#------------------------------------------------------------------------------
#$Date: 2016-03-23 21:00:38 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179435 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/32/4333295.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_4333295
loop_
_publ_author_name
'Manzur, Jorge'
'Mora, Hector'
'Vega, Andrés'
'Spodine, Evgenia'
'Venegas-Yazigi, Diego'
'Garland, María Teresa'
'El Fallah, M. Salah'
'Escuer, Albert'
_publ_section_title
;
 Copper(II) Complexes with New Polypodal Ligands Presenting
 Axial−Equatorial Phenoxo Bridges
 {2-[(Bis(2-pyridylmethyl)amino)methyl]-4-methylphenol,
 2-[(Bis(2-pyridylmethyl)amino)methyl]-4-methyl-6-(methylthio)phenol}: 
 Examples of Ferromagnetically Coupled Bi- and Trinuclear Copper(II)
 Complexes
;
_journal_issue                   17
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6924
_journal_page_last               6932
_journal_paper_doi               10.1021/ic700544b
_journal_volume                  46
_journal_year                    2007
_chemical_formula_moiety         'C40 H40 Cu2 N6 O2, 2(P F6)'
_chemical_formula_sum            'C40 H40 Cu2 F12 N6 O2 P2'
_chemical_formula_weight         1053.80
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 107.422(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   11.2421(13)
_cell_length_b                   16.7619(19)
_cell_length_c                   11.9655(14)
_cell_measurement_reflns_used    2910
_cell_measurement_temperature    299(2)
_cell_measurement_theta_max      20.062
_cell_measurement_theta_min      2.159
_cell_volume                     2151.3(4)
_computing_cell_refinement       'SAINT-NT (Bruker, 1999)'
_computing_data_collection       'SMART-NT (Bruker, 2001)'
_computing_data_reduction        'SAINT-NT (Bruker, 1999)'
_computing_molecular_graphics    'SHELXTL-NT (Bruker, 2000)'
_computing_publication_material  'SHELXTL-NT (Bruker, 2000)'
_computing_structure_refinement  'SHELXTL-NT (Bruker, 2000)'
_computing_structure_solution    'SHELXTL-NT (Bruker, 2000)'
_diffrn_ambient_temperature      299(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Siemens SMART CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0400
_diffrn_reflns_av_sigmaI/netI    0.0401
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            13278
_diffrn_reflns_theta_full        25.08
_diffrn_reflns_theta_max         25.08
_diffrn_reflns_theta_min         2.16
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.159
_exptl_absorpt_correction_T_max  0.8363
_exptl_absorpt_correction_T_min  0.6536
_exptl_absorpt_correction_type   refdelf
_exptl_absorpt_process_details   '(SADABS in SAINT-NT; Bruker, 1999)'
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.627
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       polyhedron
_exptl_crystal_F_000             1068
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.16
_refine_diff_density_max         0.592
_refine_diff_density_min         -0.251
_refine_diff_density_rms         0.065
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.042
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     290
_refine_ls_number_reflns         3815
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.042
_refine_ls_R_factor_all          0.0628
_refine_ls_R_factor_gt           0.0467
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0680P)²+0.7803P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1200
_refine_ls_wR_factor_ref         0.1301
_reflns_number_gt                2917
_reflns_number_total             3815
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic700544bsup1.cif
_cod_data_source_block           III
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4333295
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Cu Cu 1.02974(4) 0.06696(2) 0.42217(3) 0.04930(18) Uani 1 1 d .
N1 N 0.9009(3) 0.14803(17) 0.4264(2) 0.0543(7) Uani 1 1 d .
C1 C 0.8759(4) 0.1748(2) 0.5224(4) 0.0728(12) Uani 1 1 d .
H1 H 0.9288 0.1609 0.5958 0.087 Uiso 1 1 calc R
C2 C 0.7747(6) 0.2218(3) 0.5153(5) 0.0991(17) Uani 1 1 d .
H2 H 0.7601 0.2404 0.5832 0.119 Uiso 1 1 calc R
C3 C 0.6957(5) 0.2414(3) 0.4090(5) 0.1032(19) Uani 1 1 d .
