#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/64/7026420.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7026420
loop_
_publ_author_name
'Zhang, Qian'
'He, Lisi'
'Liu, Jun-Min'
'Wang, Wei'
'Zhang, Jianyong'
'Su, Cheng-Yong'
_publ_section_title
;
 Pd2L2 metallacycles as molecular containers for small molecules.
;
_journal_issue                   46
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11171
_journal_page_last               11179
_journal_paper_doi               10.1039/c0dt00406e
_journal_volume                  39
_journal_year                    2010
_chemical_formula_sum            'C53.5 H55 Cl7 N8 Pd2'
_chemical_formula_weight         1271.01
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 109.4970(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   11.7450(5)
_cell_length_b                   19.4066(8)
_cell_length_c                   12.5835(5)
_cell_measurement_reflns_used    8301
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      25.045
_cell_measurement_theta_min      2.308
_cell_volume                     2703.70(19)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker SMART APEX CCD diffractometer'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0582
_diffrn_reflns_av_sigmaI/netI    0.0517
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            19000
_diffrn_reflns_theta_full        25.08
_diffrn_reflns_theta_max         25.08
_diffrn_reflns_theta_min         2.10
_exptl_absorpt_coefficient_mu    1.056
_exptl_absorpt_correction_T_max  0.9621
_exptl_absorpt_correction_T_min  0.7384
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS, Bruker, 1997)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.561
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1286
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.04
_refine_diff_density_max         1.537
_refine_diff_density_min         -1.099
_refine_diff_density_rms         0.123
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.020
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     320
_refine_ls_number_reflns         4775
_refine_ls_number_restraints     12
_refine_ls_restrained_S_all      1.032
_refine_ls_R_factor_all          0.0816
_refine_ls_R_factor_gt           0.0702
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0330P)²+28.1141P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1418
_refine_ls_wR_factor_ref         0.1485
_reflns_number_gt                4208
_reflns_number_total             4775
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c0dt00406e.txt
_cod_data_source_block           1
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_original_formula_sum        'C53.50 H55 Cl7 N8 Pd2'
_cod_database_code               7026420
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pd Pd 0.45608(4) 0.47573(3) 0.79615(4) 0.02523(17) Uani 1 1 d . . .
Cl1 Cl 0.60199(16) 0.55754(9) 0.81305(15) 0.0343(4) Uani 1 1 d . . .
Cl2 Cl 0.30884(16) 0.39202(10) 0.75331(17) 0.0399(5) Uani 1 1 d . . .
C1 C 0.2968(6) 0.5963(4) 0.6882(6) 0.0274(15) Uani 1 1 d . . .
H1 H 0.3394 0.6057 0.6375 0.033 Uiso 1 1 calc R . .
C2 C 0.1632(6) 0.6050(4) 0.7750(6) 0.0285(15) Uani 1 1 d . . .
C3 C 0.0680(6) 0.6220(4) 0.8133(6) 0.0333(17) Uani 1 1 d . . .
H3 H 0.0115 0.6572 0.7790 0.040 Uiso 1 1 calc R . .
C4 C 0.0613(7) 0.5845(4) 0.9036(6) 0.0356(17) Uani 1 1 d . . .
H4 H -0.0024 0.5940 0.9321 0.043 Uiso 1 1 calc R . .
C5 C 0.1432(6) 0.5338(4) 0.9544(6) 0.0343(17) Uani 1 1 d . . .
H5 H 0.1356 0.5104 1.0180 0.041 Uiso 1 1 calc R . .
C6 C 0.2358(6) 0.5158(4) 0.9159(6) 0.0328(16) Uani 1 1 d . . .
H6 H 0.2915 0.4804 0.9509 0.039 Uiso 1 1 calc R . .
C7 C 0.2443(6) 0.5520(4) 0.8228(6) 0.0278(15) Uani 1 1 d . . .
C8 C 0.1389(7) 0.6892(4) 0.6167(6) 0.0338(17) Uani 1 1 d . . .
H8A H 0.1717 0.7332 0.6544 0.041 Uiso 1 1 calc R . .
H8B H 0.0513 0.6881 0.6054 0.041 Uiso 1 1 calc R . .
C9 C 0.1566(6) 0.6867(4) 0.5028(6) 0.0266(15) Uani 1 1 d . . .
C10 C 0.0911(6) 0.6384(4) 0.4237(6) 0.0290(15) Uani 1 1 d . . .
C11 C 0.0966(6) 0.6395(4) 0.3139(6) 0.0296(16) Uani 1 1 d . . .
C12 C 0.1647(6) 0.6904(4) 0.2852(6) 0.0274(15) Uani 1 1 d . . .
C13 C 0.2364(6) 0.7367(4) 0.3666(6) 0.0311(16) Uani 1 1 d . . .
