#------------------------------------------------------------------------------
#$Date: 2016-03-23 20:59:17 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179434 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/31/4333146.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_4333146
loop_
_publ_author_name
'Chen, Wei-Zhong'
'Ren, Tong'
_publ_section_title
;
 Symmetric and Unsymmetric “Dumbbells” of Ru2−Alkynyl
 Units via C−C Bond Formation Reactions
;
_journal_issue                   23
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              9175
_journal_page_last               9177
_journal_paper_doi               10.1021/ic061511a
_journal_volume                  45
_journal_year                    2006
_chemical_formula_sum            'C146 H82 Cl24 N16 O5 Ru4'
_chemical_formula_weight         3395.36
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 104.314(19)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   56.510(9)
_cell_length_b                   13.0727(18)
_cell_length_c                   23.723(4)
_cell_measurement_reflns_used    6110
_cell_measurement_temperature    300(2)
_cell_measurement_theta_max      22.098
_cell_measurement_theta_min      2.229
_cell_volume                     16981(5)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      300(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1084
_diffrn_reflns_av_sigmaI/netI    0.1090
_diffrn_reflns_limit_h_max       62
_diffrn_reflns_limit_h_min       -62
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            37942
_diffrn_reflns_theta_full        23.28
_diffrn_reflns_theta_max         23.28
_diffrn_reflns_theta_min         1.49
_exptl_absorpt_coefficient_mu    0.778
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.5699
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details
; 
  SADABS, Absorption corrections using Bruker CCD based on the method of 
  Bob Blessing.  Acta Cryst. 1995, A51, 33 
;
_exptl_crystal_colour            Black
_exptl_crystal_density_diffrn    1.328
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Plate
_exptl_crystal_F_000             6776
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.01
_refine_diff_density_max         1.002
_refine_diff_density_min         -0.740
_refine_diff_density_rms         0.117
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     783
_refine_ls_number_reflns         12202
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.037
_refine_ls_R_factor_all          0.1362
_refine_ls_R_factor_gt           0.0716
_refine_ls_shift/su_max          0.009
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1100P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1868
_refine_ls_wR_factor_ref         0.2178
_reflns_number_gt                6647
_reflns_number_total             12202
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic061511asup1.cif
_cod_data_source_block           um515s
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_cell_volume        16981(4)
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               4333146
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ru1 Ru 0.140174(12) 0.42022(5) 0.75803(3) 0.0457(2) Uani 1 1 d .
Ru2 Ru 0.105535(12) 0.53098(5) 0.77338(3) 0.0454(2) Uani 1 1 d .
N1 N 0.11129(13) 0.3304(5) 0.7172(3) 0.0502(18) Uani 1 1 d .
N2 N 0.08108(12) 0.4507(5) 0.7161(3) 0.0493(18) Uani 1 1 d .
N3 N 0.13736(12) 0.5302(6) 0.6909(3) 0.0499(18) Uani 1 1 d .
N4 N 0.10611(13) 0.6341(5) 0.7111(3) 0.0536(19) Uani 1 1 d .
N5 N 0.16642(12) 0.5074(5) 0.8090(3) 0.0504(19) Uani 1 1 d .
N6 N 0.13532(13) 0.6098(5) 0.8285(3) 0.0519(19) Uani 1 1 d .
N7 N 0.14246(13) 0.3323(5) 0.8301(3) 0.0508(19) Uani 1 1 d .
N8 N 0.10631(13) 0.4142(6) 0.8357(3) 0.0512(18) Uani 1 1 d .
Cl1 Cl 0.22051(7) 0.6531(4) 0.67132(19) 0.1515(18) Uani 1 1 d .
Cl2 Cl 0.16008(8) 0.4481(4) 0.49880(15) 0.1344(15) Uani 1 1 d .
Cl3 Cl 0.04507(9) 0.8065(4) 0.54188(19) 0.1637(19) Uani 1 1 d .
Cl4 Cl 0.07171(12) 0.9790(3) 0.7533(3) 0.201(3) Uani 1 1 d .
Cl5 Cl 0.24752(6) 0.3881(3) 0.77176(17) 0.1179(13) Uani 1 1 d .
Cl6 Cl 0.23607(6) 0.4290(4) 0.98876(15) 0.1364(15) Uani 1 1 d .
Cl7 Cl 0.14951(11) 0.9955(3) 0.8597(3) 0.197(3) Uani 1 1 d .
Cl8 Cl 0.10478(8) 0.7761(3) 0.99345(16) 0.1349(15) Uani 1 1 d .
Cl9 Cl 0.21712(7) 0.1122(3) 0.82902(19) 0.1324(15) Uani 1 1 d .
Cl10 Cl 0.19288(9) 0.2001(4) 1.02798(16) 0.1487(17) Uani 1 1 d .
Cl11 Cl 0.08139(8) 0.4801(3) 1.02568(15) 0.1304(14) Uani 1 1 d .
Cl12 Cl 0.01598(7) 0.3589(5) 0.8323(2) 0.184(2) Uani 1 1 d .
C1 C 0.15916(18) 0.3438(7) 0.7115(4) 0.062(3) Uani 1 1 d .
C2 C 0.16988(19) 0.2945(8) 0.6820(4) 0.066(3) Uani 1 1 d .
C3 C 0.1821(2) 0.2341(9) 0.6472(6) 0.079(3) Uani 1 1 d .
C4 C 0.2046(2) 0.1917(10) 0.6709(6) 0.105(4) Uani 1 1 d .
H4A H 0.2121 0.2042 0.7098 0.126 Uiso 1 1 calc R
C5 C 0.2165(3) 0.1324(13) 0.6396(9) 0.135(6) Uani 1 1 d .
H5A H 0.2321 0.1081 0.6562 0.162 Uiso 1 1 calc R
C6 C 0.2049(4) 0.1087(13) 0.5828(10) 0.144(7) Uani 1 1 d .
