#------------------------------------------------------------------------------
#$Date: 2016-03-23 20:52:13 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179428 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/25/4332549.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_4332549
loop_
_publ_author_name
'Salvador, James R.'
'Kanatzidis, Mercouri G.'
_publ_section_title
;
 Indium Flux Synthesis of RE4Ni2InGe4(RE = Dy, Ho, Er, and Tm):  An
 Ordered Quaternary Variation on the Binary Phase Mg5Si6
;
_journal_issue                   18
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              7091
_journal_page_last               7099
_journal_paper_doi               10.1021/ic0605017
_journal_volume                  45
_journal_year                    2006
_chemical_formula_sum            'Ge4 Ho4 In Ni2'
_chemical_formula_weight         1182.32
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           12
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 108.600(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   15.373(4)
_cell_length_b                   4.2101(9)
_cell_length_c                   6.9935(15)
_cell_measurement_temperature    293(2)
_cell_volume                     428.99(17)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.912
_diffrn_measured_fraction_theta_max 0.912
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0256
_diffrn_reflns_av_sigmaI/netI    0.0300
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       5
_diffrn_reflns_limit_k_min       -5
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_limit_l_min       -9
_diffrn_reflns_number            1779
_diffrn_reflns_theta_full        28.13
_diffrn_reflns_theta_max         28.13
_diffrn_reflns_theta_min         2.80
_exptl_absorpt_coefficient_mu    57.013
_exptl_absorpt_correction_type   empirical
_exptl_crystal_colour            Silver
_exptl_crystal_density_diffrn    9.153
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Rod
_exptl_crystal_F_000             1002
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.015
_exptl_crystal_size_min          0.01
_refine_diff_density_max         2.778
_refine_diff_density_min         -2.507
_refine_diff_density_rms         0.525
_refine_ls_extinction_coef       0.00124(14)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.242
_refine_ls_hydrogen_treatment    none
_refine_ls_matrix_type           full
_refine_ls_number_parameters     36
_refine_ls_number_reflns         549
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.242
_refine_ls_R_factor_all          0.0302
_refine_ls_R_factor_gt           0.0281
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0241P)²+19.3135P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0671
_refine_ls_wR_factor_ref         0.0679
_reflns_number_gt                525
_reflns_number_total             549
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic0605017sup3.cif
_cod_data_source_block           honige2c
_cod_original_cell_volume        428.99(16)
_cod_original_sg_symbol_H-M      C2/m
_cod_database_code               4332549
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ho1 Ho 0.40864(4) 0.0000 0.61004(9) 0.0065(2) Uani 1 2 d S
Ho2 Ho 0.34464(4) 0.0000 1.06289(9) 0.0066(2) Uani 1 2 d S
In In 0.5000 -0.5000 1.0000 0.0095(3) Uani 1 4 d S
Ge1 Ge 0.20256(10) 0.0000 0.2683(2) 0.0072(3) Uani 1 2 d S
Ge2 Ge 0.56447(10) -0.5000 0.6620(2) 0.0071(3) Uani 1 2 d S
Ni Ni 0.21701(12) 0.0000 0.6427(3) 0.0097(4) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ho Ho -0.2175 4.6783 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge2 Ho1 Ge2 90.91(5) 5_646 5_656
Ge2 Ho1 Ge1 83.81(3) 5_646 7_546
Ge2 Ho1 Ge1 153.12(5) 5_656 7_546
Ge2 Ho1 Ge1 153.12(5) 5_646 7_556
Ge2 Ho1 Ge1 83.81(3) 5_656 7_556
Ge1 Ho1 Ge1 89.09(5) 7_546 7_556
Ge2 Ho1 Ni 47.20(4) 5_646 7_546
Ge2 Ho1 Ni 108.34(5) 5_656 7_546
Ge1 Ho1 Ni 50.26(5) 7_546 7_546
Ge1 Ho1 Ni 109.83(5) 7_556 7_546
Ge2 Ho1 Ni 108.34(5) 5_646 7_556
Ge2 Ho1 Ni 47.20(4) 5_656 7_556
Ge1 Ho1 Ni 109.83(5) 7_546 7_556
Ge1 Ho1 Ni 50.26(5) 7_556 7_556
Ni Ho1 Ni 88.45(5) 7_546 7_556
Ge2 Ho1 Ni 112.85(4) 5_646 .
