#------------------------------------------------------------------------------
#$Date: 2016-03-23 21:26:20 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179449 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/46/4334653.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4334653
loop_
_publ_author_name
'Li-Yi Zhang'
'Liang-Jin Xu'
'Xu Zhang'
'Jin-Yun Wang'
'Jia Li'
'Zhong-Ning Chen'
_publ_section_title
;
 Spectroscopic and Phosphorescent Modulation in Triphosphine-Supported
 PtAg2 Heterotrinuclear Alkynyl Complexes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5167
_journal_page_last               5175
_journal_paper_doi               10.1021/ic4000457
_journal_volume                  52
_journal_year                    2013
_chemical_formula_sum            'C112 H102 Ag2 Cl2 N6 O10 P6 Pt'
_chemical_formula_weight         2359.55
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 98.469(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   15.147(3)
_cell_length_b                   31.486(7)
_cell_length_c                   23.127(5)
_cell_measurement_temperature    293(2)
_cell_volume                     10909(4)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.984
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0398
_diffrn_reflns_av_sigmaI/netI    0.0438
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       40
_diffrn_reflns_limit_k_min       -40
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            41310
_diffrn_reflns_theta_full        27.47
_diffrn_reflns_theta_max         27.47
_diffrn_reflns_theta_min         2.74
_exptl_absorpt_coefficient_mu    1.831
_exptl_absorpt_correction_T_max  0.7524
_exptl_absorpt_correction_T_min  0.6267
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            Green
_exptl_crystal_density_diffrn    1.437
_exptl_crystal_description       Block
_exptl_crystal_F_000             4768
_exptl_crystal_size_max          0.62
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.10
_refine_diff_density_max         2.971
_refine_diff_density_min         -1.119
_refine_diff_density_rms         0.090
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.999
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     651
_refine_ls_number_reflns         12318
_refine_ls_number_restraints     207
_refine_ls_restrained_S_all      1.027
_refine_ls_R_factor_all          0.0474
_refine_ls_R_factor_gt           0.0397
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0495P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0911
_refine_ls_wR_factor_ref         0.0961
_reflns_number_gt                9972
_reflns_number_total             12318
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic4000457_si_002_06.cif
_cod_data_source_block           5(py)_2py
_cod_database_code               4334653
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.7500 0.2500 0.5000 0.03407(6) Uani 1 2 d S . .
Ag1 Ag 0.596784(16) 0.276679(8) 0.561008(11) 0.04437(8) Uani 1 1 d . . .
P1 P 0.50067(5) 0.26199(3) 0.46677(4) 0.04030(19) Uani 1 1 d . . .
P2 P 0.66814(5) 0.24841(2) 0.40713(4) 0.03628(19) Uani 1 1 d . . .
P3 P 0.66134(5) 0.23176(3) 0.64444(4) 0.04093(19) Uani 1 1 d . . .
O1 O 0.8700(4) -0.02333(12) 0.5178(2) 0.1404(18) Uani 1 1 d . . .
N1 N 0.5695(2) 0.34590(10) 0.59328(13) 0.0568(8) Uani 1 1 d . . .
C1 C 0.55852(19) 0.27408(11) 0.40455(14) 0.0418(7) Uani 1 1 d . . .
H1A H 0.5665 0.3046 0.4026 0.050 Uiso 1 1 calc R . .
H1B H 0.5208 0.2654 0.3689 0.050 Uiso 1 1 calc R . .
C2 C 0.7217(2) 0.28264(11) 0.35909(14) 0.0434(7) Uani 1 1 d . . .
H2A H 0.7197 0.3117 0.3726 0.052 Uiso 1 1 calc R . .
H2B H 0.6882 0.2813 0.3200 0.052 Uiso 1 1 calc R . .
C3 C 0.4004(2) 0.29492(11) 0.45262(14) 0.0418(7) Uani 1 1 d . . .
C4 C 0.3852(2) 0.32545(12) 0.41013(17) 0.0557(9) Uani 1 1 d . . .
H4A H 0.4267 0.3297 0.3847 0.067 Uiso 1 1 calc R . .
C5 C 0.3084(3) 0.35014(14) 0.4047(2) 0.0700(11) Uani 1 1 d . . .
H5A H 0.2986 0.3707 0.3756 0.084 Uiso 1 1 calc R . .
