#------------------------------------------------------------------------------
#$Date: 2019-10-28 05:07:02 +0200 (Mon, 28 Oct 2019) $
#$Revision: 219657 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/51/44/4514468.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4514468
loop_
_publ_author_name
'Wang, Chun-Yun'
'Takeda, Takashi'
'Melvin Ten Kate, Otmar'
'Funahashi, Shiro'
'Xie, Rong-Jun'
'Takahashi, Kohsei'
'Hirosaki, Naoto'
_publ_section_title
;
 New Deep-Blue-Emitting Ce-Doped A₄₋ₘB n
 C₁₉₊₂ₘX₂₉₊ₘ (A = Sr, La; B =
 Li; C = Si, Al; X = O, N; 0 ≤ m ≤ 1; 0 ≤
 n ≤ 1) Phosphors for High-Color-Rendering Warm White
 Light-Emitting Diodes.
;
_journal_issue                   32
_journal_name_full               'ACS applied materials & interfaces'
_journal_page_first              29047
_journal_page_last               29055
_journal_paper_doi               10.1021/acsami.9b09982
_journal_volume                  11
_journal_year                    2019
_chemical_absolute_configuration unk
_chemical_formula_sum            'Al6.03 Eu3.6 Li N22.59 O6.82 Si13.78'
_chemical_formula_weight         1528.66
_space_group_IT_number           156
_space_group_name_Hall           'P 3 -2"'
_space_group_name_H-M_alt        'P 3 m 1'
_symmetry_cell_setting           trigonal
_symmetry_space_group_name_Hall  'P 3 -2"'
_symmetry_space_group_name_H-M   'P 3 m 1'
_audit_creation_date             2019-03-18T14:57:56-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            1
_cell_length_a                   12.12130(11)
_cell_length_b                   12.12130(11)
_cell_length_c                   4.89283(5)
_cell_measurement_reflns_used    9578
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      38.799
_cell_measurement_theta_min      3.882
_cell_volume                     622.571(10)
_computing_cell_refinement       'APEX2 (Bruker AXS, 2009)'
_computing_data_collection       'APEX2 (Bruker AXS, 2009)'
_computing_data_reduction        'SAINT (Bruker AXS, 2009)'
_computing_molecular_graphics    'VESTA (Momma and Izumi, 2011)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 8.333
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Bruker APEXII CCD area detector'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  'Bruker Helios multilayer confocal mirror'
_diffrn_radiation_source         'Bruker TXS fine-focus rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0215
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       7
_diffrn_reflns_limit_l_min       -7
_diffrn_reflns_number            26188
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.989
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         35.101
_diffrn_reflns_theta_min         1.94
_exptl_absorpt_coefficient_mu    9.909
_exptl_absorpt_correction_T_max  0.888
_exptl_absorpt_correction_T_min  0.867
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS Sheldrick 2001
;
_exptl_crystal_colour            'clear brown'
_exptl_crystal_density_diffrn    4.077
_exptl_crystal_description       columnar
_exptl_crystal_F_000             713.5
_exptl_crystal_size_max          0.094
_exptl_crystal_size_mid          0.012
_exptl_crystal_size_min          0.012
_refine_diff_density_max         2.482
_refine_diff_density_min         -0.9
_refine_diff_density_rms         0.14
_refine_ls_abs_structure_details
;
 Flack x determined using 994 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons and Flack (2004), Acta Cryst. A60, s61).