C14 C 0.2329(6) 0.7335(4) 0.4765(6) 0.0286(15) Uani 1 1 d . . .
C15 C 0.0139(7) 0.5842(4) 0.4537(7) 0.0423(19) Uani 1 1 d . . .
H15A H 0.0544 0.5394 0.4623 0.063 Uiso 1 1 calc R . .
H15B H -0.0646 0.5814 0.3935 0.063 Uiso 1 1 calc R . .
H15C H 0.0018 0.5968 0.5246 0.063 Uiso 1 1 calc R . .
C16 C 0.0303(7) 0.5846(4) 0.2323(7) 0.045(2) Uani 1 1 d . . .
H16A H 0.0575 0.5847 0.1667 0.068 Uiso 1 1 calc R . .
H16B H -0.0567 0.5938 0.2078 0.068 Uiso 1 1 calc R . .
H16C H 0.0469 0.5394 0.2693 0.068 Uiso 1 1 calc R . .
C17 C 0.3158(8) 0.7878(5) 0.3367(8) 0.052(2) Uani 1 1 d . . .
H17A H 0.2986 0.8341 0.3586 0.078 Uiso 1 1 calc R . .
H17B H 0.3004 0.7865 0.2553 0.078 Uiso 1 1 calc R . .
H17C H 0.4006 0.7764 0.3768 0.078 Uiso 1 1 calc R . .
C18 C 0.3107(7) 0.7829(5) 0.5639(8) 0.049(2) Uani 1 1 d . . .
H18A H 0.2685 0.8270 0.5583 0.074 Uiso 1 1 calc R . .
H18B H 0.3874 0.7901 0.5506 0.074 Uiso 1 1 calc R . .
H18C H 0.3265 0.7634 0.6393 0.074 Uiso 1 1 calc R . .
C19 C 0.1611(7) 0.6982(5) 0.1653(6) 0.0398(19) Uani 1 1 d . . .
H19A H 0.0874 0.6755 0.1148 0.048 Uiso 1 1 calc R . .
H19B H 0.1557 0.7478 0.1459 0.048 Uiso 1 1 calc R . .
C20 C 0.3348(6) 0.6148(4) 0.1993(6) 0.0282(15) Uani 1 1 d . . .
H20 H 0.3222 0.5914 0.2607 0.034 Uiso 1 1 calc R . .
C21 C 0.3124(6) 0.6889(4) 0.0609(5) 0.0256(14) Uani 1 1 d . . .
C22 C 0.2779(6) 0.7405(4) -0.0204(6) 0.0320(16) Uani 1 1 d . . .
H22 H 0.2126 0.7707 -0.0257 0.038 Uiso 1 1 calc R . .
C23 C 0.3428(7) 0.7455(4) -0.0926(6) 0.0326(16) Uani 1 1 d . . .
H23 H 0.3227 0.7804 -0.1488 0.039 Uiso 1 1 calc R . .
C24 C 0.4370(6) 0.7010(4) -0.0855(6) 0.0308(16) Uani 1 1 d . . .
H24 H 0.4788 0.7059 -0.1380 0.037 Uiso 1 1 calc R . .
C25 C 0.4725(6) 0.6500(4) -0.0053(6) 0.0293(16) Uani 1 1 d . . .
H25 H 0.5378 0.6199 -0.0009 0.035 Uiso 1 1 calc R . .
C26 C 0.4078(6) 0.6446(3) 0.0692(6) 0.0253(14) Uani 1 1 d . . .
N1 N 0.3278(5) 0.5466(3) 0.7658(5) 0.0302(13) Uani 1 1 d . . .
N2 N 0.1979(5) 0.6321(3) 0.6895(5) 0.0290(13) Uani 1 1 d . . .
N3 N 0.4213(5) 0.5979(3) 0.1569(5) 0.0291(13) Uani 1 1 d . . .
N4 N 0.2672(5) 0.6686(3) 0.1455(5) 0.0291(13) Uani 1 1 d . . .
C1A C 0.6584(10) 0.5702(6) 0.5238(13) 0.086(4) Uiso 0.38 1 d PDU A 1
H1A1 H 0.6929 0.5792 0.4633 0.104 Uiso 0.38 1 calc PR A 1
H1A2 H 0.7217 0.5802 0.5968 0.104 Uiso 0.38 1 calc PR A 1
Cl3A Cl 0.5351(6) 0.6266(4) 0.5064(6) 0.150(2) Uiso 0.38 1 d PDU A 1
Cl4A Cl 0.6198(8) 0.4858(5) 0.5202(8) 0.092(2) Uiso 0.38 1 d PDU A 1
C1B C 0.6584(10) 0.5702(6) 0.5238(13) 0.086(4) Uiso 0.38 1 d PDU B 2
H1B1 H 0.6356 0.5240 0.5430 0.104 Uiso 0.38 1 calc PR B 2
H1B2 H 0.6722 0.5663 0.4506 0.104 Uiso 0.38 1 calc PR B 2
Cl3B Cl 0.5351(6) 0.6266(4) 0.5064(6) 0.150(2) Uiso 0.38 1 d PDU B 2
Cl4B Cl 0.7856(7) 0.5926(4) 0.6199(7) 0.080(2) Uiso 0.38 1 d PDU B 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N3 Pd N1 172.9(2) 3_666 .
