#------------------------------------------------------------------------------
#$Date: 2016-03-23 22:14:35 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179473 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/70/4337099.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4337099
loop_
_publ_author_name
'Liang, Min-Xia'
'Ruan, Chan-Zi'
'Sun, Di'
'Kong, Xiang-Jian'
'Ren, Yan-Ping'
'Long, La-Sheng'
'Huang, Rong-Bin'
'Zheng, Lan-Sun'
_publ_section_title
;
 Solvothermal Synthesis of Four Polyoxometalate-Based Coordination
 Polymers Including Diverse Ag(I)···π Interactions.
;
_journal_issue                   2
_journal_name_full               'Inorganic chemistry'
_journal_page_first              897
_journal_page_last               902
_journal_paper_doi               10.1021/ic4022596
_journal_volume                  53
_journal_year                    2014
_chemical_formula_sum            'C77 H55 Ag17 Mo24 N44 O80 P2'
_chemical_formula_weight         7074.94
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                107.906(6)
_cell_angle_beta                 90.517(6)
_cell_angle_gamma                107.615(5)
_cell_formula_units_Z            1
_cell_length_a                   14.138(4)
_cell_length_b                   14.546(5)
_cell_length_c                   19.922(6)
_cell_measurement_temperature    298(2)
_cell_volume                     3692(2)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.976
_diffrn_measured_fraction_theta_max 0.976
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0261
_diffrn_reflns_av_sigmaI/netI    0.0552
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            18127
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.08
_exptl_absorpt_coefficient_mu    4.283
_exptl_absorpt_correction_T_max  0.6275
_exptl_absorpt_correction_T_min  0.5128
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_density_diffrn    3.182
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3302
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.12
_refine_diff_density_max         4.750
_refine_diff_density_min         -4.653
_refine_diff_density_rms         0.328
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.178
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1141
_refine_ls_number_reflns         12695
_refine_ls_number_restraints     102
_refine_ls_restrained_S_all      1.174
_refine_ls_R_factor_all          0.0977
_refine_ls_R_factor_gt           0.0891
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0901P)²+134.8017P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2212
_refine_ls_wR_factor_ref         0.2274
_reflns_number_gt                11466
_reflns_number_total             12695
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic4022596_si_002.cif
_cod_data_source_block           p2
_cod_original_sg_symbol_H-M      p-1
_cod_database_code               4337099
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Ag1 Ag 0.55693(9) -0.35968(10) -0.47193(6) 0.0272(3) Uani 1 1 d . .
Ag2 Ag 0.0035(2) -0.2829(3) -0.54906(15) 0.0637(7) Uani 0.75 1 d P .
Ag2' Ag 0.0161(7) -0.3354(7) -0.5496(5) 0.060(2) Uani 0.25 1 d P .
Ag3 Ag 0.1739(3) -0.4644(3) -0.5813(2) 0.1222(11) Uani 1 1 d . .
Ag4 Ag 0.71598(11) -0.28012(10) -0.26922(7) 0.0348(3) Uani 1 1 d . .
Ag5 Ag 0.81356(13) -0.00869(12) -0.20807(9) 0.0461(4) Uani 1 1 d . .
Ag6 Ag 0.89926(13) 0.09473(12) -0.35990(10) 0.0492(4) Uani 1 1 d . .
Ag7 Ag 0.98020(11) -0.09479(11) 0.04210(7) 0.0348(3) Uani 1 1 d . .
Ag8 Ag 0.26532(13) -0.47894(12) -0.75999(8) 0.0421(4) Uani 1 1 d . .
Ag9 Ag 0.8619(5) -0.1795(5) -0.6695(3) 0.0930(16) Uani 0.50 1 d P .
Mo4 Mo 0.14473(11) -0.53176(11) -0.27462(8) 0.0254(3) Uani 1 1 d . .
Mo6 Mo 0.01501(10) -0.36507(11) -0.26152(8) 0.0272(3) Uani 1 1 d . .
Mo7 Mo 0.14896(11) -0.08911(11) -0.21172(8) 0.0239(3) Uani 1 1 d . .
Mo8 Mo 0.18626(12) -0.26411(13) -0.38010(8) 0.0304(4) Uani 1 1 d . .
Mo10 Mo 0.43409(12) -0.15812(11) -0.32642(8) 0.0288(3) Uani 1 1 d . .
Mo11 Mo 0.41379(12) -0.43192(12) -0.21092(8) 0.0311(4) Uani 1 1 d . .
Mo13 Mo 0.53507(11) -0.17720(13) -0.16286(9) 0.0314(4) Uani 1 1 d . .
Mo14 Mo 0.22404(14) -0.10851(14) -0.05732(8) 0.0369(4) Uani 1 1 d . .
Mo15 Mo 0.11052(11) -0.38961(14) -0.11398(8) 0.0345(4) Uani 1 1 d . .
Mo16 Mo 0.39403(12) 0.00050(12) -0.15199(10) 0.0386(4) Uani 1 1 d . .
Mo19 Mo 0.32620(11) -0.41588(10) -0.38003(7) 0.0235(3) Uani 1 1 d . .
Mo20 Mo 0.37893(10) -0.27217(12) -0.05613(7) 0.0249(3) Uani 1 1 d . .
P1 P 0.2753(3) -0.2673(3) -0.2162(2) 0.0175(8) Uani 1 1 d . .
O3 O 0.1802(8) -0.3494(8) -0.2165(5) 0.019(2) Uani 1 1 d . .
O4 O 0.3614(8) -0.2812(8) -0.1785(6) 0.020(2) Uani 1 1 d . .
O5 O 0.2773(8) -0.5026(8) -0.2296(6) 0.024(2) Uani 1 1 d . .
O6 O 0.2957(7) -0.2753(8) -0.2922(5) 0.018(2) Uani 1 1 d . .
O7 O 0.1445(9) -0.0694(9) -0.1114(6) 0.029(3) Uani 1 1 d . .
O8 O 0.0853(8) -0.3425(9) -0.3426(6) 0.026(2) Uani 1 1 d . .
O9 O 0.5084(8) -0.1820(8) -0.2566(6) 0.024(2) Uani 1 1 d . .
O10 O 0.0332(8) -0.5013(9) -0.2973(6) 0.024(2) Uani 1 1 d . .
O11 O 0.2412(8) -0.3613(8) -0.0805(6) 0.024(2) Uani 1 1 d . .
O12 O 0.1759(8) -0.1507(9) -0.3028(6) 0.026(2) Uani 1 1 d . .
O13 O 0.3260(9) -0.1650(9) -0.0381(6) 0.030(3) Uani 1 1 d . .
O14 O 0.4231(9) -0.2995(9) -0.3848(6) 0.028(3) Uani 1 1 d . .
O16 O -0.1042(9) -0.3950(10) -0.2925(7) 0.035(3) Uani 1 1 d . .
O18 O 0.4799(8) -0.0672(9) -0.1360(7) 0.028(3) Uani 1 1 d . .
O19 O 0.3377(10) -0.5086(10) -0.4508(6) 0.031(3) Uani 1 1 d . .
O20 O 0.3992(8) -0.4228(9) -0.3051(6) 0.024(2) Uani 1 1 d . .
O21 O 0.4120(9) -0.0573(9) -0.2530(6) 0.029(3) Uani 1 1 d . .
O23 O 0.5325(8) -0.3149(9) -0.1944(6) 0.026(2) Uani 1 1 d . .