;
_refine_ls_abs_structure_Flack   0.008(2)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.118
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     112
_refine_ls_number_reflns         2019
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.118
_refine_ls_R_factor_all          0.0151
_refine_ls_R_factor_gt           0.0151
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[σ²(Fo²)+(0.0201P)²+0.4788P]
 where P=(Fo²+2Fc²)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0367
_reflns_number_gt                2014
_reflns_number_total             2019
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            am9b09982_si_001.cif
_cod_data_source_block           6367010302_p3m1
_cod_original_cell_volume        622.571(11)
_cod_original_formula_sum        'Al6.03 Eu3.60 Li N22.59 O6.82 Si13.78'
_cod_database_code               4514468
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'-x+y, y, z'
'x, x-y, z'
'-y, -x, z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_occupancy
_atom_site_type_symbol
Eu1 0.55401(2) 0.10801(2) 0.32409(11) 0.01789(6) Uani d 1 Eu
Eu2 1 0 0.6765(16) 0.0303(11) Uani d 0.1381 Eu
Eu3 1 0 0.8037(8) 0.0721(9) Uani d 0.458 Eu
Li1 0.3333 0.6667 0.836(6) 0.011(3) Uani d 1 Li
Si1 0.58927(8) 0.91989(8) 0.8080(3) 0.00464(13) Uani d 0.6956 Si
Al1 0.58927(8) 0.91989(8) 0.8080(3) 0.00464(13) Uani d 0.3044 Al
Si2 0.50713(13) 0.75357(7) 0.3187(6) 0.0082(2) Uani d 0.6956 Si
Al2 0.50713(13) 0.75357(7) 0.3187(6) 0.0082(2) Uani d 0.3044 Al
Si3 0.75605(9) 0.00212(9) 0.2976(3) 0.00446(15) Uani d 0.6956 Si
Al3 0.75605(9) 0.00212(9) 0.2976(3) 0.00446(15) Uani d 0.3044 Al
Si4 0.81994(6) 0.18006(6) 0.7877(3) 0.0056(2) Uani d 0.6956 Si
Al4 0.81994(6) 0.18006(6) 0.7877(3) 0.0056(2) Uani d 0.3044 Al
Si5 0.6667 0.3333 0.8256(12) 0.0130(4) Uani d 0.6956 Si
Al5 0.6667 0.3333 0.8256(12) 0.0130(4) Uani d 0.3044 Al
Si6 1 0 0.1449(15) 0.0082(6) Uani d 0.2809 Si
Al6 1 0 0.1449(15) 0.0082(6) Uani d 0.1229 Al
Si7 1 0 0.4569(14) 0.0082(6) Uani d 0.2809 Si
Al7 1 0 0.4569(14) 0.0082(6) Uani d 0.1229 Al
N1 0.8541(3) 0.1459(3) 0.4566(10) 0.0146(8) Uani d 0.7681 N
O1 0.8541(3) 0.1459(3) 0.4566(10) 0.0146(8) Uani d 0.2319 O
N2 0.6064(3) 0.9219(3) 0.4552(7) 0.0100(5) Uani d 0.7681 N
O2 0.6064(3) 0.9219(3) 0.4552(7) 0.0100(5) Uani d 0.2319 O
N3 0.8378(4) 0.9189(2) 0.2965(14) 0.0135(8) Uani d 0.7681 N
