
Si2 RhA P2 C31 -141.92(8) . .
IrA RhA P2 C31 -135.35(8) . .
C1 IrA P3 C61 100.61(12) . .
P1 IrA P3 C61 -4.98(8) . .
Si1 IrA P3 C61 -95.71(9) . .
Si2 IrA P3 C61 -156.20(8) . .
RhA IrA P3 C61 -101.47(8) . .
C1 IrA P3 C51 -21.97(11) . .
P1 IrA P3 C51 -127.56(8) . .
Si1 IrA P3 C51 141.72(8) . .
Si2 IrA P3 C51 81.23(8) . .
RhA IrA P3 C51 135.95(7) . .
C1 IrA P3 C4 -141.07(11) . .
P1 IrA P3 C4 113.34(7) . .
Si1 IrA P3 C4 22.61(8) . .
Si2 IrA P3 C4 -37.87(7) . .
RhA IrA P3 C4 16.85(7) . .
C2 RhA P4 C71 -76.43(10) . .
Si1 RhA P4 C71 131.71(8) . .
P2 RhA P4 C71 31.48(8) . .
Si2 RhA P4 C71 178.70(8) . .
IrA RhA P4 C71 126.05(8) . .
C2 RhA P4 C81 39.42(10) . .
Si1 RhA P4 C81 -112.45(8) . .
P2 RhA P4 C81 147.32(7) . .
Si2 RhA P4 C81 -65.46(7) . .
IrA RhA P4 C81 -118.11(7) . .
C2 RhA P4 C4 155.85(10) . .
Si1 RhA P4 C4 3.98(8) . .
P2 RhA P4 C4 -96.25(7) . .
Si2 RhA P4 C4 50.97(7) . .
IrA RhA P4 C4 -1.68(7) . .
C1 IrA Si1 C91 30.82(12) . .
P1 IrA Si1 C91 131.08(9) . .
P3 IrA Si1 C91 -133.53(9) . .
Si2 IrA Si1 C91 -69.11(9) . .
RhA IrA Si1 C91 -126.37(9) . .
C1 IrA Si1 RhA 157.19(8) . .
P1 IrA Si1 RhA -102.546(16) . .
P3 IrA Si1 RhA -7.15(4) . .
Si2 IrA Si1 RhA 57.265(16) . .
C2 RhA Si1 C91 -32.72(11) . .
P4 RhA Si1 C91 119.73(9) . .
P2 RhA Si1 C91 -134.48(9) . .
Si2 RhA Si1 C91 70.32(9) . .
IrA RhA Si1 C91 126.72(9) . .
C2 RhA Si1 IrA -159.44(6) . .
P4 RhA Si1 IrA -6.98(4) . .
P2 RhA Si1 IrA 98.800(16) . .
Si2 RhA Si1 IrA -56.392(16) . .
C1 IrA Si2 C101 -42.95(11) . .
P1 IrA Si2 C101 101.75(9) . .
Si1 IrA Si2 C101 57.51(8) . .
P3 IrA Si2 C101 -153.95(8) . .
RhA IrA Si2 C101 113.69(8) . .
C1 IrA Si2 C100 78.07(11) . .
P1 IrA Si2 C100 -137.22(8) . .
Si1 IrA Si2 C100 178.54(8) . .
P3 IrA Si2 C100 -32.92(8) . .
RhA IrA Si2 C100 -125.28(8) . .
C1 IrA Si2 RhA -156.65(8) . .
P1 IrA Si2 RhA -11.94(4) . .
Si1 IrA Si2 RhA -56.177(16) . .
P3 IrA Si2 RhA 92.362(16) . .
C2 RhA Si2 C101 33.26(10) . .
P4 RhA Si2 C101 138.20(7) . .
Si1 RhA Si2 C101 -63.56(7) . .
P2 RhA Si2 C101 -111.62(8) . .
IrA RhA Si2 C101 -119.77(8) . .
C2 RhA Si2 C100 -90.84(12) . .
P4 RhA Si2 C100 14.10(10) . .
Si1 RhA Si2 C100 172.35(10) . .
P2 RhA Si2 C100 124.28(10) . .
IrA RhA Si2 C100 116.13(10) . .
C2 RhA Si2 IrA 153.03(7) . .
P4 RhA Si2 IrA -102.030(16) . .
Si1 RhA Si2 IrA 56.215(16) . .
P2 RhA Si2 IrA 8.15(4) . .
P1 IrA C1 O1 -52(4) . .
Si1 IrA C1 O1 34(4) . .
P3 IrA C1 O1 -156(4) . .
Si2 IrA C1 O1 111(4) . .
RhA IrA C1 O1 72(4) . .