H3 H 0.6264 0.2732 0.4032 0.124 Uiso 1 1 calc R
C4 C 0.7196(4) 0.2135(3) 0.3099(4) 0.0813(13) Uani 1 1 d .
H4 H 0.6659 0.2257 0.2362 0.098 Uiso 1 1 calc R
C5 C 0.8232(3) 0.1676(2) 0.3207(3) 0.0571(9) Uani 1 1 d .
C6 C 0.8581(4) 0.1406(2) 0.2167(3) 0.0661(10) Uani 1 1 d .
H6A H 0.7863 0.1158 0.1614 0.079 Uiso 1 1 calc R
H6B H 0.8814 0.1865 0.1786 0.079 Uiso 1 1 calc R
N2 N 1.1849(3) 0.0358(2) 0.3814(3) 0.0614(8) Uani 1 1 d .
C10 C 1.2784(4) -0.0112(3) 0.4412(4) 0.0778(13) Uani 1 1 d .
H10 H 1.2802 -0.0302 0.5147 0.093 Uiso 1 1 calc R
C11 C 1.3729(4) -0.0318(4) 0.3937(6) 0.109(2) Uani 1 1 d .
H11 H 1.4359 -0.0665 0.4334 0.131 Uiso 1 1 calc R
C12 C 1.3726(6) -0.0008(4) 0.2890(7) 0.120(3) Uani 1 1 d .
H12 H 1.4379 -0.0118 0.2586 0.144 Uiso 1 1 calc R
C13 C 1.2779(5) 0.0457(4) 0.2294(5) 0.0998(18) Uani 1 1 d .
H13 H 1.2761 0.0659 0.1565 0.120 Uiso 1 1 calc R
C14 C 1.1833(4) 0.0635(3) 0.2762(4) 0.0701(12) Uani 1 1 d .
C15 C 1.0727(4) 0.1134(3) 0.2166(3) 0.0713(11) Uani 1 1 d .
H15A H 1.0882 0.1685 0.2414 0.086 Uiso 1 1 calc R
H15B H 1.0572 0.1112 0.1324 0.086 Uiso 1 1 calc R
O1 O 0.9253(2) -0.04379(14) 0.41298(19) 0.0548(6) Uani 1 1 d .
C20 C 0.8238(3) -0.06260(19) 0.3240(3) 0.0487(8) Uani 1 1 d .
C21 C 0.7268(3) -0.1084(2) 0.3386(3) 0.0556(9) Uani 1 1 d .
H21 H 0.7311 -0.1280 0.4125 0.067 Uiso 1 1 calc R
C22 C 0.6232(3) -0.1253(2) 0.2442(3) 0.0612(10) Uani 1 1 d .
H22 H 0.5590 -0.1557 0.2562 0.073 Uiso 1 1 calc R
C23 C 0.6131(3) -0.0981(2) 0.1331(3) 0.0631(10) Uani 1 1 d .
C24 C 0.7107(3) -0.0540(2) 0.1193(3) 0.0577(9) Uani 1 1 d .
H24 H 0.7055 -0.0353 0.0449 0.069 Uiso 1 1 calc R
C25 C 0.8172(3) -0.0357(2) 0.2112(3) 0.0500(8) Uani 1 1 d .
C26 C 0.9249(3) 0.0042(2) 0.1868(3) 0.0530(9) Uani 1 1 d .
H26A H 0.9048 0.0125 0.1030 0.064 Uiso 1 1 calc R
H26B H 0.9959 -0.0316 0.2098 0.064 Uiso 1 1 calc R
C28 C 0.5016(4) -0.1187(3) 0.0292(4) 0.0897(14) Uani 1 1 d .
H28A H 0.4268 -0.0998 0.0434 0.134 Uiso 1 1 calc R
H28B H 0.4969 -0.1754 0.0185 0.134 Uiso 1 1 calc R
H28C H 0.5106 -0.0937 -0.0400 0.134 Uiso 1 1 calc R
N3 N 0.9629(3) 0.08291(17) 0.2471(2) 0.0536(7) Uani 1 1 d .
P1 P 0.32465(11) 0.29622(7) 0.37979(9) 0.0681(3) Uani 1 1 d .
