#------------------------------------------------------------------------------
#$Date: 2016-03-25 16:04:37 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179950 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/45/7024580.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7024580
loop_
_publ_author_name
'Mobin, Shaikh M.'
'Srivastava, Ashwini K.'
'Mathur, Pradeep'
'Lahiri, Goutam Kumar'
_publ_section_title
;
 Single-crystal to single-crystal transformations in discrete hydrated
 dimeric copper complexes.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1447
_journal_page_last               1449
_journal_paper_doi               10.1039/b918761h
_journal_volume                  39
_journal_year                    2010
_chemical_formula_sum            'C19 H28 Cu2 N2 O8'
_chemical_formula_weight         539.51
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                70.964(5)
_cell_angle_beta                 76.802(3)
_cell_angle_gamma                76.981(4)
_cell_formula_units_Z            2
_cell_length_a                   7.8669(2)
_cell_length_b                   10.2403(5)
_cell_length_c                   15.6326(8)
_cell_measurement_reflns_used    5653
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      32.4689
_cell_measurement_theta_min      2.9811
_cell_volume                     1143.37(9)
_computing_cell_refinement       'CrysAlis RED, Oxford Diffraction Ltd.,'
_computing_data_collection       'CrysAlis CCD, Oxford Diffraction Ltd.,'
_computing_data_reduction        'CrysAlis RED, Oxford Diffraction Ltd.,'
_computing_molecular_graphics    Ortep3
_computing_publication_material  Shelx97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 15.9948
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measurement_device_type  'OXFORD DIFFRACTION XCALIBUR-S'
_diffrn_measurement_method       ω/q-scan
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0309
_diffrn_reflns_av_sigmaI/netI    0.0433
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            9588
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.98
_exptl_absorpt_coefficient_mu    1.906
_exptl_absorpt_correction_T_max  0.7377
_exptl_absorpt_correction_T_min  0.6683
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.31.7 (release 18-10-2006 CrysAlis171 .NET)
(compiled Oct 18 2006,16:28:17)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.567
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             556
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.17
_refine_diff_density_max         1.168
_refine_diff_density_min         -0.343
_refine_diff_density_rms         0.090
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.119
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     282
_refine_ls_number_reflns         3969
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.119
_refine_ls_R_factor_all          0.0648
_refine_ls_R_factor_gt           0.0429
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0607P)²+0.6575P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1126
_refine_ls_wR_factor_ref         0.1183
_reflns_number_gt                2917
_reflns_number_total             3969
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b918761h.txt
_cod_data_source_block           2a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_database_code               7024580
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Cu1 Cu 0.76585(6) 0.90232(6) 0.72452(4) 0.02299(17) Uani 1 1 d .
Cu2 Cu 0.41647(6) 1.07254(6) 0.78353(4) 0.02259(17) Uani 1 1 d .
O1 O 0.6365(4) 1.0908(3) 0.6990(2) 0.0242(7) Uani 1 1 d .
O2 O 0.8603(4) 0.7033(3) 0.7629(2) 0.0297(8) Uani 1 1 d .
O3 O 0.6869(4) 0.7081(4) 0.6688(3) 0.0431(9) Uani 1 1 d .
O4 O 0.5476(4) 0.8874(3) 0.8121(2) 0.0263(7) Uani 1 1 d .
O5 O 0.3213(4) 1.2722(3) 0.7549(2) 0.0252(7) Uani 1 1 d .
O6 O 0.4231(4) 1.2265(4) 0.8838(2) 0.0392(9) Uani 1 1 d .
N1 N 0.9916(4) 0.9592(4) 0.6496(3) 0.0241(9) Uani 1 1 d .
N2 N 0.1863(4) 1.0122(4) 0.8509(2) 0.0247(9) Uani 1 1 d .
C1 C 1.1451(5) 0.8821(5) 0.6759(3) 0.0265(10) Uani 1 1 d .
H1 H 1.1410 0.7927 0.7198 0.032 Uiso 1 1 calc R
C2 C 1.3059(6) 0.9261(6) 0.6427(3) 0.0324(12) Uani 1 1 d .