Ge2 Ho1 Ni 112.85(4) 5_656 .
Ge1 Ho1 Ni 47.34(3) 7_546 .
Ge1 Ho1 Ni 47.34(3) 7_556 .
Ni Ho1 Ni 65.66(5) 7_546 .
Ni Ho1 Ni 65.66(5) 7_556 .
Ge2 Ho1 Ge2 107.20(3) 5_646 1_565
Ge2 Ho1 Ge2 48.29(5) 5_656 1_565
Ge1 Ho1 Ge2 157.72(5) 7_546 1_565
Ge1 Ho1 Ge2 88.81(3) 7_556 1_565
Ni Ho1 Ge2 149.59(5) 7_546 1_565
Ni Ho1 Ge2 85.52(4) 7_556 1_565
Ni Ho1 Ge2 136.09(2) . 1_565
Ge2 Ho1 Ge2 48.29(5) 5_646 .
Ge2 Ho1 Ge2 107.20(3) 5_656 .
Ge1 Ho1 Ge2 88.81(3) 7_546 .
Ge1 Ho1 Ge2 157.72(5) 7_556 .
Ni Ho1 Ge2 85.52(4) 7_546 .
Ni Ho1 Ge2 149.59(5) 7_556 .
Ni Ho1 Ge2 136.09(2) . .
Ge2 Ho1 Ge2 84.80(4) 1_565 .
Ge2 Ho1 Ge1 80.39(4) 5_646 .
Ge2 Ho1 Ge1 80.39(4) 5_656 .
Ge1 Ho1 Ge1 72.75(4) 7_546 .
Ge1 Ho1 Ge1 72.75(4) 7_556 .
Ni Ho1 Ge1 44.73(3) 7_546 .
Ni Ho1 Ge1 44.73(3) 7_556 .
Ni Ho1 Ge1 47.38(5) . .
Ge2 Ho1 Ge1 127.40(3) 1_565 .
Ge2 Ho1 Ge1 127.40(3) . .
Ge2 Ho1 In 148.99(4) 5_646 1_565
Ge2 Ho1 In 88.19(3) 5_656 1_565
Ge1 Ho1 In 109.65(3) 7_546 1_565
Ge1 Ho1 In 57.41(3) 7_556 1_565
Ni Ho1 In 158.70(4) 7_546 1_565
Ni Ho1 In 93.55(3) 7_556 1_565
Ni Ho1 In 95.92(3) . 1_565
Ge2 Ho1 In 51.64(3) 1_565 1_565
Ge2 Ho1 In 102.72(3) . 1_565
Ge1 Ho1 In 129.80(2) . 1_565
Ge2 Ho1 In 88.19(3) 5_646 .
Ge2 Ho1 In 148.99(4) 5_656 .
Ge1 Ho1 In 57.41(3) 7_546 .
Ge1 Ho1 In 109.65(3) 7_556 .
Ni Ho1 In 93.55(3) 7_546 .
Ni Ho1 In 158.70(4) 7_556 .
Ni Ho1 In 95.92(3) . .
Ge2 Ho1 In 102.72(3) 1_565 .
Ge2 Ho1 In 51.64(3) . .
Ge1 Ho1 In 129.80(2) . .
In Ho1 In 77.15(2) 1_565 .
Ge2 Ho2 Ge2 93.38(5) 5_657 5_647
Ge2 Ho2 Ni 133.24(2) 5_657 .
Ge2 Ho2 Ni 133.24(2) 5_647 .