F1 F 0.2004(3) 0.3062(2) 0.2769(3) 0.1151(10) Uani 1 1 d .
F2 F 0.2961(3) 0.37652(18) 0.4361(3) 0.1097(10) Uani 1 1 d .
F3 F 0.4448(3) 0.2842(3) 0.4854(3) 0.1402(14) Uani 1 1 d .
F4 F 0.3520(3) 0.21681(19) 0.3244(3) 0.1249(12) Uani 1 1 d .
F5 F 0.2476(3) 0.2507(2) 0.4505(3) 0.1362(13) Uani 1 1 d .
F6 F 0.3967(4) 0.3421(2) 0.3080(3) 0.1359(13) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Cu N1 94.67(11) 3_756 .
O1 Cu N2 102.42(12) 3_756 .
N1 Cu N2 150.33(13) . .
O1 Cu N3 172.72(11) 3_756 .
N1 Cu N3 83.61(12) . .
N2 Cu N3 82.16(13) . .
O1 Cu O1 81.50(10) 3_756 .
N1 Cu O1 101.33(11) . .
N2 Cu O1 105.02(12) . .
N3 Cu O1 91.88(10) . .
C1 N1 C5 118.8(3) . .
C1 N1 Cu 126.1(3) . .
C5 N1 Cu 114.4(2) . .
N1 C1 C2 121.6(4) . .
N1 C1 H1 119.2 . .
C2 C1 H1 119.2 . .
C3 C2 C1 119.9(5) . .
C3 C2 H2 120.1 . .
C1 C2 H2 120.1 . .
C2 C3 C4 119.0(4) . .
C2 C3 H3 120.5 . .
C4 C3 H3 120.5 . .
C5 C4 C3 119.4(4) . .
C5 C4 H4 120.3 . .
C3 C4 H4 120.3 . .
N1 C5 C4 121.3(4) . .
N1 C5 C6 117.0(3) . .
C4 C5 C6 121.6(4) . .
N3 C6 C5 112.5(3) . .
N3 C6 H6A 109.1 . .
C5 C6 H6A 109.1 . .
N3 C6 H6B 109.1 . .
C5 C6 H6B 109.1 . .
H6A C6 H6B 107.8 . .
C14 N2 C10 119.7(4) . .
C14 N2 Cu 111.7(3) . .
C10 N2 Cu 128.5(3) . .
N2 C10 C11 120.1(5) . .
N2 C10 H10 119.9 . .
C11 C10 H10 119.9 . .
C12 C11 C10 119.5(6) . .
C12 C11 H11 120.2 . .
C10 C11 H11 120.2 . .
C13 C12 C11 119.8(5) . .
C13 C12 H12 120.1 . .
C11 C12 H12 120.1 . .
C12 C13 C14 119.8(6) . .
C12 C13 H13 120.1 . .
C14 C13 H13 120.1 . .
N2 C14 C13 120.9(5) . .
N2 C14 C15 114.8(3) . .
C13 C14 C15 124.2(5) . .
N3 C15 C14 109.1(3) . .
N3 C15 H15A 109.9 . .
C14 C15 H15A 109.9 . .
N3 C15 H15B 109.9 . .
C14 C15 H15B 109.9 . .
H15A C15 H15B 108.3 . .
C20 O1 Cu 131.7(2) . 3_756
C20 O1 Cu 123.8(2) . .
Cu O1 Cu 98.50(10) 3_756 .
O1 C20 C21 122.9(3) . .
O1 C20 C25 118.3(3) . .
C21 C20 C25 118.8(3) . .
C22 C21 C20 120.7(3) . .
C22 C21 H21 119.7 . .
C20 C21 H21 119.7 . .
C23 C22 C21 121.7(4) . .
C23 C22 H22 119.1 . .
C21 C22 H22 119.1 . .
C24 C23 C22 117.1(3) . .
C24 C23 C28 121.2(4) . .
C22 C23 C28 121.7(4) . .
C23 C24 C25 123.5(4) . .
C23 C24 H24 118.2 . .
C25 C24 H24 118.2 . .
C24 C25 C20 118.2(3) . .
