#------------------------------------------------------------------------------
#$Date: 2019-11-10 19:35:51 +0200 (Sun, 10 Nov 2019) $
#$Revision: 226060 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/51/60/4516022.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4516022
loop_
_publ_author_name
'Kumar, Dharmendra'
'Prakasham, A. P.'
'Das, Sharmistha'
'Datta, Anindya'
'Ghosh, Prasenjit'
_publ_section_title
;
 Cyanosilylation of Aromatic Aldehydes by Cationic Ruthenium(II) Complexes
 of Benzimidazole-Derived O-Functionalized N-Heterocyclic Carbenes at
 Ambient Temperature under Solvent-Free Conditions.
;
_journal_issue                   2
_journal_name_full               'ACS omega'
_journal_page_first              1922
_journal_page_last               1938
_journal_paper_doi               10.1021/acsomega.7b02090
_journal_volume                  3
_journal_year                    2018
_chemical_formula_moiety         'C46 H56 Ag2 N6 O2'
_chemical_formula_sum            'C46 H56 Ag2 N6 O2'
_chemical_formula_weight         940.70
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_date             2016-12-21
_audit_creation_method
;
Olex2 1.2-alpha
(compiled 2015.10.28 svn.r3245 for OlexSys, GUI svn.r5128)
;
_cell_angle_alpha                90
_cell_angle_beta                 106.163(3)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   9.8105(3)
_cell_length_b                   15.9779(3)
_cell_length_c                   14.0138(4)
_cell_measurement_reflns_used    12795
_cell_measurement_temperature    150
_cell_measurement_theta_max      31.3350
_cell_measurement_theta_min      2.2080
_cell_volume                     2109.85(10)
_computing_cell_refinement       'CrysAlisPro 1.171.38.43 (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.43 (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.43 (Rigaku OD, 2015)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      150
_diffrn_detector                 'CCD plate'
_diffrn_measured_fraction_theta_full 0.976
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
--------------------------------------------------------------------------
  1  ω    -59.00  70.00   0.50    5.00    --  -20.00  72.00-108.00  258
  2  ω    -58.50  49.00   0.50    5.00    --  -20.00  72.00-180.00  215
  3  ω    -35.00  -5.00   0.50    5.00    --  -20.00 -72.00-108.00   60
  4  ω   -110.00 -19.50   0.50    5.00    --  -20.00 -72.00-180.00  181
;
_diffrn_measurement_device       'abstract diffractometer'
_diffrn_measurement_device_type
'dtrek-CrysAlisPro-abstract goniometer imported rigaku-d*trek images'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0199414000
_diffrn_orient_matrix_UB_12      0.0364593000
_diffrn_orient_matrix_UB_13      -0.0294038000
_diffrn_orient_matrix_UB_21      0.0238932000
_diffrn_orient_matrix_UB_22      0.0252850000
_diffrn_orient_matrix_UB_23      0.0431146000
_diffrn_orient_matrix_UB_31      0.0684803000
_diffrn_orient_matrix_UB_32      0.0019082000
_diffrn_orient_matrix_UB_33      -0.0074723000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0263
_diffrn_reflns_av_unetI/netI     0.0195
_diffrn_reflns_Laue_measured_fraction_full 0.976
_diffrn_reflns_Laue_measured_fraction_max 0.976
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            12562
_diffrn_reflns_point_group_measured_fraction_full 0.976
_diffrn_reflns_point_group_measured_fraction_max 0.976
_diffrn_reflns_theta_full        24.998
_diffrn_reflns_theta_max         24.998
_diffrn_reflns_theta_min         2.601
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_source_type              'Enhance (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    0.973
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.45924
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.43 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.481
_exptl_crystal_description       block
_exptl_crystal_F_000             968
_exptl_crystal_size_max          0.396
_exptl_crystal_size_mid          0.296
_exptl_crystal_size_min          0.23
_refine_diff_density_max         1.127
_refine_diff_density_min         -0.295
_refine_diff_density_rms         0.070
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.056
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     258
_refine_ls_number_reflns         3631
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.056
_refine_ls_R_factor_all          0.0287
_refine_ls_R_factor_gt           0.0272
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0402P)²+2.0622P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0715
_refine_ls_wR_factor_ref         0.0723
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3475
_reflns_number_total             3631
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ao7b02090_si_002.cif
_cod_data_source_block           2b_PG-DK-05-120_Mo
_cod_original_cell_volume        2109.86(9)
_cod_database_code               4516022
_chemical_oxdiff_formula         C23H23Ag1N3O1
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_reflns_odcompleteness_completeness 90.16
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     31.11
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C18(H18), C21(H21)
2.b Secondary CH2 refined with riding coordinates:
 C8(H8A,H8B), C10(H10A,H10B)
2.c Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C6(H6), C14(H14), C15(H15), C16(H16)
2.d Idealised Me refined as rotating group:
 C9(H9A,H9B,H9C), C19(H19A,H19B,H19C), C20(H20A,H20B,H20C), C22(H22A,H22B,
 H22C), C23(H23A,H23B,H23C)
;
_shelx_shelxl_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
- Detector area scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.481
_oxdiff_exptl_absorpt_empirical_full_min 0.707
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
Ag1 Ag 0.40854(2) 0.58291(2) 0.49740(2) 0.02309(9) Uani 1 1 d .