Ge2 Ho2 Ge1 87.26(4) 5_657 1_556
Ge2 Ho2 Ge1 87.26(4) 5_647 1_556
Ni Ho2 Ge1 97.06(5) . 1_556
Ge2 Ho2 Ge1 163.20(5) 5_657 7_546
Ge2 Ho2 Ge1 87.14(4) 5_647 7_546
Ni Ho2 Ge1 47.48(3) . 7_546
Ge1 Ho2 Ge1 109.54(4) 1_556 7_546
Ge2 Ho2 Ge1 87.14(4) 5_657 7_556
Ge2 Ho2 Ge1 163.20(5) 5_647 7_556
Ni Ho2 Ge1 47.48(3) . 7_556
Ge1 Ho2 Ge1 109.54(3) 1_556 7_556
Ge1 Ho2 Ge1 87.59(5) 7_546 7_556
Ge2 Ho2 Ni 44.96(4) 5_657 7_557
Ge2 Ho2 Ni 102.95(4) 5_647 7_557
Ni Ho2 Ni 112.85(4) . 7_557
Ge1 Ho2 Ni 45.13(3) 1_556 7_557
Ge1 Ho2 Ni 150.87(5) 7_546 7_557
Ge1 Ho2 Ni 89.27(4) 7_556 7_557
Ge2 Ho2 Ni 102.95(4) 5_657 7_547
Ge2 Ho2 Ni 44.96(4) 5_647 7_547
Ni Ho2 Ni 112.85(4) . 7_547
Ge1 Ho2 Ni 45.13(3) 1_556 7_547
Ge1 Ho2 Ni 89.27(4) 7_546 7_547
Ge1 Ho2 Ni 150.87(5) 7_556 7_547
Ni Ho2 Ni 79.61(5) 7_557 7_547
Ge2 Ho2 In 53.90(3) 5_657 1_565
Ge2 Ho2 In 109.54(3) 5_647 1_565
Ni Ho2 In 98.36(3) . 1_565
Ge1 Ho2 In 137.335(17) 1_556 1_565
Ge1 Ho2 In 110.20(3) 7_546 1_565
Ge1 Ho2 In 57.77(3) 7_556 1_565
Ni Ho2 In 92.31(3) 7_557 1_565
Ni Ho2 In 148.53(4) 7_547 1_565
Ge2 Ho2 In 109.54(3) 5_657 .
Ge2 Ho2 In 53.90(3) 5_647 .
Ni Ho2 In 98.36(3) . .
Ge1 Ho2 In 137.335(17) 1_556 .
Ge1 Ho2 In 57.77(3) 7_546 .
Ge1 Ho2 In 110.20(3) 7_556 .
Ni Ho2 In 148.53(4) 7_557 .
Ni Ho2 In 92.31(3) 7_547 .
In Ho2 In 78.80(2) 1_565 .
Ge2 Ho2 Ho2 142.95(4) 5_657 7_547
Ge2 Ho2 Ho2 85.14(3) 5_647 7_547
Ni Ho2 Ho2 60.84(3) . 7_547
Ge1 Ho2 Ho2 55.70(3) 1_556 7_547
Ge1 Ho2 Ho2 53.84(3) 7_546 7_547
Ge1 Ho2 Ho2 104.46(4) 7_556 7_547
Ni Ho2 Ho2 99.28(4) 7_557 7_547
Ni Ho2 Ho2 52.01(3) 7_547 7_547
In Ho2 Ho2 158.85(3) 1_565 7_547
In Ho2 Ho2 99.350(19) . 7_547
Ge2 Ho2 Ho2 85.14(3) 5_657 7_557
Ge2 Ho2 Ho2 142.95(4) 5_647 7_557
Ni Ho2 Ho2 60.84(3) . 7_557
Ge1 Ho2 Ho2 55.70(3) 1_556 7_557
Ge1 Ho2 Ho2 104.46(4) 7_546 7_557
Ge1 Ho2 Ho2 53.84(3) 7_556 7_557
Ni Ho2 Ho2 52.01(3) 7_557 7_557
Ni Ho2 Ho2 99.28(4) 7_547 7_557
In Ho2 Ho2 99.350(19) 1_565 7_557
In Ho2 Ho2 158.85(3) . 7_557
Ho2 Ho2 Ho2 74.70(3) 7_547 7_557
Ge2 In Ge2 180.0 5_647 .