H6A H 0.2120 0.0636 0.5614 0.173 Uiso 1 1 calc R
C7 C 0.1839(4) 0.1508(17) 0.5599(8) 0.164(8) Uani 1 1 d .
H7A H 0.1768 0.1409 0.5205 0.197 Uiso 1 1 calc R
C8 C 0.1718(3) 0.2095(12) 0.5917(7) 0.121(5) Uani 1 1 d .
H8A H 0.1561 0.2325 0.5744 0.146 Uiso 1 1 calc R
C9 C 0.08135(16) 0.6053(7) 0.8069(4) 0.052(2) Uani 1 1 d .
C10 C 0.06557(18) 0.6459(8) 0.8219(5) 0.071(3) Uani 1 1 d .
C11 C 0.0451(3) 0.6956(11) 0.8390(6) 0.116(5) Uiso 1 1 d G
C12 C 0.0492(3) 0.7814(13) 0.8729(8) 0.322(17) Uiso 1 1 d G
H12A H 0.0648 0.8093 0.8840 0.386 Uiso 1 1 calc R
C13 C 0.0304(5) 0.8262(14) 0.8904(8) 0.353(19) Uiso 1 1 d G
H13A H 0.0332 0.8847 0.9135 0.424 Uiso 1 1 calc R
C14 C 0.0075(4) 0.7853(18) 0.8742(9) 0.240(11) Uiso 1 1 d G
H14A H -0.0053 0.8158 0.8861 0.287 Uiso 1 1 calc R
C15 C 0.0034(3) 0.700(2) 0.8403(10) 0.43(3) Uiso 1 1 d G
H15A H -0.0122 0.6716 0.8292 0.517 Uiso 1 1 calc R
C16 C 0.0222(3) 0.6547(14) 0.8228(8) 0.48(3) Uiso 1 1 d G
H16A H 0.0194 0.5962 0.7997 0.571 Uiso 1 1 calc R
C17 C 0.11656(18) 0.2193(7) 0.7118(5) 0.072(3) Uani 1 1 d .
H17A H 0.1019 0.1847 0.6921 0.108 Uiso 1 1 calc R
H17B H 0.1225 0.1904 0.7499 0.108 Uiso 1 1 calc R
H17C H 0.1287 0.2115 0.6900 0.108 Uiso 1 1 calc R
C18 C 0.08800(16) 0.3613(7) 0.7000(4) 0.050(2) Uani 1 1 d .
C19 C 0.05660(16) 0.4914(7) 0.6880(5) 0.069(3) Uani 1 1 d .
H19A H 0.0477 0.4415 0.6613 0.103 Uiso 1 1 calc R
H19B H 0.0583 0.5529 0.6672 0.103 Uiso 1 1 calc R
H19C H 0.0480 0.5062 0.7172 0.103 Uiso 1 1 calc R
C20 C 0.06948(15) 0.2930(6) 0.6601(4) 0.050(2) Uani 1 1 d .
C21 C 0.07071(19) 0.2797(8) 0.6026(5) 0.074(3) Uani 1 1 d .
H21A H 0.0823 0.3152 0.5886 0.089 Uiso 1 1 calc R
C22 C 0.0549(2) 0.2148(8) 0.5666(5) 0.076(3) Uani 1 1 d .
H22A H 0.0562 0.2045 0.5287 0.091 Uiso 1 1 calc R
C23 C 0.03687(17) 0.1641(7) 0.5865(4) 0.058(3) Uani 1 1 d .
C24 C 0.03533(18) 0.1777(8) 0.6424(5) 0.070(3) Uani 1 1 d .
H24A H 0.0234 0.1438 0.6559 0.084 Uiso 1 1 calc R
C25 C 0.05168(18) 0.2423(7) 0.6791(4) 0.063(3) Uani 1 1 d .
H25A H 0.0505 0.2513 0.7172 0.075 Uiso 1 1 calc R
C26 C 0.02003(19) 0.0948(7) 0.5473(5) 0.072(3) Uani 1 1 d .
C27 C 0.00742(19) 0.0352(7) 0.5177(5) 0.069(3) Uani 1 1 d .
C28 C 0.12247(16) 0.6102(7) 0.6812(4) 0.054(2) Uani 1 1 d .
H28A H 0.1235 0.6536 0.6508 0.064 Uiso 1 1 calc R
C29 C 0.15468(16) 0.5338(7) 0.6564(4) 0.053(2) Uani 1 1 d .
C30 C 0.17610(18) 0.5857(8) 0.6768(5) 0.068(3) Uani 1 1 d .
H30A H 0.1791 0.6186 0.7126 0.082 Uiso 1 1 calc R
C31 C 0.1930(2) 0.5891(10) 0.6445(6) 0.087(4) Uani 1 1 d .
C32 C 0.1891(2) 0.5468(9) 0.5908(6) 0.088(4) Uani 1 1 d .
H32A H 0.2007 0.5496 0.5692 0.105 Uiso 1 1 calc R
C33 C 0.1665(2) 0.4989(9) 0.5696(5) 0.081(3) Uani 1 1 d .
C34 C 0.14982(18) 0.4914(8) 0.6013(4) 0.066(3) Uani 1 1 d .
H34A H 0.1351 0.4579 0.5862 0.079 Uiso 1 1 calc R
C35 C 0.09044(17) 0.7187(7) 0.6905(5) 0.060(3) Uani 1 1 d .
C36 C 0.07732(19) 0.7223(9) 0.6319(5) 0.080(3) Uani 1 1 d .
H36A H 0.0789 0.6707 0.6061 0.097 Uiso 1 1 calc R
C37 C 0.0622(2) 0.8043(13) 0.6140(6) 0.105(4) Uani 1 1 d .
C38 C 0.0599(3) 0.8840(12) 0.6492(8) 0.118(5) Uani 1 1 d .
