#------------------------------------------------------------------------------
#$Date: 2016-03-23 20:24:42 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179410 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/07/4330795.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4330795
loop_
_publ_author_name
'Weixu Feng'
'Yao Zhang'
'Zhao Zhang'
'Xingqiang Lü'
'Han Liu'
'Guoxiang Shi'
'Dan Zou'
'Jirong Song'
'Daidi Fan'
'Wai-Kwok Wong'
'Richard A. Jones'
_publ_contact_author_address
;
Shaanxi Key Engineering Center of Bio-materials
Shaanxi Key Laboratory of Physico-inorganic Chemistry
Northwest University
Xi'an 
710069
China
;
_publ_contact_author_email       lvxq@nwu.edu.cn
_publ_contact_author_name        'Xingqiang Lu'
_publ_section_title
;
 Anion-Induced Self-Assembly of Luminescent and Magnetic Homoleptic Cyclic
 Tetranuclear Ln4(Salen)4 and Ln4(Salen)2 Complexes (Ln = Nd, Yb, Er, or
 Gd)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              11377
_journal_page_last               11386
_journal_paper_doi               10.1021/ic300918c
_journal_volume                  51
_journal_year                    2012
_chemical_formula_sum            'C56 H68 N4 O22 Yb4'
_chemical_formula_weight         1841.30
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                104.541(4)
_cell_angle_beta                 91.386(4)
_cell_angle_gamma                95.173(3)
_cell_formula_units_Z            1
_cell_length_a                   11.833(2)
_cell_length_b                   12.133(2)
_cell_length_c                   12.696(3)
_cell_measurement_reflns_used    1645
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      22.07
_cell_measurement_theta_min      2.45
_cell_volume                     1755.1(6)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.967
_diffrn_measured_fraction_theta_max 0.967
_diffrn_measurement_device_type  'Bruker Smart CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0491
_diffrn_reflns_av_sigmaI/netI    0.1104
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -6
_diffrn_reflns_number            9401
_diffrn_reflns_theta_full        26.09
_diffrn_reflns_theta_max         26.09
_diffrn_reflns_theta_min         1.66
_exptl_absorpt_coefficient_mu    5.349
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.742
_exptl_crystal_description       block
_exptl_crystal_F_000             888
_exptl_crystal_size_max          0.27
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.20
_refine_diff_density_max         3.992
_refine_diff_density_min         -2.250
_refine_diff_density_rms         0.533
_refine_ls_extinction_coef       0.0124(11)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     389
_refine_ls_number_reflns         6734
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.031
_refine_ls_R_factor_all          0.1224
_refine_ls_R_factor_gt           0.0766
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1504P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2116
_refine_ls_wR_factor_ref         0.2523
_reflns_number_gt                4207
_reflns_number_total             6734
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic300918c_si_002_3.cif
_cod_data_source_block           6
_cod_original_cell_volume        1755.2(6)
_cod_database_code               4330795
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Yb1 Yb 0.85796(6) 0.10680(6) 0.19709(6) 0.0367(3) Uani 1 1 d .
Yb2 Yb 0.94987(6) -0.14308(6) 0.01822(6) 0.0376(3) Uani 1 1 d .
C1 C 0.9327(18) 0.1840(19) -0.2634(16) 0.063(6) Uani 1 1 d .
H1A H 0.8674 0.2078 -0.2947 0.095 Uiso 1 1 calc R
H1B H 0.9426 0.1065 -0.3009 0.095 Uiso 1 1 calc R
H1C H 0.9990 0.2331 -0.2701 0.095 Uiso 1 1 calc R
C2 C 0.8236(14) 0.2442(16) -0.1054(14) 0.045(4) Uani 1 1 d .
C3 C 0.7567(18) 0.3015(19) -0.1583(16) 0.064(6) Uani 1 1 d .
H3A H 0.7754 0.3091 -0.2270 0.076 Uiso 1 1 calc R
C4 C 0.6670(17) 0.3460(19) -0.1142(17) 0.063(6) Uani 1 1 d .