O1 O 0.28889(17) 0.26814(11) 0.59093(14) 0.0327(4) Uani 1 1 d .
N1 N 0.2111(2) 0.57091(12) 0.63315(16) 0.0279(5) Uani 1 1 d .
N2 N 0.20779(19) 0.45567(12) 0.55252(14) 0.0218(4) Uani 1 1 d .
N3 N 0.48078(19) 0.34606(12) 0.58173(13) 0.0206(4) Uani 1 1 d .
C1 C 0.2700(2) 0.53179(15) 0.56944(18) 0.0245(5) Uani 1 1 d .
C2 C 0.1107(2) 0.52012(15) 0.65700(18) 0.0270(5) Uani 1 1 d .
C3 C 0.0218(3) 0.53337(18) 0.7177(2) 0.0353(6) Uani 1 1 d .
H3 H 0.0223 0.5844 0.7526 0.042 Uiso 1 1 calc R
C4 C -0.0668(3) 0.4679(2) 0.7240(2) 0.0412(7) Uani 1 1 d .
H4 H -0.1303 0.4744 0.7637 0.049 Uiso 1 1 calc R
C5 C -0.0665(3) 0.3926(2) 0.6740(2) 0.0395(6) Uani 1 1 d .
H5 H -0.1280 0.3488 0.6820 0.047 Uiso 1 1 calc R
C6 C 0.0206(2) 0.37993(17) 0.6135(2) 0.0317(6) Uani 1 1 d .
H6 H 0.0205 0.3288 0.5789 0.038 Uiso 1 1 calc R
C7 C 0.1087(2) 0.44611(15) 0.60572(17) 0.0245(5) Uani 1 1 d .
C8 C 0.2544(4) 0.65263(17) 0.6782(3) 0.0480(8) Uani 1 1 d .
H8A H 0.1694 0.6839 0.6827 0.058 Uiso 1 1 calc R
H8B H 0.3001 0.6850 0.6352 0.058 Uiso 1 1 calc R
C9 C 0.3567(4) 0.6445(3) 0.7808(3) 0.0692(11) Uani 1 1 d .
H9A H 0.4442 0.6174 0.7759 0.104 Uiso 1 1 calc GR
H9B H 0.3132 0.6105 0.8227 0.104 Uiso 1 1 calc GR
H9C H 0.3789 0.7002 0.8103 0.104 Uiso 1 1 calc GR
C10 C 0.2451(2) 0.39116(16) 0.49120(17) 0.0243(5) Uani 1 1 d .
H10A H 0.2940 0.4166 0.4453 0.029 Uiso 1 1 calc R
H10B H 0.1583 0.3628 0.4511 0.029 Uiso 1 1 calc R
C11 C 0.3436(2) 0.32741(14) 0.55932(16) 0.0219(5) Uani 1 1 d .
C12 C 0.5766(2) 0.29616(14) 0.65620(16) 0.0200(4) Uani 1 1 d .
