#------------------------------------------------------------------------------
#$Date: 2016-03-23 21:18:00 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179446 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/43/4334304.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4334304
loop_
_publ_author_name
'Hao-Ling Sun'
'Dan-Dan Yin'
'Qi Chen'
'Zhenqiang Wang'
_publ_section_title
;
 Europium Pyrimidine-4,6-dicarboxylate Framework with a
 Single-Crystal-to-Single-Crystal Transition and a Reversible
 Dehydration/Rehydration Process
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3582
_journal_page_last               3584
_journal_paper_doi               10.1021/ic302556r
_journal_volume                  52
_journal_year                    2013
_chemical_formula_sum            'C12 H12 Eu2 N4 O13'
_chemical_formula_weight         724.18
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 94.433(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   7.5721(8)
_cell_length_b                   15.5950(17)
_cell_length_c                   16.7063(19)
_cell_measurement_reflns_used    3054
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      26.38
_cell_measurement_theta_min      2.45
_cell_volume                     1966.9(4)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0393
_diffrn_reflns_av_sigmaI/netI    0.0471
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            10375
_diffrn_reflns_theta_full        26.02
_diffrn_reflns_theta_max         26.02
_diffrn_reflns_theta_min         3.58
_exptl_absorpt_coefficient_mu    6.395
_exptl_absorpt_correction_T_max  0.7840
_exptl_absorpt_correction_T_min  0.3611
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.446
_exptl_crystal_description       needle
_exptl_crystal_F_000             1368
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.04
_refine_diff_density_max         0.784
_refine_diff_density_min         -0.888
_refine_diff_density_rms         0.163
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.005
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     314
_refine_ls_number_reflns         3858
_refine_ls_number_restraints     36
_refine_ls_restrained_S_all      1.000
_refine_ls_R_factor_all          0.0365
_refine_ls_R_factor_gt           0.0267
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0172P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0483
_refine_ls_wR_factor_ref         0.0512
_reflns_number_gt                3232
_reflns_number_total             3858
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic302556r_si_002.cif
_cod_data_source_block           120310b_0m
_cod_database_code               4334304
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.7416(6) 0.1925(3) 0.5494(3) 0.0143(11) Uani 1 1 d .
C2 C 0.5999(6) 0.2352(3) 0.5947(3) 0.0145(11) Uani 1 1 d .
C3 C 0.6436(7) 0.2902(3) 0.6578(3) 0.0180(12) Uani 1 1 d .
H3A H 0.7602 0.3069 0.6711 0.022 Uiso 1 1 calc R
C4 C 0.5052(7) 0.3198(3) 0.7008(3) 0.0149(11) Uani 1 1 d .
C5 C 0.5447(7) 0.3672(3) 0.7790(3) 0.0179(12) Uani 1 1 d .
C6 C 0.3078(7) 0.2542(4) 0.6122(3) 0.0252(13) Uani 1 1 d .
H6A H 0.1905 0.2454 0.5932 0.030 Uiso 1 1 calc R
C7 C -0.2004(6) 0.0472(3) 0.6803(3) 0.0161(11) Uani 1 1 d .
C8 C -0.0426(7) 0.0882(3) 0.7266(3) 0.0165(11) Uani 1 1 d .
C9 C -0.0619(7) 0.1523(3) 0.7818(3) 0.0175(12) Uani 1 1 d .
H9A H -0.1729 0.1728 0.7926 0.021 Uiso 1 1 calc R
C10 C 0.0919(7) 0.1849(3) 0.8203(3) 0.0167(11) Uani 1 1 d .
C11 C 0.0897(7) 0.2610(3) 0.8769(3) 0.0184(12) Uani 1 1 d .
C12 C 0.2534(7) 0.0921(3) 0.7543(3) 0.0233(13) Uani 1 1 d .
H12A H 0.3641 0.0693 0.7460 0.028 Uiso 1 1 calc R
N1 N 0.4324(5) 0.2154(3) 0.5718(2) 0.0144(9) Uani 1 1 d .