C6 C 0.2472(3) 0.34425(14) 0.4419(2) 0.0673(11) Uani 1 1 d . . .
H6A H 0.1958 0.3608 0.4381 0.081 Uiso 1 1 calc R . .
C7 C 0.2613(2) 0.31408(15) 0.4848(2) 0.0667(11) Uani 1 1 d . . .
H7A H 0.2196 0.3101 0.5100 0.080 Uiso 1 1 calc R . .
C8 C 0.3376(2) 0.28953(13) 0.49045(17) 0.0559(9) Uani 1 1 d . . .
H8A H 0.3472 0.2692 0.5198 0.067 Uiso 1 1 calc R . .
C9 C 0.4574(2) 0.20831(11) 0.45190(14) 0.0436(7) Uani 1 1 d . . .
C10 C 0.4029(2) 0.19792(13) 0.39970(16) 0.0558(9) Uani 1 1 d . . .
H10A H 0.3871 0.2187 0.3715 0.067 Uiso 1 1 calc R . .
C11 C 0.3729(3) 0.15719(15) 0.3901(2) 0.0731(12) Uani 1 1 d . . .
H11A H 0.3356 0.1506 0.3557 0.088 Uiso 1 1 calc R . .
C12 C 0.3977(3) 0.12566(14) 0.4313(2) 0.0734(12) Uani 1 1 d . . .
H12A H 0.3787 0.0979 0.4238 0.088 Uiso 1 1 calc R . .
C13 C 0.4500(3) 0.13553(14) 0.4825(2) 0.0708(11) Uani 1 1 d . . .
H13A H 0.4660 0.1145 0.5103 0.085 Uiso 1 1 calc R . .
C14 C 0.4794(2) 0.17679(12) 0.49357(17) 0.0549(9) Uani 1 1 d . . .
H14A H 0.5140 0.1834 0.5290 0.066 Uiso 1 1 calc R . .
C15 C 0.6447(2) 0.19819(12) 0.36824(15) 0.0470(8) Uani 1 1 d . . .
C16 C 0.6349(3) 0.19654(17) 0.30765(18) 0.0797(14) Uani 1 1 d . . .
H16A H 0.6433 0.2208 0.2862 0.096 Uiso 1 1 calc R . .
C17 C 0.6129(4) 0.1589(2) 0.2797(2) 0.112(2) Uani 1 1 d . . .
H17A H 0.6068 0.1578 0.2391 0.135 Uiso 1 1 calc R . .
C18 C 0.5997(4) 0.12287(19) 0.3102(3) 0.0999(18) Uani 1 1 d . . .
H18A H 0.5854 0.0975 0.2904 0.120 Uiso 1 1 calc R . .
C19 C 0.6075(3) 0.12427(14) 0.3694(2) 0.0719(12) Uani 1 1 d . . .
H19A H 0.5972 0.0999 0.3901 0.086 Uiso 1 1 calc R . .
C20 C 0.6309(2) 0.16174(12) 0.39887(17) 0.0535(9) Uani 1 1 d . . .
H20A H 0.6373 0.1624 0.4395 0.064 Uiso 1 1 calc R . .
C21 C 0.6629(2) 0.25223(11) 0.71869(15) 0.0445(8) Uani 1 1 d . . .
C22 C 0.6238(3) 0.29036(15) 0.72668(17) 0.0704(12) Uani 1 1 d . . .
H22A H 0.5976 0.3057 0.6943 0.084 Uiso 1 1 calc R . .
C23 C 0.6225(4) 0.30678(18) 0.7827(2) 0.0940(17) Uani 1 1 d . . .
H23A H 0.5955 0.3328 0.7875 0.113 Uiso 1 1 calc R . .
C24 C 0.6606(3) 0.28458(19) 0.8301(2) 0.0850(15) Uani 1 1 d . . .
H24A H 0.6601 0.2954 0.8674 0.102 Uiso 1 1 calc R . .
C25 C 0.7007(3) 0.24544(17) 0.8227(2) 0.0756(14) Uani 1 1 d . . .
H25A H 0.7268 0.2301 0.8551 0.091 Uiso 1 1 calc R . .
C26 C 0.7013(3) 0.22963(14) 0.76687(16) 0.0613(10) Uani 1 1 d . . .