N3 Pd Cl1 91.48(18) 3_666 .
N1 Pd Cl1 91.95(18) . .
N3 Pd Cl2 88.56(18) 3_666 .
N1 Pd Cl2 88.92(18) . .
Cl1 Pd Cl2 171.93(7) . .
N1 C1 N2 112.7(6) . .
N1 C1 H1 123.7 . .
N2 C1 H1 123.7 . .
N2 C2 C7 106.3(6) . .
N2 C2 C3 131.3(6) . .
C7 C2 C3 122.4(7) . .
C4 C3 C2 115.7(7) . .
C4 C3 H3 122.1 . .
C2 C3 H3 122.1 . .
C3 C4 C5 122.7(7) . .
C3 C4 H4 118.7 . .
C5 C4 H4 118.7 . .
C6 C5 C4 122.0(7) . .
C6 C5 H5 119.0 . .
C4 C5 H5 119.0 . .
C5 C6 C7 117.0(7) . .
C5 C6 H6 121.5 . .
C7 C6 H6 121.5 . .
C2 C7 C6 120.2(6) . .
C2 C7 N1 109.2(6) . .
C6 C7 N1 130.6(6) . .
N2 C8 C9 112.5(6) . .
N2 C8 H8A 109.1 . .
C9 C8 H8A 109.1 . .
N2 C8 H8B 109.1 . .
C9 C8 H8B 109.1 . .
H8A C8 H8B 107.8 . .
C14 C9 C10 121.0(6) . .
C14 C9 C8 120.4(6) . .
C10 C9 C8 118.6(6) . .
C9 C10 C11 119.7(6) . .
C9 C10 C15 121.4(7) . .
C11 C10 C15 118.9(7) . .
C12 C11 C10 119.0(7) . .
C12 C11 C16 122.5(7) . .
C10 C11 C16 118.5(7) . .
C11 C12 C13 121.2(6) . .
C11 C12 C19 120.4(7) . .
C13 C12 C19 118.3(7) . .
C14 C13 C12 118.9(6) . .
C14 C13 C17 120.3(7) . .
C12 C13 C17 120.8(7) . .
C9 C14 C13 119.8(6) . .
C9 C14 C18 121.4(7) . .
C13 C14 C18 118.7(7) . .
C10 C15 H15A 109.5 . .
C10 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
C10 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
C11 C16 H16A 109.5 . .
C11 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C11 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C13 C17 H17A 109.5 . .
C13 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C13 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
C14 C18 H18A 109.5 . .
C14 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C14 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
N4 C19 C12 112.9(6) . .
N4 C19 H19A 109.0 . .
C12 C19 H19A 109.0 . .
N4 C19 H19B 109.0 . .
C12 C19 H19B 109.0 . .
H19A C19 H19B 107.8 . .
N3 C20 N4 112.8(6) . .
N3 C20 H20 123.6 . .
N4 C20 H20 123.6 . .
C26 C21 C22 122.1(6) . .
C26 C21 N4 105.7(6) . .
C22 C21 N4 132.3(6) . .
C23 C22 C21 116.6(7) . .
C23 C22 H22 121.7 . .
C21 C22 H22 121.7 . .
C22 C23 C24 121.6(7) . .
C22 C23 H23 119.2 . .
C24 C23 H23 119.2 . .
C25 C24 C23 122.4(7) . .
C25 C24 H24 118.8 . .
C23 C24 H24 118.8 . .
C24 C25 C26 116.6(6) . .
C24 C25 H25 121.7 . .
C26 C25 H25 121.7 . .
C21 C26 C25 120.7(6) . .
C21 C26 N3 109.7(6) . .
C25 C26 N3 129.5(6) . .
C1 N1 C7 104.8(5) . .
C1 N1 Pd 130.3(5) . .
C7 N1 Pd 124.8(5) . .
C1 N2 C2 107.0(6) . .
C1 N2 C8 127.6(6) . .
C2 N2 C8 125.4(6) . .
C20 N3 C26 104.8(5) . .
C20 N3 Pd 129.3(5) . 3_666
C26 N3 Pd 125.9(4) . 3_666
C20 N4 C21 106.9(5) . .
C20 N4 C19 127.5(6) . .