N2 N 0.3359(5) 0.3034(3) 0.6763(3) 0.0236(11) Uani 1 1 d .
N3 N 0.1163(5) 0.0590(3) 0.7101(3) 0.0177(10) Uani 1 1 d .
N4 N 0.2504(5) 0.1532(3) 0.8085(3) 0.0243(11) Uani 1 1 d .
O1 O 0.6869(4) 0.1406(2) 0.4935(2) 0.0161(8) Uani 1 1 d .
O2 O 0.8976(4) 0.2071(2) 0.5712(2) 0.0294(10) Uani 1 1 d .
O3 O 0.6890(5) 0.4043(2) 0.7890(2) 0.0235(9) Uani 1 1 d .
O4 O 0.4284(5) 0.3626(2) 0.8282(2) 0.0311(10) Uani 1 1 d .
O5 O -0.1648(4) -0.0086(2) 0.6270(2) 0.0172(8) Uani 1 1 d .
O6 O -0.3498(5) 0.0710(2) 0.6937(2) 0.0257(9) Uani 1 1 d .
O7 O -0.0422(5) 0.3107(2) 0.8667(2) 0.0313(10) Uani 1 1 d .
O8 O 0.2168(5) 0.2705(2) 0.9273(2) 0.0204(8) Uani 1 1 d .
O9 O 0.0924(5) 0.0755(2) 0.5130(2) 0.0123(8) Uani 1 1 d .
O10 O 0.4200(5) 0.0090(2) 0.5725(2) 0.0119(8) Uani 1 1 d .
Eu1 Eu 0.37389(3) 0.102260(15) 0.459947(15) 0.00903(7) Uani 1 1 d .
Eu2 Eu 0.13348(3) -0.050509(15) 0.594338(14) 0.00921(7) Uani 1 1 d .
O11 O -0.37(3) 0.150(11) 0.908(10) 1.39(11) Uani 0.80 1 d PU
O12 O 0.92(5) 0.43(2) 0.66(2) 1.6(2) Uani 0.50 1 d PU
O13 O -0.33(4) -0.04(2) 1.01(2) 1.35(18) Uani 0.50 1 d PU
O14 O -0.14(5) 0.04(2) 0.931(17) 1.5(2) Uani 0.50 1 d PU
O15 O -0.28(6) -0.20(3) 1.02(3) 1.8(2) Uani 0.50 1 d PU
O16 O -0.38(6) -0.03(2) 0.86(2) 0.9(2) Uani 0.20 1 d PU
H9 H 0.072(8) 0.106(4) 0.531(4) 0.018(14) Uiso 1 1 d .
H10 H 0.458(7) 0.033(3) 0.605(3) 0.018(14) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 C1 O1 125.5(4) . .
O2 C1 C2 118.2(4) . .
O1 C1 C2 116.2(4) . .
N1 C2 C3 122.0(4) . .
N1 C2 C1 116.8(4) . .
C3 C2 C1 121.2(4) . .
C2 C3 C4 117.0(5) . .
C2 C3 H3A 121.5 . .
C4 C3 H3A 121.5 . .
N2 C4 C3 121.3(5) . .
N2 C4 C5 118.6(4) . .
C3 C4 C5 120.1(5) . .
O3 C5 O4 126.7(5) . .
O3 C5 C4 117.4(4) . .
O4 C5 C4 115.9(5) . .
N2 C6 N1 126.4(5) . .
N2 C6 H6A 116.8 . .
N1 C6 H6A 116.8 . .
O6 C7 O5 125.2(5) . .
O6 C7 C8 118.7(4) . .
O5 C7 C8 116.0(4) . .
N3 C8 C9 122.0(5) . .
N3 C8 C7 116.0(4) . .
C9 C8 C7 121.9(4) . .
C8 C9 C10 116.7(5) . .
C8 C9 H9A 121.6 . .
C10 C9 H9A 121.6 . .
N4 C10 C9 122.3(5) . .
N4 C10 C11 115.9(5) . .
C9 C10 C11 121.8(4) . .