Ge2 In Ge1 87.35(4) 5_647 7_546
Ge2 In Ge1 92.65(4) . 7_546
Ge2 In Ge1 92.65(4) 5_647 3_546
Ge2 In Ge1 87.35(4) . 3_546
Ge1 In Ge1 180.0 7_546 3_546
Ge2 In Ho2 55.41(2) 5_647 1_545
Ge2 In Ho2 124.59(2) . 1_545
Ge1 In Ho2 56.63(2) 7_546 1_545
Ge1 In Ho2 123.37(2) 3_546 1_545
Ge2 In Ho2 55.41(2) 5_647 .
Ge2 In Ho2 124.59(2) . .
Ge1 In Ho2 56.63(2) 7_546 .
Ge1 In Ho2 123.37(2) 3_546 .
Ho2 In Ho2 78.80(2) 1_545 .
Ge2 In Ho2 124.59(2) 5_647 5_657
Ge2 In Ho2 55.41(2) . 5_657
Ge1 In Ho2 123.37(2) 7_546 5_657
Ge1 In Ho2 56.63(2) 3_546 5_657
Ho2 In Ho2 180.000(15) 1_545 5_657
Ho2 In Ho2 101.20(2) . 5_657
Ge2 In Ho2 124.59(2) 5_647 5_647
Ge2 In Ho2 55.41(2) . 5_647
Ge1 In Ho2 123.37(2) 7_546 5_647
Ge1 In Ho2 56.63(2) 3_546 5_647
Ho2 In Ho2 101.20(2) 1_545 5_647
Ho2 In Ho2 180.0 . 5_647
Ho2 In Ho2 78.80(2) 5_657 5_647
Ge2 In Ho1 120.44(3) 5_647 1_545
Ge2 In Ho1 59.56(3) . 1_545
Ge1 In Ho1 55.16(2) 7_546 1_545
Ge1 In Ho1 124.84(2) 3_546 1_545
Ho2 In Ho1 65.148(17) 1_545 1_545
Ho2 In Ho1 111.793(18) . 1_545
Ho2 In Ho1 114.852(17) 5_657 1_545
Ho2 In Ho1 68.207(18) 5_647 1_545
Ge2 In Ho1 59.56(3) 5_647 5_657
Ge2 In Ho1 120.44(3) . 5_657
Ge1 In Ho1 124.84(2) 7_546 5_657
Ge1 In Ho1 55.16(2) 3_546 5_657
Ho2 In Ho1 114.852(17) 1_545 5_657
Ho2 In Ho1 68.207(18) . 5_657
Ho2 In Ho1 65.148(17) 5_657 5_657
Ho2 In Ho1 111.793(18) 5_647 5_657
Ho1 In Ho1 180.0 1_545 5_657
Ge2 In Ho1 120.44(3) 5_647 .
Ge2 In Ho1 59.56(3) . .
Ge1 In Ho1 55.16(2) 7_546 .
Ge1 In Ho1 124.84(2) 3_546 .
Ho2 In Ho1 111.793(18) 1_545 .
Ho2 In Ho1 65.148(17) . .
Ho2 In Ho1 68.207(18) 5_657 .
Ho2 In Ho1 114.852(17) 5_647 .
Ho1 In Ho1 77.15(2) 1_545 .
Ho1 In Ho1 102.85(2) 5_657 .