H2 H 1.4108 0.8682 0.6622 0.039 Uiso 1 1 calc R
C3 C 1.3110(6) 1.0570(6) 0.5802(4) 0.0361(13) Uani 1 1 d .
H3 H 1.4200 1.0917 0.5575 0.043 Uiso 1 1 calc R
C4 C 1.1577(6) 1.1374(6) 0.5505(3) 0.0330(12) Uani 1 1 d .
H4 H 1.1607 1.2270 0.5068 0.040 Uiso 1 1 calc R
C5 C 0.9981(5) 1.0857(5) 0.5854(3) 0.0253(10) Uani 1 1 d .
C6 C 0.8283(6) 1.1696(5) 0.5552(3) 0.0291(11) Uani 1 1 d .
H6A H 0.7760 1.1142 0.5296 0.035 Uiso 1 1 calc R
H6B H 0.8543 1.2556 0.5057 0.035 Uiso 1 1 calc R
C7 C 0.6940(6) 1.2105(5) 0.6329(3) 0.0273(10) Uani 1 1 d .
H7A H 0.7483 1.2596 0.6621 0.033 Uiso 1 1 calc R
H7B H 0.5912 1.2753 0.6080 0.033 Uiso 1 1 calc R
C8 C 0.7877(6) 0.6416(5) 0.7252(4) 0.0322(12) Uani 1 1 d .
C9 C 0.8294(7) 0.4813(6) 0.7536(5) 0.063(2) Uani 1 1 d .
H9A H 0.7462 0.4446 0.7330 0.095 Uiso 1 1 calc R
H9B H 0.8183 0.4454 0.8206 0.095 Uiso 1 1 calc R
H9C H 0.9505 0.4513 0.7254 0.095 Uiso 1 1 calc R
C10 C 0.0358(5) 1.0902(5) 0.8215(3) 0.0281(11) Uani 1 1 d .
H10 H 0.0428 1.1750 0.7732 0.034 Uiso 1 1 calc R
C11 C -0.1289(6) 1.0496(6) 0.8600(3) 0.0328(12) Uani 1 1 d .
H11 H -0.2330 1.1059 0.8386 0.039 Uiso 1 1 calc R
C12 C -0.1382(6) 0.9260(6) 0.9299(3) 0.0338(12) Uani 1 1 d .
H12 H -0.2491 0.8960 0.9574 0.041 Uiso 1 1 calc R
C13 C 0.0145(6) 0.8470(6) 0.9592(3) 0.0317(11) Uani 1 1 d .
H13 H 0.0095 0.7613 1.0069 0.038 Uiso 1 1 calc R
C14 C 0.1758(6) 0.8912(5) 0.9199(3) 0.0267(11) Uani 1 1 d .
C15 C 0.3454(6) 0.8059(6) 0.9518(3) 0.0325(11) Uani 1 1 d .
H15A H 0.3179 0.7187 0.9996 0.039 Uiso 1 1 calc R
H15B H 0.3942 0.8596 0.9802 0.039 Uiso 1 1 calc R
C16 C 0.4855(6) 0.7677(5) 0.8751(3) 0.0337(12) Uani 1 1 d .
H16A H 0.5856 0.7012 0.9017 0.040 Uiso 1 1 calc R
H16B H 0.4346 0.7210 0.8428 0.040 Uiso 1 1 calc R
C17 C 0.3512(5) 1.3104(5) 0.8207(3) 0.0275(11) Uani 1 1 d .
C18 C 0.2915(6) 1.4627(6) 0.8158(4) 0.0378(12) Uani 1 1 d .
H18A H 0.3905 1.5144 0.7822 0.045 Uiso 1 1 calc R
H18B H 0.1930 1.5007 0.7803 0.045 Uiso 1 1 calc R
C19 C 0.2316(11) 1.4883(8) 0.9079(5) 0.080(2) Uani 1 1 d .
H19A H 0.1274 1.4438 0.9397 0.121 Uiso 1 1 calc R
H19B H 0.2010 1.5893 0.8999 0.121 Uiso 1 1 calc R
H19C H 0.3270 1.4484 0.9443 0.121 Uiso 1 1 calc R
O111 O 0.2627(4) 0.4801(4) 0.5886(3) 0.0451(9) Uani 1 1 d .