C24 C25 C26 120.1(3) . .
C20 C25 C26 121.4(3) . .
C25 C26 N3 115.5(3) . .
C25 C26 H26A 108.4 . .
N3 C26 H26A 108.4 . .
C25 C26 H26B 108.4 . .
N3 C26 H26B 108.4 . .
H26A C26 H26B 107.5 . .
C23 C28 H28A 109.5 . .
C23 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
C23 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
C15 N3 C6 112.0(3) . .
C15 N3 C26 108.8(3) . .
C6 N3 C26 111.3(3) . .
C15 N3 Cu 102.9(2) . .
C6 N3 Cu 111.3(2) . .
C26 N3 Cu 110.2(2) . .
F6 P1 F4 89.2(2) . .
F6 P1 F3 92.5(2) . .
F4 P1 F3 90.03(19) . .
F6 P1 F1 90.1(2) . .
F4 P1 F1 90.00(18) . .
F3 P1 F1 177.4(2) . .
F6 P1 F5 178.3(2) . .
F4 P1 F5 91.4(2) . .
F3 P1 F5 89.1(2) . .
F1 P1 F5 88.3(2) . .
F6 P1 F2 91.19(19) . .
F4 P1 F2 179.6(2) . .
F3 P1 F2 90.11(18) . .
F1 P1 F2 89.84(17) . .
F5 P1 F2 88.2(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cu O1 1.924(2) 3_756
Cu N1 1.998(3) .
Cu N2 2.015(3) .
Cu N3 2.020(3) .
Cu O1 2.182(2) .
Cu Cu 3.1147(8) 3_756
N1 C1 1.339(5) .
N1 C5 1.345(4) .
C1 C2 1.366(6) .
C1 H1 0.9300 .
C2 C3 1.356(7) .
C2 H2 0.9300 .
C3 C4 1.373(7) .
C3 H3 0.9300 .
C4 C5 1.370(6) .
C4 H4 0.9300 .
C5 C6 1.483(5) .
C6 N3 1.483(5) .
C6 H6A 0.9700 .
C6 H6B 0.9700 .
N2 C14 1.336(5) .
N2 C10 1.337(5) .
C10 C11 1.390(7) .
C10 H10 0.9300 .
C11 C12 1.355(9) .
C11 H11 0.9300 .
C12 C13 1.340(8) .
C12 H12 0.9300 .
C13 C14 1.376(6) .
C13 H13 0.9300 .
C14 C15 1.491(6) .
C15 N3 1.479(5) .
C15 H15A 0.9700 .
C15 H15B 0.9700 .
O1 C20 1.344(4) .
O1 Cu 1.924(2) 3_756
C20 C21 1.388(5) .
C20 C25 1.404(5) .
C21 C22 1.387(5) .
C21 H21 0.9300 .
C22 C23 1.377(5) .
C22 H22 0.9300 .
C23 C24 1.374(5) .
C23 C28 1.517(5) .
C24 C25 1.395(5) .
C24 H24 0.9300 .
C25 C26 1.487(5) .
C26 N3 1.503(4) .
C26 H26A 0.9700 .
C26 H26B 0.9700 .
C28 H28A 0.9600 .
C28 H28B 0.9600 .
C28 H28C 0.9600 .
P1 F6 1.549(3) .
P1 F4 1.558(3) .
P1 F3 1.563(3) .
P1 F1 1.570(3) .
P1 F5 1.576(3) .
P1 F2 1.581(3) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 Cu N1 C1 5.2(3) 3_756 .
N2 Cu N1 C1 -120.2(4) . .
N3 Cu N1 C1 178.1(3) . .
O1 Cu N1 C1 87.4(3) . .
O1 Cu N1 C5 -165.2(3) 3_756 .
N2 Cu N1 C5 69.4(4) . .
N3 Cu N1 C5 7.6(3) . .
O1 Cu N1 C5 -83.0(3) . .
C5 N1 C1 C2 -0.7(6) . .
Cu N1 C1 C2 -170.7(4) . .
N1 C1 C2 C3 1.1(8) . .
C1 C2 C3 C4 -0.3(9) . .
