#------------------------------------------------------------------------------
#$Date: 2016-03-25 16:17:58 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179962 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/56/7025606.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7025606
loop_
_publ_author_name
'Owen, Gareth R.'
'Gauthier, Sébastien'
'Weisbach, Nancy'
'Hampel, Frank'
'Bhuvanesh, Nattamai'
'Gladysz, John A.'
_publ_section_title
;
 Towards multistranded molecular wires: syntheses, structures, and
 reactivities of tetraplatinum bis(polyynediyl) complexes with [upper bond
 1 start]Pt-C(x)-Pt-(P(CH2)3P)2-Pt-C(x)-Pt-(P(CH2)3P[upper bond 1 end])2
 cores (x = 4, 6, 8).
;
_journal_issue                   22
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5260
_journal_page_last               5271
_journal_paper_doi               10.1039/c002041a
_journal_volume                  39
_journal_year                    2010
_chemical_formula_sum            'C148 H112 Cl8 F20 P8 Pt4'
_chemical_formula_weight         3582.10
_chemical_name_systematic
;
?
;
_space_group_IT_number           60
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2n 2ab'
_symmetry_space_group_name_H-M   'P b c n'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   26.5408(4)
_cell_length_b                   22.3417(5)
_cell_length_c                   23.4476(5)
_cell_measurement_reflns_used    16021
_cell_measurement_temperature    173(2)
_cell_volume                     13903.6(5)
_computing_cell_refinement       DENZO-SMN
_computing_data_collection       'Nonius Collect'
_computing_data_reduction        DENZO-SMN
_computing_molecular_graphics    'SHELXTL NT'
_computing_publication_material  'SHELXTL NT'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_detector_area_resol_mean 9
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0391
_diffrn_reflns_av_sigmaI/netI    0.0563
_diffrn_reflns_limit_h_max       34
_diffrn_reflns_limit_h_min       -34
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            29643
_diffrn_reflns_theta_full        27.47
_diffrn_reflns_theta_max         27.47
_diffrn_reflns_theta_min         1.19
_exptl_absorpt_coefficient_mu    4.336
_exptl_absorpt_correction_T_max  0.9183
_exptl_absorpt_correction_T_min  0.4103
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   Scalepack
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.711
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             6992
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.02
_refine_diff_density_max         1.578
_refine_diff_density_min         -1.524
_refine_diff_density_rms         0.295
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.054
_refine_ls_hydrogen_treatment    'riding model'
_refine_ls_matrix_type           full
_refine_ls_number_parameters     816
_refine_ls_number_reflns         15811
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.054
_refine_ls_R_factor_all          0.0862
_refine_ls_R_factor_gt           0.0431
_refine_ls_shift/su_max          0.011
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0516P)²+48.6481P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1030
_refine_ls_wR_factor_ref         0.1268
_reflns_number_gt                10063
_reflns_number_total             15811
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c002041a.txt
_cod_data_source_block           go08
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      Pbcn
_cod_database_code               7025606
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y+1/2, z+1/2'
'-x, y, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y-1/2, -z-1/2'
'x, -y, z-1/2'
'-x-1/2, y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pt1 Pt 0.606236(9) 0.541238(10) 0.745961(10) 0.02363(7) Uani 1 1 d .
P1 P 0.60563(7) 0.50189(7) 0.83640(7) 0.0268(4) Uani 1 1 d .
C1 C 0.5748(3) 0.4641(3) 0.7199(3) 0.0274(15) Uani 1 1 d .
C1A C 0.5413(3) 0.4978(3) 0.8648(3) 0.0267(14) Uiso 1 1 d .
H1AA H 0.5249 0.4611 0.8502 0.032 Uiso 1 1 calc R
H1AB H 0.5430 0.4946 0.9069 0.032 Uiso 1 1 calc R
C1B C 0.6129(3) 0.1496(3) 0.6957(3) 0.0291(15) Uiso 1 1 d .
H1BA H 0.6482 0.1367 0.7018 0.035 Uiso 1 1 calc R
H1BB H 0.6131 0.1934 0.6891 0.035 Uiso 1 1 calc R
Pt2 Pt 0.501035(11) 0.114092(9) 0.630276(10) 0.02171(7) Uani 1 1 d .
P2 P 0.59644(7) 0.58114(7) 0.65615(7) 0.0267(4) Uani 1 1 d .
C2 C 0.5585(3) 0.4160(3) 0.7060(3) 0.0322(16) Uani 1 1 d .
C2A C 0.5088(3) 0.5522(3) 0.8489(3) 0.0316(16) Uiso 1 1 d .
H2AA H 0.5023 0.5521 0.8074 0.038 Uiso 1 1 calc R
H2AB H 0.5271 0.5895 0.8585 0.038 Uiso 1 1 calc R
C2B C 0.5828(3) 0.1363(3) 0.7490(3) 0.0285(14) Uiso 1 1 d .
H2BA H 0.5478 0.1506 0.7433 0.034 Uiso 1 1 calc R
H2BB H 0.5815 0.0924 0.7546 0.034 Uiso 1 1 calc R
P3 P 0.58802(7) 0.11198(7) 0.63161(7) 0.0244(4) Uani 1 1 d .
C3 C 0.5410(3) 0.3608(3) 0.6887(3) 0.0329(17) Uani 1 1 d .
C3A C 0.4581(3) 0.5505(3) 0.8816(3) 0.0272(15) Uiso 1 1 d .
H3AA H 0.4622 0.5728 0.9178 0.033 Uiso 1 1 calc R
H3AB H 0.4506 0.5083 0.8916 0.033 Uiso 1 1 calc R
C3B C 0.6044(3) 0.1655(3) 0.8030(2) 0.0251(14) Uiso 1 1 d .
H3BA H 0.5925 0.2075 0.8054 0.030 Uiso 1 1 calc R
H3BB H 0.6416 0.1662 0.8005 0.030 Uiso 1 1 calc R
P4 P 0.41468(7) 0.12516(7) 0.63261(7) 0.0234(4) Uani 1 1 d .
C4 C 0.5285(3) 0.3111(3) 0.6738(3) 0.0346(17) Uani 1 1 d .
C5 C 0.5160(3) 0.2544(3) 0.6566(3) 0.0289(16) Uani 1 1 d .
C6 C 0.5076(2) 0.2025(3) 0.6428(3) 0.0271(16) Uani 1 1 d .