O3 0.8378(4) 0.9189(2) 0.2965(14) 0.0135(8) Uani d 0.2319 O
N4 0.3333 0.6667 0.3956(15) 0.0120(14) Uani d 0.7681 N
O4 0.3333 0.6667 0.3956(15) 0.0120(14) Uani d 0.2318 O
N5 0.5370(5) 0.7685(2) 0.9431(11) 0.0104(8) Uani d 0.7681 N
O5 0.5370(5) 0.7685(2) 0.9431(11) 0.0104(8) Uani d 0.2319 O
N6 0.4813(2) 0.9625(4) 0.8779(7) 0.0082(7) Uani d 0.7681 N
O6 0.4813(2) 0.9625(4) 0.8779(7) 0.0082(7) Uani d 0.2319 O
N7 0.7279(3) 0.0367(3) 0.9655(6) 0.0138(6) Uani d 0.7681 N
O7 0.7279(3) 0.0367(3) 0.9655(6) 0.0138(6) Uani d 0.2319 O
N8 0.6667 0.3333 0.1609(19) 0.0218(18) Uani d 0.7681 N
O8 0.6667 0.3333 0.1609(19) 0.0218(18) Uani d 0.2318 O
N9 0.7404(3) 0.2596(3) 0.7103(12) 0.0185(9) Uani d 0.7681 N
O9 0.7404(3) 0.2596(3) 0.7103(12) 0.0185(9) Uani d 0.2319 O
N10 1 0 0.8037(8) 0.0721(9) Uani d 0.3102 N
O10 1 0 0.8037(8) 0.0721(9) Uani d 0.0937 O
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Al Al 0.0645 0.0514 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ce Ce -0.2486 2.6331 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N8 Eu1 O6 106.3(2) . 1_544
N8 Eu1 N6 106.3(2) . 1_544
O6 Eu1 N6 0.0(2) 1_544 1_544
N8 Eu1 O2 139.39(7) . 4_545
O6 Eu1 O2 77.32(10) 1_544 4_545
N6 Eu1 O2 77.32(10) 1_544 4_545
N8 Eu1 N2 139.39(7) . 4_545
O6 Eu1 N2 77.32(10) 1_544 4_545
N6 Eu1 N2 77.32(10) 1_544 4_545
O2 Eu1 N2 0.0(2) 4_545 4_545
N8 Eu1 O2 139.39(7) . 1_545
O6 Eu1 O2 77.32(10) 1_544 1_545
N6 Eu1 O2 77.32(10) 1_544 1_545
O2 Eu1 O2 81.22(14) 4_545 1_545
N2 Eu1 O2 81.22(14) 4_545 1_545
N8 Eu1 N2 139.39(7) . 1_545
O6 Eu1 N2 77.32(10) 1_544 1_545
N6 Eu1 N2 77.32(10) 1_544 1_545
O2 Eu1 N2 81.22(14) 4_545 1_545
N2 Eu1 N2 81.22(14) 4_545 1_545
O2 Eu1 N2 0.00(5) 1_545 1_545
N8 Eu1 O9 71.3(2) . 3_665
O6 Eu1 O9 151.08(11) 1_544 3_665
N6 Eu1 O9 151.08(11) 1_544 3_665
O2 Eu1 O9 86.47(12) 4_545 3_665
N2 Eu1 O9 86.47(12) 4_545 3_665
O2 Eu1 O9 124.03(12) 1_545 3_665
N2 Eu1 O9 124.03(12) 1_545 3_665
N8 Eu1 N9 71.3(2) . 3_665
O6 Eu1 N9 151.08(11) 1_544 3_665
N6 Eu1 N9 151.08(11) 1_544 3_665
O2 Eu1 N9 86.47(12) 4_545 3_665
N2 Eu1 N9 86.47(12) 4_545 3_665
O2 Eu1 N9 124.03(12) 1_545 3_665
N2 Eu1 N9 124.03(12) 1_545 3_665
O9 Eu1 N9 0.0(3) 3_665 3_665
N8 Eu1 N9 71.3(2) . .
O6 Eu1 N9 151.08(11) 1_544 .
N6 Eu1 N9 151.08(11) 1_544 .
O2 Eu1 N9 124.03(12) 4_545 .
N2 Eu1 N9 124.03(12) 4_545 .
O2 Eu1 N9 86.47(12) 1_545 .
N2 Eu1 N9 86.47(12) 1_545 .
O9 Eu1 N9 57.0(2) 3_665 .
N9 Eu1 N9 57.0(2) 3_665 .