P4 RhA C2 O2 -167(5) . .
Si1 RhA C2 O2 -1(5) . .
P2 RhA C2 O2 84(5) . .
Si2 RhA C2 O2 -77(5) . .
IrA RhA C2 O2 -33(5) . .
C21 P1 C3 P2 -160.93(11) . .
C11 P1 C3 P2 99.17(12) . .
IrA P1 C3 P2 -32.02(13) . .
C41 P2 C3 P1 -94.22(12) . .
C31 P2 C3 P1 163.96(11) . .
RhA P2 C3 P1 31.40(13) . .
C71 P4 C4 P3 -121.88(11) . .
C81 P4 C4 P3 138.65(11) . .
RhA P4 C4 P3 13.95(13) . .
C61 P3 C4 P4 107.05(12) . .
C51 P3 C4 P4 -150.23(12) . .
IrA P3 C4 P4 -22.05(13) . .
C21 P1 C11 C12 -55.97(18) . .
C3 P1 C11 C12 48.70(19) . .
IrA P1 C11 C12 175.10(14) . .
C21 P1 C11 C16 120.40(18) . .
C3 P1 C11 C16 -134.94(17) . .
IrA P1 C11 C16 -8.5(2) . .
C16 C11 C12 C13 2.9(3) . .
P1 C11 C12 C13 179.43(17) . .
C11 C12 C13 C14 -2.1(3) . .
C12 C13 C14 C15 0.0(4) . .
C13 C14 C15 C16 1.1(4) . .
C14 C15 C16 C11 -0.2(4) . .
C12 C11 C16 C15 -1.8(3) . .
P1 C11 C16 C15 -178.23(18) . .
C3 P1 C21 C26 171.50(16) . .
C11 P1 C21 C26 -80.94(17) . .
IrA P1 C21 C26 47.92(18) . .
C3 P1 C21 C22 -13.8(2) . .
C11 P1 C21 C22 93.79(19) . .
IrA P1 C21 C22 -137.35(16) . .
C26 C21 C22 C23 -0.4(3) . .
P1 C21 C22 C23 -175.02(16) . .
C21 C22 C23 C24 1.0(3) . .
C22 C23 C24 C25 -0.5(4) . .
C23 C24 C25 C26 -0.5(4) . .
C24 C25 C26 C21 1.1(4) . .
C22 C21 C26 C25 -0.6(3) . .
P1 C21 C26 C25 174.49(18) . .
C41 P2 C31 C32 -142.28(18) . .
C3 P2 C31 C32 -35.45(19) . .
RhA P2 C31 C32 91.37(18) . .
C41 P2 C31 C36 40.04(18) . .
C3 P2 C31 C36 146.86(17) . .
RhA P2 C31 C36 -86.32(17) . .
C36 C31 C32 C33 -1.3(3) . .
P2 C31 C32 C33 -179.08(18) . .
C31 C32 C33 C34 -0.3(4) . .
C32 C33 C34 C35 1.7(4) . .
C33 C34 C35 C36 -1.4(4) . .
C34 C35 C36 C31 -0.3(3) . .
C32 C31 C36 C35 1.7(3) . .
P2 C31 C36 C35 179.48(17) . .
C3 P2 C41 C42 -8.86(19) . .
C31 P2 C41 C42 94.28(18) . .
RhA P2 C41 C42 -133.95(15) . .
C3 P2 C41 C46 170.64(16) . .
C31 P2 C41 C46 -86.22(17) . .
RhA P2 C41 C46 45.56(17) . .
C46 C41 C42 C43 -0.4(3) . .
P2 C41 C42 C43 179.12(16) . .
C41 C42 C43 C44 2.2(3) . .
C42 C43 C44 C45 -1.9(3) . .
C43 C44 C45 C46 -0.1(4) . .
C44 C45 C46 C41 1.9(3) . .
C42 C41 C46 C45 -1.7(3) . .
P2 C41 C46 C45 178.80(17) . .
C61 P3 C51 C52 -131.58(19) . .
C4 P3 C51 C52 127.93(19) . .
IrA P3 C51 C52 -0.1(2) . .
C61 P3 C51 C56 48.2(2) . .
C4 P3 C51 C56 -52.28(19) . .
IrA P3 C51 C56 179.72(15) . .
C56 C51 C52 C53 -1.1(4) . .
P3 C51 C52 C53 178.7(2) . .
C51 C52 C53 C54 -0.4(4) . .
C52 C53 C54 C55 1.4(4) . .
C53 C54 C55 C56 -1.0(4) . .
C54 C55 C56 C51 -0.5(4) . .
C52 C51 C56 C55 1.5(3) . .
