#------------------------------------------------------------------------------
#$Date: 2016-03-24 00:12:42 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179527 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/24/4342453.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4342453
loop_
_publ_author_name
'Chamayou, Anne-Christine'
'Makhloufi, Gamall'
'Nafie, Laurence A.'
'Janiak, Christoph'
'Lüdeke, Steffen'
_publ_section_title
;
 Solvation-Induced Helicity Inversion of Pseudotetrahedral Chiral
 Copper(II) Complexes.
;
_journal_issue                   5
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2193
_journal_paper_doi               10.1021/ic502661u
_journal_volume                  54
_journal_year                    2015
_chemical_absolute_configuration rmad
_chemical_formula_moiety         'C60 H52 Cl4 Cu2 N4 O4'
_chemical_formula_sum            'C60 H52 Cl4 Cu2 N4 O4'
_chemical_formula_weight         1161.96
_chemical_name_systematic
; 
Λ-Bis{(S)-N-(1-(4-chlorophenyl)ethyl)salicylaldiminato-
κ²N,O}copper(II)  
;
_space_group_IT_number           5
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'C 2y'
_symmetry_space_group_name_H-M   'C 1 2 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 112.2580(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   25.4474(9)
_cell_length_b                   11.4921(4)
_cell_length_c                   9.9626(4)
_cell_measurement_reflns_used    6859
_cell_measurement_temperature    203(2)
_cell_measurement_theta_max      23.8295
_cell_measurement_theta_min      2.705
_cell_volume                     2696.41(17)
_computing_cell_refinement       'SAINT (Bruker, 2006)'
_computing_data_collection       'APEX2 (Bruker, 2006)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'DIAMOND (Crystal Impact, 2009)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      203(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX II CCD area detector'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0481
_diffrn_reflns_av_sigmaI/netI    0.0406
_diffrn_reflns_limit_h_max       32
_diffrn_reflns_limit_h_min       -32
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            27052
_diffrn_reflns_theta_full        27.00
_diffrn_reflns_theta_max         27.00
_diffrn_reflns_theta_min         1.73
_exptl_absorpt_coefficient_mu    1.039
_exptl_absorpt_correction_T_max  0.9655
_exptl_absorpt_correction_T_min  0.8223
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.431
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       isometric
_exptl_crystal_F_000             1196
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.03
_refine_diff_density_max         0.253
_refine_diff_density_min         -0.278
_refine_diff_density_rms         0.042
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.016(9)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.005
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     334
_refine_ls_number_reflns         5894
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.005
_refine_ls_R_factor_all          0.0410
_refine_ls_R_factor_gt           0.0305
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0284P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0586
_refine_ls_wR_factor_ref         0.0621
_reflns_number_gt                5041
_reflns_number_total             5894
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic502661u_si_002.cif
_cod_data_source_block           l9cuf
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

 Adding full bibliography for 4342448--4342455.cif.
;
_cod_original_sg_symbol_H-M      'C 2'
_cod_database_code               4342453
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Cu Cu 0.070945(11) 0.88517(3) 0.08928(3) 0.03100(7) Uani 1 1 d .
Cl1 Cl 0.34664(3) 0.78154(8) 0.51752(10) 0.0742(3) Uani 1 1 d .
Cl2 Cl 0.24799(3) 0.97216(7) 0.78030(8) 0.0616(2) Uani 1 1 d .
O1 O 0.01773(7) 0.94530(14) 0.16136(18) 0.0364(4) Uani 1 1 d .
O2 O 0.10000(7) 0.82225(14) -0.04384(18) 0.0369(4) Uani 1 1 d .
N1 N 0.10703(8) 1.04080(17) 0.0931(2) 0.0322(5) Uani 1 1 d .
N2 N 0.06706(8) 0.72945(17) 0.1761(2) 0.0318(4) Uani 1 1 d .
C1 C 0.01131(10) 1.0525(2) 0.1979(2) 0.0320(5) Uani 1 1 d .
C2 C -0.02920(10) 1.0737(2) 0.2603(3) 0.0381(6) Uani 1 1 d .
H2A H -0.0501 1.0112 0.2757 0.046 Uiso 1 1 calc R
C3 C -0.03859(11) 1.1844(2) 0.2989(3) 0.0467(7) Uani 1 1 d .
H3A H -0.0655 1.1963 0.3413 0.056 Uiso 1 1 calc R
C4 C -0.00890(11) 1.2788(3) 0.2762(3) 0.0530(8) Uani 1 1 d .