Ge2 In Ho1 59.56(3) 5_647 5_647
Ge2 In Ho1 120.44(3) . 5_647
Ge1 In Ho1 124.84(2) 7_546 5_647
Ge1 In Ho1 55.16(2) 3_546 5_647
Ho2 In Ho1 68.207(18) 1_545 5_647
Ho2 In Ho1 114.852(17) . 5_647
Ho2 In Ho1 111.793(18) 5_657 5_647
Ho2 In Ho1 65.148(17) 5_647 5_647
Ho1 In Ho1 102.85(2) 1_545 5_647
Ho1 In Ho1 77.15(2) 5_657 5_647
Ho1 In Ho1 180.0 . 5_647
Ni Ge1 Ni 120.89(10) 7_556 7_546
Ni Ge1 Ni 82.32(6) 7_556 .
Ni Ge1 Ni 82.32(6) 7_546 .
Ni Ge1 Ho2 74.35(5) 7_556 1_554
Ni Ge1 Ho2 74.35(5) 7_546 1_554
Ni Ge1 Ho2 131.14(7) . 1_554
Ni Ge1 Ho1 145.89(7) 7_556 7_546
Ni Ge1 Ho1 66.89(5) 7_546 7_546
Ni Ge1 Ho1 65.22(4) . 7_546
Ho2 Ge1 Ho1 135.22(2) 1_554 7_546
Ni Ge1 Ho1 66.89(5) 7_556 7_556
Ni Ge1 Ho1 145.89(7) 7_546 7_556
Ni Ge1 Ho1 65.22(4) . 7_556
Ho2 Ge1 Ho1 135.22(2) 1_554 7_556
Ho1 Ge1 Ho1 89.09(5) 7_546 7_556
Ni Ge1 Ho2 140.89(7) 7_556 7_546
Ni Ge1 Ho2 64.65(5) 7_546 7_546
Ni Ge1 Ho2 134.57(3) . 7_546
Ho2 Ge1 Ho2 70.46(3) 1_554 7_546
Ho1 Ge1 Ho2 73.22(3) 7_546 7_546
Ho1 Ge1 Ho2 133.02(6) 7_556 7_546
Ni Ge1 Ho2 64.65(5) 7_556 7_556
Ni Ge1 Ho2 140.89(7) 7_546 7_556
Ni Ge1 Ho2 134.57(3) . 7_556
Ho2 Ge1 Ho2 70.46(3) 1_554 7_556
Ho1 Ge1 Ho2 133.02(6) 7_546 7_556
Ho1 Ge1 Ho2 73.22(3) 7_556 7_556
Ho2 Ge1 Ho2 87.59(5) 7_546 7_556
Ni Ge1 In 119.40(5) 7_556 3_454
Ni Ge1 In 119.40(5) 7_546 3_454
Ni Ge1 In 111.39(7) . 3_454
Ho2 Ge1 In 117.47(5) 1_554 3_454
Ho1 Ge1 In 67.43(3) 7_546 3_454
Ho1 Ge1 In 67.43(3) 7_556 3_454
Ho2 Ge1 In 65.60(3) 7_546 3_454
Ho2 Ge1 In 65.60(3) 7_556 3_454
Ni Ge1 Ho1 61.36(5) 7_556 .
Ni Ge1 Ho1 61.36(5) 7_546 .
Ni Ge1 Ho1 60.60(5) . .
Ho2 Ge1 Ho1 70.54(4) 1_554 .
Ho1 Ge1 Ho1 107.25(4) 7_546 .
Ho1 Ge1 Ho1 107.25(4) 7_556 .
Ho2 Ge1 Ho1 119.45(4) 7_546 .
Ho2 Ge1 Ho1 119.45(4) 7_556 .
In Ge1 Ho1 171.99(5) 3_454 .
Ni Ge2 Ge2 117.31(10) 3_545 5_646
Ni Ge2 In 130.98(7) 3_545 .
Ge2 Ge2 In 111.70(8) 5_646 .
