#------------------------------------------------------------------------------
#$Date: 2016-02-13 14:50:18 +0200 (Sat, 13 Feb 2016) $
#$Revision: 176428 $
#$URL: svn://www.crystallography.net/cod/cif/4/51/36/4513609.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4513609
loop_
_publ_author_name
'Liu, Jian-Jun'
'Guan, Ying-Fang'
'Lin, Mei-Jin'
'Huang, Chang-Cang'
'Dai, Wen-Xin'
_publ_section_title
;
 Luminescent Coordination Polymer with Conjugated Lewis Acid Sites for the
 Detection of Organic Amines
;
_journal_issue                   10
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              5040
_journal_paper_doi               10.1021/acs.cgd.5b01026
_journal_volume                  15
_journal_year                    2015
_chemical_formula_moiety         'C72 H48 Eu3 N13 O35, 10(C H4 O)'
_chemical_formula_sum            'C82 H88 Eu3 N13 O45'
_chemical_formula_weight         2431.53
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 115.85(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   23.068(5)
_cell_length_b                   19.934(4)
_cell_length_c                   22.714(5)
_cell_measurement_reflns_used    13967
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.5010
_cell_measurement_theta_min      3.2406
_cell_volume                     9400(4)
_computing_cell_refinement       'CrystalClear (Rigaku Inc., 2007)'
_computing_data_collection       'CrystalClear (Rigaku Inc., 2007)'
_computing_data_reduction        'CrystalClear (Rigaku Inc., 2007)'
_computing_molecular_graphics    'DIAMOND (Brandenburg, 2004)'
_computing_publication_material  'SHELXL97 and publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Saturn724 (2x2 bin mode)'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0706
_diffrn_reflns_av_sigmaI/netI    0.0694
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            39322
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         3.12
_exptl_absorpt_coefficient_mu    2.082
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.7952
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'CrystalClear (Rigaku Inc., 2007)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.718
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             4880
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.22
_platon_squeeze_details
;
SQUEEZE removed 10 disordered methanol molecules per formula. 
This value calculated based upon volume/count_electrons analysis 
and TGA and elemental analysis
;
_refine_diff_density_max         1.145
_refine_diff_density_min         -1.479
_refine_diff_density_rms         0.155
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.111
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     566
_refine_ls_number_reflns         10777
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.111
_refine_ls_R_factor_all          0.0872
_refine_ls_R_factor_gt           0.0706
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0728P)²+78.6357P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1675
_refine_ls_wR_factor_ref         0.1775
_reflns_number_gt                9018
_reflns_number_total             10777
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg5b01026_si_002.cif
_cod_data_source_block           c2c
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3271 2015-04-21 07:52:19Z andrius 

 Adding full bibliography for 4513609.cif.
;
_cod_original_cell_volume        9400(3)
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               4513609
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu -0.209000(17) 1.09130(2) 0.250767(17) 0.03209(12) Uani 1 1 d . . .
Eu2 Eu 0.0000 0.99227(2) 0.2500 0.02560(13) Uani 1 2 d S . .
C1 C -0.1684(3) 0.9640(4) 0.1691(3) 0.0305(15) Uani 1 1 d . . .
C2 C -0.2017(3) 0.9293(3) 0.1034(3) 0.0266(14) Uani 1 1 d . A .
C3 C -0.1638(3) 0.9006(4) 0.0765(4) 0.0376(18) Uani 1 1 d . . .
H3 H -0.1192 0.9032 0.0986 0.045 Uiso 1 1 calc R A .
C4 C -0.1925(3) 0.8683(4) 0.0171(3) 0.0346(17) Uani 1 1 d . A .
H4 H -0.1675 0.8509 -0.0022 0.042 Uiso 1 1 calc R . .
C5 C -0.2591(3) 0.8619(3) -0.0136(3) 0.0278(14) Uani 1 1 d . . .
C6 C -0.2973(3) 0.8891(4) 0.0130(3) 0.0314(15) Uani 1 1 d . A .