H4A H 0.6202 0.3801 -0.1539 0.076 Uiso 1 1 calc R
C5 C 0.6411(17) 0.3429(16) -0.0094(15) 0.053(5) Uani 1 1 d .
H5A H 0.5782 0.3766 0.0218 0.063 Uiso 1 1 calc R
C6 C 0.7099(15) 0.2886(16) 0.0502(15) 0.046(4) Uani 1 1 d .
C7 C 0.8026(14) 0.2316(15) 0.0008(14) 0.041(4) Uani 1 1 d .
C8 C 0.6764(16) 0.2871(16) 0.1597(15) 0.051(5) Uani 1 1 d .
H8A H 0.6122 0.3240 0.1818 0.061 Uiso 1 1 calc R
C9 C 0.667(2) 0.2610(17) 0.3349(16) 0.063(6) Uani 1 1 d .
H9A H 0.5866 0.2307 0.3200 0.075 Uiso 1 1 calc R
C10 C 0.668(2) 0.3852(18) 0.3956(15) 0.064(6) Uani 1 1 d .
H10A H 0.6291 0.4263 0.3518 0.076 Uiso 1 1 calc R
H10B H 0.7461 0.4197 0.4101 0.076 Uiso 1 1 calc R
C11 C 0.610(3) 0.393(2) 0.5028(18) 0.095(10) Uani 1 1 d .
H11A H 0.6202 0.4721 0.5461 0.114 Uiso 1 1 calc R
H11B H 0.5288 0.3728 0.4871 0.114 Uiso 1 1 calc R
C12 C 0.652(2) 0.320(2) 0.5664(19) 0.079(7) Uani 1 1 d .
H12A H 0.6047 0.3235 0.6283 0.094 Uiso 1 1 calc R
H12B H 0.7281 0.3517 0.5949 0.094 Uiso 1 1 calc R
C13 C 0.6564(19) 0.1946(19) 0.5073(15) 0.061(6) Uani 1 1 d .
H13A H 0.6962 0.1558 0.5528 0.074 Uiso 1 1 calc R
H13B H 0.5801 0.1566 0.4898 0.074 Uiso 1 1 calc R
C14 C 0.7190(17) 0.1916(18) 0.4032(17) 0.056(5) Uani 1 1 d .
C15 C 0.6912(14) -0.012(2) 0.3582(19) 0.061(6) Uani 1 1 d .
H15A H 0.6522 -0.0036 0.4221 0.073 Uiso 1 1 calc R
C16 C 0.7004(13) -0.1313(15) 0.2948(14) 0.038(4) Uani 1 1 d .
C17 C 0.6297(17) -0.2137(16) 0.3230(17) 0.057(5) Uani 1 1 d .
H17A H 0.5787 -0.1922 0.3772 0.068 Uiso 1 1 calc R
C18 C 0.6328(19) -0.3303(18) 0.272(2) 0.068(6) Uani 1 1 d .
H18A H 0.5842 -0.3851 0.2921 0.082 Uiso 1 1 calc R
C19 C 0.7081(17) -0.3636(17) 0.191(2) 0.067(6) Uani 1 1 d .
H19A H 0.7105 -0.4400 0.1546 0.080 Uiso 1 1 calc R
C20 C 0.7827(13) -0.2740(19) 0.1655(16) 0.049(5) Uani 1 1 d .
C21 C 0.7776(13) -0.1645(14) 0.2154(13) 0.033(4) Uani 1 1 d .
C22 C 0.880(2) -0.4219(19) 0.046(2) 0.091(9) Uani 1 1 d .
H22A H 0.8342 -0.4669 0.0848 0.137 Uiso 1 1 calc R
H22B H 0.9584 -0.4305 0.0577 0.137 Uiso 1 1 calc R
H22C H 0.8589 -0.4475 -0.0303 0.137 Uiso 1 1 calc R
C23 C 0.6935(14) -0.072(2) 0.0118(18) 0.056(5) Uani 1 1 d .
C24 C 0.575(2) -0.140(2) -0.019(3) 0.113(11) Uani 1 1 d .