O24 O 0.5253(10) -0.0936(10) -0.3626(7) 0.040(3) Uani 1 1 d . .
O25 O 0.4635(10) -0.5257(10) -0.2267(7) 0.041(3) Uani 1 1 d . .
O26 O 0.1070(10) -0.6610(9) -0.3082(7) 0.037(3) Uani 1 1 d . .
O28 O 0.4690(10) 0.1199(11) -0.1327(10) 0.058(4) Uani 1 1 d . .
O29 O 0.1033(8) -0.5141(10) -0.1789(6) 0.032(3) Uani 1 1 d . .
O30 O 0.1369(9) -0.2415(10) -0.0798(6) 0.031(3) Uani 1 1 d . .
O31 O 0.2096(8) -0.4922(8) -0.3460(5) 0.022(2) Uani 1 1 d . .
O32 O 0.2645(7) -0.1634(8) -0.1775(5) 0.020(2) Uani 1 1 d . .
O35 O 0.0027(8) -0.3875(9) -0.1746(6) 0.027(3) Uani 1 1 d . .
O36 O 0.2278(8) -0.3742(9) -0.4259(6) 0.025(2) Uani 1 1 d . .
O37 O 0.4113(8) -0.3936(9) -0.1133(6) 0.026(2) Uani 1 1 d . .
O38 O 0.3358(9) 0.0010(9) -0.0681(7) 0.034(3) Uani 1 1 d . .
O40 O 0.0561(8) -0.2263(8) -0.2242(6) 0.023(2) Uani 1 1 d . .
O43 O 0.0478(10) -0.4256(12) -0.0520(7) 0.045(4) Uani 1 1 d . .
O44 O 0.4019(10) -0.2789(10) 0.0238(6) 0.034(3) Uani 1 1 d . .
O45 O 0.6560(9) -0.1149(11) -0.1457(8) 0.043(3) Uani 1 1 d . .
O47 O 0.5034(8) -0.1956(9) -0.0725(6) 0.026(2) Uani 1 1 d . .
O51 O 0.3196(9) -0.1760(9) -0.3833(6) 0.027(3) Uani 1 1 d . .
O52 O 0.2707(9) 0.0137(8) -0.1894(6) 0.028(3) Uani 1 1 d . .
O57 O 0.0719(10) -0.0279(9) -0.2264(7) 0.035(3) Uani 1 1 d . .
O59 O 0.1237(12) -0.2524(12) -0.4470(6) 0.047(4) Uani 1 1 d . .
O68 O 0.2001(12) -0.0528(12) 0.0243(7) 0.050(4) Uani 1 1 d . .
N1 N 0.8190(10) -0.2061(10) -0.1700(6) 0.021(2) Uani 1 1 d U .
N2 N 0.8689(10) -0.1083(10) -0.1569(7) 0.022(3) Uani 1 1 d . .
N3 N 0.9237(10) -0.0716(10) -0.0962(7) 0.023(3) Uani 1 1 d . .
N4 N 0.9102(10) -0.1446(10) -0.0667(6) 0.022(2) Uani 1 1 d U .
N5 N 0.9099(12) -0.2078(14) 0.2197(8) 0.039(4) Uani 1 1 d . .
N6 N 1.0067(11) -0.1562(13) 0.2370(8) 0.035(4) Uani 1 1 d . .
N7 N 1.0393(12) -0.1235(12) 0.1865(8) 0.033(3) Uani 1 1 d . .
N8 N 0.9646(10) -0.1554(10) 0.1344(7) 0.024(3) Uani 1 1 d . .
N9 N 0.6792(10) -0.2174(10) -0.4161(8) 0.026(3) Uani 1 1 d . .
N10 N 0.6998(10) -0.1886(10) -0.3458(7) 0.024(3) Uani 1 1 d . .
N11 N 0.7552(10) -0.0932(11) -0.3242(7) 0.029(3) Uani 1 1 d . .
N12 N 0.7706(11) -0.0569(11) -0.3787(7) 0.028(3) Uani 1 1 d . .
N13 N 0.4527(9) -0.4379(9) -0.5695(7) 0.020(3) Uani 1 1 d . .
N14 N 0.4223(10) -0.5416(9) -0.5981(6) 0.021(3) Uani 1 1 d . .
N15 N 0.3664(10) -0.5680(10) -0.6574(7) 0.023(3) Uani 1 1 d . .
N16 N 0.3633(11) -0.4828(10) -0.6689(7) 0.026(3) Uani 1 1 d . .
N17 N 0.1459(11) -0.2327(11) -0.6573(9) 0.033(3) Uani 1 1 d . .
N18 N 0.1342(13) -0.2886(12) -0.6139(9) 0.038(4) Uani 1 1 d . .
N19 N 0.1671(12) -0.3650(11) -0.6409(9) 0.035(4) Uani 1 1 d . .
N20 N 0.1997(11) -0.3600(11) -0.7036(8) 0.030(3) Uani 1 1 d . .
N21 N 0.973(3) -0.133(3) -0.5145(18) 0.042(3) Uani 0.50 1 d PU 1
N23 N 0.968(3) -0.007(3) -0.451(2) 0.047(3) Uani 0.50 1 d PU 1
N24 N 1.0013(15) 0.0581(17) -0.4415(10) 0.050(3) Uani 1 1 d U .
C1 C 0.8420(12) -0.2305(12) -0.1135(8) 0.0206(19) Uani 1 1 d U .
C2 C 0.8034(12) -0.3299(11) -0.1030(7) 0.019(2) Uani 1 1 d U .
C3 C 0.8550(14) -0.3603(14) -0.0607(9) 0.030(4) Uani 1 1 d . .
H3 H 0.9182 -0.3177 -0.0388 0.036 Uiso 1 1 calc R .
C4 C 0.8170(15) -0.4496(14) -0.0499(10) 0.036(4) Uani 1 1 d . .
H4 H 0.8544 -0.4695 -0.0218 0.043 Uiso 1 1 calc R .
C5 C 0.7220(14) -0.5130(13) -0.0806(10) 0.034(4) Uani 1 1 d . .
H5 H 0.6954 -0.5741 -0.0714 0.041 Uiso 1 1 calc R .
C6 C 0.6674(14) -0.4879(14) -0.1236(9) 0.029(4) Uani 1 1 d . .
H6 H 0.6042 -0.5317 -0.1448 0.035 Uiso 1 1 calc R .
C7 C 0.7073(13) -0.3946(15) -0.1357(9) 0.032(4) Uani 1 1 d . .
H7 H 0.6709 -0.3755 -0.1651 0.038 Uiso 1 1 calc R .
C8 C 0.8838(12) -0.2093(12) 0.1552(8) 0.022(3) Uani 1 1 d . .
C9 C 0.7858(14) -0.2561(13) 0.1179(9) 0.028(4) Uani 1 1 d . .
C10 C 0.7520(14) -0.2087(14) 0.0773(8) 0.030(4) Uani 1 1 d . .
H10 H 0.7922 -0.1462 0.0752 0.036 Uiso 1 1 calc R .
C11 C 0.6565(14) -0.2555(14) 0.0393(11) 0.039(5) Uani 1 1 d . .
H11 H 0.6340 -0.2237 0.0115 0.047 Uiso 1 1 calc R .
C12 C 0.5979(14) -0.3441(16) 0.0422(12) 0.047(5) Uani 1 1 d . .
H12 H 0.5342 -0.3728 0.0176 0.057 Uiso 1 1 calc R .