H6 H -0.3418 0.8841 -0.0076 0.038 Uiso 1 1 calc R . .
C7 C -0.2674(3) 0.9245(4) 0.0719(3) 0.0279(14) Uani 1 1 d . . .
H7 H -0.2924 0.9450 0.0897 0.033 Uiso 1 1 calc R A .
C8 C -0.2560(4) 0.7745(4) -0.0864(3) 0.0321(15) Uani 1 1 d . . .
H8 H -0.2167 0.7611 -0.0532 0.038 Uiso 1 1 calc R A .
C9 C -0.2797(4) 0.7419(4) -0.1456(3) 0.0328(16) Uani 1 1 d . A .
H9 H -0.2559 0.7079 -0.1528 0.039 Uiso 1 1 calc R . .
C10 C -0.3389(3) 0.7597(4) -0.1943(3) 0.0268(14) Uani 1 1 d . . .
C11 C -0.3735(4) 0.8098(4) -0.1806(3) 0.0384(17) Uani 1 1 d . A .
H11 H -0.4147 0.8210 -0.2115 0.046 Uiso 1 1 calc R . .
C12 C -0.3466(4) 0.8426(4) -0.1216(3) 0.0385(17) Uani 1 1 d . . .
H12 H -0.3691 0.8772 -0.1134 0.046 Uiso 1 1 calc R A .
C13 C -0.3470(3) 0.6621(4) -0.2668(3) 0.0285(14) Uani 1 1 d . . .
H13 H -0.3144 0.6409 -0.2313 0.034 Uiso 1 1 calc R A .
C14 C -0.3763(3) 0.6298(4) -0.3266(3) 0.0268(14) Uani 1 1 d . A .
H14 H -0.3644 0.5861 -0.3307 0.032 Uiso 1 1 calc R . .
C15 C -0.4392(3) 0.7241(3) -0.3733(3) 0.0286(14) Uani 1 1 d . A .
H15 H -0.4694 0.7457 -0.4102 0.034 Uiso 1 1 calc R . .
C16 C -0.4130(4) 0.7566(4) -0.3145(3) 0.0323(15) Uani 1 1 d . . .
H16 H -0.4265 0.7998 -0.3110 0.039 Uiso 1 1 calc R A .
C17 C -0.3665(3) 0.7256(4) -0.2603(3) 0.0272(14) Uani 1 1 d . A .
C18 C -0.4168(3) 0.5928(4) -0.4665(3) 0.0330(16) Uani 1 1 d . . .
H18 H -0.3724 0.5896 -0.4426 0.040 Uiso 1 1 calc R . .
C19 C -0.4481(3) 0.5635(4) -0.5283(3) 0.0327(16) Uani 1 1 d . . .
H19 H -0.4242 0.5407 -0.5460 0.039 Uiso 1 1 calc R . .
C20 C -0.5143(3) 0.5681(3) -0.5635(3) 0.0213(12) Uani 1 1 d . . .
C21 C -0.5493(3) 0.6006(3) -0.5354(3) 0.0229(13) Uani 1 1 d . . .
H21 H -0.5939 0.6030 -0.5583 0.028 Uiso 1 1 calc R . .
C22 C -0.5191(3) 0.6294(3) -0.4741(3) 0.0237(13) Uani 1 1 d . . .
H22 H -0.5430 0.6501 -0.4553 0.028 Uiso 1 1 calc R . .
C23 C -0.4535(3) 0.6268(3) -0.4418(3) 0.0240(13) Uani 1 1 d . A .
C24 C -0.5474(3) 0.5399(3) -0.6315(3) 0.0248(13) Uani 1 1 d . . .
C25 C -0.1014(4) 1.1370(4) 0.1882(4) 0.0416(19) Uani 1 1 d . . .
C26 C -0.0844(3) 1.1946(3) 0.1551(4) 0.0304(15) Uani 1 1 d . A .
C27 C -0.1288(4) 1.2452(4) 0.1280(5) 0.051(2) Uani 1 1 d . . .