C13 C 0.6146(2) 0.32406(15) 0.75550(17) 0.0253(5) Uani 1 1 d .
C14 C 0.7203(3) 0.28084(16) 0.82460(18) 0.0303(5) Uani 1 1 d .
H14 H 0.7474 0.2988 0.8919 0.036 Uiso 1 1 calc R
C15 C 0.7863(3) 0.21258(16) 0.79767(18) 0.0316(6) Uani 1 1 d .
H15 H 0.8608 0.1851 0.8455 0.038 Uiso 1 1 calc R
C16 C 0.7442(3) 0.18407(15) 0.70119(18) 0.0272(5) Uani 1 1 d .
H16 H 0.7879 0.1356 0.6837 0.033 Uiso 1 1 calc R
C17 C 0.6393(2) 0.22479(14) 0.62905(16) 0.0218(5) Uani 1 1 d .
C18 C 0.5396(3) 0.39902(18) 0.7857(2) 0.0342(6) Uani 1 1 d .
H18 H 0.5156 0.4383 0.7279 0.041 Uiso 1 1 calc R
C19 C 0.6313(4) 0.4487(2) 0.8757(3) 0.0543(8) Uani 1 1 d .
H19A H 0.6487 0.4141 0.9357 0.082 Uiso 1 1 calc GR
H19B H 0.5812 0.4998 0.8847 0.082 Uiso 1 1 calc GR
H19C H 0.7220 0.4635 0.8637 0.082 Uiso 1 1 calc GR
C20 C 0.4031(3) 0.3751(2) 0.8054(3) 0.0500(8) Uani 1 1 d .
H20A H 0.3455 0.3426 0.7492 0.075 Uiso 1 1 calc GR
H20B H 0.3514 0.4257 0.8140 0.075 Uiso 1 1 calc GR
H20C H 0.4226 0.3412 0.8660 0.075 Uiso 1 1 calc GR
C21 C 0.5931(3) 0.18979(15) 0.52447(18) 0.0276(5) Uani 1 1 d .
H21 H 0.5359 0.2339 0.4803 0.033 Uiso 1 1 calc R
C22 C 0.7167(4) 0.1677(2) 0.4843(2) 0.0508(8) Uani 1 1 d .
H22A H 0.7858 0.2136 0.4981 0.076 Uiso 1 1 calc GR
H22B H 0.6822 0.1588 0.4124 0.076 Uiso 1 1 calc GR
H22C H 0.7621 0.1164 0.5164 0.076 Uiso 1 1 calc GR
C23 C 0.4979(4) 0.11463(18) 0.5209(2) 0.0435(7) Uani 1 1 d .
H23A H 0.5510 0.0706 0.5643 0.065 Uiso 1 1 calc GR
H23B H 0.4653 0.0937 0.4526 0.065 Uiso 1 1 calc GR
H23C H 0.4158 0.1310 0.5436 0.065 Uiso 1 1 calc GR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N3 Ag1 Ag1 95.23(5) 3_666 3_666
C1 Ag1 Ag1 95.89(6) . 3_666
C1 Ag1 N3 168.61(8) . 3_666
C1 N1 C2 110.7(2) . .
C1 N1 C8 125.1(2) . .
C2 N1 C8 124.0(2) . .
C1 N2 C7 110.7(2) . .
C1 N2 C10 124.5(2) . .
C7 N2 C10 124.7(2) . .
C11 N3 Ag1 129.68(15) . 3_666
C11 N3 C12 117.54(18) . .
C12 N3 Ag1 110.83(13) . 3_666
N1 C1 Ag1 126.96(17) . .
N1 C1 N2 106.2(2) . .
N2 C1 Ag1 126.46(17) . .
N1 C2 C3 131.7(2) . .
C7 C2 N1 106.5(2) . .
C7 C2 C3 121.8(2) . .
C2 C3 H3 122.1 . .
C4 C3 C2 115.9(3) . .
C4 C3 H3 122.1 . .
C3 C4 H4 118.9 . .
C3 C4 C5 122.3(3) . .
C5 C4 H4 118.9 . .
C4 C5 H5 119.2 . .
C6 C5 C4 121.6(3) . .
C6 C5 H5 119.2 . .