O3 Eu2 N3 0.00(18) 2_755 2_755
O3 Eu2 O3 71.6(3) 2_755 1_545
N3 Eu2 O3 71.6(3) 2_755 1_545
O3 Eu2 N3 71.6(3) 2_755 1_545
N3 Eu2 N3 71.6(3) 2_755 1_545
O3 Eu2 N3 0.0(3) 1_545 1_545
O3 Eu2 O3 71.6(3) 2_755 3_665
N3 Eu2 O3 71.6(3) 2_755 3_665
O3 Eu2 O3 71.6(3) 1_545 3_665
N3 Eu2 O3 71.6(3) 1_545 3_665
O3 Eu3 N3 0.00(8) 2_756 2_756
O3 Eu3 O3 59.9(2) 2_756 3_666
N3 Eu3 O3 59.9(2) 2_756 3_666
O3 Eu3 N3 59.9(2) 2_756 3_666
N3 Eu3 N3 59.9(2) 2_756 3_666
O3 Eu3 N3 0.00(19) 3_666 3_666
O3 Eu3 O3 59.9(2) 2_756 1_546
N3 Eu3 O3 59.9(2) 2_756 1_546
O3 Eu3 O3 59.9(2) 3_666 1_546
N3 Eu3 O3 59.9(2) 3_666 1_546
O3 Eu3 N3 59.9(2) 2_756 1_546
N3 Eu3 N3 59.9(2) 2_756 1_546
O3 Eu3 N3 59.9(2) 3_666 1_546
N3 Eu3 N3 59.9(2) 3_666 1_546
O3 Eu3 N3 0.0(3) 1_546 1_546
O3 Eu3 O3 110.33(14) 2_756 2_755
N3 Eu3 O3 110.33(14) 2_756 2_755
O3 Eu3 O3 146.80(6) 3_666 2_755
N3 Eu3 O3 146.80(6) 3_666 2_755
O3 Eu3 O3 146.80(6) 1_546 2_755
N3 Eu3 O3 146.80(6) 1_546 2_755
N4 Li1 O5 103.7(8) . 2_665
N4 Li1 N5 103.7(8) . 2_665
O5 Li1 N5 0.00(8) 2_665 2_665
N4 Li1 N5 103.7(8) . .
O5 Li1 N5 114.5(6) 2_665 .
N5 Li1 N5 114.5(6) 2_665 .
N4 Li1 O5 103.7(8) . 3_565
O5 Li1 O5 114.5(6) 2_665 3_565
N5 Li1 O5 114.5(6) 2_665 3_565
N5 Li1 O5 114.5(6) . 3_565
N4 Li1 N5 103.7(8) . 3_565
O5 Li1 N5 114.5(6) 2_665 3_565
N5 Li1 N5 114.5(6) 2_665 3_565
N5 Li1 N5 114.5(6) . 3_565
O5 Li1 N5 0.00(14) 3_565 3_565
N6 Si1 N2 107.86(17) . .
N6 Si1 O7 104.19(19) . 1_565
N2 Si1 O7 111.58(16) . 1_565
N6 Si1 N7 104.19(19) . 1_565
N2 Si1 N7 111.58(16) . 1_565
O7 Si1 N7 0.0(3) 1_565 1_565
N6 Si1 N5 108.7(2) . .
N2 Si1 N5 111.7(2) . .
O7 Si1 N5 112.5(2) 1_565 .
N7 Si1 N5 112.5(2) 1_565 .
N4 Si2 O5 111.3(3) . 1_554
N4 Si2 N5 111.3(3) . 1_554
O5 Si2 N5 0.00(18) 1_554 1_554
N4 Si2 N2 117.84(16) . .
O5 Si2 N2 104.74(16) 1_554 .
N5 Si2 N2 104.74(16) 1_554 .