O222 O 0.5392(5) 0.6294(4) 0.5533(3) 0.0523(11) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
O1 Cu1 O4 75.83(12)
O1 Cu1 O2 170.58(13)
O4 Cu1 O2 94.91(13)
O1 Cu1 N1 94.20(14)
O4 Cu1 N1 164.01(14)
O2 Cu1 N1 95.21(14)
O1 Cu1 Cu2 38.22(9)
O4 Cu1 Cu2 37.64(9)
O2 Cu1 Cu2 132.44(9)
N1 Cu1 Cu2 131.61(11)
O4 Cu2 O1 76.55(12)
O4 Cu2 O5 169.74(12)
O1 Cu2 O5 96.35(13)
O4 Cu2 N2 94.14(14)
O1 Cu2 N2 162.40(14)
O5 Cu2 N2 94.58(14)
O4 Cu2 Cu1 38.35(9)
O1 Cu2 Cu1 38.23(9)
O5 Cu2 Cu1 134.36(9)
N2 Cu2 Cu1 130.37(11)
C7 O1 Cu2 129.8(3)
C7 O1 Cu1 126.7(3)
Cu2 O1 Cu1 103.54(14)
C8 O2 Cu1 107.7(3)
C16 O4 Cu2 126.1(3)
C16 O4 Cu1 129.5(3)
Cu2 O4 Cu1 104.01(15)
C17 O5 Cu2 104.5(3)
C1 N1 C5 118.2(4)
C1 N1 Cu1 118.2(3)
C5 N1 Cu1 122.3(3)
C10 N2 C14 118.9(4)
C10 N2 Cu2 118.3(3)
C14 N2 Cu2 122.6(3)
N1 C1 C2 123.6(5)
N1 C1 H1 118.2
C2 C1 H1 118.2
C1 C2 C3 118.1(4)
C1 C2 H2 120.9
C3 C2 H2 120.9
C2 C3 C4 120.0(4)
C2 C3 H3 120.0
C4 C3 H3 120.0
C3 C4 C5 119.3(5)
C3 C4 H4 120.3
C5 C4 H4 120.3
N1 C5 C4 120.8(4)
N1 C5 C6 118.0(4)
C4 C5 C6 121.2(4)
C5 C6 C7 112.8(4)
C5 C6 H6A 109.0
C7 C6 H6A 109.0
C5 C6 H6B 109.0
C7 C6 H6B 109.0
H6A C6 H6B 107.8
O1 C7 C6 110.5(4)
O1 C7 H7A 109.6
C6 C7 H7A 109.6
O1 C7 H7B 109.6
C6 C7 H7B 109.6
H7A C7 H7B 108.1
O3 C8 O2 121.9(5)
O3 C8 C9 121.6(4)
O2 C8 C9 116.5(4)
C8 C9 H9A 109.5
C8 C9 H9B 109.5
H9A C9 H9B 109.5
C8 C9 H9C 109.5
H9A C9 H9C 109.5
H9B C9 H9C 109.5
N2 C10 C11 121.9(5)
N2 C10 H10 119.0
C11 C10 H10 119.0
C12 C11 C10 118.8(4)
C12 C11 H11 120.6
C10 C11 H11 120.6
C13 C12 C11 119.1(4)
C13 C12 H12 120.4
C11 C12 H12 120.4
C12 C13 C14 120.5(5)
C12 C13 H13 119.7
C14 C13 H13 119.7
N2 C14 C13 120.7(4)
N2 C14 C15 118.1(4)
C13 C14 C15 121.2(4)
C14 C15 C16 113.5(4)
C14 C15 H15A 108.9
C16 C15 H15A 108.9
C14 C15 H15B 108.9
C16 C15 H15B 108.9
H15A C15 H15B 107.7
O4 C16 C15 111.1(4)
O4 C16 H16A 109.4
C15 C16 H16A 109.4
O4 C16 H16B 109.4
C15 C16 H16B 109.4
H16A C16 H16B 108.0
O6 C17 O5 121.8(4)