P3 C51 C56 C55 -178.30(18) . .
C51 P3 C61 C66 -147.15(17) . .
C4 P3 C61 C66 -45.39(18) . .
IrA P3 C61 C66 82.39(17) . .
C51 P3 C61 C62 33.67(19) . .
C4 P3 C61 C62 135.43(17) . .
IrA P3 C61 C62 -96.79(17) . .
C66 C61 C62 C63 1.2(3) . .
P3 C61 C62 C63 -179.60(17) . .
C61 C62 C63 C64 -1.1(3) . .
C62 C63 C64 C65 -0.5(4) . .
C63 C64 C65 C66 1.9(4) . .
C64 C65 C66 C61 -1.7(4) . .
C62 C61 C66 C65 0.1(3) . .
P3 C61 C66 C65 -179.07(17) . .
C81 P4 C71 C72 -76.76(16) . .
C4 P4 C71 C72 -179.92(15) . .
RhA P4 C71 C72 48.58(17) . .
C81 P4 C71 C76 96.66(19) . .
C4 P4 C71 C76 -6.5(2) . .
RhA P4 C71 C76 -138.00(16) . .
C76 C71 C72 C73 -2.3(3) . .
P4 C71 C72 C73 171.68(17) . .
C71 C72 C73 C74 1.3(3) . .
C72 C73 C74 C75 0.9(3) . .
C73 C74 C75 C76 -1.9(3) . .
C72 C71 C76 C75 1.3(3) . .
P4 C71 C76 C75 -171.99(17) . .
C74 C75 C76 C71 0.8(3) . .
C71 P4 C81 C82 122.73(18) . .
C4 P4 C81 C82 -130.47(18) . .
RhA P4 C81 C82 -6.9(2) . .
C71 P4 C81 C86 -56.5(2) . .
C4 P4 C81 C86 50.3(2) . .
RhA P4 C81 C86 173.80(16) . .
C86 C81 C82 C83 -0.8(3) . .
P4 C81 C82 C83 179.89(17) . .
C81 C82 C83 C84 -0.3(4) . .
C82 C83 C84 C85 0.4(4) . .
C83 C84 C85 C86 0.6(4) . .
C84 C85 C86 C81 -1.8(4) . .
C82 C81 C86 C85 1.9(4) . .
P4 C81 C86 C85 -178.8(2) . .
IrA Si1 C91 C92 -30.2(2) . .
RhA Si1 C91 C92 -129.55(17) . .
IrA Si1 C91 C96 157.65(15) . .
RhA Si1 C91 C96 58.3(2) . .
C96 C91 C92 C93 -0.5(3) . .
Si1 C91 C92 C93 -172.73(19) . .
C91 C92 C93 C94 -0.6(4) . .
C92 C93 C94 C95 0.7(4) . .
C93 C94 C95 C96 0.2(5) . .
C94 C95 C96 C91 -1.3(4) . .
C92 C91 C96 C95 1.4(4) . .
Si1 C91 C96 C95 174.0(2) . .
C100 Si2 C101 C106 103.72(19) . .
IrA Si2 C101 C106 -123.28(17) . .
RhA Si2 C101 C106 -36.3(2) . .
C100 Si2 C101 C102 -67.42(19) . .
IrA Si2 C101 C102 65.57(19) . .
RhA Si2 C101 C102 152.57(15) . .
C106 C101 C102 C103 0.1(3) . .
Si2 C101 C102 C103 171.78(18) . .
C101 C102 C103 C104 -0.5(4) . .
C102 C103 C104 C105 0.3(4) . .
C103 C104 C105 C106 0.2(4) . .
C102 C101 C106 C105 0.4(3) . .
Si2 C101 C106 C105 -171.0(2) . .
C104 C105 C106 C101 -0.6(4) . .
C16S C11S C12S C13S 1.2(6) . .
C11S C12S C13S C14S -2.0(6) . .
C12S C13S C14S C15S 2.1(6) . .
C13S C14S C15S C16S -1.2(5) . .
C14S C15S C16S C11S 0.3(5) . .
C12S C11S C16S C15S -0.3(6) . .
C26S C21S C22S C23S -0.1(6) . .
C21S C22S C23S C24S 1.1(6) . .
C22S C23S C24S C25S -0.5(6) . .
C23S C24S C25S C26S -1.1(6) . .
C24S C25S C26S C21S 2.2(7) . .
C22S C21S C26S C25S -1.6(6) . .
C32S C31S C32S C33S -0.6(3) 2_655 .
C31S C32S C33S C34S 1.3(7) . .
C32S C33S C34S C33S -0.7(3) . 2_655