N4 Si2 O2 117.84(16) . 5_565
O5 Si2 O2 104.74(16) 1_554 5_565
N5 Si2 O2 104.74(16) 1_554 5_565
N2 Si2 O2 98.6(2) . 5_565
N4 Si2 N2 117.84(16) . 5_565
O5 Si2 N2 104.74(16) 1_554 5_565
N5 Si2 N2 104.74(16) 1_554 5_565
N2 Si2 N2 98.6(2) . 5_565
O2 Si2 N2 0.0(2) 5_565 5_565
N1 Si3 O3 106.5(3) . 1_545
N1 Si3 N3 106.5(3) . 1_545
O3 Si3 N3 0.0(5) 1_545 1_545
N1 Si3 O2 111.17(18) . 1_545
O3 Si3 O2 114.4(2) 1_545 1_545
N3 Si3 O2 114.4(2) 1_545 1_545
N1 Si3 N2 111.17(18) . 1_545
O3 Si3 N2 114.4(2) 1_545 1_545
N3 Si3 N2 114.4(2) 1_545 1_545
O2 Si3 N2 0.0(3) 1_545 1_545
N1 Si3 O7 107.1(2) . 1_554
O3 Si3 O7 111.9(3) 1_545 1_554
N3 Si3 O7 111.9(3) 1_545 1_554
O2 Si3 O7 105.62(17) 1_545 1_554
N2 Si3 O7 105.62(17) 1_545 1_554
N1 Si3 N7 107.1(2) . 1_554
O3 Si3 N7 111.9(3) 1_545 1_554
N3 Si3 N7 111.9(3) 1_545 1_554
O2 Si3 N7 105.62(17) 1_545 1_554
N2 Si3 N7 105.62(17) 1_545 1_554
O7 Si3 N7 0.0(3) 1_554 1_554
N9 Si4 N7 114.13(16) . .
N9 Si4 O7 114.13(16) . 6_665
N7 Si4 O7 108.7(2) . 6_665
N9 Si4 N7 114.13(16) . 6_665
N7 Si4 N7 108.7(2) . 6_665
O7 Si4 N7 0.0(3) 6_665 6_665
N9 Si4 N1 101.1(3) . .
N7 Si4 N1 109.21(16) . .
O7 Si4 N1 109.21(16) 6_665 .
N7 Si4 N1 109.21(16) 6_665 .
O8 Si5 N8 0.000(3) 1_556 1_556
O8 Si5 O9 110.0(3) 1_556 3_665
N8 Si5 O9 110.0(3) 1_556 3_665
O8 Si5 N9 110.0(3) 1_556 3_665
N8 Si5 N9 110.0(3) 1_556 3_665
O9 Si5 N9 0.0(5) 3_665 3_665
O8 Si5 O9 110.0(3) 1_556 2_655
N8 Si5 O9 110.0(3) 1_556 2_655
O9 Si5 O9 108.9(3) 3_665 2_655
N9 Si5 O9 108.9(3) 3_665 2_655
O8 Si5 N9 110.0(3) 1_556 2_655
N8 Si5 N9 110.0(3) 1_556 2_655
O9 Si5 N9 108.9(3) 3_665 2_655
N9 Si5 N9 108.9(3) 3_665 2_655
O9 Si5 N9 0.0(5) 2_655 2_655
O8 Si5 N9 110.0(3) 1_556 .
N8 Si5 N9 110.0(3) 1_556 .
O9 Si5 N9 108.9(3) 3_665 .
N9 Si5 N9 108.9(3) 3_665 .
O9 Si5 N9 108.9(3) 2_655 .
N9 Si5 N9 108.9(3) 2_655 .