H24A H 0.5812 -0.2066 -0.0766 0.170 Uiso 1 1 calc R
H24B H 0.5242 -0.0920 -0.0422 0.170 Uiso 1 1 calc R
H24C H 0.5459 -0.1616 0.0437 0.170 Uiso 1 1 calc R
C25 C 1.0403(18) 0.3350(18) 0.212(2) 0.064(6) Uani 1 1 d .
C26 C 1.081(3) 0.450(2) 0.274(2) 0.099(9) Uani 1 1 d .
H26A H 1.1369 0.4832 0.2344 0.148 Uiso 1 1 calc R
H26B H 1.1147 0.4474 0.3430 0.148 Uiso 1 1 calc R
H26C H 1.0186 0.4966 0.2867 0.148 Uiso 1 1 calc R
C27 C 1.066(2) 0.113(2) 0.3674(16) 0.065(6) Uani 1 1 d .
C28 C 1.106(2) 0.131(4) 0.481(3) 0.169(19) Uani 1 1 d .
H28A H 1.0435 0.1448 0.5273 0.254 Uiso 1 1 calc R
H28B H 1.1620 0.1965 0.4998 0.254 Uiso 1 1 calc R
H28C H 1.1396 0.0648 0.4896 0.254 Uiso 1 1 calc R
N1 N 0.7198(11) 0.2445(12) 0.2276(11) 0.037(3) Uani 1 1 d .
N2 N 0.7305(12) 0.0782(13) 0.3348(12) 0.042(4) Uani 1 1 d .
O1 O 0.9164(10) 0.1908(11) -0.1492(10) 0.049(3) Uani 1 1 d .
O2 O 0.8695(10) 0.1768(9) 0.0436(9) 0.040(3) Uani 1 1 d .
O3 O 0.8531(10) -0.0887(11) 0.1821(10) 0.046(3) Uani 1 1 d .
O4 O 0.8604(11) -0.3030(10) 0.0854(11) 0.055(3) Uani 1 1 d .
O5 O 1.0115(9) 0.0411(9) 0.1074(9) 0.035(2) Uani 1 1 d .
O6 O 0.6994(10) 0.0207(12) 0.0874(12) 0.057(3) Uani 1 1 d .
O7 O 0.7738(10) -0.1225(12) -0.0335(11) 0.057(3) Uani 1 1 d .
O8 O 0.9650(12) 0.2809(11) 0.2572(10) 0.055(3) Uani 1 1 d .
O9 O 1.0795(11) 0.2986(11) 0.1254(11) 0.052(3) Uani 1 1 d .
O10 O 0.9681(11) 0.1055(12) 0.3482(10) 0.058(4) Uani 1 1 d .
O11 O 1.1397(13) 0.0943(17) 0.2977(13) 0.091(6) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Yb Yb -0.3850 5.5486 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 Yb1 O10 83.1(4) . .
O5 Yb1 O6 106.9(4) . .
O10 Yb1 O6 145.0(5) . .
O5 Yb1 O8 87.2(4) . .
O10 Yb1 O8 70.8(5) . .
O6 Yb1 O8 141.3(5) . .
O5 Yb1 O2 72.2(4) . .
O10 Yb1 O2 139.4(4) . .
O6 Yb1 O2 74.5(4) . .
O8 Yb1 O2 76.1(4) . .
O5 Yb1 O3 71.5(4) . .
O10 Yb1 O3 78.9(5) . .
O6 Yb1 O3 73.2(4) . .
O8 Yb1 O3 144.9(5) . .
O2 Yb1 O3 120.6(4) . .
O5 Yb1 N2 143.3(4) . .
O10 Yb1 N2 72.9(5) . .
O6 Yb1 N2 80.5(5) . .
O8 Yb1 N2 109.7(5) . .
O2 Yb1 N2 142.3(4) . .
O3 Yb1 N2 76.9(5) . .
O5 Yb1 N1 148.1(4) . .
O10 Yb1 N1 115.1(5) . .
O6 Yb1 N1 73.8(5) . .