H38A H 0.0500 0.9400 0.6354 0.141 Uiso 1 1 calc R
C39 C 0.0729(3) 0.8774(10) 0.7066(8) 0.109(5) Uani 1 1 d .
C40 C 0.0878(2) 0.7958(8) 0.7284(5) 0.080(3) Uani 1 1 d .
H40A H 0.0959 0.7925 0.7676 0.096 Uiso 1 1 calc R
C41 C 0.15841(16) 0.5842(7) 0.8360(4) 0.053(2) Uani 1 1 d .
H41A H 0.1700 0.6228 0.8621 0.064 Uiso 1 1 calc R
C42 C 0.19164(15) 0.4783(7) 0.8319(4) 0.053(2) Uani 1 1 d .
C43 C 0.20121(18) 0.4732(8) 0.8927(5) 0.067(3) Uani 1 1 d .
H43A H 0.1918 0.4920 0.9181 0.081 Uiso 1 1 calc R
C44 C 0.2248(2) 0.4397(9) 0.9134(5) 0.081(3) Uani 1 1 d .
C45 C 0.2393(2) 0.4127(8) 0.8773(6) 0.082(3) Uani 1 1 d .
H45A H 0.2553 0.3912 0.8923 0.098 Uiso 1 1 calc R
C46 C 0.22971(19) 0.4181(8) 0.8190(6) 0.076(3) Uani 1 1 d .
C47 C 0.20520(17) 0.4518(7) 0.7953(5) 0.062(3) Uani 1 1 d .
H47A H 0.1988 0.4552 0.7553 0.075 Uiso 1 1 calc R
C48 C 0.13207(16) 0.7013(7) 0.8601(4) 0.053(2) Uani 1 1 d .
C49 C 0.1410(2) 0.7943(8) 0.8462(5) 0.080(3) Uani 1 1 d .
H49A H 0.1491 0.7990 0.8165 0.096 Uiso 1 1 calc R
C50 C 0.1378(2) 0.8796(9) 0.8777(7) 0.100(4) Uani 1 1 d .
C51 C 0.1275(2) 0.8745(12) 0.9224(7) 0.114(5) Uani 1 1 d .
H51A H 0.1267 0.9320 0.9450 0.137 Uiso 1 1 calc R
C52 C 0.1179(2) 0.7819(11) 0.9348(5) 0.086(4) Uani 1 1 d .
C53 C 0.12008(18) 0.6980(8) 0.9039(4) 0.063(3) Uani 1 1 d .
H53A H 0.1134 0.6366 0.9123 0.076 Uiso 1 1 calc R
C54 C 0.12350(17) 0.3459(7) 0.8538(4) 0.053(2) Uani 1 1 d .
H54A H 0.1225 0.3046 0.8850 0.063 Uiso 1 1 calc R
C55 C 0.16227(17) 0.2714(7) 0.8620(5) 0.060(3) Uani 1 1 d .
C56 C 0.16726(19) 0.2661(7) 0.9231(5) 0.071(3) Uani 1 1 d .
H56A H 0.1575 0.3006 0.9433 0.085 Uiso 1 1 calc R
C57 C 0.1868(2) 0.2089(10) 0.9519(5) 0.085(3) Uani 1 1 d .
C58 C 0.2019(2) 0.1628(9) 0.9252(6) 0.091(4) Uani 1 1 d .
H58A H 0.2152 0.1257 0.9461 0.109 Uiso 1 1 calc R
C59 C 0.19723(19) 0.1714(9) 0.8660(6) 0.083(3) Uani 1 1 d .
C60 C 0.17761(17) 0.2250(7) 0.8336(5) 0.060(3) Uani 1 1 d .
H60A H 0.1749 0.2296 0.7933 0.072 Uiso 1 1 calc R
C61 C 0.08735(18) 0.4121(7) 0.8668(4) 0.059(3) Uani 1 1 d .
C62 C 0.0929(2) 0.4401(7) 0.9244(4) 0.066(3) Uani 1 1 d .
H62A H 0.1087 0.4580 0.9437 0.080 Uiso 1 1 calc R
C63 C 0.0745(2) 0.4411(9) 0.9532(5) 0.082(3) Uani 1 1 d .
C64 C 0.0513(2) 0.4137(10) 0.9270(6) 0.102(4) Uani 1 1 d .
H64A H 0.0392 0.4125 0.9474 0.123 Uiso 1 1 calc R
C65 C 0.0463(2) 0.3873(10) 0.8687(6) 0.098(4) Uani 1 1 d .
C66 C 0.06398(19) 0.3852(9) 0.8386(5) 0.079(3) Uani 1 1 d .
H66A H 0.0602 0.3659 0.7997 0.095 Uiso 1 1 calc R
O1 O 0.2328(3) 0.8369(12) 0.9325(7) 0.250 Uiso 0.939(12) 1 d PG
C101 C 0.2113(4) 0.7792(16) 0.9293(10) 0.250 Uiso 0.939(12) 1 d PG
C102 C 0.2039(4) 0.7369(15) 0.8728(12) 0.250 Uiso 0.939(12) 1 d PG
C103 C 0.2208(5) 0.7684(18) 0.8411(8) 0.250 Uiso 0.939(12) 1 d PG
C104 C 0.2386(3) 0.8302(16) 0.8780(11) 0.250 Uiso 0.939(12) 1 d PG
O2 O 0.1654(4) 0.124(3) 0.2109(14) 0.350 Uiso 0.843(14) 1 d PG
C201 C 0.1596(7) 0.167(2) 0.156(2) 0.350 Uiso 0.843(14) 1 d PG
C202 C 0.1432(7) 0.103(4) 0.1189(12) 0.350 Uiso 0.843(14) 1 d PG
C203 C 0.1389(6) 0.020(3) 0.151(2) 0.350 Uiso 0.843(14) 1 d PG
C204 C 0.1526(7) 0.032(3) 0.2081(18) 0.350 Uiso 0.843(14) 1 d PG
O3 O 0.0096(4) 0.4284(15) 0.5177(9) 0.250 Uiso 0.984(18) 1 d P
C301 C 0.0104(6) 0.532(2) 0.5477(13) 0.250 Uiso 0.984(18) 1 d P
O4 O -0.0868(6) 0.128(3) 0.5849(11) 0.350 Uiso 0.789(14) 1 d PG
C401 C -0.0795(6) 0.058(2) 0.538(2) 0.350 Uiso 0.789(14) 1 d PG
C402 C -0.0987(9) 0.074(3) 0.4789(15) 0.350 Uiso 0.789(14) 1 d PG
C403 C -0.1179(6) 0.155(3) 0.4887(18) 0.350 Uiso 0.789(14) 1 d PG
C404 C -0.1105(7) 0.188(2) 0.554(2) 0.350 Uiso 0.789(14) 1 d PG
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
C1 Ru1 N5 101.5(3) .