C11 C 0.6420(3) 0.6183(3) 0.7749(3) 0.0260(15) Uani 1 1 d .
F12 F 0.56565(17) 0.66607(17) 0.79893(18) 0.0425(11) Uani 1 1 d .
C12 C 0.6165(3) 0.6671(3) 0.7956(3) 0.0297(16) Uani 1 1 d .
F13 F 0.61180(19) 0.76408(18) 0.8363(2) 0.0540(13) Uani 1 1 d .
C13 C 0.6390(3) 0.7184(3) 0.8162(3) 0.0375(18) Uani 1 1 d .
F14 F 0.7136(2) 0.7721(2) 0.8337(2) 0.0706(16) Uani 1 1 d .
C14 C 0.6902(3) 0.7224(3) 0.8139(3) 0.0406(19) Uani 1 1 d .
F15 F 0.76876(19) 0.6791(2) 0.7921(3) 0.0729(16) Uani 1 1 d .
C15 C 0.7180(3) 0.6756(3) 0.7931(3) 0.0427(19) Uani 1 1 d .
F16 F 0.72376(16) 0.57991(18) 0.75419(19) 0.0492(12) Uani 1 1 d .
C16 C 0.6934(3) 0.6251(3) 0.7740(3) 0.0319(16) Uani 1 1 d .
C21 C 0.6430(3) 0.5413(3) 0.8905(3) 0.0327(16) Uani 1 1 d .
C22 C 0.6942(3) 0.5358(4) 0.8899(3) 0.044(2) Uani 1 1 d .
H22A H 0.7096 0.5113 0.8617 0.052 Uiso 1 1 calc R
C23 C 0.7241(4) 0.5650(4) 0.9291(4) 0.057(2) Uani 1 1 d .
H23A H 0.7596 0.5600 0.9281 0.068 Uiso 1 1 calc R
C24 C 0.7028(4) 0.6007(4) 0.9691(4) 0.071(3) Uani 1 1 d .
H24A H 0.7231 0.6212 0.9962 0.086 Uiso 1 1 calc R
C25 C 0.6530(5) 0.6067(6) 0.9697(5) 0.106(5) Uani 1 1 d .
H25A H 0.6380 0.6316 0.9978 0.127 Uiso 1 1 calc R
C26 C 0.6221(4) 0.5776(5) 0.9305(4) 0.079(3) Uani 1 1 d .
H26A H 0.5866 0.5832 0.9317 0.095 Uiso 1 1 calc R
C31 C 0.6298(3) 0.4261(3) 0.8399(3) 0.0283(15) Uani 1 1 d .
C32 C 0.6703(3) 0.4099(3) 0.8056(3) 0.044(2) Uani 1 1 d .
H32A H 0.6836 0.4381 0.7793 0.052 Uiso 1 1 calc R
C33 C 0.6914(3) 0.3537(3) 0.8089(4) 0.053(2) Uani 1 1 d .
H33A H 0.7197 0.3440 0.7860 0.064 Uiso 1 1 calc R
C34 C 0.6714(3) 0.3119(3) 0.8453(4) 0.048(2) Uani 1 1 d .
H34A H 0.6850 0.2726 0.8466 0.057 Uiso 1 1 calc R
C35 C 0.6313(3) 0.3275(3) 0.8799(4) 0.057(2) Uani 1 1 d .
H35A H 0.6176 0.2989 0.9057 0.068 Uiso 1 1 calc R
C36 C 0.6112(3) 0.3841(3) 0.8773(3) 0.045(2) Uani 1 1 d .
H36A H 0.5840 0.3944 0.9017 0.054 Uiso 1 1 calc R
C41 C 0.5916(3) 0.6622(3) 0.6582(3) 0.0274(15) Uani 1 1 d .
C42 C 0.6355(3) 0.6969(3) 0.6567(3) 0.0355(17) Uani 1 1 d .
H42A H 0.6671 0.6790 0.6481 0.043 Uiso 1 1 calc R
C43 C 0.6324(3) 0.7584(3) 0.6680(3) 0.046(2) Uani 1 1 d .
H43A H 0.6620 0.7823 0.6664 0.055 Uiso 1 1 calc R
C44 C 0.5872(4) 0.7845(3) 0.6812(4) 0.051(2) Uani 1 1 d .
H44A H 0.5858 0.8262 0.6893 0.061 Uiso 1 1 calc R
C45 C 0.5436(3) 0.7505(3) 0.6829(3) 0.045(2) Uani 1 1 d .
H45A H 0.5121 0.7686 0.6913 0.054 Uiso 1 1 calc R
C46 C 0.5469(3) 0.6895(3) 0.6722(3) 0.0367(17) Uani 1 1 d .
H46A H 0.5172 0.6659 0.6746 0.044 Uiso 1 1 calc R
C51 C 0.6475(3) 0.5677(3) 0.6070(3) 0.0321(16) Uani 1 1 d .
C52 C 0.6894(3) 0.5360(4) 0.6253(4) 0.046(2) Uani 1 1 d .
H52A H 0.6906 0.5206 0.6630 0.055 Uiso 1 1 calc R
C53 C 0.7295(4) 0.5269(4) 0.5886(4) 0.065(3) Uani 1 1 d .
H53A H 0.7584 0.5057 0.6015 0.078 Uiso 1 1 calc R
C54 C 0.7279(4) 0.5485(4) 0.5333(4) 0.062(3) Uani 1 1 d .
H54A H 0.7552 0.5412 0.5080 0.074 Uiso 1 1 calc R
C55 C 0.6868(4) 0.5802(4) 0.5152(4) 0.057(2) Uani 1 1 d .
H55A H 0.6859 0.5958 0.4775 0.068 Uiso 1 1 calc R
C56 C 0.6462(3) 0.5899(4) 0.5519(3) 0.047(2) Uani 1 1 d .
H56A H 0.6176 0.6117 0.5390 0.057 Uiso 1 1 calc R
C61 C 0.4985(3) 0.0220(3) 0.6232(3) 0.0257(14) Uani 1 1 d .
F62 F 0.53813(15) 0.02633(17) 0.53185(15) 0.0354(10) Uani 1 1 d .
C62 C 0.5174(3) -0.0067(3) 0.5749(3) 0.0291(15) Uani 1 1 d .
F63 F 0.53687(19) -0.09259(18) 0.51935(18) 0.0519(13) Uani 1 1 d .
C63 C 0.5168(3) -0.0685(3) 0.5669(3) 0.0386(19) Uani 1 1 d .