O8 C11 O7 125.5(5) . .
O8 C11 C10 118.2(5) . .
O7 C11 C10 116.3(5) . .
O8 C11 Eu1 34.9(2) . 4_566
O7 C11 Eu1 98.3(3) . 4_566
C10 C11 Eu1 137.5(3) . 4_566
N4 C12 N3 127.5(5) . .
N4 C12 H12A 116.3 . .
N3 C12 H12A 116.3 . .
C2 N1 C6 116.2(4) . .
C2 N1 Eu1 118.2(3) . .
C6 N1 Eu1 125.6(3) . .
C6 N2 C4 116.6(4) . .
C12 N3 C8 115.5(4) . .
C12 N3 Eu2 126.0(3) . .
C8 N3 Eu2 118.5(3) . .
C12 N4 C10 115.8(5) . .
C1 O1 Eu1 124.7(3) . .
C1 O1 Eu2 128.5(3) . 3_656
Eu1 O1 Eu2 106.64(12) . 3_656
C5 O3 Eu2 133.2(3) . 2_656
C5 O4 Eu1 142.1(4) . 4_566
C7 O5 Eu2 125.4(3) . .
C7 O5 Eu1 129.2(3) . 3_556
Eu2 O5 Eu1 105.36(12) . 3_556
C11 O7 Eu2 139.8(4) . 2_556
C11 O8 O15 120(10) . 3_557
C11 O8 Eu1 127.6(3) . 4_566
O15 O8 Eu1 112(10) 3_557 4_566
Eu2 O9 Eu1 105.73(14) . .
Eu2 O9 Eu2 110.01(14) . 3_556
Eu1 O9 Eu2 110.55(14) . 3_556
Eu2 O9 H9 114(7) . .
Eu1 O9 H9 109(6) . .
Eu2 O9 H9 108(7) 3_556 .
Eu1 O10 Eu2 106.00(14) . .
Eu1 O10 Eu1 108.58(13) . 3_656
Eu2 O10 Eu1 111.14(14) . 3_656
Eu1 O10 H10 107(5) . .
Eu2 O10 H10 114(5) . .
Eu1 O10 H10 109(5) 3_656 .
O4 Eu1 O8 72.95(12) 4_565 4_565
O4 Eu1 O10 149.49(12) 4_565 .
O8 Eu1 O10 137.56(12) 4_565 .
O4 Eu1 O9 127.87(14) 4_565 .
O8 Eu1 O9 77.62(12) 4_565 .
O10 Eu1 O9 71.54(12) . .
O4 Eu1 O10 78.10(12) 4_565 3_656
O8 Eu1 O10 150.92(12) 4_565 3_656
O10 Eu1 O10 71.42(13) . 3_656
O9 Eu1 O10 124.22(12) . 3_656
O4 Eu1 O1 85.43(13) 4_565 .
O8 Eu1 O1 107.90(12) 4_565 .
O10 Eu1 O1 83.63(12) . .
O9 Eu1 O1 145.17(12) . .
O10 Eu1 O1 66.44(11) 3_656 .
O4 Eu1 O5 75.12(13) 4_565 3_556
O8 Eu1 O5 94.08(12) 4_565 3_556
O10 Eu1 O5 98.48(12) . 3_556
O9 Eu1 O5 65.08(11) . 3_556
O10 Eu1 O5 81.00(11) 3_656 3_556
O1 Eu1 O5 144.95(10) . 3_556
O4 Eu1 N1 119.24(14) 4_565 .
O8 Eu1 N1 69.36(13) 4_565 .
O10 Eu1 N1 80.76(12) . .
O9 Eu1 N1 87.63(12) . .
O10 Eu1 N1 124.99(13) 3_656 .
O1 Eu1 N1 64.03(11) . .
O5 Eu1 N1 151.00(11) 3_556 .