H4A H -0.0159 1.3544 0.3015 0.064 Uiso 1 1 calc R
C5 C 0.03100(11) 1.2599(2) 0.2160(3) 0.0440(6) Uani 1 1 d .
H5A H 0.0509 1.3236 0.1993 0.053 Uiso 1 1 calc R
C6 C 0.04267(10) 1.1480(2) 0.1791(3) 0.0329(6) Uani 1 1 d .
C7 C 0.08866(12) 1.1353(2) 0.1287(3) 0.0356(7) Uani 1 1 d .
H7A H 0.1073 1.2042 0.1211 0.043 Uiso 1 1 calc R
C8 C 0.15835(10) 1.0414(2) 0.0561(3) 0.0356(6) Uani 1 1 d .
H8A H 0.1488 0.9974 -0.0355 0.043 Uiso 1 1 calc R
C9 C 0.17972(11) 1.1607(2) 0.0321(3) 0.0482(7) Uani 1 1 d .
H9A H 0.1494 1.2020 -0.0428 0.072 Uiso 1 1 calc R
H9B H 0.2115 1.1510 0.0020 0.072 Uiso 1 1 calc R
H9C H 0.1918 1.2049 0.1216 0.072 Uiso 1 1 calc R
C10 C 0.20484(9) 0.9741(2) 0.1727(3) 0.0325(5) Uani 1 1 d .
C11 C 0.22411(10) 1.0098(2) 0.3167(3) 0.0362(6) Uani 1 1 d .
H11A H 0.2069 1.0738 0.3425 0.043 Uiso 1 1 calc R
C12 C 0.26831(11) 0.9521(2) 0.4224(3) 0.0423(6) Uani 1 1 d .
H12A H 0.2822 0.9782 0.5190 0.051 Uiso 1 1 calc R
C13 C 0.29165(10) 0.8561(2) 0.3840(3) 0.0439(7) Uani 1 1 d .
C14 C 0.27256(11) 0.8172(3) 0.2433(3) 0.0488(7) Uani 1 1 d .
H14A H 0.2885 0.7506 0.2188 0.059 Uiso 1 1 calc R
C15 C 0.22941(9) 0.8778(3) 0.1384(3) 0.0419(5) Uani 1 1 d .
H15A H 0.2166 0.8527 0.0415 0.050 Uiso 1 1 calc R
C16 C 0.10695(10) 0.7134(2) -0.0702(3) 0.0313(5) Uani 1 1 d .
C17 C 0.12773(11) 0.6866(2) -0.1796(3) 0.0397(6) Uani 1 1 d .
H17A H 0.1358 0.7475 -0.2318 0.048 Uiso 1 1 calc R
C18 C 0.13636(11) 0.5748(2) -0.2114(3) 0.0432(6) Uani 1 1 d .
H18A H 0.1504 0.5604 -0.2845 0.052 Uiso 1 1 calc R
C19 C 0.12488(12) 0.4818(2) -0.1382(3) 0.0478(7) Uani 1 1 d .
H19A H 0.1307 0.4048 -0.1611 0.057 Uiso 1 1 calc R
C20 C 0.10481(12) 0.5052(2) -0.0316(3) 0.0466(7) Uani 1 1 d .
H20A H 0.0970 0.4427 0.0187 0.056 Uiso 1 1 calc R
C21 C 0.09551(10) 0.6190(2) 0.0055(3) 0.0328(5) Uani 1 1 d .
C22 C 0.07783(12) 0.6339(3) 0.1257(3) 0.0373(7) Uani 1 1 d .
H22A H 0.0737 0.5655 0.1726 0.045 Uiso 1 1 calc R
C23 C 0.05424(11) 0.7300(2) 0.3104(3) 0.0359(6) Uani 1 1 d .
H23A H 0.0196 0.7773 0.2900 0.043 Uiso 1 1 calc R
C24 C 0.04314(13) 0.6105(2) 0.3620(3) 0.0491(7) Uani 1 1 d .
H24A H 0.0121 0.5729 0.2850 0.074 Uiso 1 1 calc R
H24B H 0.0333 0.6199 0.4464 0.074 Uiso 1 1 calc R
H24C H 0.0770 0.5630 0.3872 0.074 Uiso 1 1 calc R
C25 C 0.10268(10) 0.7924(2) 0.4274(3) 0.0342(5) Uani 1 1 d .