F64 F 0.49381(19) -0.16348(17) 0.6001(2) 0.0608(15) Uani 1 1 d .
C64 C 0.4955(3) -0.1041(3) 0.6084(3) 0.0351(17) Uani 1 1 d .
F65 F 0.45661(19) -0.11309(18) 0.69733(19) 0.0536(13) Uani 1 1 d .
C65 C 0.4773(3) -0.0787(3) 0.6568(3) 0.0376(17) Uani 1 1 d .
F66 F 0.45919(16) 0.00524(17) 0.71181(16) 0.0377(10) Uani 1 1 d .
C66 C 0.4786(3) -0.0172(3) 0.6628(3) 0.0281(15) Uani 1 1 d .
C71 C 0.6181(3) 0.1506(3) 0.5718(3) 0.0307(16) Uani 1 1 d .
C72 C 0.6696(3) 0.1585(3) 0.5711(3) 0.045(2) Uani 1 1 d .
H72A H 0.6892 0.1457 0.6028 0.055 Uiso 1 1 calc R
C73 C 0.6932(3) 0.1849(4) 0.5246(4) 0.055(2) Uani 1 1 d .
H73A H 0.7287 0.1907 0.5246 0.066 Uiso 1 1 calc R
C74 C 0.6645(4) 0.2029(4) 0.4776(3) 0.054(2) Uani 1 1 d .
H74A H 0.6803 0.2205 0.4454 0.065 Uiso 1 1 calc R
C75 C 0.6139(4) 0.1949(3) 0.4784(3) 0.051(2) Uani 1 1 d .
H75A H 0.5944 0.2076 0.4467 0.061 Uiso 1 1 calc R
C76 C 0.5898(3) 0.1685(3) 0.5249(3) 0.0350(17) Uani 1 1 d .
H76A H 0.5543 0.1628 0.5245 0.042 Uiso 1 1 calc R
C81 C 0.6178(3) 0.0381(3) 0.6294(3) 0.0297(16) Uani 1 1 d .
C82 C 0.6356(3) 0.0149(3) 0.5773(3) 0.0371(18) Uani 1 1 d .
H82A H 0.6362 0.0397 0.5443 0.045 Uiso 1 1 calc R
C83 C 0.6522(3) -0.0441(3) 0.5739(4) 0.043(2) Uani 1 1 d .
H83A H 0.6635 -0.0597 0.5384 0.052 Uiso 1 1 calc R
C84 C 0.6524(3) -0.0801(3) 0.6216(4) 0.049(2) Uani 1 1 d .
H84A H 0.6638 -0.1203 0.6189 0.059 Uiso 1 1 calc R
C85 C 0.6363(3) -0.0580(3) 0.6726(4) 0.048(2) Uani 1 1 d .
H85A H 0.6371 -0.0826 0.7056 0.058 Uiso 1 1 calc R
C86 C 0.6184(3) 0.0012(3) 0.6762(3) 0.0404(19) Uani 1 1 d .
H86A H 0.6065 0.0159 0.7117 0.048 Uiso 1 1 calc R
C91 C 0.3759(3) 0.0575(3) 0.6315(3) 0.0277(15) Uani 1 1 d .
C92 C 0.3822(3) 0.0172(3) 0.5861(3) 0.0296(16) Uani 1 1 d .
H92A H 0.4045 0.0268 0.5558 0.036 Uiso 1 1 calc R
C93 C 0.3562(3) -0.0365(3) 0.5853(3) 0.0407(19) Uani 1 1 d .
H93A H 0.3614 -0.0638 0.5548 0.049 Uiso 1 1 calc R
C94 C 0.3231(3) -0.0509(3) 0.6280(3) 0.048(2) Uani 1 1 d .
H94A H 0.3051 -0.0876 0.6267 0.058 Uiso 1 1 calc R
C95 C 0.3158(3) -0.0114(3) 0.6730(3) 0.0427(19) Uani 1 1 d .
H95A H 0.2932 -0.0211 0.7030 0.051 Uiso 1 1 calc R
C96 C 0.3419(3) 0.0423(3) 0.6734(3) 0.0322(16) Uani 1 1 d .
H96A H 0.3362 0.0696 0.7037 0.039 Uiso 1 1 calc R
C101 C 0.3869(3) 0.1686(3) 0.5746(3) 0.0246(15) Uani 1 1 d .
C102 C 0.4161(3) 0.1958(3) 0.5327(3) 0.0276(15) Uani 1 1 d .
H10A H 0.4518 0.1925 0.5341 0.033 Uiso 1 1 calc R
C103 C 0.3937(3) 0.2278(3) 0.4887(3) 0.045(2) Uani 1 1 d .
H10B H 0.4140 0.2458 0.4600 0.054 Uiso 1 1 calc R
C104 C 0.3416(3) 0.2335(3) 0.4868(3) 0.044(2) Uani 1 1 d .
H10C H 0.3262 0.2556 0.4569 0.053 Uiso 1 1 calc R
C105 C 0.3127(3) 0.2075(3) 0.5275(3) 0.0420(19) Uani 1 1 d .
H10D H 0.2771 0.2121 0.5261 0.050 Uiso 1 1 calc R
C106 C 0.3345(3) 0.1740(3) 0.5716(3) 0.0340(17) Uani 1 1 d .
H10E H 0.3138 0.1550 0.5993 0.041 Uiso 1 1 calc R
C100 C 0.5242(5) 0.3263(4) 0.5274(4) 0.072(3) Uani 1 1 d .
H10F H 0.4984 0.3084 0.5506 0.087 Uiso 1 1 d R
H10G H 0.5563 0.3118 0.5402 0.087 Uiso 1 1 d R
Cl11 Cl 0.52156(13) 0.40295(12) 0.53627(12) 0.0861(9) Uani 1 1 d .
Cl12 Cl 0.51427(11) 0.30466(11) 0.45733(11) 0.0721(8) Uani 1 1 d .