H26A H 0.7279 0.2035 0.7619 0.074 Uiso 1 1 calc R . .
C27 C 0.6045(2) 0.18096(13) 0.64804(15) 0.0512(8) Uani 1 1 d . . .
C28 C 0.5248(3) 0.18052(18) 0.6706(2) 0.0833(14) Uani 1 1 d . . .
H28A H 0.5047 0.2052 0.6865 0.100 Uiso 1 1 calc R . .
C29 C 0.4749(4) 0.1440(2) 0.6700(2) 0.106(2) Uani 1 1 d . . .
H29A H 0.4215 0.1444 0.6853 0.128 Uiso 1 1 calc R . .
C30 C 0.5015(4) 0.1080(2) 0.6478(3) 0.1006(19) Uani 1 1 d . . .
H30A H 0.4676 0.0834 0.6488 0.121 Uiso 1 1 calc R . .
C31 C 0.5801(4) 0.10691(17) 0.6229(3) 0.0997(18) Uani 1 1 d . . .
H31A H 0.5985 0.0821 0.6065 0.120 Uiso 1 1 calc R . .
C32 C 0.6301(3) 0.14407(14) 0.6233(2) 0.0741(13) Uani 1 1 d . . .
H32A H 0.6821 0.1439 0.6064 0.089 Uiso 1 1 calc R . .
C33 C 0.7791(2) 0.18800(11) 0.50552(14) 0.0421(7) Uani 1 1 d . . .
C34 C 0.7988(2) 0.15097(11) 0.51368(16) 0.0494(8) Uani 1 1 d . . .
C35 C 0.8161(3) 0.10622(11) 0.51746(17) 0.0565(9) Uani 1 1 d . . .
C36 C 0.9024(3) 0.08979(14) 0.5323(2) 0.0782(13) Uani 1 1 d . . .
H36A H 0.9499 0.1082 0.5431 0.094 Uiso 1 1 calc R . .
C37 C 0.9178(4) 0.04708(16) 0.5312(3) 0.0998(18) Uani 1 1 d . . .
H37A H 0.9758 0.0369 0.5403 0.120 Uiso 1 1 calc R . .
C38 C 0.8480(4) 0.01882(15) 0.5167(3) 0.0942(16) Uani 1 1 d . . .
C39 C 0.7621(4) 0.03359(15) 0.5029(2) 0.0883(17) Uani 1 1 d . . .
H39A H 0.7148 0.0148 0.4933 0.106 Uiso 1 1 calc R . .
C40 C 0.7470(3) 0.07758(14) 0.50350(19) 0.0726(13) Uani 1 1 d . . .
H40A H 0.6890 0.0877 0.4943 0.087 Uiso 1 1 calc R . .
C41 C 0.8008(7) -0.05285(19) 0.5018(4) 0.183(4) Uani 1 1 d . . .
H41A H 0.8247 -0.0811 0.5053 0.275 Uiso 1 1 calc R . .
H41B H 0.7743 -0.0478 0.4621 0.275 Uiso 1 1 calc R . .
H41C H 0.7563 -0.0497 0.5270 0.275 Uiso 1 1 calc R . .
C42 C 0.6374(3) 0.37061(16) 0.6141(2) 0.0791(13) Uani 1 1 d . . .
H42A H 0.6947 0.3596 0.6164 0.095 Uiso 1 1 calc R . .
C43 C 0.6282(5) 0.4112(2) 0.6325(3) 0.114(2) Uani 1 1 d . . .
H43A H 0.6780 0.4273 0.6472 0.137 Uiso 1 1 calc R . .
C44 C 0.5467(6) 0.4272(2) 0.6289(4) 0.155(3) Uani 1 1 d . . .
H44A H 0.5392 0.4551 0.6404 0.186 Uiso 1 1 calc R . .
C45 C 0.4735(5) 0.4032(2) 0.6083(4) 0.139(3) Uani 1 1 d . . .
H45A H 0.4160 0.4139 0.6070 0.167 Uiso 1 1 calc R . .
C46 C 0.4880(3) 0.36268(16) 0.5897(2) 0.0814(13) Uani 1 1 d . . .
H46A H 0.4392 0.3463 0.5741 0.098 Uiso 1 1 calc R . .