H27 H -0.1682 1.2433 0.1300 0.061 Uiso 1 1 calc R A .
C28 C -0.1142(4) 1.3003(4) 0.0972(6) 0.061(3) Uani 1 1 d . A .
H28 H -0.1437 1.3347 0.0784 0.073 Uiso 1 1 calc R . .
C29 C -0.0558(4) 1.3014(4) 0.0960(4) 0.0347(16) Uani 1 1 d . . .
C30 C -0.0116(4) 1.2512(4) 0.1211(4) 0.044(2) Uani 1 1 d . A .
H30 H 0.0272 1.2525 0.1179 0.053 Uiso 1 1 calc R . .
C31 C -0.0264(4) 1.1979(4) 0.1519(4) 0.046(2) Uani 1 1 d . . .
H31 H 0.0037 1.1639 0.1707 0.056 Uiso 1 1 calc R A .
C32 C -0.0791(5) 1.3813(5) 0.0063(5) 0.068(3) Uani 1 1 d . . .
H32 H -0.1172 1.3582 -0.0181 0.082 Uiso 1 1 calc R A .
C33 C -0.0649(5) 1.4351(5) -0.0200(5) 0.066(3) Uani 1 1 d . A .
H33 H -0.0932 1.4488 -0.0619 0.080 Uiso 1 1 calc R . .
C34 C -0.0093(4) 1.4705(4) 0.0139(4) 0.047(2) Uani 1 1 d . . .
C35 C 0.0348(4) 1.4440(4) 0.0743(4) 0.046(2) Uani 1 1 d . A .
H35 H 0.0753 1.4632 0.0968 0.055 Uiso 1 1 calc R . .
C36 C 0.0173(4) 1.3895(4) 0.0992(4) 0.047(2) Uani 1 1 d . . .
H36 H 0.0461 1.3728 0.1397 0.057 Uiso 1 1 calc R A .
O1 O -0.2039(2) 0.9949(3) 0.1891(2) 0.0345(12) Uani 1 1 d . A .
O2 O -0.1097(2) 0.9569(3) 0.1996(2) 0.0414(14) Uani 1 1 d . A .
O3 O -0.5139(2) 0.5056(3) -0.6512(2) 0.0376(13) Uani 1 1 d . . .
O4 O -0.6063(2) 0.5517(2) -0.6647(2) 0.0293(10) Uani 1 1 d . . .
O5A O -0.0518(12) 1.0983(8) 0.2221(15) 0.055(8) Uani 0.60(5) 1 d P A 1
O5B O -0.0773(9) 1.0780(10) 0.1832(15) 0.033(6) Uani 0.40(5) 1 d P A 2
O6 O -0.1487(2) 1.1397(3) 0.1982(3) 0.0392(12) Uani 1 1 d . A .
O7 O -0.0001(2) 0.8728(2) 0.2979(2) 0.0285(10) Uani 1 1 d . A .
O8 O 0.0000 0.7776(3) 0.2500 0.053(2) Uani 1 2 d S . .
O9 O -0.2265(3) 0.9966(3) 0.3221(3) 0.0487(15) Uani 1 1 d . . .
O10 O -0.2146(3) 1.0960(3) 0.3632(2) 0.0378(12) Uani 1 1 d . . .
O11 O -0.2226(6) 1.0113(5) 0.4181(4) 0.120(4) Uani 1 1 d . . .
O12 O -0.3281(4) 1.0215(4) 0.1861(3) 0.0669(19) Uani 1 1 d . . .
O13 O -0.3245(3) 1.1077(5) 0.2426(3) 0.070(2) Uani 1 1 d . . .
O14 O -0.4149(4) 1.0620(6) 0.1874(5) 0.112(4) Uani 1 1 d . . .
O15 O -0.2900(3) 1.1287(5) 0.1297(3) 0.0598(19) Uani 1 1 d . . .
O16 O -0.2628(4) 1.2099(4) 0.1987(4) 0.073(2) Uani 1 1 d . . .
O17 O -0.3190(4) 1.2305(6) 0.0939(4) 0.107(4) Uani 1 1 d . . .