O6 C17 C18 122.1(4)
O5 C17 C18 116.2(4)
C19 C18 C17 113.7(5)
C19 C18 H18A 108.8
C17 C18 H18A 108.8
C19 C18 H18B 108.8
C17 C18 H18B 108.8
H18A C18 H18B 107.7
C18 C19 H19A 109.5
C18 C19 H19B 109.5
H19A C19 H19B 109.5
C18 C19 H19C 109.5
H19A C19 H19C 109.5
H19B C19 H19C 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Cu1 O1 1.928(3)
Cu1 O4 1.937(3)
Cu1 O2 1.947(3)
Cu1 N1 1.984(4)
Cu1 Cu2 3.0292(7)
Cu2 O4 1.907(3)
Cu2 O1 1.928(3)
Cu2 O5 1.951(3)
Cu2 N2 1.994(4)
O1 C7 1.408(5)
O2 C8 1.278(5)
O3 C8 1.247(6)
O4 C16 1.405(6)
O5 C17 1.296(5)
O6 C17 1.231(6)
N1 C1 1.355(5)
N1 C5 1.359(6)
N2 C10 1.354(5)
N2 C14 1.357(6)
C1 C2 1.370(6)
C1 H1 0.9500
C2 C3 1.380(7)
C2 H2 0.9500
C3 C4 1.381(7)
C3 H3 0.9500
C4 C5 1.397(6)
C4 H4 0.9500
C5 C6 1.501(6)
C6 C7 1.521(6)
C6 H6A 0.9900
C6 H6B 0.9900
C7 H7A 0.9900
C7 H7B 0.9900
C8 C9 1.533(7)
C9 H9A 0.9800
C9 H9B 0.9800
C9 H9C 0.9800
C10 C11 1.392(6)
C10 H10 0.9500
C11 C12 1.380(7)
C11 H11 0.9500
C12 C13 1.371(7)
C12 H12 0.9500
C13 C14 1.384(6)
C13 H13 0.9500
C14 C15 1.512(6)
C15 C16 1.521(6)
C15 H15A 0.9900
C15 H15B 0.9900
C16 H16A 0.9900
C16 H16B 0.9900
C17 C18 1.506(7)
C18 C19 1.498(8)
C18 H18A 0.9900
C18 H18B 0.9900
C19 H19A 0.9800
C19 H19B 0.9800
C19 H19C 0.9800
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C11 H11 O1 0.95 2.67 3.316(5) 125.4 1_455
C2 H2 O3 0.95 2.41 3.329(6) 163.1 1_655
C4 H4 O3 0.95 2.66 3.341(6) 129.1 2_776
C12 H12 O6 0.95 2.61 3.401(6) 141.3 2_577
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
O1 Cu1 Cu2 O4 -176.7(2)
O2 Cu1 Cu2 O4 5.20(19)
N1 Cu1 Cu2 O4 -162.5(2)
O4 Cu1 Cu2 O1 176.7(2)
O2 Cu1 Cu2 O1 -178.14(19)
N1 Cu1 Cu2 O1 14.18(19)
O1 Cu1 Cu2 O5 -7.51(19)
O4 Cu1 Cu2 O5 169.16(19)
O2 Cu1 Cu2 O5 174.36(18)
N1 Cu1 Cu2 O5 6.67(18)
O1 Cu1 Cu2 N2 160.5(2)
O4 Cu1 Cu2 N2 -22.84(19)
O2 Cu1 Cu2 N2 -17.64(19)
N1 Cu1 Cu2 N2 174.68(19)
O4 Cu2 O1 C7 -178.4(4)
O5 Cu2 O1 C7 -5.9(4)
N2 Cu2 O1 C7 122.2(5)
Cu1 Cu2 O1 C7 179.5(4)
O4 Cu2 O1 Cu1 2.13(13)