Cl1 Cl 0.0000 0.18035(6) 0.7500 0.0730(4) Uani 1 2 d S . .
O2 O -0.0370(3) 0.15524(13) 0.70160(14) 0.1045(12) Uani 1 1 d . . .
O3 O 0.0676(3) 0.20655(15) 0.73264(17) 0.1207(14) Uani 1 1 d . . .
Cl2 Cl 0.4905(8) 0.0021(4) 0.5151(5) 0.189(3) Uani 0.50 1 d PDU A -1
O4 O 0.5333(10) 0.0293(5) 0.4649(7) 0.216(5) Uani 0.50 1 d PDU A -1
O5 O 0.4271(8) 0.0308(4) 0.5238(6) 0.192(4) Uani 0.50 1 d PDU A -1
O6 O 0.5633(9) -0.0017(5) 0.5535(6) 0.215(5) Uani 0.50 1 d PDU A -1
O7 O 0.4595(9) -0.0317(4) 0.4813(8) 0.199(5) Uani 0.50 1 d PDU A -1
N2 N 0.2176(11) 0.4586(5) 0.3141(8) 0.252(6) Uani 1 1 d DU . .
C47 C 0.2178(10) 0.4292(6) 0.2730(7) 0.231(7) Uani 1 1 d DU . .
H47A H 0.1641 0.4200 0.2520 0.278 Uiso 1 1 calc R . .
C48 C 0.2954(15) 0.4126(4) 0.2613(6) 0.226(6) Uani 1 1 d DU . .
H48A H 0.2947 0.3919 0.2326 0.271 Uiso 1 1 calc R . .
C49 C 0.3708(9) 0.4253(4) 0.2897(8) 0.212(5) Uani 1 1 d DU . .
H49A H 0.4241 0.4146 0.2804 0.254 Uiso 1 1 calc R . .
C50 C 0.3720(10) 0.4537(6) 0.3321(7) 0.221(6) Uani 1 1 d DU . .
H50A H 0.4263 0.4619 0.3533 0.265 Uiso 1 1 calc R . .
C51 C 0.2971(15) 0.4705(5) 0.3448(6) 0.230(7) Uani 1 1 d DU . .
H51A H 0.2990 0.4904 0.3747 0.276 Uiso 1 1 calc R . .
N3 N 0.7866(14) 0.4886(6) 0.8458(7) 0.308(7) Uani 1 1 d DU . .
C52 C 0.8030(13) 0.4508(6) 0.8164(8) 0.290(7) Uani 1 1 d DU . .
H52A H 0.8605 0.4402 0.8173 0.348 Uiso 1 1 calc R . .
C53 C 0.7312(16) 0.4307(6) 0.7868(8) 0.289(9) Uani 1 1 d DU . .
H53A H 0.7357 0.4046 0.7686 0.347 Uiso 1 1 calc R . .
C54 C 0.6527(13) 0.4510(6) 0.7857(7) 0.263(6) Uani 1 1 d DU . .
H54A H 0.6039 0.4368 0.7655 0.316 Uiso 1 1 calc R . .
C55 C 0.6332(14) 0.4881(6) 0.8086(8) 0.286(7) Uani 1 1 d DU . .
H55A H 0.5766 0.5002 0.8015 0.343 Uiso 1 1 calc R . .
C56 C 0.7022(17) 0.5068(6) 0.8430(9) 0.296(9) Uani 1 1 d DU . .
H56A H 0.6936 0.5311 0.8642 0.355 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C33 Pt1 C33 180.000(1) 7_656 .
C33 Pt1 P2 83.06(9) 7_656 .
C33 Pt1 P2 96.94(9) . .
C33 Pt1 P2 96.94(9) 7_656 7_656
C33 Pt1 P2 83.06(9) . 7_656
P2 Pt1 P2 180.0 . 7_656
C33 Pt1 Ag1 114.86(9) 7_656 7_656
C33 Pt1 Ag1 65.14(9) . 7_656
P2 Pt1 Ag1 84.47(3) . 7_656
P2 Pt1 Ag1 95.53(3) 7_656 7_656
C33 Pt1 Ag1 65.14(9) 7_656 .
C33 Pt1 Ag1 114.86(9) . .
P2 Pt1 Ag1 95.53(3) . .