O4 Eu1 C11 66.69(13) 4_565 4_565
O8 Eu1 C11 17.49(13) 4_565 4_565
O10 Eu1 C11 141.90(12) . 4_565
O9 Eu1 C11 72.33(13) . 4_565
O10 Eu1 C11 142.01(12) 3_656 4_565
O1 Eu1 C11 121.91(12) . 4_565
O5 Eu1 C11 76.72(12) 3_556 4_565
N1 Eu1 C11 86.10(13) . 4_565
O4 Eu1 Eu2 145.61(10) 4_565 .
O8 Eu1 Eu2 113.92(8) 4_565 .
O10 Eu1 Eu2 37.29(8) . .
O9 Eu1 Eu2 37.03(9) . .
O10 Eu1 Eu2 91.67(8) 3_656 .
O1 Eu1 Eu2 120.65(8) . .
O5 Eu1 Eu2 70.86(8) 3_556 .
N1 Eu1 Eu2 93.63(9) . .
C11 Eu1 Eu2 109.17(9) 4_565 .
O4 Eu1 Eu1 113.44(9) 4_565 3_656
O8 Eu1 Eu1 173.33(9) 4_565 3_656
O10 Eu1 Eu1 36.07(8) . 3_656
O9 Eu1 Eu1 98.97(9) . 3_656
O10 Eu1 Eu1 35.35(8) 3_656 3_656
O1 Eu1 Eu1 71.58(8) . 3_656
O5 Eu1 Eu1 89.59(8) 3_556 3_656
N1 Eu1 Eu1 104.96(9) . 3_656
C11 Eu1 Eu1 165.89(9) 4_565 3_656
Eu2 Eu1 Eu1 62.125(9) . 3_656
O4 Eu1 Eu2 94.07(10) 4_565 3_556
O8 Eu1 Eu2 69.84(9) 4_565 3_556
O10 Eu1 Eu2 97.86(8) . 3_556
O9 Eu1 Eu2 34.77(9) . 3_556
O10 Eu1 Eu2 115.65(8) 3_656 3_556
O1 Eu1 Eu2 177.71(8) . 3_556
O5 Eu1 Eu2 36.65(7) 3_556 3_556
N1 Eu1 Eu2 114.44(9) . 3_556
C11 Eu1 Eu2 55.93(9) 4_565 3_556
Eu2 Eu1 Eu2 60.719(8) . 3_556
Eu1 Eu1 Eu2 110.632(11) 3_656 3_556
O4 Eu1 H9 129.5(14) 4_565 .
O8 Eu1 H9 69.5(13) 4_565 .
O10 Eu1 H9 74.9(14) . .
O9 Eu1 H9 12.0(12) . .
O10 Eu1 H9 134.9(12) 3_656 .
O1 Eu1 H9 137.7(14) . .
O5 Eu1 H9 75.2(13) 3_556 .
N1 Eu1 H9 76.7(13) . .
C11 Eu1 H9 67.3(14) 4_565 .
Eu2 Eu1 H9 44.5(13) . .
Eu1 Eu1 H9 106.2(13) 3_656 .
Eu2 Eu1 H9 41.6(14) 3_556 .
O4 Eu1 H10 153.9(12) 4_565 .
O8 Eu1 H10 128.9(11) 4_565 .
O10 Eu1 H10 14.5(11) . .
O9 Eu1 H10 75.7(12) . .
O10 Eu1 H10 78.6(12) 3_656 .
O1 Eu1 H10 74.6(12) . .
O5 Eu1 H10 112.4(11) 3_556 .
N1 Eu1 H10 66.7(11) . .
C11 Eu1 H10 138.5(12) 4_565 .
Eu2 Eu1 H10 46.5(12) . .
Eu1 Eu1 H10 44.5(11) 3_656 .
Eu2 Eu1 H10 106.5(12) 3_556 .
H9 Eu1 H10 76.0(19) . .
O7 Eu2 O3 70.44(13) 2_546 2_646
O7 Eu2 O9 150.94(13) 2_546 .
O3 Eu2 O9 138.18(13) 2_646 .
O7 Eu2 O9 81.48(13) 2_546 3_556
O3 Eu2 O9 151.82(13) 2_646 3_556
O9 Eu2 O9 69.99(15) . 3_556
O7 Eu2 O10 132.47(13) 2_546 .