O5 Cu2 O1 Cu1 174.61(13)
N2 Cu2 O1 Cu1 -57.3(5)
O4 Cu1 O1 C7 178.4(3)
O2 Cu1 O1 C7 -171.1(7)
N1 Cu1 O1 C7 11.1(3)
Cu2 Cu1 O1 C7 -179.5(4)
O4 Cu1 O1 Cu2 -2.10(13)
O2 Cu1 O1 Cu2 8.4(9)
N1 Cu1 O1 Cu2 -169.42(14)
O1 Cu1 O2 C8 70.0(9)
O4 Cu1 O2 C8 80.3(3)
N1 Cu1 O2 C8 -112.1(3)
Cu2 Cu1 O2 C8 77.1(3)
O1 Cu2 O4 C16 -175.2(4)
O5 Cu2 O4 C16 137.9(7)
N2 Cu2 O4 C16 -10.3(4)
Cu1 Cu2 O4 C16 -173.0(4)
O1 Cu2 O4 Cu1 -2.12(13)
O5 Cu2 O4 Cu1 -49.0(8)
N2 Cu2 O4 Cu1 162.75(15)
O1 Cu1 O4 C16 174.8(4)
O2 Cu1 O4 C16 -3.5(4)
N1 Cu1 O4 C16 -132.5(5)
Cu2 Cu1 O4 C16 172.7(4)
O1 Cu1 O4 Cu2 2.13(13)
O2 Cu1 O4 Cu2 -176.15(14)
N1 Cu1 O4 Cu2 54.8(6)
O4 Cu2 O5 C17 -54.4(8)
O1 Cu2 O5 C17 -100.0(3)
N2 Cu2 O5 C17 93.8(3)
Cu1 Cu2 O5 C17 -95.3(3)
O1 Cu1 N1 C1 148.8(3)
O4 Cu1 N1 C1 98.2(6)
O2 Cu1 N1 C1 -30.9(3)
Cu2 Cu1 N1 C1 140.0(3)
O1 Cu1 N1 C5 -17.8(3)
O4 Cu1 N1 C5 -68.3(6)
O2 Cu1 N1 C5 162.6(3)
Cu2 Cu1 N1 C5 -26.5(4)
O4 Cu2 N2 C10 -151.3(3)
O1 Cu2 N2 C10 -94.2(6)
O5 Cu2 N2 C10 34.1(3)
Cu1 Cu2 N2 C10 -137.3(3)
O4 Cu2 N2 C14 23.5(4)
O1 Cu2 N2 C14 80.6(6)
O5 Cu2 N2 C14 -151.1(3)
Cu1 Cu2 N2 C14 37.5(4)
C5 N1 C1 C2 1.4(6)
Cu1 N1 C1 C2 -165.6(3)
N1 C1 C2 C3 1.0(7)
C1 C2 C3 C4 -2.2(7)
C2 C3 C4 C5 0.9(7)
C1 N1 C5 C4 -2.7(6)
Cu1 N1 C5 C4 163.8(3)
C1 N1 C5 C6 178.9(4)
Cu1 N1 C5 C6 -14.6(5)
C3 C4 C5 N1 1.6(7)
C3 C4 C5 C6 179.9(4)
N1 C5 C6 C7 62.4(6)
C4 C5 C6 C7 -116.0(5)
Cu2 O1 C7 C6 -153.4(3)
Cu1 O1 C7 C6 26.0(5)
C5 C6 C7 O1 -66.4(5)
Cu1 O2 C8 O3 5.2(5)
Cu1 O2 C8 C9 -174.2(4)
C14 N2 C10 C11 -0.1(6)
Cu2 N2 C10 C11 174.9(3)
N2 C10 C11 C12 -0.2(7)
C10 C11 C12 C13 -0.1(7)
C11 C12 C13 C14 0.6(7)
C10 N2 C14 C13 0.7(6)
Cu2 N2 C14 C13 -174.1(3)
C10 N2 C14 C15 -179.9(4)
Cu2 N2 C14 C15 5.4(5)
C12 C13 C14 N2 -1.0(7)
C12 C13 C14 C15 179.6(4)
N2 C14 C15 C16 -55.4(6)
C13 C14 C15 C16 124.0(5)
Cu2 O4 C16 C15 -29.2(5)
Cu1 O4 C16 C15 159.5(3)
C14 C15 C16 O4 67.1(5)
Cu2 O5 C17 O6 -0.9(5)
Cu2 O5 C17 C18 179.6(3)
O6 C17 C18 C19 -32.5(7)
O5 C17 C18 C19 147.0(5)