P2 Pt1 Ag1 84.47(3) 7_656 .
Ag1 Pt1 Ag1 180.0 7_656 .
N1 Ag1 P3 110.41(8) . .
N1 Ag1 P1 110.06(8) . .
P3 Ag1 P1 133.80(3) . .
N1 Ag1 Pt1 126.11(8) . .
P3 Ag1 Pt1 87.86(2) . .
P1 Ag1 Pt1 85.94(3) . .
C9 P1 C3 103.03(15) . .
C9 P1 C1 104.15(16) . .
C3 P1 C1 102.85(15) . .
C9 P1 Ag1 119.07(11) . .
C3 P1 Ag1 114.59(11) . .
C1 P1 Ag1 111.40(11) . .
C2 P2 C15 106.45(16) . .
C2 P2 C1 101.62(14) . .
C15 P2 C1 104.78(15) . .
C2 P2 Pt1 109.07(11) . .
C15 P2 Pt1 120.89(12) . .
C1 P2 Pt1 112.20(11) . .
C27 P3 C21 101.93(16) . .
C27 P3 C2 104.47(17) . 7_656
C21 P3 C2 104.39(15) . 7_656
C27 P3 Ag1 113.68(11) . .
C21 P3 Ag1 118.62(12) . .
C2 P3 Ag1 112.23(10) 7_656 .
C38 O1 C41 117.7(5) . .
C42 N1 C46 116.8(4) . .
C42 N1 Ag1 119.8(3) . .
C46 N1 Ag1 123.3(3) . .
P1 C1 P2 114.65(17) . .
P2 C2 P3 113.53(17) . 7_656
C4 C3 C8 118.5(3) . .
C4 C3 P1 125.0(3) . .
C8 C3 P1 116.4(3) . .
C3 C4 C5 120.5(4) . .
C6 C5 C4 120.2(4) . .
C7 C6 C5 120.2(4) . .
C6 C7 C8 119.9(4) . .
C7 C8 C3 120.7(4) . .
C14 C9 C10 118.9(3) . .
C14 C9 P1 119.2(3) . .
C10 C9 P1 121.9(3) . .
C11 C10 C9 120.0(4) . .
C10 C11 C12 120.6(4) . .
C13 C12 C11 119.9(4) . .
C12 C13 C14 120.3(4) . .
C13 C14 C9 120.3(4) . .
C20 C15 C16 119.0(4) . .
C20 C15 P2 120.0(3) . .
C16 C15 P2 120.9(3) . .
C17 C16 C15 119.5(5) . .
C18 C17 C16 121.3(5) . .
C19 C18 C17 119.8(5) . .
C18 C19 C20 120.2(5) . .
C15 C20 C19 120.2(4) . .
C22 C21 C26 119.1(4) . .
C22 C21 P3 119.4(3) . .
C26 C21 P3 121.5(3) . .
C21 C22 C23 121.1(4) . .
C24 C23 C22 119.7(5) . .
C23 C24 C25 119.9(4) . .
C26 C25 C24 119.6(4) . .
C21 C26 C25 120.6(4) . .
C32 C27 C28 117.6(4) . .
C32 C27 P3 123.8(3) . .
C28 C27 P3 118.0(3) . .
C29 C28 C27 120.8(5) . .
C30 C29 C28 121.4(5) . .
C29 C30 C31 120.2(5) . .
C32 C31 C30 118.3(5) . .
C27 C32 C31 121.7(5) . .
C34 C33 Pt1 174.7(3) . .
C33 C34 C35 173.8(4) . .
C40 C35 C36 117.6(4) . .
C40 C35 C34 120.0(3) . .
C36 C35 C34 122.3(4) . .
C37 C36 C35 121.0(5) . .
C36 C37 C38 120.7(5) . .
O1 C38 C39 123.6(5) . .
O1 C38 C37 116.3(5) . .
C39 C38 C37 120.1(4) . .
C38 C39 C40 118.7(5) . .
C35 C40 C39 121.8(4) . .
N1 C42 C43 123.9(5) . .
C44 C43 C42 118.4(6) . .
C43 C44 C45 120.7(6) . .
C44 C45 C46 117.6(6) . .
N1 C46 C45 122.5(5) . .
O2 Cl1 O2 112.2(4) . 2_556
O2 Cl1 O3 108.6(2) . .