C5 C6 H6 121.8 . .
C5 C6 C7 116.3(3) . .
C7 C6 H6 121.8 . .
N2 C7 C6 132.0(2) . .
C2 C7 N2 105.9(2) . .
C2 C7 C6 122.0(2) . .
N1 C8 H8A 109.3 . .
N1 C8 H8B 109.3 . .
N1 C8 C9 111.7(3) . .
H8A C8 H8B 107.9 . .
C9 C8 H8A 109.3 . .
C9 C8 H8B 109.3 . .
C8 C9 H9A 109.5 . .
C8 C9 H9B 109.5 . .
C8 C9 H9C 109.5 . .
H9A C9 H9B 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
N2 C10 H10A 109.9 . .
N2 C10 H10B 109.9 . .
N2 C10 C11 108.71(18) . .
H10A C10 H10B 108.3 . .
C11 C10 H10A 109.9 . .
C11 C10 H10B 109.9 . .
O1 C11 N3 127.0(2) . .
O1 C11 C10 118.2(2) . .
N3 C11 C10 114.7(2) . .
C13 C12 N3 118.8(2) . .
C17 C12 N3 120.24(19) . .
C17 C12 C13 120.8(2) . .
C12 C13 C18 120.5(2) . .
C14 C13 C12 118.2(2) . .
C14 C13 C18 121.4(2) . .
C13 C14 H14 119.3 . .
C15 C14 C13 121.4(2) . .
C15 C14 H14 119.3 . .
C14 C15 H15 120.1 . .
C14 C15 C16 119.8(2) . .
C16 C15 H15 120.1 . .
C15 C16 H16 119.4 . .
C15 C16 C17 121.3(2) . .
C17 C16 H16 119.4 . .
C12 C17 C21 121.9(2) . .
C16 C17 C12 118.5(2) . .
C16 C17 C21 119.5(2) . .
C13 C18 H18 106.9 . .
C13 C18 C19 114.3(2) . .
C19 C18 H18 106.9 . .
C20 C18 C13 112.2(2) . .
C20 C18 H18 106.9 . .
C20 C18 C19 109.2(2) . .
C18 C19 H19A 109.5 . .
C18 C19 H19B 109.5 . .
C18 C19 H19C 109.5 . .
H19A C19 H19B 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
C18 C20 H20A 109.5 . .
C18 C20 H20B 109.5 . .
C18 C20 H20C 109.5 . .
H20A C20 H20B 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C17 C21 H21 107.7 . .
C22 C21 C17 113.0(2) . .
C22 C21 H21 107.7 . .
C23 C21 C17 109.9(2) . .
C23 C21 H21 107.7 . .
C23 C21 C22 110.7(2) . .
C21 C22 H22A 109.5 . .
C21 C22 H22B 109.5 . .
C21 C22 H22C 109.5 . .
H22A C22 H22B 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C21 C23 H23A 109.5 . .
C21 C23 H23B 109.5 . .
C21 C23 H23C 109.5 . .
H23A C23 H23B 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 Ag1 3.1894(3) 3_666
Ag1 N3 2.0898(18) 3_666
Ag1 C1 2.073(2) .
O1 C11 1.230(3) .
N1 C1 1.345(3) .
N1 C2 1.387(3) .
N1 C8 1.461(3) .
N2 C1 1.352(3) .
N2 C7 1.388(3) .
N2 C10 1.453(3) .
N3 Ag1 2.0897(18) 3_666
N3 C11 1.328(3) .
N3 C12 1.436(3) .
C2 C3 1.394(3) .
C2 C7 1.381(4) .
C3 H3 0.9500 .
C3 C4 1.378(4) .
C4 H4 0.9500 .
C4 C5 1.393(5) .
C5 H5 0.9500 .
C5 C6 1.377(4) .
C6 H6 0.9500 .
C6 C7 1.389(4) .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
C8 C9 1.513(5) .
C9 H9A 0.9800 .
C9 H9B 0.9800 .
C9 H9C 0.9800 .
C10 H10A 0.9900 .
C10 H10B 0.9900 .
C10 C11 1.539(3) .
C12 C13 1.409(3) .
C12 C17 1.398(3) .