C200 C 0.3101(8) 0.3637(8) 0.8852(9) 0.132(8) Uiso 0.680(5) 1 d PD
H20A H 0.2945 0.3701 0.9216 0.158 Uiso 0.680(5) 1 d PR
H20B H 0.3360 0.3935 0.8819 0.158 Uiso 0.680(5) 1 d PR
Cl21 Cl 0.27035(19) 0.38342(19) 0.8396(2) 0.0955(12) Uani 0.680(5) 1 d PD
Cl22 Cl 0.34116(19) 0.30164(19) 0.8910(2) 0.0955(12) Uani 0.680(5) 1 d PD
C201 C 0.3239(12) 0.3096(12) 0.830(2) 0.132(8) Uiso 0.32 1 d PD
H20C H 0.3448 0.2862 0.8552 0.158 Uiso 0.320(5) 1 d PR
H20D H 0.3417 0.3117 0.7949 0.158 Uiso 0.320(5) 1 d PR
Cl2A Cl 0.3278(4) 0.3741(4) 0.8588(5) 0.0955(12) Uani 0.32 1 d PD
Cl2B Cl 0.2765(4) 0.2656(4) 0.8206(5) 0.0955(12) Uani 0.32 1 d PD
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Pt1 C11 176.8(3) . .
C1 Pt1 P1 87.10(18) . .
C11 Pt1 P1 91.11(19) . .
C1 Pt1 P2 90.41(18) . .
C11 Pt1 P2 91.65(18) . .
P1 Pt1 P2 173.10(7) . .
C1 Pt1 Pt2 9.43(19) . .
C11 Pt1 Pt2 167.46(18) . .
P1 Pt1 Pt2 83.49(4) . .
P2 Pt1 Pt2 95.00(4) . .
C31 P1 C21 103.0(3) . .
C31 P1 C1A 105.5(3) . .
C21 P1 C1A 106.0(3) . .
C31 P1 Pt1 113.4(2) . .
C21 P1 Pt1 116.8(2) . .
C1A P1 Pt1 111.2(2) . .
C2 C1 Pt1 175.8(6) . .
C2A C1A P1 113.3(4) . .
C2B C1B P3 113.2(5) . .
C6 Pt2 C61 175.1(3) . .
C6 Pt2 P4 88.66(19) . .
C61 Pt2 P4 94.4(2) . .
C6 Pt2 P3 86.09(19) . .
C61 Pt2 P3 90.8(2) . .
P4 Pt2 P3 174.57(6) . .
C6 Pt2 Pt1 13.00(19) . .
C61 Pt2 Pt1 162.27(18) . .
P4 Pt2 Pt1 99.42(4) . .
P3 Pt2 Pt1 75.20(4) . .
C51 P2 C3A 102.8(3) . 3_656
C51 P2 C41 103.6(3) . .
C3A P2 C41 109.3(3) 3_656 .
C51 P2 Pt1 115.8(3) . .
C3A P2 Pt1 112.8(2) 3_656 .
C41 P2 Pt1 111.7(2) . .
C1 C2 C3 178.1(8) . .
C1A C2A C3A 110.4(5) . .
C3B C2B C1B 113.6(5) . .
C71 P3 C81 102.5(3) . .
C71 P3 C1B 104.7(3) . .
C81 P3 C1B 106.2(3) . .
C71 P3 Pt2 114.6(2) . .
C81 P3 Pt2 116.7(2) . .
C1B P3 Pt2 111.1(2) . .
C4 C3 C2 176.1(8) . .
C2A C3A P2 116.0(5) . 3_656
C2B C3B P4 111.6(4) . 3_656
C101 P4 C91 101.6(3) . .
C101 P4 C3B 103.9(3) . 3_656
C91 P4 C3B 105.3(3) . 3_656
C101 P4 Pt2 116.1(2) . .
C91 P4 Pt2 118.0(2) . .
C3B P4 Pt2 110.3(2) 3_656 .
C3 C4 C5 178.1(9) . .
C6 C5 C4 176.0(8) . .
C5 C6 Pt2 170.9(6) . .
C12 C11 C16 114.1(6) . .
C12 C11 Pt1 123.3(5) . .
C16 C11 Pt1 122.6(5) . .
F12 C12 C11 119.9(6) . .
F12 C12 C13 115.3(6) . .
C11 C12 C13 124.8(7) . .
C14 C13 F13 120.1(6) . .
C14 C13 C12 118.2(7) . .
F13 C13 C12 121.6(7) . .
C13 C14 F14 119.9(7) . .
C13 C14 C15 120.1(7) . .
F14 C14 C15 120.0(7) . .
F15 C15 C16 120.9(7) . .
F15 C15 C14 120.0(7) . .
C16 C15 C14 119.1(7) . .
C15 C16 C11 123.7(7) . .
C15 C16 F16 115.8(7) . .
C11 C16 F16 120.5(6) . .
C26 C21 C22 117.9(7) . .
C26 C21 P1 122.9(7) . .
C22 C21 P1 119.2(6) . .
C23 C22 C21 121.5(8) . .
C22 C23 C24 120.1(9) . .
C25 C24 C23 118.8(9) . .
C24 C25 C26 122.1(10) . .
C21 C26 C25 119.6(9) . .
C36 C31 C32 117.9(6) . .
C36 C31 P1 122.7(5) . .
C32 C31 P1 119.4(5) . .
C31 C32 C33 121.3(7) . .
C34 C33 C32 119.9(8) . .
C33 C34 C35 119.4(7) . .
C36 C35 C34 120.2(8) . .
C35 C36 C31 121.2(8) . .
C46 C41 C42 118.7(6) . .
C46 C41 P2 120.7(5) . .
C42 C41 P2 119.5(5) . .
C41 C42 C43 119.3(7) . .
C44 C43 C42 120.8(8) . .
C45 C44 C43 120.2(7) . .
C44 C45 C46 118.9(8) . .
C41 C46 C45 122.1(7) . .
C52 C51 C56 119.4(7) . .
C52 C51 P2 119.3(6) . .
C56 C51 P2 121.2(6) . .
C51 C52 C53 120.1(8) . .
C54 C53 C52 120.5(9) . .
C55 C54 C53 119.7(8) . .
C54 C55 C56 120.3(8) . .
C51 C56 C55 120.0(8) . .
C62 C61 C66 113.0(6) . .
C62 C61 Pt2 120.8(5) . .
C66 C61 Pt2 126.1(5) . .
F62 C62 C63 116.1(6) . .
F62 C62 C61 119.7(6) . .
C63 C62 C61 124.2(7) . .
F63 C63 C64 121.0(6) . .
F63 C63 C62 120.2(7) . .
C64 C63 C62 118.8(7) . .
F64 C64 C63 118.8(7) . .
F64 C64 C65 121.5(7) . .
C63 C64 C65 119.7(6) . .