C26 C 0.15744(11) 0.7485(2) 0.4752(3) 0.0414(6) Uani 1 1 d .
H26A H 0.1645 0.6803 0.4330 0.050 Uiso 1 1 calc R
C27 C 0.20167(11) 0.8027(2) 0.5832(3) 0.0433(6) Uani 1 1 d .
H27A H 0.2384 0.7708 0.6154 0.052 Uiso 1 1 calc R
C28 C 0.19170(11) 0.9037(3) 0.6437(3) 0.0419(7) Uani 1 1 d .
C29 C 0.13795(12) 0.9500(2) 0.5987(3) 0.0430(6) Uani 1 1 d .
H29A H 0.1314 1.0188 0.6410 0.052 Uiso 1 1 calc R
C30 C 0.09363(10) 0.8946(3) 0.4907(2) 0.0381(5) Uani 1 1 d .
H30B H 0.0569 0.9264 0.4597 0.046 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
O1 Cu O2 159.19(7) .
O1 Cu N1 93.19(8) .
O2 Cu N1 93.23(8) .
O1 Cu N2 90.17(8) .
O2 Cu N2 93.30(7) .
N1 Cu N2 152.24(8) .
O1 Cu Cu 54.60(5) 2
O2 Cu Cu 104.81(5) 2
N1 Cu Cu 113.70(5) 2
N2 Cu Cu 90.55(5) 2
C1 O1 Cu 129.19(16) .
C16 O2 Cu 128.87(15) .
C7 N1 C8 120.7(2) .
C7 N1 Cu 123.21(18) .
C8 N1 Cu 116.07(15) .
C22 N2 C23 120.5(2) .
C22 N2 Cu 122.92(18) .
C23 N2 Cu 116.49(15) .
O1 C1 C6 123.9(2) .
O1 C1 C2 118.2(2) .
C6 C1 C2 117.9(2) .
C3 C2 C1 121.0(3) .
C3 C2 H2A 119.5 .
C1 C2 H2A 119.5 .
C2 C3 C4 120.9(3) .
C2 C3 H3A 119.5 .
C4 C3 H3A 119.5 .
C5 C4 C3 118.9(3) .
C5 C4 H4A 120.5 .
C3 C4 H4A 120.5 .
C4 C5 C6 121.6(3) .
C4 C5 H5A 119.2 .
C6 C5 H5A 119.2 .
C5 C6 C1 119.5(2) .
C5 C6 C7 117.6(2) .
C1 C6 C7 122.8(2) .
N1 C7 C6 127.5(3) .
N1 C7 H7A 116.3 .
C6 C7 H7A 116.3 .
N1 C8 C10 108.16(18) .
N1 C8 C9 116.3(2) .
C10 C8 C9 110.9(2) .
N1 C8 H8A 107.0 .
C10 C8 H8A 107.0 .
C9 C8 H8A 107.0 .
C8 C9 H9A 109.5 .
C8 C9 H9B 109.5 .
H9A C9 H9B 109.5 .
C8 C9 H9C 109.5 .
H9A C9 H9C 109.5 .
H9B C9 H9C 109.5 .
C15 C10 C11 118.5(2) .
C15 C10 C8 121.0(2) .
C11 C10 C8 120.5(2) .
C12 C11 C10 120.7(2) .
C12 C11 H11A 119.6 .
C10 C11 H11A 119.6 .
C13 C12 C11 119.0(2) .
C13 C12 H12A 120.5 .
C11 C12 H12A 120.5 .
C14 C13 C12 121.5(2) .
C14 C13 Cl1 119.3(2) .
C12 C13 Cl1 119.2(2) .
C13 C14 C15 118.7(3) .
C13 C14 H14A 120.7 .
C15 C14 H14A 120.7 .
C10 C15 C14 121.5(2) .
C10 C15 H15A 119.2 .
C14 C15 H15A 119.2 .
O2 C16 C21 123.9(2) .
O2 C16 C17 118.9(2) .
C21 C16 C17 117.2(2) .
C18 C17 C16 121.7(2) .
C18 C17 H17A 119.1 .
C16 C17 H17A 119.1 .
C17 C18 C19 121.4(2) .
C17 C18 H18A 119.3 .
C19 C18 H18A 119.3 .
C20 C19 C18 118.1(2) .
C20 C19 H19A 120.9 .
C18 C19 H19A 120.9 .
C19 C20 C21 122.5(3) .
C19 C20 H20A 118.7 .