C1 Ru1 N7 104.6(3) .
N5 Ru1 N7 86.0(3) .
C1 Ru1 N1 85.8(3) .
N5 Ru1 N1 171.1(3) .
N7 Ru1 N1 87.2(3) .
C1 Ru1 N3 82.7(3) .
N5 Ru1 N3 88.6(3) .
N7 Ru1 N3 171.6(3) .
N1 Ru1 N3 97.5(3) .
C1 Ru1 Ru2 155.4(3) .
N5 Ru1 Ru2 94.0(2) .
N7 Ru1 Ru2 95.3(2) .
N1 Ru1 Ru2 80.90(19) .
N3 Ru1 Ru2 78.68(19) .
N2 Ru2 C9 95.8(3) .
N2 Ru2 N4 89.2(3) .
C9 Ru2 N4 96.0(3) .
N2 Ru2 N8 89.3(3) .
C9 Ru2 N8 88.3(3) .
N4 Ru2 N8 175.6(3) .
N2 Ru2 N6 172.1(3) .
C9 Ru2 N6 92.0(3) .
N4 Ru2 N6 88.5(3) .
N8 Ru2 N6 92.5(3) .
N2 Ru2 Ru1 91.8(2) .
C9 Ru2 Ru1 164.9(3) .
N4 Ru2 Ru1 97.1(2) .
N8 Ru2 Ru1 78.7(2) .
N6 Ru2 Ru1 80.99(19) .
C18 N1 C17 117.9(7) .
C18 N1 Ru1 125.4(6) .
C17 N1 Ru1 116.4(6) .
C18 N2 C19 120.0(7) .
C18 N2 Ru2 117.5(6) .
C19 N2 Ru2 122.3(6) .
C28 N3 C29 111.8(7) .
C28 N3 Ru1 126.2(6) .
C29 N3 Ru1 121.3(5) .
C28 N4 C35 116.9(8) .
C28 N4 Ru2 112.0(6) .
C35 N4 Ru2 130.7(6) .
C41 N5 C42 116.1(7) .
C41 N5 Ru1 115.3(6) .
C42 N5 Ru1 125.9(6) .
C41 N6 C48 112.9(7) .
C41 N6 Ru2 124.6(6) .
C48 N6 Ru2 122.5(5) .
C54 N7 C55 117.1(8) .
C54 N7 Ru1 112.7(6) .
C55 N7 Ru1 129.6(6) .
C54 N8 C61 113.8(7) .
C54 N8 Ru2 127.3(6) .
C61 N8 Ru2 118.7(6) .
C2 C1 Ru1 177.2(9) .
C1 C2 C3 178.5(12) .
C8 C3 C4 116.1(12) .
C8 C3 C2 122.8(12) .
C4 C3 C2 120.9(12) .
C5 C4 C3 122.5(15) .
C4 C5 C6 118.9(17) .
C7 C6 C5 118.5(17) .
C6 C7 C8 122.4(18) .
C3 C8 C7 121.2(15) .
C10 C9 Ru2 173.6(9) .
C9 C10 C11 178.0(13) .
C12 C11 C16 120.0 .
C12 C11 C10 119.6(14) .
C16 C11 C10 120.4(14) .
C11 C12 C13 120.0 .
C14 C13 C12 120.0 .
C13 C14 C15 120.0 .
C14 C15 C16 120.0 .
C11 C16 C15 120.0 .
N2 C18 N1 121.2(8) .
N2 C18 C20 119.6(8) .
N1 C18 C20 119.2(7) .
C25 C20 C21 118.6(9) .
C25 C20 C18 122.0(8) .
C21 C20 C18 119.4(8) .
C22 C21 C20 120.4(9) .
C21 C22 C23 120.2(10) .
C24 C23 C22 119.7(9) .
C24 C23 C26 120.7(9) .
C22 C23 C26 119.6(9) .
C23 C24 C25 119.8(9) .
C20 C25 C24 121.2(9) .
C27 C26 C23 176.2(12) .
C26 C27 C27 179.5(18) 5_556
N3 C28 N4 125.9(8) .
C30 C29 C34 119.0(9) .
C30 C29 N3 119.2(9) .
C34 C29 N3 121.7(8) .
C31 C30 C29 119.9(10) .
C32 C31 C30 122.5(11) .
C32 C31 Cl1 117.7(10) .
C30 C31 Cl1 119.8(9) .
C31 C32 C33 116.4(10) .
C34 C33 C32 122.2(11) .
C34 C33 Cl2 119.9(9) .
C32 C33 Cl2 117.8(9) .
C33 C34 C29 119.7(10) .
C40 C35 C36 120.3(10) .
C40 C35 N4 120.0(10) .
C36 C35 N4 119.7(10) .
C37 C36 C35 117.9(12) .
C38 C37 C36 123.7(14) .
C38 C37 Cl3 118.4(12) .
C36 C37 Cl3 117.9(13) .