O10 Si6 N10 0 1_554 1_554
O10 Si6 O3 113.5(3) 1_554 2_755
N10 Si6 O3 113.5(3) 1_554 2_755
O10 Si6 N3 113.5(3) 1_554 2_755
N10 Si6 N3 113.5(3) 1_554 2_755
O3 Si6 N3 0.00(19) 2_755 2_755
O10 Si6 O3 113.5(3) 1_554 3_665
N10 Si6 O3 113.5(3) 1_554 3_665
O3 Si6 O3 105.1(3) 2_755 3_665
N3 Si6 O3 105.1(3) 2_755 3_665
O10 Si6 N3 113.5(3) 1_554 3_665
N10 Si6 N3 113.5(3) 1_554 3_665
O3 Si6 N3 105.1(3) 2_755 3_665
N3 Si6 N3 105.1(3) 2_755 3_665
O3 Si6 N3 0.0(4) 3_665 3_665
O10 Si6 N3 113.5(3) 1_554 1_545
N10 Si6 N3 113.5(3) 1_554 1_545
O3 Si6 N3 105.1(3) 2_755 1_545
N3 Si6 N3 105.1(3) 2_755 1_545
O3 Si6 N3 105.1(3) 3_665 1_545
N3 Si6 N3 105.1(3) 3_665 1_545
O10 Si6 O3 113.5(3) 1_554 1_545
N10 Si6 O3 113.5(3) 1_554 1_545
O3 Si6 O3 105.1(3) 2_755 1_545
N3 Si6 O3 105.1(3) 2_755 1_545
O3 Si6 O3 105.1(3) 3_665 1_545
N3 Si6 O3 105.1(3) 3_665 1_545
N3 Si6 O3 0.0(3) 1_545 1_545
O3 Si7 N3 0.00(19) 2_755 2_755
O3 Si7 O3 103.7(3) 2_755 1_545
N3 Si7 O3 103.7(3) 2_755 1_545
O3 Si7 N3 103.7(3) 2_755 1_545
N3 Si7 N3 103.7(3) 2_755 1_545
O3 Si7 N3 0.0(3) 1_545 1_545
O3 Si7 O3 103.7(3) 2_755 3_665
N3 Si7 O3 103.7(3) 2_755 3_665
O3 Si7 O3 103.7(3) 1_545 3_665
N3 Si7 O3 103.7(3) 1_545 3_665
O3 Si7 N3 103.7(3) 2_755 3_665
N3 Si7 N3 103.7(3) 2_755 3_665
O3 Si7 N3 103.7(3) 1_545 3_665
N3 Si7 N3 103.7(3) 1_545 3_665
O3 Si7 N3 0.0(4) 3_665 3_665
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Eu1 N8 . 2.497(3)
Eu1 O6 1_544 2.665(4)
Eu1 N6 1_544 2.665(4)
Eu1 O2 4_545 2.709(3)
Eu1 N2 4_545 2.709(3)
Eu1 O2 1_545 2.709(3)
Eu1 N2 1_545 2.709(3)
Eu1 O9 3_665 2.811(4)
Eu1 N9 3_665 2.811(4)
Eu1 N9 . 2.811(4)
Eu2 Eu3 . 0.622(8)
Eu2 Si7 . 1.075(11)
Eu2 Al6 1_556 2.292(11)
Eu2 Si6 1_556 2.292(11)
Eu2 O3 2_755 2.521(8)
Eu2 N3 2_755 2.521(8)
Eu2 O3 1_545 2.521(9)
Eu2 N3 1_545 2.521(9)
Eu2 O3 3_665 2.521(9)
Eu3 Al6 1_556 1.670(8)
Eu3 Si6 1_556 1.670(8)
Eu3 Si7 . 1.697(8)
Eu3 O3 2_756 2.952(7)
Eu3 N3 2_756 2.952(7)
Eu3 O3 3_666 2.952(7)
Eu3 N3 3_666 2.952(7)
Eu3 O3 1_546 2.952(7)
Eu3 N3 1_546 2.952(7)
Eu3 O3 2_755 3.009(7)
Li1 N4 . 2.16(3)
Li1 O5 2_665 2.201(9)
Li1 N5 2_665 2.201(9)
Li1 N5 . 2.201(9)
Li1 O5 3_565 2.201(9)