O3 Eu2 O10 77.34(12) 2_646 .
O9 Eu2 O10 71.18(12) . .
O9 Eu2 O10 122.93(12) 3_556 .
O7 Eu2 O5 83.66(13) 2_546 .
O3 Eu2 O5 111.57(12) 2_646 .
O9 Eu2 O5 79.97(12) . .
O9 Eu2 O5 66.19(12) 3_556 .
O10 Eu2 O5 141.73(12) . .
O7 Eu2 O1 80.35(12) 2_546 3_656
O3 Eu2 O1 90.88(12) 2_646 3_656
O9 Eu2 O1 100.41(12) . 3_656
O9 Eu2 O1 81.94(11) 3_556 3_656
O10 Eu2 O1 65.94(11) . 3_656
O5 Eu2 O1 146.10(11) . 3_656
O7 Eu2 N3 111.30(14) 2_546 .
O3 Eu2 N3 69.07(13) 2_646 .
O9 Eu2 N3 82.56(13) . .
O9 Eu2 N3 126.02(12) 3_556 .
O10 Eu2 N3 87.54(12) . .
O5 Eu2 N3 63.79(12) . .
O1 Eu2 N3 150.12(12) 3_656 .
O7 Eu2 Eu1 152.64(10) 2_546 .
O3 Eu2 Eu1 113.52(8) 2_646 .
O9 Eu2 Eu1 37.24(9) . .
O9 Eu2 Eu1 90.38(9) 3_556 .
O10 Eu2 Eu1 36.71(9) . .
O5 Eu2 Eu1 116.88(8) . .
O1 Eu2 Eu1 72.64(8) 3_656 .
N3 Eu2 Eu1 94.65(9) . .
O7 Eu2 Eu2 116.16(10) 2_546 3_556
O3 Eu2 Eu2 173.31(9) 2_646 3_556
O9 Eu2 Eu2 35.14(9) . 3_556
O9 Eu2 Eu2 34.85(9) 3_556 3_556
O10 Eu2 Eu2 97.86(9) . 3_556
O5 Eu2 Eu2 69.32(8) . 3_556
O1 Eu2 Eu2 91.37(8) 3_656 3_556
N3 Eu2 Eu2 106.35(10) . 3_556
Eu1 Eu2 Eu2 61.304(9) . 3_556
O7 Eu2 Eu1 65.16(10) 2_546 3_556
O3 Eu2 Eu1 127.00(8) 2_646 3_556
O9 Eu2 Eu1 87.50(9) . 3_556
O9 Eu2 Eu1 34.68(9) 3_556 3_556
O10 Eu2 Eu1 155.63(9) . 3_556
O5 Eu2 Eu1 37.99(8) . 3_556
O1 Eu2 Eu1 108.19(7) 3_656 3_556
N3 Eu2 Eu1 101.62(9) . 3_556
Eu1 Eu2 Eu1 119.281(8) . 3_556
Eu2 Eu2 Eu1 57.978(7) 3_556 3_556
O7 Eu2 Eu1 100.07(10) 2_546 3_656
O3 Eu2 Eu1 69.40(8) 2_646 3_656
O9 Eu2 Eu1 96.88(9) . 3_656
O9 Eu2 Eu1 114.83(8) 3_556 3_656
O10 Eu2 Eu1 34.51(8) . 3_656
O5 Eu2 Eu1 176.21(8) . 3_656
O1 Eu2 Eu1 36.33(7) 3_656 3_656
N3 Eu2 Eu1 113.88(9) . 3_656
Eu1 Eu2 Eu1 59.818(8) . 3_656
Eu2 Eu2 Eu1 109.271(11) 3_556 3_656
Eu1 Eu2 Eu1 144.498(10) 3_556 3_656
O7 Eu2 H9 152.8(14) 2_546 .
O3 Eu2 H9 131.4(14) 2_646 .
O9 Eu2 H9 11.4(12) . .
O9 Eu2 H9 76.2(14) 3_556 .