O18 O -0.1557(4) 1.1959(3) 0.3154(3) 0.0613(19) Uani 1 1 d . . .
N1 N -0.2881(3) 0.8251(3) -0.0754(3) 0.0284(12) Uani 1 1 d . A .
N2 N -0.4214(3) 0.6605(3) -0.3782(2) 0.0226(11) Uani 1 1 d . . .
N3 N -0.0397(3) 1.3594(3) 0.0676(3) 0.0416(16) Uani 1 1 d . A .
N4 N 0.0000 0.8411(4) 0.2500 0.0325(19) Uani 1 2 d S . .
N5 N -0.2220(4) 1.0340(5) 0.3679(3) 0.052(2) Uani 1 1 d . . .
N6 N -0.3540(4) 1.0637(5) 0.2071(4) 0.060(2) Uani 1 1 d . . .
N7 N -0.2912(4) 1.1918(6) 0.1403(5) 0.073(3) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O6 Eu1 O1 81.06(19) . .
O6 Eu1 O4 86.98(17) . 3_556
O1 Eu1 O4 85.55(16) . 3_556
O6 Eu1 O18 73.6(2) . .
O1 Eu1 O18 149.0(2) . .
O4 Eu1 O18 75.6(2) 3_556 .
O6 Eu1 O13 135.3(2) . .
O1 Eu1 O13 111.5(2) . .
O4 Eu1 O13 135.00(19) 3_556 .
O18 Eu1 O13 99.2(3) . .
O6 Eu1 O10 139.39(19) . .
O1 Eu1 O10 129.22(18) . .
O4 Eu1 O10 71.79(16) 3_556 .
O18 Eu1 O10 67.9(2) . .
O13 Eu1 O10 65.24(19) . .
O6 Eu1 O9 150.96(19) . .
O1 Eu1 O9 81.15(19) . .
O4 Eu1 O9 68.91(18) 3_556 .
O18 Eu1 O9 113.51(19) . .
O13 Eu1 O9 73.0(2) . .
O10 Eu1 O9 48.53(18) . .
O6 Eu1 O15 70.85(19) . .
O1 Eu1 O15 79.2(2) . .
O4 Eu1 O15 154.70(19) 3_556 .
O18 Eu1 O15 108.1(2) . .
O13 Eu1 O15 70.0(2) . .
O10 Eu1 O15 133.3(2) . .
O9 Eu1 O15 127.4(2) . .
O6 Eu1 O16 71.6(2) . .
O1 Eu1 O16 125.0(2) . .
O4 Eu1 O16 137.2(2) 3_556 .
O18 Eu1 O16 63.0(3) . .
O13 Eu1 O16 66.3(3) . .
O10 Eu1 O16 100.9(2) . .
O9 Eu1 O16 137.4(2) . .
O15 Eu1 O16 47.2(3) . .
O6 Eu1 O12 125.3(2) . .
O1 Eu1 O12 65.93(19) . .
O4 Eu1 O12 129.4(2) 3_556 .
O18 Eu1 O12 144.5(2) . .
O13 Eu1 O12 45.5(2) . .
O10 Eu1 O12 94.25(19) . .
O9 Eu1 O12 66.1(2) . .
O15 Eu1 O12 61.4(2) . .
O16 Eu1 O12 92.7(3) . .
O6 Eu1 N5 153.07(19) . .
O1 Eu1 N5 105.0(2) . .
O4 Eu1 N5 67.73(18) 3_556 .
O18 Eu1 N5 90.6(2) . .
O13 Eu1 N5 67.7(2) . .
O10 Eu1 N5 24.4(2) . .
O9 Eu1 N5 24.2(2) . .
O15 Eu1 N5 135.8(2) . .
O16 Eu1 N5 120.9(2) . .
O12 Eu1 N5 80.0(2) . .
O6 Eu1 N6 133.8(2) . .
O1 Eu1 N6 89.5(2) . .
O4 Eu1 N6 137.5(2) 3_556 .