C21 C20 H20A 118.7 .
C20 C21 C16 119.0(2) .
C20 C21 C22 117.9(2) .
C16 C21 C22 123.0(2) .
N2 C22 C21 127.5(3) .
N2 C22 H22A 116.2 .
C21 C22 H22A 116.2 .
N2 C23 C25 107.50(18) .
N2 C23 C24 115.4(2) .
C25 C23 C24 111.5(2) .
N2 C23 H23A 107.4 .
C25 C23 H23A 107.4 .
C24 C23 H23A 107.4 .
C23 C24 H24A 109.5 .
C23 C24 H24B 109.5 .
H24A C24 H24B 109.5 .
C23 C24 H24C 109.5 .
H24A C24 H24C 109.5 .
H24B C24 H24C 109.5 .
C26 C25 C30 117.9(2) .
C26 C25 C23 120.7(2) .
C30 C25 C23 121.4(2) .
C27 C26 C25 121.5(2) .
C27 C26 H26A 119.3 .
C25 C26 H26A 119.3 .
C28 C27 C26 119.5(2) .
C28 C27 H27A 120.3 .
C26 C27 H27A 120.3 .
C29 C28 C27 120.6(2) .
C29 C28 Cl2 120.1(2) .
C27 C28 Cl2 119.3(2) .
C28 C29 C30 119.5(2) .
C28 C29 H29A 120.2 .
C30 C29 H29A 120.2 .
C29 C30 C25 120.9(2) .
C29 C30 H30B 119.5 .
C25 C30 H30B 119.5 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cu O1 1.8878(16) .
Cu O2 1.8897(17) .
Cu N1 2.0044(19) .
Cu N2 2.0062(19) .
Cu Cu 3.3669(5) 2
Cl1 C13 1.747(3) .
Cl2 C28 1.745(3) .
O1 C1 1.312(3) .
O2 C16 1.304(3) .
N1 C7 1.285(3) .
N1 C8 1.485(3) .
N2 C22 1.279(3) .
N2 C23 1.492(3) .
C1 C6 1.411(3) .
C1 C2 1.412(3) .
C2 C3 1.376(3) .
C2 H2A 0.9400 .
C3 C4 1.388(4) .
C3 H3A 0.9400 .
C4 C5 1.378(4) .
C4 H4A 0.9400 .
C5 C6 1.400(4) .
C5 H5A 0.9400 .
C6 C7 1.445(4) .
C7 H7A 0.9400 .
C8 C10 1.518(3) .
C8 C9 1.527(3) .
C8 H8A 0.9900 .
C9 H9A 0.9700 .
C9 H9B 0.9700 .
C9 H9C 0.9700 .
C10 C15 1.376(4) .
C10 C11 1.391(3) .
C11 C12 1.384(3) .
C11 H11A 0.9400 .
C12 C13 1.375(4) .
C12 H12A 0.9400 .
C13 C14 1.372(4) .
C14 C15 1.384(4) .
C14 H14A 0.9400 .
C15 H15A 0.9400 .
C16 C21 1.413(3) .
C16 C17 1.414(3) .
C17 C18 1.360(3) .
C17 H17A 0.9400 .
C18 C19 1.386(4) .
C18 H18A 0.9400 .
C19 C20 1.368(3) .
C19 H19A 0.9400 .
C20 C21 1.403(3) .
C20 H20A 0.9400 .
C21 C22 1.440(4) .
C22 H22A 0.9400 .
C23 C25 1.519(3) .
C23 C24 1.529(3) .
C23 H23A 0.9900 .
C24 H24A 0.9700 .
C24 H24B 0.9700 .
C24 H24C 0.9700 .
C25 C26 1.386(3) .
C25 C30 1.393(4) .
C26 C27 1.376(4) .
C26 H26A 0.9400 .
C27 C28 1.376(4) .
C27 H27A 0.9400 .
C28 C29 1.375(4) .
C29 C30 1.384(3) .
C29 H29A 0.9400 .
C30 H30B 0.9400 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
O2 Cu O1 C1 -108.2(2) .
N1 Cu O1 C1 -0.4(2) .
N2 Cu O1 C1 152.00(19) .
Cu Cu O1 C1 -117.4(2) 2
O1 Cu O2 C16 -92.7(3) .
N1 Cu O2 C16 159.5(2) .
N2 Cu O2 C16 6.5(2) .
Cu Cu O2 C16 -84.9(2) 2
O1 Cu N1 C7 -3.6(2) .