O2 Cl1 O3 109.3(2) 2_556 .
O2 Cl1 O3 109.3(2) . 2_556
O2 Cl1 O3 108.6(2) 2_556 2_556
O3 Cl1 O3 108.9(4) . 2_556
O6 Cl2 O5 120.2(10) . .
O6 Cl2 O7 120.0(11) . .
O5 Cl2 O7 114.5(11) . .
O6 Cl2 O4 98.3(10) . .
O5 Cl2 O4 96.8(10) . .
O7 Cl2 O4 98.0(8) . .
C47 N2 C51 118.1(14) . .
N2 C47 C48 120.5(11) . .
C49 C48 C47 120.6(10) . .
C48 C49 C50 119.9(11) . .
C51 C50 C49 121.1(10) . .
C50 C51 N2 119.8(11) . .
C56 N3 C52 123.3(19) . .
C53 C52 N3 117.0(17) . .
C54 C53 C52 115.3(18) . .
C55 C54 C53 131(2) . .
C54 C55 C56 114.6(19) . .
C55 C56 N3 118.3(18) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 C33 2.001(3) 7_656
Pt1 C33 2.001(3) .
Pt1 P2 2.3170(10) .
Pt1 P2 2.3170(10) 7_656
Pt1 Ag1 3.0077(5) 7_656
Pt1 Ag1 3.0077(5) .
Ag1 N1 2.360(3) .
Ag1 P3 2.4746(10) .
Ag1 P1 2.4797(10) .
P1 C9 1.827(4) .
P1 C3 1.828(3) .
P1 C1 1.832(3) .
P2 C2 1.822(3) .
P2 C15 1.828(3) .
P2 C1 1.840(3) .
P3 C27 1.824(4) .
P3 C21 1.831(4) .
P3 C2 1.841(3) 7_656
O1 C38 1.368(6) .
O1 C41 1.409(9) .
N1 C42 1.322(5) .
N1 C46 1.334(5) .
C2 P3 1.841(3) 7_656
C3 C4 1.370(5) .
C3 C8 1.395(4) .
C4 C5 1.389(5) .
C5 C6 1.368(6) .
C6 C7 1.367(6) .
C7 C8 1.380(5) .
C9 C14 1.389(5) .
C9 C10 1.397(5) .
C10 C11 1.368(6) .
C11 C12 1.388(6) .
C12 C13 1.361(6) .
C13 C14 1.385(6) .
C15 C20 1.381(5) .
C15 C16 1.388(5) .
C16 C17 1.369(7) .
C17 C18 1.365(8) .
C18 C19 1.357(7) .
C19 C20 1.383(5) .
C21 C22 1.363(5) .
C21 C26 1.377(5) .
C22 C23 1.398(6) .
C23 C24 1.355(7) .
C24 C25 1.395(7) .
C25 C26 1.385(6) .
C27 C32 1.376(6) .
C27 C28 1.384(5) .
C28 C29 1.375(7) .
C29 C30 1.331(8) .
C30 C31 1.397(8) .
C31 C32 1.393(6) .
C33 C34 1.211(5) .
C34 C35 1.433(5) .
C35 C40 1.383(5) .
C35 C36 1.400(5) .
C36 C37 1.366(6) .
C37 C38 1.385(7) .
C38 C39 1.374(7) .
C39 C40 1.404(6) .
C42 C43 1.359(7) .
C43 C44 1.325(9) .
C44 C45 1.369(9) .
C45 C46 1.374(7) .
Cl1 O2 1.417(3) .
Cl1 O2 1.417(3) 2_556
Cl1 O3 1.418(4) .
Cl1 O3 1.418(4) 2_556
Cl2 O6 1.315(14) .
Cl2 O5 1.353(13) .
Cl2 O7 1.363(14) .
Cl2 O4 1.652(15) .
N2 C47 1.329(11) .
N2 C51 1.358(11) .
C47 C48 1.349(12) .
C48 C49 1.295(11) .
C49 C50 1.324(11) .
C50 C51 1.323(12) .
N3 C56 1.394(13) .
N3 C52 1.410(13) .
C52 C53 1.355(13) .
C53 C54 1.347(12) .
C54 C55 1.334(12) .
C55 C56 1.351(13) .