C13 C 0.6321(16) -0.3961(18) 0.0832(14) 0.053(6) Uani 1 1 d . .
H13 H 0.5931 -0.4602 0.0835 0.064 Uiso 1 1 calc R .
C14 C 0.7256(16) -0.3474(18) 0.1224(13) 0.050(6) Uani 1 1 d . .
H14 H 0.7476 -0.3769 0.1521 0.059 Uiso 1 1 calc R .
C15 C 0.7230(11) -0.1355(10) -0.4339(8) 0.020(3) Uani 1 1 d . .
C16 C 0.7223(12) -0.1323(14) -0.5087(9) 0.027(4) Uani 1 1 d . .
C17 C 0.7038(17) -0.2183(17) -0.5649(9) 0.046(5) Uani 1 1 d . .
H17 H 0.6879 -0.2810 -0.5573 0.055 Uiso 1 1 calc R .
C18 C 0.7082(18) -0.215(2) -0.6325(11) 0.055(6) Uani 1 1 d . .
H18 H 0.6586 -0.2737 -0.6670 0.066 Uiso 1 1 calc R .
C19 C 0.721(2) -0.129(2) -0.6462(12) 0.065(8) Uani 1 1 d . .
H19 H 0.6798 -0.1340 -0.6879 0.078 Uiso 1 1 calc R .
C20 C 0.738(2) -0.041(2) -0.5906(16) 0.070(8) Uani 1 1 d . .
H20 H 0.7484 0.0201 -0.5993 0.084 Uiso 1 1 calc R .
C21 C 0.7410(16) -0.0419(15) -0.5219(10) 0.037(5) Uani 1 1 d . .
H21A H 0.7556 0.0190 -0.4844 0.044 Uiso 1 1 calc R .
C22 C 0.4167(11) -0.4042(12) -0.6143(8) 0.023(3) Uani 1 1 d . .
C23 C 0.4282(12) -0.2997(12) -0.6048(8) 0.024(3) Uani 1 1 d . .
C24 C 0.4051(17) -0.2387(13) -0.5411(10) 0.042(5) Uani 1 1 d . .
H24 H 0.3880 -0.2663 -0.5048 0.051 Uiso 1 1 calc R .
C25 C 0.4070(19) -0.1413(17) -0.5306(11) 0.050(6) Uani 1 1 d . .
H25 H 0.3884 -0.1035 -0.4892 0.061 Uiso 1 1 calc R .
C26 C 0.4376(18) -0.1011(19) -0.5840(14) 0.058(6) Uani 1 1 d . .
H26 H 0.4426 -0.0335 -0.5769 0.069 Uiso 1 1 calc R .
C27 C 0.4616(15) -0.1569(16) -0.6482(13) 0.046(5) Uani 1 1 d . .
H27 H 0.4819 -0.1277 -0.6833 0.055 Uiso 1 1 calc R .
C28 C 0.4543(14) -0.2570(15) -0.6579(10) 0.037(4) Uani 1 1 d . .
H28 H 0.4672 -0.2966 -0.7011 0.045 Uiso 1 1 calc R .
C29 C 0.1844(12) -0.2800(14) -0.7114(9) 0.029(4) Uani 1 1 d . .
C30 C 0.2144(15) -0.2400(15) -0.7690(9) 0.034(4) Uani 1 1 d . .
C31 C 0.177(2) -0.293(2) -0.8376(12) 0.060(7) Uani 1 1 d . .
H31 H 0.1290 -0.3575 -0.8505 0.072 Uiso 1 1 calc R .
C32 C 0.215(2) -0.243(3) -0.8920(12) 0.066(8) Uani 1 1 d . .
H32 H 0.1935 -0.2783 -0.9398 0.080 Uiso 1 1 calc R .
C33 C 0.280(2) -0.149(2) -0.8735(12) 0.066(9) Uani 1 1 d . .
H33 H 0.3022 -0.1193 -0.9082 0.079 Uiso 1 1 calc R .
C34 C 0.3130(18) -0.099(2) -0.8078(13) 0.057(6) Uani 1 1 d . .
H34 H 0.3590 -0.0338 -0.7963 0.068 Uiso 1 1 calc R .
C35 C 0.2813(15) -0.1401(17) -0.7509(12) 0.043(5) Uani 1 1 d . .
H35 H 0.3045 -0.1013 -0.7038 0.052 Uiso 1 1 calc R .
C39 C 0.8798(19) -0.2866(16) -0.4985(11) 0.042(4) Uani 0.50 1 d PGU .
H39 H 0.8478 -0.3471 -0.5349 0.050 Uiso 0.50 1 calc PR .
C38 C 0.8887(19) -0.2867(15) -0.4290(13) 0.040(4) Uani 0.50 1 d PGU .
H38 H 0.8626 -0.3472 -0.4189 0.048 Uiso 0.50 1 calc PR .
C37 C 0.9366(19) -0.1964(19) -0.3746(10) 0.038(4) Uani 0.50 1 d PGU .
H37 H 0.9425 -0.1965 -0.3280 0.045 Uiso 0.50 1 calc PR .
C36 C 0.9756(19) -0.1060(15) -0.3897(11) 0.041(3) Uani 0.50 1 d PGU .
H36 H 1.0076 -0.0456 -0.3532 0.049 Uiso 0.50 1 calc PR .
C42 C 0.967(2) -0.1059(16) -0.4592(13) 0.042(3) Uani 0.50 1 d PGU .
C40 C 0.919(2) -0.196(2) -0.5136(10) 0.043(3) Uani 0.50 1 d PGU .
H21 H 0.9234 -0.1976 -0.5581 0.051 Uiso 0.50 1 d PR .
C41 C 1.005(3) -0.020(4) -0.484(2) 0.044(3) Uani 0.50 1 d PU .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N13 Ag1 N9 143.0(5) . .
N13 Ag1 N14 117.5(4) . 2_644
N9 Ag1 N14 98.4(5) . 2_644
Ag2' Ag2 C40 146(6) . 1_455
Ag2' Ag2 C39 105.4(10) . 1_455
C40 Ag2 C39 41(6) 1_455 1_455
Ag2' Ag2 N21 163.9(11) . 1_455
C40 Ag2 N21 27(6) 1_455 1_455
C39 Ag2 N21 66.2(10) 1_455 1_455
Ag2' Ag2 N18 73.5(8) . .
C40 Ag2 N18 141(6) 1_455 .
C39 Ag2 N18 175.3(7) 1_455 .
N21 Ag2 N18 116.0(10) 1_455 .
Ag2' Ag2 O59 67.6(8) . .
C40 Ag2 O59 107(6) 1_455 .
C39 Ag2 O59 98.9(7) 1_455 .
N21 Ag2 O59 99.3(10) 1_455 .
N18 Ag2 O59 85.0(5) . .
Ag2 Ag2' N18 85.1(8) . .
Ag2 Ag2' O59 92.8(9) . .
N18 Ag2' O59 91.6(7) . .
Ag2 Ag2' C39 54.9(8) . 1_455
N18 Ag2' C39 139.8(8) . 1_455
O59 Ag2' C39 94.4(7) . 1_455
Ag2 Ag2' C40 24(4) . 1_455
N18 Ag2' C40 109(4) . 1_455
O59 Ag2' C40 91(4) . 1_455
C39 Ag2' C40 31(4) 1_455 1_455
Ag2 Ag2' Ag3 147.6(8) . .