Ni Ge2 Ho2 76.30(5) 3_545 5_657
Ge2 Ge2 Ho2 132.90(3) 5_646 5_657
In Ge2 Ho2 70.69(4) . 5_657
Ni Ge2 Ho2 76.30(5) 3_545 5_647
Ge2 Ge2 Ho2 132.90(3) 5_646 5_647
In Ge2 Ho2 70.69(4) . 5_647
Ho2 Ge2 Ho2 93.38(5) 5_657 5_647
Ni Ge2 Ho1 67.82(4) 3_545 5_646
Ge2 Ge2 Ho1 69.39(5) 5_646 5_646
In Ge2 Ho1 133.94(2) . 5_646
Ho2 Ge2 Ho1 144.07(6) 5_657 5_646
Ho2 Ge2 Ho1 76.86(3) 5_647 5_646
Ni Ge2 Ho1 67.82(4) 3_545 5_656
Ge2 Ge2 Ho1 69.39(5) 5_646 5_656
In Ge2 Ho1 133.94(2) . 5_656
Ho2 Ge2 Ho1 76.86(3) 5_657 5_656
Ho2 Ge2 Ho1 144.07(6) 5_647 5_656
Ho1 Ge2 Ho1 90.91(5) 5_646 5_656
Ni Ge2 Ho1 136.32(3) 3_545 1_545
Ge2 Ge2 Ho1 62.32(4) 5_646 1_545
In Ge2 Ho1 68.80(3) . 1_545
Ho2 Ge2 Ho1 139.29(6) 5_657 1_545
Ho2 Ge2 Ho1 77.10(3) 5_647 1_545
Ho1 Ge2 Ho1 72.80(3) 5_646 1_545
Ho1 Ge2 Ho1 131.71(5) 5_656 1_545
Ni Ge2 Ho1 136.32(3) 3_545 .
Ge2 Ge2 Ho1 62.32(4) 5_646 .
In Ge2 Ho1 68.80(3) . .
Ho2 Ge2 Ho1 77.10(3) 5_657 .
Ho2 Ge2 Ho1 139.29(6) 5_647 .
Ho1 Ge2 Ho1 131.71(5) 5_646 .
Ho1 Ge2 Ho1 72.80(3) 5_656 .
Ho1 Ge2 Ho1 84.80(4) 1_545 .
Ge2 Ni Ge1 114.54(5) 3_455 7_556
Ge2 Ni Ge1 114.54(5) 3_455 7_546
Ge1 Ni Ge1 120.89(10) 7_556 7_546
Ge2 Ni Ge1 106.94(8) 3_455 .
Ge1 Ni Ge1 97.68(6) 7_556 .
Ge1 Ni Ge1 97.68(6) 7_546 .
Ge2 Ni Ho2 107.14(8) 3_455 .
Ge1 Ni Ho2 67.87(5) 7_556 .
Ge1 Ni Ho2 67.87(5) 7_546 .
Ge1 Ni Ho2 145.92(8) . .
Ge2 Ni Ho1 64.99(5) 3_455 7_546
Ge1 Ni Ho1 159.44(8) 7_556 7_546
Ge1 Ni Ho1 73.91(4) 7_546 7_546
Ge1 Ni Ho1 64.52(4) . 7_546
Ho2 Ni Ho1 132.65(3) . 7_546
Ge2 Ni Ho1 64.99(5) 3_455 7_556
Ge1 Ni Ho1 73.91(4) 7_556 7_556
Ge1 Ni Ho1 159.44(8) 7_546 7_556
Ge1 Ni Ho1 64.52(4) . 7_556
Ho2 Ni Ho1 132.65(3) . 7_556
Ho1 Ni Ho1 88.45(5) 7_546 7_556
Ge2 Ni Ho1 178.96(9) 3_455 .
Ge1 Ni Ho1 65.77(5) 7_556 .
Ge1 Ni Ho1 65.77(5) 7_546 .
Ge1 Ni Ho1 72.02(6) . .
Ho2 Ni Ho1 73.90(5) . .
Ho1 Ni Ho1 114.34(5) 7_546 .
Ho1 Ni Ho1 114.34(5) 7_556 .