O8 Yb1 N1 75.8(5) . .
O2 Yb1 N1 77.6(4) . .
O3 Yb1 N1 135.2(4) . .
N2 Yb1 N1 68.5(5) . .
O5 Yb1 C14 154.9(5) . .
O10 Yb1 C14 71.8(5) . .
O6 Yb1 C14 94.0(5) . .
O8 Yb1 C14 84.8(5) . .
O2 Yb1 C14 128.2(5) . .
O3 Yb1 C14 102.6(5) . .
N2 Yb1 C14 26.6(5) . .
N1 Yb1 C14 51.0(5) . .
O5 Yb1 Yb2 38.3(3) . .
O10 Yb1 Yb2 97.4(4) . .
O6 Yb1 Yb2 74.9(3) . .
O8 Yb1 Yb2 125.5(3) . .
O2 Yb1 Yb2 83.0(3) . .
O3 Yb1 Yb2 41.0(3) . .
N2 Yb1 Yb2 117.2(4) . .
N1 Yb1 Yb2 146.5(3) . .
C14 Yb1 Yb2 143.5(4) . .
O5 Yb1 Yb2 36.1(3) . 2_755
O10 Yb1 Yb2 107.8(3) . 2_755
O6 Yb1 Yb2 98.4(4) . 2_755
O8 Yb1 Yb2 71.8(3) . 2_755
O2 Yb1 Yb2 37.7(3) . 2_755
O3 Yb1 Yb2 101.9(3) . 2_755
N2 Yb1 Yb2 178.5(4) . 2_755
N1 Yb1 Yb2 112.1(3) . 2_755
C14 Yb1 Yb2 154.8(4) . 2_755
Yb2 Yb1 Yb2 61.46(2) . 2_755
O7 Yb2 O9 80.8(5) . 2_755
O7 Yb2 O5 80.3(4) . 2_755
O9 Yb2 O5 86.1(4) 2_755 2_755
O7 Yb2 O5 100.6(5) . .
O9 Yb2 O5 156.6(4) 2_755 .
O5 Yb2 O5 71.2(4) 2_755 .
O7 Yb2 O2 144.0(4) . 2_755
O9 Yb2 O2 75.3(4) 2_755 2_755
O5 Yb2 O2 71.7(4) 2_755 2_755
O5 Yb2 O2 91.5(4) . 2_755
O7 Yb2 O3 74.6(4) . .
O9 Yb2 O3 131.4(4) 2_755 .
O5 Yb2 O3 128.5(4) 2_755 .
O5 Yb2 O3 70.3(4) . .
O2 Yb2 O3 141.1(4) 2_755 .
O7 Yb2 O1 150.1(4) . 2_755
O9 Yb2 O1 106.9(5) 2_755 2_755
O5 Yb2 O1 128.3(4) 2_755 2_755
O5 Yb2 O1 83.7(4) . 2_755
O2 Yb2 O1 64.5(4) 2_755 2_755
O3 Yb2 O1 79.2(4) . 2_755
O7 Yb2 O4 85.1(5) . .
O9 Yb2 O4 72.2(5) 2_755 .
O5 Yb2 O4 155.6(4) 2_755 .
O5 Yb2 O4 131.2(4) . .
O2 Yb2 O4 112.0(4) 2_755 .
O3 Yb2 O4 64.6(4) . .
O1 Yb2 O4 70.6(4) 2_755 .
O7 Yb2 C7 158.1(5) . 2_755
O9 Yb2 C7 78.6(4) 2_755 2_755
O5 Yb2 C7 91.0(4) 2_755 2_755
O5 Yb2 C7 95.5(4) . 2_755
O2 Yb2 C7 19.5(4) 2_755 2_755
O3 Yb2 C7 125.4(4) . 2_755
O1 Yb2 C7 46.4(4) 2_755 2_755
O4 Yb2 C7 95.6(4) . 2_755
O7 Yb2 Yb1 71.1(4) . .
O9 Yb2 Yb1 151.8(3) 2_755 .
O5 Yb2 Yb1 89.5(3) 2_755 .