N18 Ag2' Ag3 63.7(5) . .
O59 Ag2' Ag3 80.3(4) . .
C39 Ag2' Ag3 156.5(7) 1_455 .
C40 Ag2' Ag3 169(4) 1_455 .
N19 Ag3 Ag2' 59.4(5) . .
N15 Ag4 N1 140.7(5) 2_644 .
N15 Ag4 N10 96.5(5) 2_644 .
N1 Ag4 N10 121.3(5) . .
N11 Ag5 N7 115.5(5) . 2_755
N11 Ag5 N2 111.4(5) . .
N7 Ag5 N2 97.6(5) 2_755 .
N11 Ag5 C34 92.4(7) . 2_654
N7 Ag5 C34 98.6(7) 2_755 2_654
N2 Ag5 C34 141.6(6) . 2_654
N17 Ag6 N24 120.1(7) 2_654 .
N17 Ag6 N12 116.0(5) 2_654 .
N24 Ag6 N12 105.2(7) . .
N17 Ag6 N23 136.4(10) 2_654 .
N24 Ag6 N23 21.6(9) . .
N12 Ag6 N23 84.0(11) . .
N17 Ag6 N6 94.5(6) 2_654 2_755
N24 Ag6 N6 109.4(6) . 2_755
N12 Ag6 N6 111.1(5) . 2_755
N23 Ag6 N6 114.8(10) . 2_755
N17 Ag6 Ag9 104.6(4) 2_654 2_754
N24 Ag6 Ag9 55.8(5) . 2_754
N12 Ag6 Ag9 138.8(4) . 2_754
N23 Ag6 Ag9 70.5(10) . 2_754
N6 Ag6 Ag9 56.8(4) 2_755 2_754
N4 Ag7 N8 137.1(5) . .
N4 Ag7 N3 120.3(5) . 2_755
N8 Ag7 N3 101.4(5) . 2_755
N20 Ag8 N16 101.6(5) . .
N20 Ag8 C7 154.5(6) . 2_644
N16 Ag8 C7 103.9(5) . 2_644
N20 Ag8 C6 130.8(6) . 2_644
N16 Ag8 C6 115.0(6) . 2_644
C7 Ag8 C6 33.1(6) 2_644 2_644
C18 Ag9 N5 130.9(8) . 1_554
C18 Ag9 C19 33.6(9) . .
N5 Ag9 C19 119.0(7) 1_554 .
C18 Ag9 O26 101.6(8) . 2_644
N5 Ag9 O26 77.9(6) 1_554 2_644
C19 Ag9 O26 133.8(9) . 2_644
C18 Ag9 Ag6 152.0(6) . 2_754
N5 Ag9 Ag6 77.0(4) 1_554 2_754
C19 Ag9 Ag6 141.8(8) . 2_754
O26 Ag9 Ag6 81.3(4) 2_644 2_754
O26 Mo4 O31 103.1(5) . .
O26 Mo4 O10 102.8(6) . .
O31 Mo4 O10 92.4(5) . .
O26 Mo4 O5 101.3(6) . .
O31 Mo4 O5 85.4(5) . .
O10 Mo4 O5 155.7(5) . .
O26 Mo4 O29 100.0(6) . .
O31 Mo4 O29 156.4(5) . .
O10 Mo4 O29 87.2(5) . .
O5 Mo4 O29 85.4(5) . .
O26 Mo4 O3 172.2(5) . .
O31 Mo4 O3 84.0(4) . .
O10 Mo4 O3 73.4(4) . .
O5 Mo4 O3 82.3(4) . .
O29 Mo4 O3 73.3(4) . .
O16 Mo6 O40 103.6(6) . .
O16 Mo6 O35 101.7(6) . .
O40 Mo6 O35 95.4(5) . .
O16 Mo6 O8 102.2(6) . .
O40 Mo6 O8 85.2(5) . .
O35 Mo6 O8 155.2(5) . .
O16 Mo6 O10 100.2(6) . .
O40 Mo6 O10 155.4(5) . .
O35 Mo6 O10 85.8(5) . .
O8 Mo6 O10 83.8(5) . .
O16 Mo6 O3 170.9(5) . .
O40 Mo6 O3 85.0(4) . .
O35 Mo6 O3 73.8(4) . .
O8 Mo6 O3 81.5(4) . .
O10 Mo6 O3 71.7(4) . .
O57 Mo7 O52 101.6(6) . .
O57 Mo7 O12 102.7(5) . .
O52 Mo7 O12 93.5(5) . .
O57 Mo7 O7 101.6(5) . .
O52 Mo7 O7 88.4(5) . .
O12 Mo7 O7 154.7(5) . .
O57 Mo7 O40 102.2(6) . .
O52 Mo7 O40 156.1(5) . .
O12 Mo7 O40 83.6(5) . .
O7 Mo7 O40 84.6(5) . .
O57 Mo7 O32 173.6(5) . .
O52 Mo7 O32 75.2(4) . .
O12 Mo7 O32 83.2(4) . .
O7 Mo7 O32 73.0(4) . .
O40 Mo7 O32 80.9(4) . .
O59 Mo8 O36 102.0(6) . .
O59 Mo8 O8 102.6(6) . .
O36 Mo8 O8 92.5(5) . .
O59 Mo8 O12 100.6(6) . .
O36 Mo8 O12 157.3(5) . .
O8 Mo8 O12 84.8(5) . .
O59 Mo8 O51 100.0(6) . .
O36 Mo8 O51 87.7(5) . .
O8 Mo8 O51 156.8(5) . .
O12 Mo8 O51 86.1(5) . .
O59 Mo8 O6 172.2(6) . .
O36 Mo8 O6 74.7(4) . .
O8 Mo8 O6 84.7(4) . .
O12 Mo8 O6 82.6(4) . .
O51 Mo8 O6 73.0(4) . .
O24 Mo10 O21 102.9(6) . .
O24 Mo10 O51 102.6(6) . .
O21 Mo10 O51 93.3(5) . .
O24 Mo10 O9 101.4(6) . .
O21 Mo10 O9 86.4(5) . .
O51 Mo10 O9 155.4(5) . .
O24 Mo10 O14 99.7(6) . .
O21 Mo10 O14 157.0(5) . .
O51 Mo10 O14 86.0(5) . .
O9 Mo10 O14 84.9(5) . .
O24 Mo10 O6 170.5(5) . .
O21 Mo10 O6 86.1(5) . .
O51 Mo10 O6 73.4(4) . .
O9 Mo10 O6 82.0(4) . .
O14 Mo10 O6 71.6(4) . .
O25 Mo11 O37 102.5(6) . .
O25 Mo11 O5 102.6(6) . .
O37 Mo11 O5 93.3(5) . .
O25 Mo11 O20 101.0(6) . .
O37 Mo11 O20 156.3(5) . .
O5 Mo11 O20 84.2(5) . .
O25 Mo11 O23 100.9(6) . .
O37 Mo11 O23 87.4(5) . .
O5 Mo11 O23 155.7(5) . .
O20 Mo11 O23 85.4(5) . .
O25 Mo11 O4 172.6(5) . .
O37 Mo11 O4 74.0(4) . .
O5 Mo11 O4 84.3(4) . .
O20 Mo11 O4 82.4(4) . .
O23 Mo11 O4 72.6(4) . .
O45 Mo13 O9 102.1(6) . .
O45 Mo13 O23 102.0(6) . .
O9 Mo13 O23 91.1(5) . .