O18 Eu1 N6 121.0(3) . .
O13 Eu1 N6 21.9(2) . .
O10 Eu1 N6 79.2(2) . .
O9 Eu1 N6 68.6(2) . .
O15 Eu1 N6 63.0(2) . .
O16 Eu1 N6 77.8(3) . .
O12 Eu1 N6 23.6(2) . .
N5 Eu1 N6 73.0(2) . .
O5A Eu2 O5A 54.2(14) 2 .
O5A Eu2 O2 134.2(7) 2 .
O5A Eu2 O2 80.2(7) . .
O5A Eu2 O2 80.2(7) 2 2
O5A Eu2 O2 134.2(7) . 2
O2 Eu2 O2 145.6(3) . 2
O5A Eu2 O3 84.8(5) 2 3_556
O5A Eu2 O3 84.0(6) . 3_556
O2 Eu2 O3 86.32(18) . 3_556
O2 Eu2 O3 97.42(17) 2 3_556
O5A Eu2 O3 84.0(6) 2 4_454
O5A Eu2 O3 84.8(5) . 4_454
O2 Eu2 O3 97.42(17) . 4_454
O2 Eu2 O3 86.32(18) 2 4_454
O3 Eu2 O3 167.4(3) 3_556 4_454
O5A Eu2 O5B 21.7(4) 2 2
O5A Eu2 O5B 72.0(14) . 2
O2 Eu2 O5B 146.5(4) . 2
O2 Eu2 O5B 65.0(5) 2 2
O3 Eu2 O5B 72.8(6) 3_556 2
O3 Eu2 O5B 98.2(6) 4_454 2
O5A Eu2 O5B 72.0(14) 2 .
O5A Eu2 O5B 21.7(4) . .
O2 Eu2 O5B 65.0(5) . .
O2 Eu2 O5B 146.5(4) 2 .
O3 Eu2 O5B 98.2(6) 3_556 .
O3 Eu2 O5B 72.8(6) 4_454 .
O5B Eu2 O5B 91.9(14) 2 .
O5A Eu2 O7 146.0(3) 2 2
O5A Eu2 O7 142.2(8) . 2
O2 Eu2 O7 74.02(17) . 2
O2 Eu2 O7 74.81(18) 2 2
O3 Eu2 O7 120.69(17) 3_556 2
O3 Eu2 O7 71.90(17) 4_454 2
O5B Eu2 O7 139.2(4) 2 2
O5B Eu2 O7 120.5(8) . 2
O5A Eu2 O7 142.2(8) 2 .
O5A Eu2 O7 146.0(3) . .
O2 Eu2 O7 74.81(19) . .
O2 Eu2 O7 74.02(17) 2 .
O3 Eu2 O7 71.90(17) 3_556 .
O3 Eu2 O7 120.69(17) 4_454 .
O5B Eu2 O7 120.5(8) 2 .
O5B Eu2 O7 139.2(4) . .
O7 Eu2 O7 49.2(2) 2 .
O5A Eu2 N4 152.9(7) 2 .
O5A Eu2 N4 152.9(7) . .
O2 Eu2 N4 72.82(15) . .
O2 Eu2 N4 72.82(15) 2 .
O3 Eu2 N4 96.30(13) 3_556 .
O3 Eu2 N4 96.30(13) 4_454 .
O5B Eu2 N4 134.1(7) 2 .
O5B Eu2 N4 134.1(7) . .
O7 Eu2 N4 24.58(10) 2 .
O7 Eu2 N4 24.58(10) . .
O2 C1 O1 125.7(6) . .
O2 C1 C2 117.6(6) . .
O1 C1 C2 116.6(6) . .
C7 C2 C3 120.4(6) . .
C7 C2 C1 121.2(6) . .
C3 C2 C1 118.3(6) . .
C4 C3 C2 119.9(6) . .
C3 C4 C5 119.3(6) . .
C6 C5 C4 121.5(6) . .
C6 C5 N1 120.4(6) . .
C4 C5 N1 118.1(6) . .