C37 C38 C39 116.6(13) .
C40 C39 C38 123.0(13) .
C40 C39 Cl4 118.0(13) .
C38 C39 Cl4 118.9(12) .
C39 C40 C35 118.4(12) .
N6 C41 N5 124.9(8) .
C47 C42 C43 121.0(9) .
C47 C42 N5 119.6(9) .
C43 C42 N5 119.4(8) .
C44 C43 C42 118.3(10) .
C43 C44 C45 122.5(11) .
C43 C44 Cl6 117.9(10) .
C45 C44 Cl6 119.6(9) .
C46 C45 C44 118.1(10) .
C45 C46 C47 121.5(10) .
C45 C46 Cl5 119.9(9) .
C47 C46 Cl5 118.6(9) .
C42 C47 C46 118.6(10) .
C53 C48 C49 118.9(9) .
C53 C48 N6 121.0(8) .
C49 C48 N6 120.1(9) .
C50 C49 C48 118.3(11) .
C51 C50 C49 122.2(12) .
C51 C50 Cl7 120.4(11) .
C49 C50 Cl7 117.3(11) .
C50 C51 C52 118.8(12) .
C53 C52 C51 120.4(11) .
C53 C52 Cl8 121.2(11) .
C51 C52 Cl8 118.3(10) .
C52 C53 C48 121.1(10) .
N8 C54 N7 123.9(8) .
C60 C55 C56 119.8(9) .
C60 C55 N7 119.7(10) .
C56 C55 N7 120.2(9) .
C57 C56 C55 118.2(11) .
C58 C57 C56 123.0(11) .
C58 C57 Cl10 118.4(10) .
C56 C57 Cl10 118.6(10) .
C57 C58 C59 118.0(11) .
C58 C59 C60 122.6(11) .
C58 C59 Cl9 119.3(10) .
C60 C59 Cl9 118.1(10) .
C55 C60 C59 118.3(11) .
C66 C61 C62 120.5(10) .
C66 C61 N8 120.2(9) .
C62 C61 N8 119.2(9) .
C61 C62 C63 118.7(11) .
C64 C63 C62 122.4(11) .
C64 C63 Cl11 119.1(10) .
C62 C63 Cl11 118.6(10) .
C63 C64 C65 117.4(11) .
C66 C65 C64 122.2(12) .
C66 C65 Cl12 119.4(10) .
C64 C65 Cl12 118.4(10) .
C65 C66 C61 118.8(11) .
C101 O1 C104 108.0 .
O1 C101 C102 108.0 .
C101 C102 C103 108.0 .
C104 C103 C102 108.0 .
C103 C104 O1 108.0 .
C201 O2 C204 108.0 .
C202 C201 O2 108.0 .
C201 C202 C203 108.0 .
C204 C203 C202 108.0 .
C203 C204 O2 108.0 .
C301 O3 C301 95(2) 5_566
O3 C301 O3 85(2) 5_566
C404 O4 C401 108.0 .
C402 C401 O4 108.0 .
C403 C402 C401 108.0 .
C404 C403 C402 108.0 .
C403 C404 O4 108.0 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ru1 C1 1.988(11) .
Ru1 N5 2.019(7) .
Ru1 N7 2.037(7) .
Ru1 N1 2.049(7) .
Ru1 N3 2.123(7) .
Ru1 Ru2 2.5325(10) .
Ru2 N2 1.982(7) .
Ru2 C9 1.996(9) .
Ru2 N4 2.007(7) .
Ru2 N8 2.118(7) .
Ru2 N6 2.126(7) .
N1 C18 1.340(10) .
N1 C17 1.494(11) .
N2 C18 1.319(10) .
N2 C19 1.478(11) .
N3 C28 1.326(11) .
N3 C29 1.423(11) .
N4 C28 1.333(10) .
N4 C35 1.426(11) .
N5 C41 1.329(10) .
N5 C42 1.445(11) .
N6 C41 1.316(10) .
N6 C48 1.446(10) .
N7 C54 1.340(10) .
N7 C55 1.429(11) .
N8 C54 1.311(11) .
N8 C61 1.443(11) .
Cl1 C31 1.740(11) .
Cl2 C33 1.758(11) .
Cl3 C37 1.745(14) .
Cl4 C39 1.741(14) .
Cl5 C46 1.727(11) .
Cl6 C44 1.749(11) .
Cl7 C50 1.748(13) .
Cl8 C52 1.733(12) .
Cl9 C59 1.765(12) .
Cl10 C57 1.756(12) .
Cl11 C63 1.744(12) .
Cl12 C65 1.757(13) .
C1 C2 1.216(12) .
C2 C3 1.439(14) .
C3 C8 1.341(17) .
C3 C4 1.374(16) .
C4 C5 1.357(17) .
C5 C6 1.38(2) .
C6 C7 1.30(2) .
C7 C8 1.371(19) .
C9 C10 1.166(11) .
C10 C11 1.470(15) .
C11 C12 1.365(9) .
C11 C16 1.365(9) .
C12 C13 1.365(9) .
C13 C14 1.365(9) .
C14 C15 1.365(9) .
C15 C16 1.365(9) .
C18 C20 1.516(12) .
C20 C25 1.370(12) .
C20 C21 1.394(13) .
C21 C22 1.366(13) .
C22 C23 1.395(13) .
C23 C24 1.361(13) .
C23 C26 1.467(13) .
C24 C25 1.388(13) .
C26 C27 1.167(12) .
C27 C27 1.381(19) 5_556
C29 C30 1.367(12) .
C29 C34 1.384(12) .
C30 C31 1.366(14) .
C31 C32 1.356(15) .
C32 C33 1.399(15) .
C33 C34 1.346(13) .
C35 C40 1.382(14) .
C35 C36 1.405(14) .
C36 C37 1.372(16) .
C37 C38 1.362(18) .