O45 Mo13 O18 101.6(6) . .
O9 Mo13 O18 85.7(5) . .
O23 Mo13 O18 156.3(5) . .
O45 Mo13 O47 101.4(6) . .
O9 Mo13 O47 156.3(5) . .
O23 Mo13 O47 86.9(5) . .
O18 Mo13 O47 86.8(5) . .
O45 Mo13 O4 172.6(6) . .
O9 Mo13 O4 84.0(4) . .
O23 Mo13 O4 73.4(4) . .
O18 Mo13 O4 82.9(4) . .
O47 Mo13 O4 72.7(4) . .
O68 Mo14 O30 102.6(7) . .
O68 Mo14 O7 100.7(6) . .
O30 Mo14 O7 94.2(5) . .
O68 Mo14 O38 100.4(7) . .
O30 Mo14 O38 156.4(5) . .
O7 Mo14 O38 86.7(5) . .
O68 Mo14 O13 101.9(6) . .
O30 Mo14 O13 85.2(5) . .
O7 Mo14 O13 156.9(5) . .
O38 Mo14 O13 84.8(5) . .
O68 Mo14 O32 171.1(6) . .
O30 Mo14 O32 85.0(4) . .
O7 Mo14 O32 73.9(4) . .
O38 Mo14 O32 72.5(4) . .
O13 Mo14 O32 83.0(4) . .
O43 Mo15 O11 103.2(6) . .
O43 Mo15 O29 101.2(7) . .
O11 Mo15 O29 93.6(5) . .
O43 Mo15 O35 100.5(6) . .
O11 Mo15 O35 155.5(5) . .
O29 Mo15 O35 87.6(5) . .
O43 Mo15 O30 102.3(6) . .
O11 Mo15 O30 86.2(5) . .
O29 Mo15 O30 156.0(5) . .
O35 Mo15 O30 82.9(5) . .
O43 Mo15 O3 171.7(5) . .
O11 Mo15 O3 84.7(4) . .
O29 Mo15 O3 75.2(5) . .
O35 Mo15 O3 72.0(4) . .
O30 Mo15 O3 80.8(4) . .
O28 Mo16 O18 102.8(6) . .
O28 Mo16 O38 102.9(7) . .
O18 Mo16 O38 93.8(5) . .
O28 Mo16 O52 99.8(6) . .
O18 Mo16 O52 156.4(5) . .
O38 Mo16 O52 87.4(5) . .
O28 Mo16 O21 101.2(7) . .
O18 Mo16 O21 84.1(5) . .
O38 Mo16 O21 155.7(5) . .
O52 Mo16 O21 85.1(5) . .
O28 Mo16 O32 171.6(6) . .
O18 Mo16 O32 85.1(4) . .
O38 Mo16 O32 73.3(4) . .
O52 Mo16 O32 72.7(4) . .
O21 Mo16 O32 82.3(4) . .
O19 Mo19 O20 104.7(5) . .
O19 Mo19 O14 103.7(6) . .
O20 Mo19 O14 93.1(5) . .
O19 Mo19 O31 100.0(6) . .
O20 Mo19 O31 85.7(5) . .
O14 Mo19 O31 155.7(5) . .
O19 Mo19 O36 98.4(5) . .
O20 Mo19 O36 156.1(5) . .
O14 Mo19 O36 87.3(5) . .
O31 Mo19 O36 84.2(5) . .
O19 Mo19 O6 170.6(5) . .
O20 Mo19 O6 84.6(4) . .
O14 Mo19 O6 74.4(4) . .
O31 Mo19 O6 81.4(4) . .
O36 Mo19 O6 72.4(4) . .
O44 Mo20 O13 103.8(6) . .
O44 Mo20 O47 102.9(6) . .
O13 Mo20 O47 94.1(5) . .
O44 Mo20 O11 99.9(6) . .
O13 Mo20 O11 85.8(5) . .
O47 Mo20 O11 156.5(5) . .
O44 Mo20 O37 98.4(5) . .
O13 Mo20 O37 157.0(5) . .
O47 Mo20 O37 86.4(5) . .
O11 Mo20 O37 84.7(5) . .
O44 Mo20 O4 170.6(5) . .
O13 Mo20 O4 85.4(4) . .
O47 Mo20 O4 74.2(4) . .
O11 Mo20 O4 82.3(4) . .
O37 Mo20 O4 72.6(4) . .
O3 P1 O6 109.3(6) . .
O3 P1 O4 109.4(6) . .
O6 P1 O4 109.0(6) . .
O3 P1 O32 109.1(6) . .
O6 P1 O32 110.1(6) . .
O4 P1 O32 109.8(6) . .
P1 O3 Mo6 126.2(6) . .
P1 O3 Mo15 126.8(6) . .
Mo6 O3 Mo15 88.6(3) . .
P1 O3 Mo4 125.9(6) . .
Mo6 O3 Mo4 89.4(3) . .
Mo15 O3 Mo4 87.5(3) . .
P1 O4 Mo20 126.3(6) . .
P1 O4 Mo13 125.9(6) . .
Mo20 O4 Mo13 88.5(3) . .
P1 O4 Mo11 126.2(6) . .
Mo20 O4 Mo11 88.9(3) . .
Mo13 O4 Mo11 88.9(3) . .
Mo11 O5 Mo4 152.6(6) . .
P1 O6 Mo8 125.4(6) . .
P1 O6 Mo19 127.1(6) . .
Mo8 O6 Mo19 89.4(3) . .
P1 O6 Mo10 124.9(6) . .
Mo8 O6 Mo10 88.8(3) . .
Mo19 O6 Mo10 89.4(3) . .
Mo14 O7 Mo7 124.5(6) . .
Mo8 O8 Mo6 150.7(6) . .
Mo13 O9 Mo10 150.9(6) . .
Mo4 O10 Mo6 125.4(6) . .
Mo15 O11 Mo20 151.6(6) . .
Mo7 O12 Mo8 154.2(7) . .
Mo20 O13 Mo14 151.0(7) . .
Mo19 O14 Mo10 124.6(6) . .
Mo16 O18 Mo13 152.6(7) . .
Mo19 O20 Mo11 152.3(6) . .
Mo10 O21 Mo16 151.1(7) . .
Mo13 O23 Mo11 125.0(6) . .
Mo4 O26 Ag9 151.1(8) . 2_644
Mo15 O29 Mo4 124.0(7) . .
Mo14 O30 Mo15 151.0(7) . .
Mo4 O31 Mo19 151.5(6) . .
P1 O32 Mo7 127.3(6) . .
P1 O32 Mo14 125.6(6) . .
Mo7 O32 Mo14 88.5(3) . .
P1 O32 Mo16 126.0(6) . .
Mo7 O32 Mo16 88.4(4) . .
Mo14 O32 Mo16 88.8(3) . .
Mo6 O35 Mo15 125.5(6) . .
Mo8 O36 Mo19 123.3(6) . .
Mo11 O37 Mo20 124.4(6) . .
Mo16 O38 Mo14 125.3(6) . .
Mo6 O40 Mo7 153.2(6) . .
Mo20 O47 Mo13 124.6(6) . .
Mo10 O51 Mo8 124.7(6) . .
Mo7 O52 Mo16 123.6(6) . .
Mo8 O59 Ag2' 146.4(9) . .
Mo8 O59 Ag2 164.4(9) . .
Ag2' O59 Ag2 19.6(2) . .
N2 N1 C1 107.0(12) . .