C5 C6 C7 118.3(6) . .
C2 C7 C6 120.5(6) . .
N1 C8 C9 121.6(7) . .
C8 C9 C10 119.7(7) . .
C9 C10 C11 117.9(6) . .
C9 C10 C17 121.4(6) . .
C11 C10 C17 120.6(6) . .
C12 C11 C10 120.0(7) . .
N1 C12 C11 120.7(7) . .
C17 C13 C14 119.4(6) . .
N2 C14 C13 120.7(6) . .
N2 C15 C16 120.2(6) . .
C15 C16 C17 120.0(7) . .
C13 C17 C16 118.9(6) . .
C13 C17 C10 120.3(6) . .
C16 C17 C10 120.7(6) . .
C23 C18 C19 118.3(6) . .
C20 C19 C18 120.7(6) . .
C19 C20 C21 118.8(5) . .
C19 C20 C24 120.5(6) . .
C21 C20 C24 120.7(5) . .
C22 C21 C20 121.2(6) . .
C23 C22 C21 118.8(6) . .
C22 C23 C18 122.2(6) . .
C22 C23 N2 118.5(6) . .
C18 C23 N2 119.3(6) . .
O3 C24 O4 124.2(6) . .
O3 C24 C20 117.1(6) . .
O4 C24 C20 118.6(5) . .
O6 C25 O5A 122.8(8) . .
O6 C25 O5B 120.1(9) . .
O5A C25 O5B 40.5(7) . .
O6 C25 C26 120.7(6) . .
O5A C25 C26 112.9(9) . .
O5B C25 C26 114.9(9) . .
C31 C26 C27 119.6(7) . .
C31 C26 C25 122.1(6) . .
C27 C26 C25 118.3(7) . .
C26 C27 C28 119.8(8) . .
C29 C28 C27 118.2(7) . .
C28 C29 C30 123.1(7) . .
C28 C29 N3 118.0(7) . .
C30 C29 N3 118.9(7) . .
C29 C30 C31 117.9(7) . .
C26 C31 C30 121.3(7) . .
C33 C32 N3 122.0(8) . .
C32 C33 C34 121.0(8) . .
C33 C34 C35 117.2(7) . .
C33 C34 C34 122.8(9) . 5_585
C35 C34 C34 119.5(9) . 5_585
C36 C35 C34 119.0(7) . .
N3 C36 C35 122.4(7) . .
C1 O1 Eu1 143.7(5) . .
C1 O2 Eu2 156.0(6) . .
C24 O3 Eu2 138.1(4) . 3_444
C24 O4 Eu1 163.3(5) . 3_444
C25 O5A Eu2 153(2) . .
C25 O5B Eu2 141(2) . .
C25 O6 Eu1 147.5(5) . .
N4 O7 Eu2 95.5(4) . .
N5 O9 Eu1 96.1(5) . .
N5 O10 Eu1 96.6(4) . .
N6 O12 Eu1 89.3(6) . .
N6 O13 Eu1 102.7(6) . .
N7 O15 Eu1 98.2(6) . .
N7 O16 Eu1 98.1(7) . .
C8 N1 C12 120.0(6) . .
C8 N1 C5 120.0(6) . .
C12 N1 C5 120.1(6) . .
C14 N2 C15 120.6(5) . .
C14 N2 C23 121.5(5) . .
C15 N2 C23 117.9(5) . .
C36 N3 C32 117.8(7) . .
C36 N3 C29 120.2(6) . .
C32 N3 C29 121.7(7) . .
O7 N4 O7 119.8(8) . 2
O7 N4 O8 120.1(4) . .
O7 N4 O8 120.1(4) 2 .
O7 N4 Eu2 59.9(4) . .
O7 N4 Eu2 59.9(4) 2 .
O8 N4 Eu2 180.000(1) . .
O11 N5 O9 121.5(9) . .
O11 N5 O10 119.7(9) . .
O9 N5 O10 118.7(7) . .
O11 N5 Eu1 175.4(8) . .