C38 C39 1.382(19) .
C39 C40 1.377(16) .
C42 C47 1.338(12) .
C42 C43 1.410(13) .
C43 C44 1.373(14) .
C44 C45 1.373(15) .
C45 C46 1.356(15) .
C46 C47 1.430(14) .
C48 C53 1.375(12) .
C48 C49 1.388(13) .
C49 C50 1.379(15) .
C50 C51 1.334(17) .
C51 C52 1.386(17) .
C52 C53 1.340(14) .
C55 C60 1.364(13) .
C55 C56 1.408(14) .
C56 C57 1.368(14) .
C57 C58 1.326(15) .
C58 C59 1.370(16) .
C59 C60 1.375(14) .
C61 C66 1.370(13) .
C61 C62 1.375(13) .
C62 C63 1.378(14) .
C63 C64 1.350(16) .
C64 C65 1.386(16) .
C65 C66 1.364(14) .
O1 C101 1.414(11) .
O1 C104 1.414(11) .
C101 C102 1.414(11) .
C102 C103 1.415(11) .
C103 C104 1.414(11) .
O2 C201 1.389(17) .
O2 C204 1.389(17) .
C201 C202 1.389(17) .
C202 C203 1.389(17) .
C203 C204 1.389(17) .
O3 C301 1.53(3) .
O3 C301 1.76(3) 5_566
C301 O3 1.76(3) 5_566
O4 C404 1.567(18) .
O4 C401 1.568(18) .
C401 C402 1.568(18) .
C402 C403 1.567(18) .
C403 C404 1.567(18) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C1 Ru1 Ru2 N2 44.8(7) . .
N5 Ru1 Ru2 N2 174.2(3) . .
N7 Ru1 Ru2 N2 -99.4(3) . .
N1 Ru1 Ru2 N2 -13.2(3) . .
N3 Ru1 Ru2 N2 86.5(3) . .
C1 Ru1 Ru2 C9 165.2(11) . .
N5 Ru1 Ru2 C9 -65.4(10) . .
N7 Ru1 Ru2 C9 21.0(10) . .
N1 Ru1 Ru2 C9 107.2(10) . .
N3 Ru1 Ru2 C9 -153.1(10) . .
C1 Ru1 Ru2 N4 -44.6(7) . .
N5 Ru1 Ru2 N4 84.8(3) . .
N7 Ru1 Ru2 N4 171.2(3) . .
N1 Ru1 Ru2 N4 -102.5(3) . .
N3 Ru1 Ru2 N4 -2.9(3) . .
C1 Ru1 Ru2 N8 133.7(7) . .
N5 Ru1 Ru2 N8 -96.9(3) . .
N7 Ru1 Ru2 N8 -10.5(3) . .
N1 Ru1 Ru2 N8 75.8(3) . .
N3 Ru1 Ru2 N8 175.4(3) . .
C1 Ru1 Ru2 N6 -131.9(7) . .
N5 Ru1 Ru2 N6 -2.5(3) . .
N7 Ru1 Ru2 N6 83.9(3) . .
N1 Ru1 Ru2 N6 170.2(3) . .
N3 Ru1 Ru2 N6 -90.2(3) . .
C1 Ru1 N1 C18 -142.8(8) . .
N5 Ru1 N1 C18 72(2) . .
N7 Ru1 N1 C18 112.3(7) . .
N3 Ru1 N1 C18 -60.7(7) . .
Ru2 Ru1 N1 C18 16.4(7) . .
C1 Ru1 N1 C17 43.4(7) . .
N5 Ru1 N1 C17 -101.7(19) . .
N7 Ru1 N1 C17 -61.5(7) . .
N3 Ru1 N1 C17 125.4(7) . .
Ru2 Ru1 N1 C17 -157.4(7) . .
C9 Ru2 N2 C18 -152.3(7) . .
N4 Ru2 N2 C18 111.8(6) . .
N8 Ru2 N2 C18 -64.1(6) . .
N6 Ru2 N2 C18 39(2) . .
Ru1 Ru2 N2 C18 14.6(6) . .
C9 Ru2 N2 C19 32.8(7) . .
N4 Ru2 N2 C19 -63.1(7) . .
N8 Ru2 N2 C19 121.1(7) . .
N6 Ru2 N2 C19 -135.8(19) . .
Ru1 Ru2 N2 C19 -160.2(7) . .
C1 Ru1 N3 C28 167.2(8) . .
N5 Ru1 N3 C28 -91.0(8) . .
N7 Ru1 N3 C28 -41(2) . .
N1 Ru1 N3 C28 82.5(8) . .
Ru2 Ru1 N3 C28 3.4(7) . .
C1 Ru1 N3 C29 -23.2(7) . .
N5 Ru1 N3 C29 78.6(7) . .
N7 Ru1 N3 C29 128.3(18) . .
N1 Ru1 N3 C29 -107.9(6) . .
Ru2 Ru1 N3 C29 173.0(7) . .
N2 Ru2 N4 C28 -88.4(6) . .
C9 Ru2 N4 C28 175.8(6) . .
N8 Ru2 N4 C28 -19(4) . .
N6 Ru2 N4 C28 84.0(6) . .
Ru1 Ru2 N4 C28 3.3(6) . .
N2 Ru2 N4 C35 83.7(9) . .
C9 Ru2 N4 C35 -12.1(9) . .
N8 Ru2 N4 C35 154(3) . .
N6 Ru2 N4 C35 -103.9(9) . .
Ru1 Ru2 N4 C35 175.4(8) . .
C1 Ru1 N5 C41 165.3(6) . .
N7 Ru1 N5 C41 -90.6(6) . .
N1 Ru1 N5 C41 -50(2) . .
N3 Ru1 N5 C41 83.0(6) . .
Ru2 Ru1 N5 C41 4.4(6) . .
C1 Ru1 N5 C42 -34.1(8) . .