N2 N1 Ag4 115.3(10) . .
C1 N1 Ag4 137.5(11) . .
N3 N2 N1 110.1(12) . .
N3 N2 Ag5 123.1(10) . .
N1 N2 Ag5 121.8(9) . .
N2 N3 N4 109.4(12) . .
N2 N3 Ag7 126.4(10) . 2_755
N4 N3 Ag7 124.1(10) . 2_755
N3 N4 C1 106.0(12) . .
N3 N4 Ag7 115.5(9) . .
C1 N4 Ag7 137.8(11) . .
C8 N5 N6 108.4(14) . .
C8 N5 Ag9 142.3(13) . 1_556
N6 N5 Ag9 98.6(11) . 1_556
N7 N6 N5 108.3(14) . .
N7 N6 Ag6 124.3(12) . 2_755
N5 N6 Ag6 125.8(11) . 2_755
N6 N7 N8 109.1(15) . .
N6 N7 Ag5 119.1(12) . 2_755
N8 N7 Ag5 128.9(11) . 2_755
C8 N8 N7 107.4(13) . .
C8 N8 Ag7 130.0(10) . .
N7 N8 Ag7 121.6(11) . .
C15 N9 N10 105.7(13) . .
C15 N9 Ag1 131.8(11) . .
N10 N9 Ag1 119.8(10) . .
N11 N10 N9 107.6(13) . .
N11 N10 Ag4 114.6(10) . .
N9 N10 Ag4 131.9(10) . .
N10 N11 N12 110.9(13) . .
N10 N11 Ag5 121.4(11) . .
N12 N11 Ag5 127.7(11) . .
C15 N12 N11 103.8(13) . .
C15 N12 Ag6 135.9(11) . .
N11 N12 Ag6 117.1(10) . .
C22 N13 N14 106.8(12) . .
C22 N13 Ag1 132.3(10) . .
N14 N13 Ag1 120.5(9) . .
N15 N14 N13 108.3(12) . .
N15 N14 Ag1 130.3(10) . 2_644
N13 N14 Ag1 119.7(9) . 2_644
N14 N15 N16 108.1(12) . .
N14 N15 Ag4 130.1(10) . 2_644
N16 N15 Ag4 121.8(10) . 2_644
C22 N16 N15 107.6(13) . .
C22 N16 Ag8 127.2(11) . .
N15 N16 Ag8 124.8(10) . .
C29 N17 N18 105.2(15) . .
C29 N17 Ag6 129.1(12) . 2_654
N18 N17 Ag6 125.7(12) . 2_654
N19 N18 N17 109.3(15) . .
N19 N18 Ag2' 107.7(11) . .
N17 N18 Ag2' 133.4(13) . .
N19 N18 Ag2 128.5(11) . .
N17 N18 Ag2 113.7(12) . .
Ag2' N18 Ag2 21.4(3) . .
N18 N19 N20 108.1(13) . .
N18 N19 Ag3 120.2(12) . .
N20 N19 Ag3 131.5(12) . .
C29 N20 N19 105.6(14) . .
C29 N20 Ag8 138.6(12) . .
N19 N20 Ag8 115.8(11) . .
C40 N21 C42 84(3) . .
C40 N21 C41 142(4) . .
C42 N21 C41 67(3) . .
C40 N21 N24 140(3) . 2_754
C42 N21 N24 121(3) . 2_754
C41 N21 N24 55(2) . 2_754
C40 N21 Ag2 61(2) . 1_655
C42 N21 Ag2 113(3) . 1_655
C41 N21 Ag2 152(3) . 1_655
N24 N21 Ag2 122(2) 2_754 1_655
C40 N21 H21 49.3 . .
C42 N21 H21 131.7 . .
C41 N21 H21 142.0 . .
N24 N21 H21 95.1 2_754 .
Ag2 N21 H21 60.4 1_655 .
C41 N23 N24 88(5) . .
C41 N23 C42 76(4) . .
N24 N23 C42 150(5) . .
C41 N23 C41 41(5) . 2_754
N24 N23 C41 68(3) . 2_754
C42 N23 C41 111(4) . 2_754
C41 N23 Ag6 157(5) . .
N24 N23 Ag6 70(3) . .
C42 N23 Ag6 126(2) . .
C41 N23 Ag6 122(3) 2_754 .
N23 N24 C41 45(3) . .
N23 N24 C41 77(4) . 2_754
C41 N24 C41 45(3) . 2_754
N23 N24 N21 135(4) . 2_754
C41 N24 N21 102(3) . 2_754
C41 N24 N21 60(2) 2_754 2_754
N23 N24 Ag6 89(3) . .
C41 N24 Ag6 134(3) . .
C41 N24 Ag6 137(2) 2_754 .
N21 N24 Ag6 113.3(16) 2_754 .
N1 C1 N4 107.5(13) . .
N1 C1 C2 127.0(13) . .
N4 C1 C2 125.5(14) . .
C3 C2 C7 118.9(15) . .
C3 C2 C1 122.5(15) . .
C7 C2 C1 118.5(14) . .
C4 C3 C2 121.5(18) . .
C4 C3 H3 119.3 . .
C2 C3 H3 119.3 . .
C3 C4 C5 120.2(18) . .
C3 C4 H4 119.9 . .
C5 C4 H4 119.9 . .
C6 C5 C4 121.3(16) . .
C6 C5 H5 119.4 . .
C4 C5 H5 119.4 . .
C5 C6 C7 118.8(17) . .
C5 C6 Ag8 107.1(13) . 2_644
C7 C6 Ag8 71.8(10) . 2_644
C5 C6 H6 120.6 . .
C7 C6 H6 120.6 . .
Ag8 C6 H6 91.0 2_644 .
C6 C7 C2 119.3(16) . .
C6 C7 Ag8 75.1(10) . 2_644
C2 C7 Ag8 105.6(11) . 2_644
C6 C7 H7 120.4 . .
C2 C7 H7 120.4 . .
Ag8 C7 H7 89.4 2_644 .
N5 C8 N8 106.8(14) . .
N5 C8 C9 125.7(15) . .
N8 C8 C9 127.4(14) . .
C14 C9 C10 120.2(18) . .
C14 C9 C8 120.5(16) . .
C10 C9 C8 119.3(16) . .
C9 C10 C11 119.5(18) . .
C9 C10 H10 120.2 . .
C11 C10 H10 120.2 . .
C12 C11 C10 121.2(19) . .
C12 C11 H11 119.4 . .
C10 C11 H11 119.4 . .
C11 C12 C13 120.4(18) . .
C11 C12 H12 119.8 . .
C13 C12 H12 119.8 . .
C14 C13 C12 117.7(19) . .
C14 C13 H13 121.1 . .
C12 C13 H13 121.1 . .
C9 C14 C13 120.8(19) . .
C9 C14 H14 119.6 . .
C13 C14 H14 119.6 . .
N12 C15 N9 112.0(14) . .
N12 C15 C16 123.2(14) . .
N9 C15 C16 124.7(14) . .
C17 C16 C21 117.8(17) . .
C17 C16 C15 121.1(16) . .
C21 C16 C15 121.1(16) . .
C16 C17 C18 121(2) . .
C16 C17 H17 119.4 . .
C18 C17 H17 119.4 . .
C19 C18 C17 121(2) . .
C19 C18 Ag9 76.0(16) . .
C17 C18 Ag9 116.2(18) . .
C19 C18 H18 112.8 . .