Li1 N5 3_565 2.201(9)
Li1 Al2 2_666 2.98(2)
Li1 Si2 2_666 2.98(2)
Li1 Al2 1_556 2.98(2)
Li1 Si2 1_556 2.98(2)
Si1 N6 . 1.6657(17)
Si1 N2 . 1.738(3)
Si1 O7 1_565 1.744(3)
Si1 N7 1_565 1.744(3)
Si1 N5 . 1.745(3)
Si1 Eu1 1_565 3.4590(12)
Si1 Eu1 1_566 3.5685(12)
Si2 N4 . 1.863(2)
Si2 O5 1_554 1.864(6)
Si2 N5 1_554 1.864(6)
Si2 N2 . 1.898(3)
Si2 O2 5_565 1.898(3)
Si2 N2 5_565 1.898(3)
Si2 Li1 1_554 2.98(2)
Si3 N1 . 1.728(3)
Si3 O3 1_545 1.732(2)
Si3 N3 1_545 1.732(2)
Si3 O2 1_545 1.751(3)
Si3 N2 1_545 1.751(3)
Si3 O7 1_554 1.754(3)
Si3 N7 1_554 1.754(3)
Si4 N9 . 1.711(6)
Si4 N7 . 1.756(3)
Si4 O7 6_665 1.756(3)
Si4 N7 6_665 1.756(3)
Si4 N1 . 1.771(5)
Si5 O8 1_556 1.640(12)
Si5 N8 1_556 1.640(12)
Si5 O9 3_665 1.649(6)
Si5 N9 3_665 1.649(6)
Si5 O9 2_655 1.649(6)
Si5 N9 2_655 1.649(6)
Si5 N9 . 1.649(6)
Si5 Eu1 2_656 3.398(4)
Si5 Eu1 1_556 3.398(4)
Si5 Eu1 3_666 3.398(4)
Si5 Eu1 2_655 3.408(4)
Si6 Si7 . 1.527(8)
Si6 O10 1_554 1.670(8)
Si6 N10 1_554 1.670(8)
Si6 Eu3 1_554 1.670(8)
Si6 O3 2_755 1.857(6)
Si6 N3 2_755 1.857(6)
Si6 O3 3_665 1.857(6)
Si6 N3 3_665 1.857(6)
Si6 N3 1_545 1.857(6)
Si6 O3 1_545 1.857(6)
Si6 Eu2 1_554 2.292(11)
Si7 O3 2_755 1.875(6)
Si7 N3 2_755 1.875(6)
Si7 O3 1_545 1.875(6)
Si7 N3 1_545 1.875(6)
Si7 O3 3_665 1.875(6)
Si7 N3 3_665 1.875(6)
N1 Al3 6_665 1.728(3)
N1 Si3 6_665 1.728(3)
N2 Al3 1_565 1.751(3)
N2 Si3 1_565 1.751(3)
N2 Eu1 1_565 2.709(3)
N3 Al3 1_565 1.732(2)
N3 Si3 1_565 1.732(2)
N3 Al3 5 1.732(2)
N3 Si3 5 1.732(2)
N3 Al6 1_565 1.857(6)
N3 Si6 1_565 1.857(6)
N3 Al7 1_565 1.875(6)
N3 Si7 1_565 1.875(6)
N3 Eu2 1_565 2.521(9)
N3 Eu3 1_564 2.952(7)
N3 Eu3 1_565 3.010(8)
N4 Al2 2_665 1.863(2)
N4 Si2 2_665 1.863(2)
N4 Al2 3_565 1.863(2)
N4 Si2 3_565 1.863(2)
N5 Al1 5_565 1.745(3)
N5 Si1 5_565 1.745(3)
N5 Al2 1_556 1.864(6)
N5 Si2 1_556 1.864(6)
N6 Al1 4 1.6657(17)
N6 Si1 4 1.6657(17)
N6 Eu1 1_566 2.665(4)
N6 Eu1 1_565 3.110(4)
N7 Al1 1_545 1.744(3)
N7 Si1 1_545 1.744(3)
N7 Al3 1_556 1.754(3)
N7 Si3 1_556 1.754(3)
N7 Eu1 1_556 3.177(4)
N8 Al5 1_554 1.640(12)
N8 Si5 1_554 1.640(12)
N8 Eu1 2_655 2.497(3)
N8 Eu1 3_665 2.497(3)
N9 Eu1 2_655 2.811(4)