F65 C65 C64 120.0(6) . .
F65 C65 C66 120.5(7) . .
C64 C65 C66 119.5(7) . .
F66 C66 C65 116.4(6) . .
F66 C66 C61 118.7(5) . .
C65 C66 C61 124.8(6) . .
C76 C71 C72 119.4(7) . .
C76 C71 P3 120.4(6) . .
C72 C71 P3 120.1(6) . .
C71 C72 C73 120.6(8) . .
C74 C73 C72 119.7(8) . .
C73 C74 C75 119.5(7) . .
C76 C75 C74 121.4(8) . .
C75 C76 C71 119.4(8) . .
C82 C81 C86 118.0(6) . .
C82 C81 P3 120.0(5) . .
C86 C81 P3 121.6(5) . .
C81 C82 C83 120.2(7) . .
C84 C83 C82 120.4(7) . .
C85 C84 C83 120.1(7) . .
C84 C85 C86 119.9(7) . .
C81 C86 C85 121.4(7) . .
C96 C91 C92 117.5(6) . .
C96 C91 P4 124.2(5) . .
C92 C91 P4 118.3(5) . .
C91 C92 C93 120.4(7) . .
C92 C93 C94 120.9(7) . .
C95 C94 C93 119.7(7) . .
C94 C95 C96 119.0(7) . .
C91 C96 C95 122.4(7) . .
C102 C101 C106 118.7(6) . .
C102 C101 P4 122.3(5) . .
C106 C101 P4 119.1(5) . .
C101 C102 C103 120.8(7) . .
C104 C103 C102 119.8(7) . .
C105 C104 C103 120.1(7) . .
C104 C105 C106 120.9(8) . .
C105 C106 C101 119.7(7) . .
Cl11 C100 Cl12 112.7(5) . .
Cl2A C200 Cl21 77.9(14) . .
Cl2A C200 Cl22 90.8(16) . .
Cl21 C200 Cl22 130.0(14) . .
Cl2A C200 C201 62(2) . .
Cl21 C200 C201 80.7(16) . .
Cl22 C200 C201 51.8(17) . .
C200 Cl21 Cl2A 29.6(9) . .
C200 Cl21 C201 54.3(13) . .
Cl2A Cl21 C201 46.5(7) . .
C201 Cl22 C200 70.3(15) . .
C201 Cl22 Cl2A 56.2(9) . .
C200 Cl22 Cl2A 26.4(9) . .
Cl22 C201 Cl2A 72.1(14) . .
Cl22 C201 Cl2B 108(3) . .
Cl2A C201 Cl2B 132(2) . .
Cl22 C201 C200 57.9(13) . .
Cl2A C201 C200 26.8(10) . .
Cl2B C201 C200 111(2) . .
Cl22 C201 Cl21 101.3(17) . .
Cl2A C201 Cl21 47.1(10) . .
Cl2B C201 Cl21 88.1(16) . .
C200 C201 Cl21 45.0(8) . .
C200 Cl2A C201 91(3) . .
C200 Cl2A Cl21 72.5(13) . .
C201 Cl2A Cl21 86.4(15) . .
C200 Cl2A Cl22 62.7(12) . .
C201 Cl2A Cl22 51.7(18) . .
Cl21 Cl2A Cl22 114.6(7) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 C1 2.010(6) .
Pt1 C11 2.080(6) .
Pt1 P1 2.2958(17) .
Pt1 P2 2.3014(17) .
Pt1 Pt2 10.3066(4) .
P1 C31 1.813(6) .
P1 C21 1.836(7) .
P1 C1A 1.834(7) .
C1 C2 1.203(8) .
C1A C2A 1.536(9) .
C1B C2B 1.512(9) .
C1B P3 1.845(6) .
Pt2 C6 2.003(6) .
Pt2 C61 2.065(6) .
Pt2 P4 2.3059(18) .
Pt2 P3 2.3093(18) .
P2 C51 1.803(7) .
P2 C3A 1.829(7) 3_656
P2 C41 1.817(6) .
C2 C3 1.378(9) .
C2A C3A 1.551(9) .
C2B C3B 1.536(8) .
P3 C71 1.831(7) .
P3 C81 1.832(7) .
C3 C4 1.210(9) .
C3A P2 1.829(7) 3_656
C3B P4 1.831(6) 3_656
P4 C101 1.825(6) .
P4 C91 1.829(7) .
P4 C3B 1.831(6) 3_656
C4 C5 1.371(9) .
C5 C6 1.225(9) .
C11 C12 1.372(9) .
C11 C16 1.375(10) .
F12 C12 1.352(8) .
C12 C13 1.379(9) .
F13 C13 1.335(8) .
C13 C14 1.362(11) .
F14 C14 1.354(8) .
C14 C15 1.370(11) .
F15 C15 1.350(9) .
C15 C16 1.378(10) .
F16 C16 1.372(8) .
C21 C26 1.359(11) .
C21 C22 1.365(10) .
C22 C23 1.378(11) .
C23 C24 1.354(13) .
C24 C25 1.328(14) .
C25 C26 1.393(13) .
C31 C36 1.375(9) .
C31 C32 1.390(10) .
C32 C33 1.376(10) .
C33 C34 1.371(11) .
C34 C35 1.385(11) .
C35 C36 1.373(10) .
C41 C46 1.374(10) .
C41 C42 1.400(9) .
C42 C43 1.402(10) .
C43 C44 1.370(12) .
C44 C45 1.385(11) .
C45 C46 1.387(9) .
C51 C52 1.387(10) .
C51 C56 1.384(10) .
C52 C53 1.383(11) .
C53 C54 1.385(13) .
C54 C55 1.368(12) .
C55 C56 1.397(11) .
C61 C62 1.394(9) .
C61 C66 1.383(9) .
F62 C62 1.367(8) .
C62 C63 1.393(9) .
F63 C63 1.348(8) .
C63 C64 1.379(11) .
F64 C64 1.341(7) .
C64 C65 1.357(10) .
F65 C65 1.339(8) .
C65 C66 1.382(9) .
F66 C66 1.355(7) .
C71 C76 1.391(10) .
C71 C72 1.380(10) .
C72 C73 1.389(10) .
C73 C74 1.398(12) .
C74 C75 1.355(12) .
C75 C76 1.394(10) .
C81 C82 1.409(9) .
C81 C86 1.371(9) .
C82 C83 1.394(10) .
C83 C84 1.377(11) .