C13 C14 1.390(3) .
C13 C18 1.526(4) .
C14 H14 0.9500 .
C14 C15 1.374(4) .
C15 H15 0.9500 .
C15 C16 1.377(4) .
C16 H16 0.9500 .
C16 C17 1.388(3) .
C17 C21 1.515(3) .
C18 H18 1.0000 .
C18 C19 1.549(4) .
C18 C20 1.490(4) .
C19 H19A 0.9800 .
C19 H19B 0.9800 .
C19 H19C 0.9800 .
C20 H20A 0.9800 .
C20 H20B 0.9800 .
C20 H20C 0.9800 .
C21 H21 1.0000 .
C21 C22 1.514(4) .
C21 C23 1.513(4) .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
C23 H23A 0.9800 .
C23 H23B 0.9800 .
C23 H23C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
Ag1 N3 C11 O1 157.53(19) 3_666
Ag1 N3 C11 C10 -26.4(3) 3_666
Ag1 N3 C12 C13 100.4(2) 3_666
Ag1 N3 C12 C17 -74.7(2) 3_666
N1 C2 C3 C4 179.7(3) .
N1 C2 C7 N2 -0.3(3) .
N1 C2 C7 C6 179.1(2) .
N2 C10 C11 O1 88.3(3) .
N2 C10 C11 N3 -88.2(2) .
N3 C12 C13 C14 -172.2(2) .
N3 C12 C13 C18 8.6(3) .
N3 C12 C17 C16 172.2(2) .
N3 C12 C17 C21 -9.5(3) .
C1 N1 C2 C3 -178.9(3) .
C1 N1 C2 C7 0.3(3) .
C1 N1 C8 C9 -96.4(3) .
C1 N2 C7 C2 0.2(3) .
C1 N2 C7 C6 -179.2(2) .
C1 N2 C10 C11 99.6(2) .
C2 N1 C1 Ag1 172.63(17) .
C2 N1 C1 N2 -0.2(3) .
C2 N1 C8 C9 78.1(3) .
C2 C3 C4 C5 0.9(4) .
C3 C2 C7 N2 179.0(2) .
C3 C2 C7 C6 -1.6(4) .
C3 C4 C5 C6 -1.5(4) .
C4 C5 C6 C7 0.6(4) .
C5 C6 C7 N2 -179.7(2) .
C5 C6 C7 C2 1.0(4) .
C7 N2 C1 Ag1 -172.89(16) .
C7 N2 C1 N1 0.0(2) .
C7 N2 C10 C11 -76.9(3) .
C7 C2 C3 C4 0.6(4) .
C8 N1 C1 Ag1 -12.3(4) .
C8 N1 C1 N2 174.9(2) .
C8 N1 C2 C3 6.0(4) .
C8 N1 C2 C7 -174.8(2) .
C10 N2 C1 Ag1 10.2(3) .
C10 N2 C1 N1 -177.0(2) .
C10 N2 C7 C2 177.2(2) .
C10 N2 C7 C6 -2.2(4) .
C11 N3 C12 C13 -94.0(2) .
C11 N3 C12 C17 91.0(3) .
C12 N3 C11 O1 -5.0(3) .
C12 N3 C11 C10 171.11(19) .
C12 C13 C14 C15 -0.2(4) .
C12 C13 C18 C19 -151.7(2) .
C12 C13 C18 C20 83.2(3) .
C12 C17 C21 C22 134.1(2) .
C12 C17 C21 C23 -101.7(3) .
C13 C12 C17 C16 -2.7(3) .
C13 C12 C17 C21 175.6(2) .
C13 C14 C15 C16 -2.4(4) .
C14 C13 C18 C19 29.1(4) .
C14 C13 C18 C20 -95.9(3) .
C14 C15 C16 C17 2.4(4) .
C15 C16 C17 C12 0.2(3) .
C15 C16 C17 C21 -178.2(2) .
C16 C17 C21 C22 -47.6(3) .
C16 C17 C21 C23 76.6(3) .
C17 C12 C13 C14 2.7(3) .
C17 C12 C13 C18 -176.4(2) .
C18 C13 C14 C15 179.0(2) .