C17 C18 H18 112.8 . .
Ag9 C18 H18 112.8 . .
C18 C19 C20 118(2) . .
C18 C19 Ag9 70.4(15) . .
C20 C19 Ag9 114(2) . .
C18 C19 H19 115.6 . .
C20 C19 H19 115.6 . .
Ag9 C19 H19 115.6 . .
C19 C20 C21 121(2) . .
C19 C20 H20 119.4 . .
C21 C20 H20 119.4 . .
C16 C21 C20 120(2) . .
C16 C21 H21A 120.1 . .
C20 C21 H21A 120.1 . .
N13 C22 N16 109.1(14) . .
N13 C22 C23 125.8(14) . .
N16 C22 C23 124.9(14) . .
C28 C23 C24 117.8(17) . .
C28 C23 C22 122.5(16) . .
C24 C23 C22 119.5(15) . .
C25 C24 C23 122.6(18) . .
C25 C24 H24 118.7 . .
C23 C24 H24 118.7 . .
C24 C25 C26 117(2) . .
C24 C25 H25 121.4 . .
C26 C25 H25 121.4 . .
C25 C26 C27 123(2) . .
C25 C26 H26 118.5 . .
C27 C26 H26 118.5 . .
C28 C27 C26 117.9(19) . .
C28 C27 H27 121.1 . .
C26 C27 H27 121.1 . .
C27 C28 C23 121.3(19) . .
C27 C28 H28 119.3 . .
C23 C28 H28 119.3 . .
N20 C29 N17 111.9(15) . .
N20 C29 C30 125.3(16) . .
N17 C29 C30 122.6(17) . .
C31 C30 C35 120(2) . .
C31 C30 C29 123(2) . .
C35 C30 C29 117.3(17) . .
C30 C31 C32 117(2) . .
C30 C31 H31 121.5 . .
C32 C31 H31 121.5 . .
C33 C32 C31 122(2) . .
C33 C32 H32 119.2 . .
C31 C32 H32 119.2 . .
C34 C33 C32 120(2) . .
C34 C33 H33 119.9 . .
C32 C33 H33 119.9 . .
C33 C34 C35 123(3) . .
C33 C34 Ag5 93.6(15) . 2_654
C35 C34 Ag5 95.2(13) . 2_654
C33 C34 H34 118.6 . .
C35 C34 H34 118.6 . .
Ag5 C34 H34 80.7 2_654 .
C30 C35 C34 118(2) . .
C30 C35 H35 120.9 . .
C34 C35 H35 120.9 . .
C38 C39 C40 120.0 . .
C38 C39 Ag2 115.8(12) . 1_655
C40 C39 Ag2 67.9(11) . 1_655
C38 C39 Ag2' 105.1(11) . 1_655
C40 C39 Ag2' 87.5(11) . 1_655
Ag2 C39 Ag2' 19.7(3) 1_655 1_655
C38 C39 H39 120.0 . .
C40 C39 H39 120.0 . .
Ag2 C39 H39 86.6 1_655 .
Ag2' C39 H39 77.5 1_655 .
C39 C38 C37 120.0 . .
C39 C38 H38 120.0 . .
C37 C38 H38 120.0 . .
C38 C37 C36 120.0 . .
C38 C37 H37 120.0 . .
C36 C37 H37 120.0 . .
C42 C36 C37 120.0 . .
C42 C36 H36 120.0 . .
C37 C36 H36 120.0 . .
N21 C42 C36 154(3) . .
N21 C42 C40 46(2) . .
C36 C42 C40 120.0 . .
N21 C42 N23 101(3) . .
C36 C42 N23 103(2) . .
C40 C42 N23 129(2) . .
N21 C42 C41 71(3) . .
C36 C42 C41 127(2) . .
C40 C42 C41 113(2) . .
N23 C42 C41 35(2) . .
N21 C40 C42 50(2) . .
N21 C40 C39 156(3) . .
C42 C40 C39 120.0 . .
N21 C40 Ag2 92(3) . 1_655
C42 C40 Ag2 114.3(12) . 1_655
C39 C40 Ag2 71.4(11) . 1_655
N21 C40 Ag2' 101(3) . 1_655
C42 C40 Ag2' 116.6(11) . 1_655
C39 C40 Ag2' 61.6(10) . 1_655
Ag2 C40 Ag2' 10.0(3) 1_655 1_655
N21 C40 H21 71.0 . .
C42 C40 H21 119.0 . .
C39 C40 H21 120.0 . .
Ag2 C40 H21 75.9 1_655 .
Ag2' C40 H21 83.4 1_655 .
N23 C41 C41 105(7) . 2_754
N23 C41 N24 47(4) . .
C41 C41 N24 79(6) 2_754 .
N23 C41 N24 141(5) . 2_754
C41 C41 N24 57(5) 2_754 2_754
N24 C41 N24 135(3) . 2_754
N23 C41 C42 69(4) . .
C41 C41 C42 149(7) 2_754 .
N24 C41 C42 112(4) . .
N24 C41 C42 107(3) 2_754 .
N23 C41 N23 139(5) . 2_754
C41 C41 N23 34(4) 2_754 2_754
N24 C41 N23 105(3) . 2_754
N24 C41 N23 35.2(19) 2_754 2_754
C42 C41 N23 142(4) . 2_754
N23 C41 N21 105(5) . .
C41 C41 N21 118(7) 2_754 .
N24 C41 N21 152(4) . .
N24 C41 N21 65(3) 2_754 .
C42 C41 N21 42(2) . .
N23 C41 N21 99(4) 2_754 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N13 2.194(12) .
Ag1 N9 2.213(13) .
Ag1 N14 2.360(13) 2_644
Ag2 Ag2' 0.832(8) .
Ag2 C40 1.98(14) 1_455
Ag2 C39 2.02(3) 1_455
Ag2 N21 2.25(4) 1_455
Ag2 N18 2.272(16) .
Ag2 O59 2.479(13) .
Ag2' N18 2.186(17) .
Ag2' O59 2.295(17) .
Ag2' C39 2.38(3) 1_455
Ag2' C40 2.70(15) 1_455
Ag2' Ag3 3.276(10) .
Ag3 N19 2.156(15) .
Ag4 N15 2.191(13) 2_644
Ag4 N1 2.209(12) .
Ag4 N10 2.362(13) .
Ag5 N11 2.269(13) .
Ag5 N7 2.294(15) 2_755
Ag5 N2 2.308(13) .
Ag5 C34 2.68(2) 2_654
Ag6 N17 2.217(15) 2_654
Ag6 N24 2.233(19) .
Ag6 N12 2.317(14) .
Ag6 N23 2.38(4) .
Ag6 N6 2.536(15) 2_755
Ag6 Ag9 3.204(7) 2_754
Ag7 N4 2.182(13) .
Ag7 N8 2.257(13) .
Ag7 N3 2.290(13) 2_755
Ag8 N20 2.217(15) .
Ag8 N16 2.298(14) .
Ag8 C7 2.438(18) 2_644
Ag8 C6 2.480(16) 2_644
Ag9 C18 2.26(2) .
Ag9 N5 2.266(16) 1_554
Ag9 C19 2.33(3) .
Ag9 O26 2.401(14) 2_644
Ag9 Ag6 3.204(7) 2_754
Mo4 O26 1.696(13) .
Mo4 O31 1.844(10) .
Mo4 O10 1.849(11) .
Mo4 O5 1.937(11) .
Mo4 O29 1.964(12) .