C84 C85 1.362(11) .
C85 C86 1.408(10) .
C91 C96 1.377(9) .
C91 C92 1.403(9) .
C92 C93 1.384(9) .
C93 C94 1.370(11) .
C94 C95 1.388(11) .
C95 C96 1.387(9) .
C101 C102 1.393(9) .
C101 C106 1.398(9) .
C102 C103 1.388(10) .
C103 C104 1.390(11) .
C104 C105 1.355(10) .
C105 C106 1.403(10) .
C100 Cl11 1.727(9) .
C100 Cl12 1.732(10) .
C200 Cl2A 0.81(2) .
C200 Cl21 1.565(13) .
C200 Cl22 1.618(13) .
C200 C201 1.80(4) .
Cl21 Cl2A 1.605(12) .
Cl21 C201 2.19(4) .
Cl22 C201 1.50(5) .
Cl22 Cl2A 1.820(11) .
C201 Cl2A 1.590(16) .
C201 Cl2B 1.614(16) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C1 Pt1 P1 C31 47.4(3) . .
C11 Pt1 P1 C31 -130.0(3) . .
P2 Pt1 P1 C31 116.4(5) . .
Pt2 Pt1 P1 C31 38.6(2) . .
C1 Pt1 P1 C21 167.0(3) . .
C11 Pt1 P1 C21 -10.4(3) . .
P2 Pt1 P1 C21 -124.0(5) . .
Pt2 Pt1 P1 C21 158.2(3) . .
C1 Pt1 P1 C1A -71.2(3) . .
C11 Pt1 P1 C1A 111.4(3) . .
P2 Pt1 P1 C1A -2.2(6) . .
Pt2 Pt1 P1 C1A -80.0(2) . .
C11 Pt1 C1 C2 3(12) . .
P1 Pt1 C1 C2 -53(9) . .
P2 Pt1 C1 C2 133(9) . .
Pt2 Pt1 C1 C2 14(8) . .
C31 P1 C1A C2A -162.3(5) . .
C21 P1 C1A C2A 88.9(5) . .
Pt1 P1 C1A C2A -39.0(5) . .
C1 Pt1 Pt2 C6 14.2(14) . .
C11 Pt1 Pt2 C6 -168.7(12) . .
P1 Pt1 Pt2 C6 126.3(8) . .
P2 Pt1 Pt2 C6 -46.9(8) . .
C1 Pt1 Pt2 C61 -160.9(13) . .
C11 Pt1 Pt2 C61 16.2(11) . .
P1 Pt1 Pt2 C61 -48.8(6) . .
P2 Pt1 Pt2 C61 138.0(6) . .
C1 Pt1 Pt2 P4 -20.3(11) . .
C11 Pt1 Pt2 P4 156.8(9) . .
P1 Pt1 Pt2 P4 91.79(6) . .
P2 Pt1 Pt2 P4 -81.44(6) . .
C1 Pt1 Pt2 P3 160.4(11) . .
C11 Pt1 Pt2 P3 -22.5(9) . .
P1 Pt1 Pt2 P3 -87.48(6) . .
P2 Pt1 Pt2 P3 99.29(6) . .
C1 Pt1 P2 C51 -88.2(3) . .
C11 Pt1 P2 C51 89.4(3) . .
P1 Pt1 P2 C51 -157.0(5) . .
Pt2 Pt1 P2 C51 -79.9(2) . .
C1 Pt1 P2 C3A 29.9(3) . 3_656
C11 Pt1 P2 C3A -152.5(3) . 3_656
P1 Pt1 P2 C3A -38.9(6) . 3_656
Pt2 Pt1 P2 C3A 38.2(2) . 3_656
C1 Pt1 P2 C41 153.5(3) . .
C11 Pt1 P2 C41 -28.9(3) . .
P1 Pt1 P2 C41 84.7(6) . .
Pt2 Pt1 P2 C41 161.7(3) . .
Pt1 C1 C2 C3 -79(29) . .
P1 C1A C2A C3A -171.5(4) . .
P3 C1B C2B C3B 177.9(4) . .
C2B C1B P3 C71 164.3(5) . .
C2B C1B P3 C81 -87.8(5) . .
C2B C1B P3 Pt2 40.1(5) . .
C6 Pt2 P3 C71 -66.5(3) . .
C61 Pt2 P3 C71 117.3(3) . .
P4 Pt2 P3 C71 -81.3(7) . .
Pt1 Pt2 P3 C71 -73.7(2) . .
C6 Pt2 P3 C81 173.8(3) . .
C61 Pt2 P3 C81 -2.4(3) . .
P4 Pt2 P3 C81 159.0(6) . .
Pt1 Pt2 P3 C81 166.6(3) . .
C6 Pt2 P3 C1B 51.9(3) . .
C61 Pt2 P3 C1B -124.3(3) . .
P4 Pt2 P3 C1B 37.0(7) . .
Pt1 Pt2 P3 C1B 44.7(2) . .
C1 C2 C3 C4 55(33) . .
C1A C2A C3A P2 -146.8(5) . 3_656
C1B C2B C3B P4 -155.7(5) . 3_656
C6 Pt2 P4 C101 65.7(3) . .
C61 Pt2 P4 C101 -118.2(3) . .
P3 Pt2 P4 C101 80.5(7) . .
Pt1 Pt2 P4 C101 73.0(2) . .
C6 Pt2 P4 C91 -173.3(3) . .
C61 Pt2 P4 C91 2.9(3) . .
P3 Pt2 P4 C91 -158.5(6) . .
Pt1 Pt2 P4 C91 -166.0(2) . .
C6 Pt2 P4 C3B -52.2(3) . 3_656
C61 Pt2 P4 C3B 123.9(3) . 3_656
P3 Pt2 P4 C3B -37.4(7) . 3_656
Pt1 Pt2 P4 C3B -44.9(2) . 3_656
C2 C3 C4 C5 -17(32) . .
C3 C4 C5 C6 35(31) . .
C4 C5 C6 Pt2 23(14) . .
C61 Pt2 C6 C5 0(6) . .
P4 Pt2 C6 C5 128(4) . .
P3 Pt2 C6 C5 -50(4) . .
Pt1 Pt2 C6 C5 -18(3) . .
C1 Pt1 C11 C12 -143(5) . .
P1 Pt1 C11 C12 -87.4(6) . .
P2 Pt1 C11 C12 86.3(6) . .
Pt2 Pt1 C11 C12 -151.6(6) . .