N7 Ru1 N5 C42 70.0(7) . .
N1 Ru1 N5 C42 110.2(18) . .
N3 Ru1 N5 C42 -116.4(7) . .
Ru2 Ru1 N5 C42 165.1(7) . .
N2 Ru2 N6 C41 -23(2) . .
C9 Ru2 N6 C41 167.9(7) . .
N4 Ru2 N6 C41 -96.2(7) . .
N8 Ru2 N6 C41 79.5(7) . .
Ru1 Ru2 N6 C41 1.3(7) . .
N2 Ru2 N6 C48 153.7(18) . .
C9 Ru2 N6 C48 -15.0(7) . .
N4 Ru2 N6 C48 81.0(7) . .
N8 Ru2 N6 C48 -103.4(7) . .
Ru1 Ru2 N6 C48 178.4(7) . .
C1 Ru1 N7 C54 -153.7(6) . .
N5 Ru1 N7 C54 105.4(6) . .
N1 Ru1 N7 C54 -68.8(6) . .
N3 Ru1 N7 C54 56(2) . .
Ru2 Ru1 N7 C54 11.7(6) . .
C1 Ru1 N7 C55 35.6(8) . .
N5 Ru1 N7 C55 -65.2(8) . .
N1 Ru1 N7 C55 120.5(8) . .
N3 Ru1 N7 C55 -115.1(19) . .
Ru2 Ru1 N7 C55 -158.9(7) . .
N2 Ru2 N8 C54 105.1(8) . .
C9 Ru2 N8 C54 -159.1(8) . .
N4 Ru2 N8 C54 35(4) . .
N6 Ru2 N8 C54 -67.2(8) . .
Ru1 Ru2 N8 C54 13.1(7) . .
N2 Ru2 N8 C61 -81.3(7) . .
C9 Ru2 N8 C61 14.6(7) . .
N4 Ru2 N8 C61 -151(4) . .
N6 Ru2 N8 C61 106.5(7) . .
Ru1 Ru2 N8 C61 -173.2(7) . .
N5 Ru1 C1 C2 172(18) . .
N7 Ru1 C1 C2 83(18) . .
N1 Ru1 C1 C2 -3(18) . .
N3 Ru1 C1 C2 -101(18) . .
Ru2 Ru1 C1 C2 -60(18) . .
Ru1 C1 C2 C3 -22(66) . .
C1 C2 C3 C8 66(53) . .
C1 C2 C3 C4 -109(53) . .
C8 C3 C4 C5 3(2) . .
C2 C3 C4 C5 178.4(13) . .
C3 C4 C5 C6 -4(3) . .
C4 C5 C6 C7 5(3) . .
C5 C6 C7 C8 -7(3) . .
C4 C3 C8 C7 -4(2) . .
C2 C3 C8 C7 -179.3(15) . .
C6 C7 C8 C3 6(3) . .
N2 Ru2 C9 C10 -16(8) . .
N4 Ru2 C9 C10 74(8) . .
N8 Ru2 C9 C10 -105(8) . .
N6 Ru2 C9 C10 162(8) . .
Ru1 Ru2 C9 C10 -136(7) . .
Ru2 C9 C10 C11 4(42) . .
C9 C10 C11 C12 -154(36) . .
C9 C10 C11 C16 28(36) . .
C16 C11 C12 C13 0.0 . .
C10 C11 C12 C13 -178.0(11) . .
C11 C12 C13 C14 0.0 . .
C12 C13 C14 C15 0.0 . .
C13 C14 C15 C16 0.0 . .
C12 C11 C16 C15 0.0 . .
C10 C11 C16 C15 178.0(11) . .
C14 C15 C16 C11 0.0 . .
C19 N2 C18 N1 168.6(8) . .
Ru2 N2 C18 N1 -6.4(11) . .
C19 N2 C18 C20 -10.0(12) . .
Ru2 N2 C18 C20 175.0(6) . .
C17 N1 C18 N2 163.2(8) . .
Ru1 N1 C18 N2 -10.5(12) . .
C17 N1 C18 C20 -18.2(12) . .
Ru1 N1 C18 C20 168.0(6) . .
N2 C18 C20 C25 -72.5(12) . .
N1 C18 C20 C25 108.9(10) . .
N2 C18 C20 C21 108.6(10) . .
N1 C18 C20 C21 -70.0(12) . .
C25 C20 C21 C22 -2.0(16) . .
C18 C20 C21 C22 176.9(10) . .
C20 C21 C22 C23 2.3(17) . .
C21 C22 C23 C24 -1.4(16) . .
C21 C22 C23 C26 179.9(10) . .
C22 C23 C24 C25 0.2(16) . .
C26 C23 C24 C25 179.0(9) . .
C21 C20 C25 C24 0.9(15) . .
C18 C20 C25 C24 -178.1(9) . .
C23 C24 C25 C20 0.0(16) . .
C24 C23 C26 C27 -78(20) . .
C22 C23 C26 C27 101(20) . .
C23 C26 C27 C27 -107(100) . 5_556
C29 N3 C28 N4 -172.4(8) . .
Ru1 N3 C28 N4 -2.0(13) . .
C35 N4 C28 N3 -174.8(9) . .
Ru2 N4 C28 N3 -1.6(12) . .
C28 N3 C29 C30 87.0(10) . .
Ru1 N3 C29 C30 -83.9(10) . .
C28 N3 C29 C34 -89.1(11) . .
Ru1 N3 C29 C34 100.0(9) . .
C34 C29 C30 C31 -4.4(16) . .
N3 C29 C30 C31 179.4(9) . .
C29 C30 C31 C32 3.3(19) . .
C29 C30 C31 Cl1 -178.8(8) . .
C30 C31 C32 C33 0.0(19) . .
Cl1 C31 C32 C33 -177.9(9) . .
C31 C32 C33 C34 -2.3(19) . .
C31 C32 C33 Cl2 177.3(10) . .