O2 Cu N1 C7 156.6(2) .
N2 Cu N1 C7 -100.1(2) .
Cu Cu N1 C7 48.9(2) 2
O1 Cu N1 C8 174.59(15) .
O2 Cu N1 C8 -25.22(16) .
N2 Cu N1 C8 78.1(2) .
Cu Cu N1 C8 -132.94(14) 2
O1 Cu N2 C22 153.8(2) .
O2 Cu N2 C22 -5.7(2) .
N1 Cu N2 C22 -109.0(2) .
Cu Cu N2 C22 99.2(2) 2
O1 Cu N2 C23 -29.91(16) .
O2 Cu N2 C23 170.62(16) .
N1 Cu N2 C23 67.3(2) .
Cu Cu N2 C23 -84.51(15) 2
Cu O1 C1 C6 4.7(3) .
Cu O1 C1 C2 -175.04(15) .
O1 C1 C2 C3 -179.0(2) .
C6 C1 C2 C3 1.3(3) .
C1 C2 C3 C4 0.7(4) .
C2 C3 C4 C5 -1.0(4) .
C3 C4 C5 C6 -0.8(4) .
C4 C5 C6 C1 2.8(4) .
C4 C5 C6 C7 -174.6(2) .
O1 C1 C6 C5 177.3(2) .
C2 C1 C6 C5 -2.9(3) .
O1 C1 C6 C7 -5.4(4) .
C2 C1 C6 C7 174.3(2) .
C8 N1 C7 C6 -174.3(2) .
Cu N1 C7 C6 3.8(4) .
C5 C6 C7 N1 178.2(3) .
C1 C6 C7 N1 0.9(4) .
C7 N1 C8 C10 113.1(2) .
Cu N1 C8 C10 -65.2(2) .
C7 N1 C8 C9 -12.4(3) .
Cu N1 C8 C9 169.35(18) .
N1 C8 C10 C15 121.2(2) .
C9 C8 C10 C15 -110.2(3) .
N1 C8 C10 C11 -59.8(3) .
C9 C8 C10 C11 68.8(3) .
C15 C10 C11 C12 2.1(4) .
C8 C10 C11 C12 -176.9(2) .
C10 C11 C12 C13 -2.3(4) .
C11 C12 C13 C14 0.7(4) .
C11 C12 C13 Cl1 -178.9(2) .
C12 C13 C14 C15 1.1(4) .
Cl1 C13 C14 C15 -179.3(2) .
C11 C10 C15 C14 -0.3(4) .
C8 C10 C15 C14 178.8(2) .
C13 C14 C15 C10 -1.3(4) .
Cu O2 C16 C21 -3.1(3) .
Cu O2 C16 C17 177.67(16) .
O2 C16 C17 C18 179.4(2) .
C21 C16 C17 C18 0.1(4) .
C16 C17 C18 C19 0.3(4) .
C17 C18 C19 C20 -0.4(4) .
C18 C19 C20 C21 0.1(4) .
C19 C20 C21 C16 0.3(4) .
C19 C20 C21 C22 -176.0(3) .
O2 C16 C21 C20 -179.7(2) .
C17 C16 C21 C20 -0.4(3) .
O2 C16 C21 C22 -3.5(4) .
C17 C16 C21 C22 175.8(2) .
C23 N2 C22 C21 -174.4(2) .
Cu N2 C22 C21 1.8(4) .
C20 C21 C22 N2 -179.8(3) .
C16 C21 C22 N2 4.0(4) .
C22 N2 C23 C25 113.1(3) .
Cu N2 C23 C25 -63.3(2) .
C22 N2 C23 C24 -12.0(3) .
Cu N2 C23 C24 171.62(18) .
N2 C23 C25 C26 -62.4(3) .
C24 C23 C25 C26 64.9(3) .
N2 C23 C25 C30 118.0(2) .
C24 C23 C25 C30 -114.6(3) .
C30 C25 C26 C27 0.9(4) .
C23 C25 C26 C27 -178.7(2) .
C25 C26 C27 C28 -1.1(4) .
C26 C27 C28 C29 0.9(4) .
C26 C27 C28 Cl2 -179.8(2) .
C27 C28 C29 C30 -0.5(4) .
Cl2 C28 C29 C30 -179.73(19) .
C28 C29 C30 C25 0.3(4) .
C26 C25 C30 C29 -0.4(4) .
C23 C25 C30 C29 179.1(2) .