C1 Pt1 C11 C16 38(5) . .
P1 Pt1 C11 C16 93.5(6) . .
P2 Pt1 C11 C16 -92.8(6) . .
Pt2 Pt1 C11 C16 29.3(13) . .
C16 C11 C12 F12 -179.7(6) . .
Pt1 C11 C12 F12 1.1(9) . .
C16 C11 C12 C13 -2.3(10) . .
Pt1 C11 C12 C13 178.6(5) . .
F12 C12 C13 C14 -179.8(6) . .
C11 C12 C13 C14 2.7(11) . .
F12 C12 C13 F13 -1.8(10) . .
C11 C12 C13 F13 -179.4(6) . .
F13 C13 C14 F14 2.1(11) . .
C12 C13 C14 F14 -180.0(7) . .
F13 C13 C14 C15 -179.7(7) . .
C12 C13 C14 C15 -1.8(12) . .
C13 C14 C15 F15 -178.5(7) . .
F14 C14 C15 F15 -0.4(12) . .
C13 C14 C15 C16 0.8(12) . .
F14 C14 C15 C16 178.9(7) . .
F15 C15 C16 C11 178.8(7) . .
C14 C15 C16 C11 -0.4(12) . .
F15 C15 C16 F16 -0.2(11) . .
C14 C15 C16 F16 -179.5(7) . .
C12 C11 C16 C15 1.1(11) . .
Pt1 C11 C16 C15 -179.8(6) . .
C12 C11 C16 F16 -179.9(6) . .
Pt1 C11 C16 F16 -0.7(9) . .
C31 P1 C21 C26 -132.1(8) . .
C1A P1 C21 C26 -21.6(8) . .
Pt1 P1 C21 C26 102.9(8) . .
C31 P1 C21 C22 50.1(7) . .
C1A P1 C21 C22 160.7(6) . .
Pt1 P1 C21 C22 -74.9(6) . .
C26 C21 C22 C23 1.4(12) . .
P1 C21 C22 C23 179.3(6) . .
C21 C22 C23 C24 -0.9(13) . .
C22 C23 C24 C25 0.3(16) . .
C23 C24 C25 C26 0(2) . .
C22 C21 C26 C25 -1.3(16) . .
P1 C21 C26 C25 -179.1(9) . .
C24 C25 C26 C21 1(2) . .
C21 P1 C31 C36 87.2(7) . .
C1A P1 C31 C36 -23.8(7) . .
Pt1 P1 C31 C36 -145.6(6) . .
C21 P1 C31 C32 -89.8(7) . .
C1A P1 C31 C32 159.2(6) . .
Pt1 P1 C31 C32 37.4(7) . .
C36 C31 C32 C33 -0.4(12) . .
P1 C31 C32 C33 176.8(7) . .
C31 C32 C33 C34 2.2(13) . .
C32 C33 C34 C35 -2.4(14) . .
C33 C34 C35 C36 0.9(14) . .
C34 C35 C36 C31 0.9(14) . .
C32 C31 C36 C35 -1.2(12) . .
P1 C31 C36 C35 -178.2(7) . .
C51 P2 C41 C46 154.5(6) . .
C3A P2 C41 C46 45.4(6) 3_656 .
Pt1 P2 C41 C46 -80.1(6) . .
C51 P2 C41 C42 -38.1(6) . .
C3A P2 C41 C42 -147.2(5) 3_656 .
Pt1 P2 C41 C42 87.3(5) . .
C46 C41 C42 C43 -1.6(10) . .
P2 C41 C42 C43 -169.3(5) . .
C41 C42 C43 C44 1.0(11) . .
C42 C43 C44 C45 -0.9(12) . .
C43 C44 C45 C46 1.4(12) . .
C42 C41 C46 C45 2.2(11) . .
P2 C41 C46 C45 169.7(6) . .
C44 C45 C46 C41 -2.0(12) . .
C3A P2 C51 C52 -124.7(6) 3_656 .
C41 P2 C51 C52 121.5(6) . .
Pt1 P2 C51 C52 -1.2(7) . .
C3A P2 C51 C56 57.1(7) 3_656 .
C41 P2 C51 C56 -56.7(7) . .
Pt1 P2 C51 C56 -179.4(5) . .
C56 C51 C52 C53 0.1(12) . .
P2 C51 C52 C53 -178.1(7) . .
C51 C52 C53 C54 -0.9(14) . .
C52 C53 C54 C55 1.5(15) . .
C53 C54 C55 C56 -1.3(14) . .
C52 C51 C56 C55 0.1(12) . .
P2 C51 C56 C55 178.2(6) . .
C54 C55 C56 C51 0.5(13) . .
C6 Pt2 C61 C62 -115(3) . .
P4 Pt2 C61 C62 116.9(5) . .
P3 Pt2 C61 C62 -64.8(5) . .
Pt1 Pt2 C61 C62 -102.0(7) . .
C6 Pt2 C61 C66 66(3) . .
P4 Pt2 C61 C66 -62.4(6) . .
P3 Pt2 C61 C66 115.9(6) . .
Pt1 Pt2 C61 C66 78.7(9) . .
C66 C61 C62 F62 179.7(6) . .
Pt2 C61 C62 F62 0.3(9) . .
C66 C61 C62 C63 -0.3(10) . .
Pt2 C61 C62 C63 -179.7(6) . .
F62 C62 C63 F63 1.3(10) . .
C61 C62 C63 F63 -178.7(7) . .
F62 C62 C63 C64 -178.7(6) . .
C61 C62 C63 C64 1.3(12) . .
F63 C63 C64 F64 -1.6(11) . .
C62 C63 C64 F64 178.4(6) . .
F63 C63 C64 C65 177.6(7) . .
C62 C63 C64 C65 -2.4(12) . .
F64 C64 C65 F65 -0.6(12) . .
C63 C64 C65 F65 -179.8(7) . .
F64 C64 C65 C66 -178.3(7) . .
C63 C64 C65 C66 2.6(12) . .
F65 C65 C66 F66 1.6(11) . .
C64 C65 C66 F66 179.2(7) . .
F65 C65 C66 C61 -179.2(7) . .
C64 C65 C66 C61 -1.6(12) . .
C62 C61 C66 F66 179.6(6) . .
Pt2 C61 C66 F66 -1.0(10) . .
C62 C61 C66 C65 0.5(10) . .
Pt2 C61 C66 C65 179.8(6) . .