O9 N5 Eu1 59.8(4) . .
O10 N5 Eu1 59.0(4) . .
O13 N6 O12 122.3(8) . .
O13 N6 O14 118.3(10) . .
O12 N6 O14 119.2(10) . .
O13 N6 Eu1 55.4(5) . .
O12 N6 Eu1 67.0(5) . .
O14 N6 Eu1 171.1(9) . .
O17 N7 O16 124.2(12) . .
O17 N7 O15 119.8(12) . .
O16 N7 O15 116.0(9) . .
O17 N7 Eu1 173.1(8) . .
O16 N7 Eu1 58.6(5) . .
O15 N7 Eu1 57.8(4) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O6 2.396(5) .
Eu1 O1 2.411(5) .
Eu1 O4 2.440(5) 3_556
Eu1 O18 2.538(6) .
Eu1 O13 2.610(7) .
Eu1 O10 2.614(5) .
Eu1 O9 2.631(6) .
Eu1 O15 2.670(6) .
Eu1 O16 2.692(7) .
Eu1 O12 2.849(8) .
Eu1 N5 3.028(7) .
Eu1 N6 3.094(8) .
Eu2 O5A 2.374(10) 2
Eu2 O5A 2.374(10) .
Eu2 O2 2.384(5) .
Eu2 O2 2.384(5) 2
Eu2 O3 2.416(5) 3_556
Eu2 O3 2.416(5) 4_454
Eu2 O5B 2.457(15) 2
Eu2 O5B 2.457(15) .
Eu2 O7 2.620(5) 2
Eu2 O7 2.620(5) .
Eu2 N4 3.014(8) .
C1 O2 1.231(8) .
C1 O1 1.256(8) .
C1 C2 1.515(8) .
C2 C7 1.368(9) .
C2 C3 1.391(9) .
C3 C4 1.376(9) .
C4 C5 1.388(9) .
C5 C6 1.380(10) .
C5 N1 1.463(8) .
C6 C7 1.398(9) .
C8 N1 1.336(9) .
C8 C9 1.376(9) .
C9 C10 1.378(10) .
C10 C11 1.396(11) .
C10 C17 1.511(8) .
C11 C12 1.372(10) .
C12 N1 1.346(10) .
C13 C17 1.372(10) .
C13 C14 1.384(9) .
C14 N2 1.329(9) .
C15 N2 1.351(9) .
C15 C16 1.367(9) .
C16 C17 1.377(10) .
C18 C23 1.380(9) .
C18 C19 1.396(9) .
C19 C20 1.384(9) .
C20 C21 1.389(8) .
C20 C24 1.502(8) .
C21 C22 1.381(8) .
C22 C23 1.364(9) .
C23 N2 1.469(7) .
C24 O3 1.252(8) .
C24 O4 1.257(8) .
C25 O6 1.209(9) .
C25 O5A 1.315(19) .
C25 O5B 1.33(2) .
C25 C26 1.515(9) .
C26 C31 1.372(10) .
C26 C27 1.376(10) .
C27 C28 1.420(12) .
C28 C29 1.360(11) .
C29 C30 1.363(11) .
C29 N3 1.448(9) .
C30 C31 1.394(11) .
C32 C33 1.335(12) .
C32 N3 1.362(10) .
C33 C34 1.369(12) .
C34 C35 1.406(11) .
C34 C34 1.485(16) 5_585
C35 C36 1.364(11) .
C36 N3 1.336(10) .
O3 Eu2 2.416(5) 3_444
O4 Eu1 2.440(5) 3_444
O7 N4 1.260(6) .
O8 N4 1.266(11) .
O9 N5 1.246(9) .
O10 N5 1.259(10) .
O11 N5 1.233(9) .
O12 N6 1.239(11) .
O13 N6 1.185(11) .
O14 N6 1.276(11) .
O15 N7 1.283(12) .
O16 N7 1.249(12) .
O17 N7 1.236(11) .
N4 O7 1.260(6) 2
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.331 -0.159 0.001 2556 742 ' '