O5 Yb2 Yb1 38.0(3) . .
O2 Yb2 Yb1 129.3(3) 2_755 .
O3 Yb2 Yb1 40.0(3) . .
O1 Yb2 Yb1 97.6(3) 2_755 .
O4 Yb2 Yb1 104.1(3) . .
C7 Yb2 Yb1 129.4(3) 2_755 .
O7 Yb2 Yb1 109.0(3) . 2_755
O9 Yb2 Yb1 70.8(3) 2_755 2_755
O5 Yb2 Yb1 35.8(3) 2_755 2_755
O5 Yb2 Yb1 86.9(3) . 2_755
O2 Yb2 Yb1 37.4(3) 2_755 2_755
O3 Yb2 Yb1 157.1(3) . 2_755
O1 Yb2 Yb1 100.8(3) 2_755 2_755
O4 Yb2 Yb1 137.3(3) . 2_755
C7 Yb2 Yb1 56.9(3) 2_755 2_755
Yb1 Yb2 Yb1 118.54(2) . 2_755
O7 Yb2 Yb2 90.5(4) . 2_755
O9 Yb2 Yb2 121.5(3) 2_755 2_755
O5 Yb2 Yb2 35.6(3) 2_755 2_755
O5 Yb2 Yb2 35.6(3) . 2_755
O2 Yb2 Yb2 79.8(3) 2_755 2_755
O3 Yb2 Yb2 100.1(3) . 2_755
O1 Yb2 Yb2 108.3(3) 2_755 2_755
O4 Yb2 Yb2 164.7(3) . 2_755
C7 Yb2 Yb2 94.0(3) 2_755 2_755
Yb1 Yb2 Yb2 60.68(3) . 2_755
Yb1 Yb2 Yb2 57.86(2) 2_755 2_755
C3 C2 O1 124.3(16) . .
C3 C2 C7 122.7(17) . .
O1 C2 C7 112.9(15) . .
C4 C3 C2 121.4(19) . .
C3 C4 C5 120.8(18) . .
C4 C5 C6 119.9(18) . .
C5 C6 C7 120.3(17) . .
C5 C6 C8 116.9(17) . .
C7 C6 C8 122.7(17) . .
O2 C7 C2 118.3(16) . .
O2 C7 C6 127.0(17) . .
C2 C7 C6 114.6(16) . .
O2 C7 Yb2 37.7(8) . 2_755
C2 C7 Yb2 82.2(10) . 2_755
C6 C7 Yb2 158.2(12) . 2_755
N1 C8 C6 130.2(17) . .
C10 C9 N1 113.1(16) . .
C10 C9 C14 111.9(18) . .
N1 C9 C14 110.8(15) . .
C9 C10 C11 109.1(18) . .
C12 C11 C10 113.5(19) . .
C11 C12 C13 117(2) . .
C14 C13 C12 107.2(18) . .
N2 C14 C9 108.8(17) . .
N2 C14 C13 115.3(16) . .
C9 C14 C13 112.0(17) . .
N2 C14 Yb1 47.9(8) . .
C9 C14 Yb1 83.7(11) . .
C13 C14 Yb1 161.6(14) . .
N2 C15 C16 126.9(19) . .
C17 C16 C21 118.8(17) . .
C17 C16 C15 115.6(15) . .
C21 C16 C15 125.5(15) . .
C16 C17 C18 121.3(18) . .
C19 C18 C17 120.0(17) . .
C18 C19 C20 116.8(18) . .
C21 C20 O4 119.2(16) . .
C21 C20 C19 121.7(16) . .
O4 C20 C19 119.1(18) . .
C20 C21 O3 115.2(15) . .
C20 C21 C16 121.3(16) . .
O3 C21 C16 123.5(15) . .
O7 C23 O6 127.7(17) . .
O7 C23 C24 115(2) . .
O6 C23 C24 117.2(19) . .
O9 C25 O8 126(2) . .
O9 C25 C26 118(2) . .
O8 C25 C26 116(2) . .
O10 C27 O11 125(2) . .