C81 P3 C71 C76 115.4(6) . .
C1B P3 C71 C76 -134.0(6) . .
Pt2 P3 C71 C76 -12.0(6) . .
C81 P3 C71 C72 -60.0(6) . .
C1B P3 C71 C72 50.6(7) . .
Pt2 P3 C71 C72 172.6(5) . .
C76 C71 C72 C73 1.1(12) . .
P3 C71 C72 C73 176.5(6) . .
C71 C72 C73 C74 -1.0(13) . .
C72 C73 C74 C75 0.8(13) . .
C73 C74 C75 C76 -0.7(13) . .
C74 C75 C76 C71 0.9(12) . .
C72 C71 C76 C75 -1.1(11) . .
P3 C71 C76 C75 -176.5(5) . .
C71 P3 C81 C82 -28.2(7) . .
C1B P3 C81 C82 -137.7(6) . .
Pt2 P3 C81 C82 97.8(6) . .
C71 P3 C81 C86 159.4(6) . .
C1B P3 C81 C86 49.9(7) . .
Pt2 P3 C81 C86 -74.6(6) . .
C86 C81 C82 C83 1.1(11) . .
P3 C81 C82 C83 -171.6(6) . .
C81 C82 C83 C84 -1.2(12) . .
C82 C83 C84 C85 -0.1(13) . .
C83 C84 C85 C86 1.4(13) . .
C82 C81 C86 C85 0.2(11) . .
P3 C81 C86 C85 172.8(6) . .
C84 C85 C86 C81 -1.5(13) . .
C101 P4 C91 C96 -110.6(6) . .
C3B P4 C91 C96 -2.4(7) 3_656 .
Pt2 P4 C91 C96 121.2(6) . .
C101 P4 C91 C92 71.7(6) . .
C3B P4 C91 C92 179.8(5) 3_656 .
Pt2 P4 C91 C92 -56.6(6) . .
C96 C91 C92 C93 -2.1(10) . .
P4 C91 C92 C93 175.8(5) . .
C91 C92 C93 C94 1.4(11) . .
C92 C93 C94 C95 -0.6(12) . .
C93 C94 C95 C96 0.8(12) . .
C92 C91 C96 C95 2.3(10) . .
P4 C91 C96 C95 -175.5(6) . .
C94 C95 C96 C91 -1.7(12) . .
C91 P4 C101 C102 -132.2(5) . .
C3B P4 C101 C102 118.6(5) 3_656 .
Pt2 P4 C101 C102 -2.8(6) . .
C91 P4 C101 C106 46.8(6) . .
C3B P4 C101 C106 -62.4(6) 3_656 .
Pt2 P4 C101 C106 176.2(4) . .
C106 C101 C102 C103 0.1(9) . .
P4 C101 C102 C103 179.1(5) . .
C101 C102 C103 C104 0.8(11) . .
C102 C103 C104 C105 -0.4(12) . .
C103 C104 C105 C106 -0.9(12) . .
C104 C105 C106 C101 1.8(11) . .
C102 C101 C106 C105 -1.4(9) . .
P4 C101 C106 C105 179.6(5) . .
Cl22 C200 Cl21 Cl2A -81(2) . .
C201 C200 Cl21 Cl2A -63.2(19) . .
Cl2A C200 Cl21 C201 63.2(19) . .
Cl22 C200 Cl21 C201 -17.6(17) . .
Cl2A C200 Cl22 C201 -53(2) . .
Cl21 C200 Cl22 C201 22(2) . .
Cl21 C200 Cl22 Cl2A 75(2) . .
C201 C200 Cl22 Cl2A 53(2) . .
C200 Cl22 C201 Cl2A 25.2(12) . .
C200 Cl22 C201 Cl2B -104(2) . .
Cl2A Cl22 C201 Cl2B -129(2) . .
Cl2A Cl22 C201 C200 -25.2(12) . .
C200 Cl22 C201 Cl21 -12.2(11) . .
Cl2A Cl22 C201 Cl21 -37.4(7) . .
Cl2A C200 C201 Cl22 116(2) . .
Cl21 C200 C201 Cl22 -162.9(16) . .
Cl21 C200 C201 Cl2A 81.2(16) . .
Cl22 C200 C201 Cl2A -116(2) . .
Cl2A C200 C201 Cl2B -146(4) . .
Cl21 C200 C201 Cl2B -65(3) . .
Cl22 C200 C201 Cl2B 98(3) . .
Cl2A C200 C201 Cl21 -81.2(16) . .
Cl22 C200 C201 Cl21 162.9(16) . .
C200 Cl21 C201 Cl22 14.7(13) . .
Cl2A Cl21 C201 Cl22 52.1(9) . .
C200 Cl21 C201 Cl2A -37.4(13) . .
C200 Cl21 C201 Cl2B 122(3) . .
Cl2A Cl21 C201 Cl2B 160(3) . .
Cl2A Cl21 C201 C200 37.4(13) . .
Cl21 C200 Cl2A C201 -85.8(16) . .
Cl22 C200 Cl2A C201 45.0(19) . .
Cl22 C200 Cl2A Cl21 130.8(12) . .
C201 C200 Cl2A Cl21 85.8(16) . .
Cl21 C200 Cl2A Cl22 -130.8(12) . .
C201 C200 Cl2A Cl22 -45.0(19) . .
Cl22 C201 Cl2A C200 -53.1(18) . .
Cl2B C201 Cl2A C200 45(4) . .
Cl21 C201 Cl2A C200 72.4(13) . .
Cl22 C201 Cl2A Cl21 -125.5(11) . .
Cl2B C201 Cl2A Cl21 -28(4) . .
C200 C201 Cl2A Cl21 -72.4(13) . .
Cl2B C201 Cl2A Cl22 98(4) . .
C200 C201 Cl2A Cl22 53.1(18) . .
Cl21 C201 Cl2A Cl22 125.5(11) . .
C201 Cl21 Cl2A C200 -92(3) . .
C200 Cl21 Cl2A C201 92(3) . .
C200 Cl21 Cl2A Cl22 47.7(16) . .
C201 Cl21 Cl2A Cl22 -44.7(17) . .
C201 Cl22 Cl2A C200 116(3) . .
C200 Cl22 Cl2A C201 -116(3) . .
C201 Cl22 Cl2A Cl21 63.3(17) . .
C200 Cl22 Cl2A Cl21 -52.5(18) . .