C32 C33 C34 C29 1.2(17) . .
Cl2 C33 C34 C29 -178.4(8) . .
C30 C29 C34 C33 2.2(15) . .
N3 C29 C34 C33 178.3(9) . .
C28 N4 C35 C40 -129.4(10) . .
Ru2 N4 C35 C40 58.8(12) . .
C28 N4 C35 C36 52.0(12) . .
Ru2 N4 C35 C36 -119.8(9) . .
C40 C35 C36 C37 0.4(16) . .
N4 C35 C36 C37 179.0(10) . .
C35 C36 C37 C38 3(2) . .
C35 C36 C37 Cl3 -177.9(9) . .
C36 C37 C38 C39 -3(2) . .
Cl3 C37 C38 C39 177.5(12) . .
C37 C38 C39 C40 0(2) . .
C37 C38 C39 Cl4 177.6(11) . .
C38 C39 C40 C35 2(2) . .
Cl4 C39 C40 C35 -174.8(9) . .
C36 C35 C40 C39 -2.8(16) . .
N4 C35 C40 C39 178.6(10) . .
C48 N6 C41 N5 -175.5(8) . .
Ru2 N6 C41 N5 1.9(13) . .
C42 N5 C41 N6 -167.4(8) . .
Ru1 N5 C41 N6 -4.7(11) . .
C41 N5 C42 C47 -141.2(9) . .
Ru1 N5 C42 C47 58.2(11) . .
C41 N5 C42 C43 42.0(12) . .
Ru1 N5 C42 C43 -118.6(8) . .
C47 C42 C43 C44 -0.4(15) . .
N5 C42 C43 C44 176.4(9) . .
C42 C43 C44 C45 0.9(17) . .
C42 C43 C44 Cl6 -177.6(8) . .
C43 C44 C45 C46 -1.0(18) . .
Cl6 C44 C45 C46 177.5(9) . .
C44 C45 C46 C47 0.5(17) . .
C44 C45 C46 Cl5 178.3(9) . .
C43 C42 C47 C46 -0.1(14) . .
N5 C42 C47 C46 -176.8(8) . .
C45 C46 C47 C42 0.0(16) . .
Cl5 C46 C47 C42 -177.9(7) . .
C41 N6 C48 C53 -116.1(9) . .
Ru2 N6 C48 C53 66.4(10) . .
C41 N6 C48 C49 64.1(12) . .
Ru2 N6 C48 C49 -113.4(9) . .
C53 C48 C49 C50 0.8(16) . .
N6 C48 C49 C50 -179.4(10) . .
C48 C49 C50 C51 3(2) . .
C48 C49 C50 Cl7 179.5(9) . .
C49 C50 C51 C52 -5(2) . .
Cl7 C50 C51 C52 178.8(11) . .
C50 C51 C52 C53 3(2) . .
C50 C51 C52 Cl8 179.5(11) . .
C51 C52 C53 C48 1.0(18) . .
Cl8 C52 C53 C48 -175.3(8) . .
C49 C48 C53 C52 -2.9(15) . .
N6 C48 C53 C52 177.3(9) . .
C61 N8 C54 N7 178.0(8) . .
Ru2 N8 C54 N7 -8.1(13) . .
C55 N7 C54 N8 166.8(8) . .
Ru1 N7 C54 N8 -5.1(11) . .
C54 N7 C55 C60 157.2(8) . .
Ru1 N7 C55 C60 -32.5(12) . .
C54 N7 C55 C56 -28.2(12) . .
Ru1 N7 C55 C56 142.1(8) . .
C60 C55 C56 C57 -3.8(15) . .
N7 C55 C56 C57 -178.4(9) . .
C55 C56 C57 C58 3.6(18) . .
C55 C56 C57 Cl10 -179.0(8) . .
C56 C57 C58 C59 -1(2) . .
Cl10 C57 C58 C59 -179.0(9) . .
C57 C58 C59 C60 -0.4(19) . .
C57 C58 C59 Cl9 179.3(10) . .
C56 C55 C60 C59 2.0(14) . .
N7 C55 C60 C59 176.7(9) . .
C58 C59 C60 C55 0.1(17) . .
Cl9 C59 C60 C55 -179.6(7) . .
C54 N8 C61 C66 -114.6(10) . .
Ru2 N8 C61 C66 70.9(10) . .
C54 N8 C61 C62 67.1(11) . .
Ru2 N8 C61 C62 -107.4(9) . .
C66 C61 C62 C63 -0.4(15) . .
N8 C61 C62 C63 177.9(9) . .
C61 C62 C63 C64 1.3(17) . .
C61 C62 C63 Cl11 -178.2(8) . .
C62 C63 C64 C65 -2(2) . .
Cl11 C63 C64 C65 177.3(10) . .
C63 C64 C65 C66 2(2) . .
C63 C64 C65 Cl12 -176.1(10) . .
C64 C65 C66 C61 -1(2) . .
Cl12 C65 C66 C61 177.0(9) . .
C62 C61 C66 C65 0.4(17) . .
N8 C61 C66 C65 -177.9(11) . .
C104 O1 C101 C102 0.0 . .
O1 C101 C102 C103 0.0 . .
C101 C102 C103 C104 0.0 . .
C102 C103 C104 O1 0.0 . .
C101 O1 C104 C103 0.0 . .
C204 O2 C201 C202 0.0 . .
O2 C201 C202 C203 0.0 . .
C201 C202 C203 C204 0.0 . .
C202 C203 C204 O2 0.0 . .
C201 O2 C204 C203 0.0 . .
C301 O3 C301 O3 0.000(3) 5_566 5_566
C404 O4 C401 C402 0.0 . .
O4 C401 C402 C403 0.0 . .
C401 C402 C403 C404 0.0 . .
C402 C403 C404 O4 0.0 . .
C401 O4 C404 C403 0.0 . .