O10 C27 C28 118(2) . .
O11 C27 C28 116(2) . .
C8 N1 C9 117.1(15) . .
C8 N1 Yb1 127.3(12) . .
C9 N1 Yb1 114.5(10) . .
C15 N2 C14 123.1(17) . .
C15 N2 Yb1 130.7(14) . .
C14 N2 Yb1 105.5(10) . .
C2 O1 C1 116.2(13) . .
C2 O1 Yb2 116.1(10) . 2_755
C1 O1 Yb2 127.1(11) . 2_755
C7 O2 Yb1 132.0(11) . .
C7 O2 Yb2 122.9(11) . 2_755
Yb1 O2 Yb2 104.9(4) . 2_755
C21 O3 Yb1 132.5(10) . .
C21 O3 Yb2 121.8(10) . .
Yb1 O3 Yb2 99.1(4) . .
C20 O4 C22 118.4(15) . .
C20 O4 Yb2 115.8(10) . .
C22 O4 Yb2 125.7(12) . .
Yb1 O5 Yb2 108.1(4) . 2_755
Yb1 O5 Yb2 103.7(4) . .
Yb2 O5 Yb2 108.8(4) 2_755 .
C23 O6 Yb1 126.5(11) . .
C23 O7 Yb2 135.1(13) . .
C25 O8 Yb1 132.6(14) . .
C25 O9 Yb2 138.3(13) . 2_755
C27 O10 Yb1 133.9(14) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Yb1 O5 2.267(10) .
Yb1 O10 2.298(12) .
Yb1 O6 2.311(13) .
Yb1 O8 2.304(12) .
Yb1 O2 2.316(11) .
Yb1 O3 2.326(12) .
Yb1 N2 2.406(14) .
Yb1 N1 2.411(13) .
Yb1 C14 3.13(2) .
Yb1 Yb2 3.5762(12) .
Yb1 Yb2 3.6827(11) 2_755
Yb2 O7 2.224(12) .
Yb2 O9 2.265(13) 2_755
Yb2 O5 2.282(10) 2_755
Yb2 O5 2.281(11) .
Yb2 O2 2.330(12) 2_755
Yb2 O3 2.374(12) .
Yb2 O1 2.475(11) 2_755
Yb2 O4 2.473(12) .
Yb2 C7 3.204(17) 2_755
Yb2 Yb1 3.6826(11) 2_755
Yb2 Yb2 3.7104(15) 2_755
C1 O1 1.45(2) .
C2 C3 1.37(2) .
C2 O1 1.38(2) .
C2 C7 1.42(2) .
C3 C4 1.31(3) .
C4 C5 1.38(2) .
C5 C6 1.41(2) .
C6 C7 1.42(2) .
C6 C8 1.46(2) .
C7 O2 1.272(19) .
C7 Yb2 3.204(17) 2_755
C8 N1 1.24(2) .
C9 C10 1.51(3) .
C9 N1 1.49(2) .
C9 C14 1.51(3) .
C10 C11 1.53(3) .
C11 C12 1.45(3) .
C12 C13 1.53(3) .
C13 C14 1.53(3) .
C14 N2 1.45(3) .
C15 N2 1.26(2) .
C15 C16 1.48(3) .
C16 C17 1.37(2) .
C16 C21 1.39(2) .
C17 C18 1.41(3) .
C18 C19 1.38(3) .
C19 C20 1.44(3) .
C20 C21 1.33(3) .
C20 O4 1.388(19) .
C21 O3 1.37(2) .
C22 O4 1.44(2) .
C23 O7 1.25(2) .
C23 O6 1.28(2) .
C23 C24 1.55(3) .
C25 O9 1.20(2) .
C25 O8 1.29(2) .
C25 C26 1.46(3) .
C27 O10 1.17(2) .
C27 O11 1.25(2) .
C27 C28 1.46(3) .
O1 Yb2 2.475(11) 2_755
O2 Yb2 2.330(12) 2_755
O5 Yb2 2.282(10) 2_755
O9 Yb2 2.265(13) 2_755