Mo4 O3 2.434(10) .
Mo6 O16 1.668(12) .
Mo6 O40 1.824(11) .
Mo6 O35 1.858(12) .
Mo6 O8 1.966(11) .
Mo6 O10 1.986(11) .
Mo6 O3 2.414(10) .
Mo7 O57 1.675(12) .
Mo7 O52 1.848(11) .
Mo7 O12 1.860(11) .
Mo7 O7 1.935(12) .
Mo7 O40 1.967(11) .
Mo7 O32 2.409(10) .
Mo8 O59 1.672(12) .
Mo8 O36 1.850(11) .
Mo8 O8 1.858(12) .
Mo8 O12 1.924(11) .
Mo8 O51 1.947(12) .
Mo8 O6 2.402(10) .
Mo10 O24 1.662(12) .
Mo10 O21 1.831(12) .
Mo10 O51 1.872(12) .
Mo10 O9 1.911(11) .
Mo10 O14 1.985(12) .
Mo10 O6 2.433(10) .
Mo11 O25 1.666(13) .
Mo11 O37 1.854(11) .
Mo11 O5 1.863(11) .
Mo11 O20 1.934(11) .
Mo11 O23 1.934(12) .
Mo11 O4 2.428(10) .
Mo13 O45 1.650(13) .
Mo13 O9 1.877(11) .
Mo13 O23 1.894(12) .
Mo13 O18 1.922(11) .
Mo13 O47 1.938(11) .
Mo13 O4 2.421(10) .
Mo14 O68 1.668(13) .
Mo14 O30 1.865(13) .
Mo14 O7 1.868(11) .
Mo14 O38 1.942(13) .
Mo14 O13 1.949(12) .
Mo14 O32 2.413(10) .
Mo15 O43 1.648(13) .
Mo15 O11 1.837(11) .
Mo15 O29 1.846(13) .
Mo15 O35 1.950(12) .
Mo15 O30 1.962(13) .
Mo15 O3 2.431(10) .
Mo16 O28 1.660(15) .
Mo16 O18 1.858(12) .
Mo16 O38 1.869(13) .
Mo16 O52 1.975(12) .
Mo16 O21 1.979(12) .
Mo16 O32 2.427(11) .
Mo19 O19 1.673(11) .
Mo19 O20 1.853(11) .
Mo19 O14 1.857(12) .
Mo19 O31 1.946(10) .
Mo19 O36 1.991(11) .
Mo19 O6 2.403(10) .
Mo20 O44 1.660(12) .
Mo20 O13 1.867(11) .
Mo20 O47 1.868(11) .
Mo20 O11 1.944(11) .
Mo20 O37 1.973(12) .
Mo20 O4 2.407(11) .
P1 O3 1.502(11) .
P1 O6 1.520(10) .
P1 O4 1.520(11) .
P1 O32 1.526(10) .
O26 Ag9 2.401(14) 2_644
N1 N2 1.322(18) .
N1 C1 1.34(2) .
N2 N3 1.298(18) .
N3 N4 1.331(19) .
N3 Ag7 2.290(13) 2_755
N4 C1 1.378(19) .
N5 C8 1.32(2) .
N5 N6 1.33(2) .
N5 Ag9 2.266(16) 1_556
N6 N7 1.27(2) .
N6 Ag6 2.536(15) 2_755
N7 N8 1.340(19) .
N7 Ag5 2.294(15) 2_755
N8 C8 1.33(2) .
N9 C15 1.32(2) .
N9 N10 1.334(19) .
N10 N11 1.30(2) .
N11 N12 1.34(2) .
N12 C15 1.31(2) .
N13 C22 1.31(2) .
N13 N14 1.363(17) .
N14 N15 1.301(18) .
N14 Ag1 2.360(13) 2_644
N15 N16 1.341(19) .
N15 Ag4 2.191(12) 2_644
N16 C22 1.33(2) .
N17 C29 1.31(2) .
N17 N18 1.34(2) .
N17 Ag6 2.217(15) 2_654
N18 N19 1.30(2) .
N19 N20 1.35(2) .
N20 C29 1.30(2) .
N21 C40 1.01(4) .
N21 C42 1.06(4) .
N21 C41 1.49(6) .
N21 N24 1.56(4) 2_754
N21 Ag2 2.25(4) 1_655
N21 H21 1.1012 .
N23 C41 0.86(5) .
N23 N24 0.88(4) .
N23 C42 1.40(5) .
N23 C41 1.48(6) 2_754
N24 C41 1.20(5) .
N24 C41 1.41(5) 2_754
N24 N21 1.56(4) 2_754
C1 C2 1.46(2) .
C2 C3 1.36(2) .
C2 C7 1.41(2) .
C3 C4 1.33(3) .
C3 H3 0.9300 .
C4 C5 1.38(3) .
C4 H4 0.9300 .
C5 C6 1.35(3) .
C5 H5 0.9300 .
C6 C7 1.40(3) .
C6 Ag8 2.480(16) 2_644
C6 H6 0.9300 .
C7 Ag8 2.438(18) 2_644
C7 H7 0.9300 .
C8 C9 1.43(2) .
C9 C14 1.37(3) .
C9 C10 1.37(2) .
C10 C11 1.40(3) .
C10 H10 0.9300 .
C11 C12 1.32(3) .
C11 H11 0.9300 .
C12 C13 1.44(3) .
C12 H12 0.9300 .
C13 C14 1.39(3) .
C13 H13 0.9300 .
C14 H14 0.9300 .
C15 C16 1.51(2) .
C16 C17 1.35(3) .
C16 C21 1.37(2) .
C17 C18 1.36(3) .
C17 H17 0.9300 .
C18 C19 1.33(4) .
C18 H18 0.9800 .
C19 C20 1.36(4) .
C19 H19 0.9800 .
C20 C21 1.37(3) .
C20 H20 0.9300 .
C21 H21A 0.9300 .
C22 C23 1.43(2) .
C23 C28 1.38(2) .
C23 C24 1.41(3) .
C24 C25 1.36(3) .
C24 H24 0.9300 .
C25 C26 1.38(3) .
C25 H25 0.9300 .
C26 C27 1.40(3) .
C26 H26 0.9300 .
C27 C28 1.38(3) .
C27 H27 0.9300 .
C28 H28 0.9300 .
C29 C30 1.45(2) .
C30 C31 1.36(3) .
C30 C35 1.41(3) .
C31 C32 1.50(4) .
C31 H31 0.9300 .
C32 C33 1.33(4) .
C32 H32 0.9300 .
C33 C34 1.29(4) .
C33 H33 0.9300 .
C34 C35 1.45(3) .
C34 Ag5 2.68(2) 2_654
C34 H34 0.9300 .
C35 H35 0.9300 .
C39 C38 1.3900 .
C39 C40 1.3900 .
C39 Ag2 2.02(3) 1_655
C39 Ag2' 2.38(3) 1_655
C39 H39 0.9300 .
C38 C37 1.3900 .
C38 H38 0.9300 .
C37 C36 1.3900 .
C37 H37 0.9300 .
C36 C42 1.3900 .
C36 H36 0.9300 .
C42 C40 1.3900 .
C42 C41 1.45(5) .
C40 Ag2 1.98(3) 1_655
C40 Ag2' 2.70(3) 1_655
C40 H21 0.8833 .
C41 C41 1.01(8) 2_754
C41 N24 1.41(5) 2_754
C41 N23 1.48(6) 2_754