Ge2 Ni Ho2 58.74(4) 3_455 7_557
Ge1 Ni Ho2 60.52(4) 7_556 7_557
Ge1 Ni Ho2 128.44(8) 7_546 7_557
Ge1 Ni Ho2 133.87(4) . 7_557
Ho2 Ni Ho2 67.15(4) . 7_557
Ho1 Ni Ho2 123.70(6) 7_546 7_557
Ho1 Ni Ho2 70.23(3) 7_556 7_557
Ho1 Ni Ho2 121.95(5) . 7_557
Ge2 Ni Ho2 58.74(4) 3_455 7_547
Ge1 Ni Ho2 128.44(8) 7_556 7_547
Ge1 Ni Ho2 60.52(4) 7_546 7_547
Ge1 Ni Ho2 133.87(4) . 7_547
Ho2 Ni Ho2 67.15(4) . 7_547
Ho1 Ni Ho2 70.23(3) 7_546 7_547
Ho1 Ni Ho2 123.70(6) 7_556 7_547
Ho1 Ni Ho2 121.95(5) . 7_547
Ho2 Ni Ho2 79.61(5) 7_557 7_547
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ho1 Ge2 2.9537(12) 5_646
Ho1 Ge2 2.9537(12) 5_656
Ho1 Ge1 3.0008(12) 7_546
Ho1 Ge1 3.0008(12) 7_556
Ho1 Ni 3.0182(14) 7_546
Ho1 Ni 3.0182(14) 7_556
Ho1 Ni 3.027(2) .
Ho1 Ge2 3.1219(12) 1_565
Ho1 Ge2 3.1219(12) .
Ho1 Ge1 3.3042(17) .
Ho1 In 3.3761(7) 1_565
Ho1 In 3.3761(7) .
Ho2 Ge2 2.8930(12) 5_657
Ho2 Ge2 2.8930(12) 5_647
Ho2 Ni 2.967(2) .
Ho2 Ge1 2.9727(17) 1_556
Ho2 Ge1 3.0416(13) 7_546
Ho2 Ge1 3.0416(13) 7_556
Ho2 Ni 3.2882(16) 7_557
Ho2 Ni 3.2882(16) 7_547
Ho2 In 3.3165(7) 1_565
Ho2 In 3.3165(7) .
Ho2 Ho2 3.4698(11) 7_547
Ho2 Ho2 3.4698(11) 7_557
In Ge2 2.8395(16) 5_647
In Ge2 2.8395(16) .
In Ge1 3.0807(16) 7_546
In Ge1 3.0807(16) 3_546
In Ho2 3.3165(7) 1_545
In Ho2 3.3165(7) 5_657
In Ho2 3.3165(7) 5_647
In Ho1 3.3761(7) 1_545
In Ho1 3.3761(7) 5_657
In Ho1 3.3761(7) 5_647
Ge1 Ni 2.4200(12) 7_556
Ge1 Ni 2.4200(12) 7_546
Ge1 Ni 2.556(3) .
Ge1 Ho2 2.9727(17) 1_554
Ge1 Ho1 3.0008(12) 7_546
Ge1 Ho1 3.0008(12) 7_556
Ge1 Ho2 3.0416(13) 7_546
Ge1 Ho2 3.0416(13) 7_556
Ge1 In 3.0807(16) 3_454
Ge2 Ni 2.391(2) 3_545
Ge2 Ge2 2.490(3) 5_646
Ge2 Ho2 2.8930(12) 5_657
Ge2 Ho2 2.8930(12) 5_647
Ge2 Ho1 2.9537(12) 5_646
Ge2 Ho1 2.9537(12) 5_656
Ge2 Ho1 3.1219(12) 1_545
Ni Ge2 2.391(2) 3_455
Ni Ge1 2.4200(12) 7_556
Ni Ge1 2.4200(12) 7_546
Ni Ho1 3.0182(14) 7_546
Ni Ho1 3.0182(14) 7_556
Ni Ho2 3.2881(16) 7_557
Ni Ho2 3.2881(16) 7_547