O10 Eu2 H9 73.8(13) . .
O5 Eu2 H9 73.3(13) . .
O1 Eu2 H9 111.2(12) 3_656 .
N3 Eu2 H9 71.4(12) . .
Eu1 Eu2 H9 43.8(13) . .
Eu2 Eu2 H9 42.1(13) 3_556 .
Eu1 Eu2 H9 87.7(14) 3_556 .
Eu1 Eu2 H9 103.2(13) 3_656 .
O7 Eu2 H10 133.4(12) 2_546 .
O3 Eu2 H10 69.4(12) 2_646 .
O9 Eu2 H10 74.0(12) . .
O9 Eu2 H10 134.0(12) 3_556 .
O10 Eu2 H10 13.3(11) . .
O5 Eu2 H10 133.3(11) . .
O1 Eu2 H10 77.5(11) 3_656 .
N3 Eu2 H10 74.8(11) . .
Eu1 Eu2 H10 44.3(12) . .
Eu2 Eu2 H10 104.9(12) 3_556 .
Eu1 Eu2 H10 161.4(12) 3_556 .
Eu1 Eu2 H10 43.2(11) 3_656 .
H9 Eu2 H10 73.8(18) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O2 1.230(6) .
C1 O1 1.281(6) .
C1 C2 1.513(6) .
C2 N1 1.333(6) .
C2 C3 1.380(7) .
C3 C4 1.394(6) .
C3 H3A 0.9300 .
C4 N2 1.340(6) .
C4 C5 1.511(7) .
C5 O3 1.236(6) .
C5 O4 1.253(6) .
C6 N2 1.322(6) .
C6 N1 1.345(6) .
C6 H6A 0.9300 .
C7 O6 1.228(6) .
C7 O5 1.288(6) .
C7 C8 1.514(7) .
C8 N3 1.335(6) .
C8 C9 1.375(7) .
C9 C10 1.383(7) .
C9 H9A 0.9300 .
C10 N4 1.326(6) .
C10 C11 1.518(7) .
C11 O8 1.238(6) .
C11 O7 1.265(6) .
C11 Eu1 3.263(5) 4_566
C12 N4 1.317(6) .
C12 N3 1.331(6) .
C12 H12A 0.9300 .
N1 Eu1 2.583(4) .
N3 Eu2 2.591(4) .
O1 Eu1 2.467(3) .
O1 Eu2 2.507(3) 3_656
O3 Eu2 2.386(4) 2_656
O4 Eu1 2.335(3) 4_566
O5 Eu2 2.453(3) .
O5 Eu1 2.529(3) 3_556
O7 Eu2 2.378(4) 2_556
O8 O15 1.5(4) 3_557
O8 Eu1 2.355(3) 4_566
O9 Eu2 2.396(4) .
O9 Eu1 2.407(4) .
O9 Eu2 2.413(4) 3_556
O9 H9 0.58(5) .
O10 Eu1 2.381(4) .
O10 Eu2 2.414(3) .
O10 Eu1 2.423(3) 3_656
O10 H10 0.70(5) .
Eu1 O4 2.335(3) 4_565
Eu1 O8 2.355(3) 4_565
Eu1 O10 2.423(3) 3_656
Eu1 O5 2.529(3) 3_556
Eu1 C11 3.263(5) 4_565
Eu1 Eu2 3.8292(4) .
Eu1 Eu1 3.9008(6) 3_656
Eu1 Eu2 3.9617(5) 3_556
Eu1 H9 2.65(6) .
Eu1 H10 2.68(6) .
Eu2 O7 2.378(4) 2_546
Eu2 O3 2.386(4) 2_646
Eu2 O9 2.413(4) 3_556
Eu2 O1 2.507(3) 3_656
Eu2 Eu2 3.9393(6) 3_556
Eu2 Eu1 3.9617(5) 3_556
Eu2 Eu1 3.9889(5) 3_656
Eu2 H9 2.68(6) .
Eu2 H10 2.78(5) .
O15 O8 1.5(4) 3_557