C2 C3 C4 C5 -0.8(8) . .
C1 N1 C5 C4 -0.5(6) . .
Cu N1 C5 C4 170.7(3) . .
C1 N1 C5 C6 176.7(3) . .
Cu N1 C5 C6 -12.2(4) . .
C3 C4 C5 N1 1.2(7) . .
C3 C4 C5 C6 -175.8(4) . .
N1 C5 C6 N3 10.6(5) . .
C4 C5 C6 N3 -172.3(4) . .
O1 Cu N2 C14 -166.3(3) 3_756 .
N1 Cu N2 C14 -42.6(4) . .
N3 Cu N2 C14 19.5(3) . .
O1 Cu N2 C14 109.3(3) . .
O1 Cu N2 C10 18.7(3) 3_756 .
N1 Cu N2 C10 142.4(3) . .
N3 Cu N2 C10 -155.6(3) . .
O1 Cu N2 C10 -65.7(3) . .
C14 N2 C10 C11 -0.6(6) . .
Cu N2 C10 C11 174.1(3) . .
N2 C10 C11 C12 3.1(7) . .
C10 C11 C12 C13 -3.6(9) . .
C11 C12 C13 C14 1.8(9) . .
C10 N2 C14 C13 -1.3(6) . .
Cu N2 C14 C13 -176.9(3) . .
C10 N2 C14 C15 178.3(3) . .
Cu N2 C14 C15 2.8(4) . .
C12 C13 C14 N2 0.8(7) . .
C12 C13 C14 C15 -178.9(5) . .
N2 C14 C15 N3 -33.9(5) . .
C13 C14 C15 N3 145.8(4) . .
O1 Cu O1 C20 155.4(3) 3_756 .
N1 Cu O1 C20 62.3(3) . .
N2 Cu O1 C20 -104.0(3) . .
N3 Cu O1 C20 -21.6(3) . .
O1 Cu O1 Cu 0.0 3_756 3_756
N1 Cu O1 Cu -93.10(12) . 3_756
N2 Cu O1 Cu 100.66(13) . 3_756
N3 Cu O1 Cu -176.95(12) . 3_756
Cu O1 C20 C21 -1.9(5) 3_756 .
Cu O1 C20 C21 -148.4(3) . .
Cu O1 C20 C25 179.2(2) 3_756 .
Cu O1 C20 C25 32.7(4) . .
O1 C20 C21 C22 179.1(3) . .
C25 C20 C21 C22 -1.9(5) . .
C20 C21 C22 C23 0.5(6) . .
C21 C22 C23 C24 0.6(6) . .
C21 C22 C23 C28 178.2(4) . .
C22 C23 C24 C25 -0.2(6) . .
C28 C23 C24 C25 -177.8(4) . .
C23 C24 C25 C20 -1.2(6) . .
C23 C24 C25 C26 172.8(3) . .
O1 C20 C25 C24 -178.8(3) . .
C21 C20 C25 C24 2.3(5) . .
O1 C20 C25 C26 7.2(5) . .
C21 C20 C25 C26 -171.7(3) . .
C24 C25 C26 N3 121.5(4) . .
C20 C25 C26 N3 -64.6(4) . .
C14 C15 N3 C6 165.5(3) . .
C14 C15 N3 C26 -71.0(4) . .
C14 C15 N3 Cu 45.9(3) . .
C5 C6 N3 C15 -118.4(4) . .
C5 C6 N3 C26 119.5(3) . .
C5 C6 N3 Cu -3.9(4) . .
C25 C26 N3 C15 178.4(3) . .
C25 C26 N3 C6 -57.6(4) . .
C25 C26 N3 Cu 66.3(3) . .
N1 Cu N3 C15 118.4(2) . .
N2 Cu N3 C15 -35.5(2) . .
O1 Cu N3 C15 -140.4(2) . .
N1 Cu N3 C6 -1.7(2) . .
N2 Cu N3 C6 -155.6(3) . .
O1 Cu N3 C6 99.5(2) . .
N1 Cu N3 C26 -125.7(2) . .
N2 Cu N3 C26 80.4(2) . .
O1 Cu N3 C26 -24.5(2) . .