C21 N4 C19 125.5(6) . .
Cl4A C1A Cl3A 113.2(8) . .
Cl4A C1A H1A1 108.9 . .
Cl3A C1A H1A1 108.9 . .
Cl4A C1A H1A2 108.9 . .
Cl3A C1A H1A2 108.9 . .
H1A1 C1A H1A2 107.8 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pd N3 1.974(5) 3_666
Pd N1 1.981(5) .
Pd Cl1 2.2934(18) .
Pd Cl2 2.3016(19) .
C1 N1 1.334(9) .
C1 N2 1.358(8) .
C1 H1 0.9500 .
C2 N2 1.375(9) .
C2 C7 1.395(9) .
C2 C3 1.396(9) .
C3 C4 1.373(10) .
C3 H3 0.9500 .
C4 C5 1.377(10) .
C4 H4 0.9500 .
C5 C6 1.375(10) .
C5 H5 0.9500 .
C6 C7 1.397(10) .
C6 H6 0.9500 .
C7 N1 1.398(9) .
C8 N2 1.459(9) .
C8 C9 1.517(9) .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
C9 C14 1.392(10) .
C9 C10 1.396(10) .
C10 C11 1.405(10) .
C10 C15 1.517(10) .
C11 C12 1.393(10) .
C11 C16 1.504(10) .
C12 C13 1.411(10) .
C12 C19 1.502(10) .
C13 C14 1.398(10) .
C13 C17 1.493(10) .
C14 C18 1.513(10) .
C15 H15A 0.9800 .
C15 H15B 0.9800 .
C15 H15C 0.9800 .
C16 H16A 0.9800 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
C17 H17A 0.9800 .
C17 H17B 0.9800 .
C17 H17C 0.9800 .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
C19 N4 1.468(8) .
C19 H19A 0.9900 .
C19 H19B 0.9900 .
C20 N3 1.336(8) .
C20 N4 1.350(8) .
C20 H20 0.9500 .
C21 C26 1.388(9) .
C21 C22 1.391(9) .
C21 N4 1.396(8) .
C22 C23 1.370(10) .
C22 H22 0.9500 .
C23 C24 1.382(10) .
C23 H23 0.9500 .
C24 C25 1.376(10) .
C24 H24 0.9500 .
C25 C26 1.394(9) .
C25 H25 0.9500 .
C26 N3 1.396(9) .
N3 Pd 1.974(5) 3_666
C1A Cl4A 1.696(11) .
C1A Cl3A 1.769(10) .
C1A H1A1 0.9900 .
C1A H1A2 0.9900 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N2 C2 C3 C4 -178.8(7) . .
C7 C2 C3 C4 2.0(11) . .
C2 C3 C4 C5 0.5(11) . .
C3 C4 C5 C6 -1.8(12) . .
C4 C5 C6 C7 0.6(11) . .
N2 C2 C7 C6 177.4(6) . .
C3 C2 C7 C6 -3.2(10) . .
N2 C2 C7 N1 -0.4(8) . .
C3 C2 C7 N1 179.0(6) . .
C5 C6 C7 C2 1.8(10) . .
C5 C6 C7 N1 179.0(7) . .
N2 C8 C9 C14 -107.8(8) . .
N2 C8 C9 C10 74.8(8) . .
C14 C9 C10 C11 -3.8(10) . .
C8 C9 C10 C11 173.6(6) . .
C14 C9 C10 C15 176.1(6) . .
C8 C9 C10 C15 -6.5(10) . .
C9 C10 C11 C12 -2.0(10) . .
C15 C10 C11 C12 178.2(6) . .
C9 C10 C11 C16 176.9(6) . .
C15 C10 C11 C16 -3.0(10) . .
C10 C11 C12 C13 5.7(10) . .
C16 C11 C12 C13 -173.1(7) . .
C10 C11 C12 C19 -172.8(6) . .
C16 C11 C12 C19 8.4(10) . .
C11 C12 C13 C14 -3.7(10) . .
C19 C12 C13 C14 174.9(6) . .
C11 C12 C13 C17 175.6(7) . .
C19 C12 C13 C17 -5.9(10) . .
C10 C9 C14 C13 5.8(10) . .
C8 C9 C14 C13 -171.5(6) . .
C10 C9 C14 C18 -175.8(7) . .
C8 C9 C14 C18 6.8(10) . .
C12 C13 C14 C9 -2.1(10) . .
C17 C13 C14 C9 178.6(7) . .
C12 C13 C14 C18 179.5(6) . .
C17 C13 C14 C18 0.2(10) . .
C11 C12 C19 N4 -101.9(8) . .
C13 C12 C19 N4 79.6(9) . .
C26 C21 C22 C23 0.1(10) . .
N4 C21 C22 C23 -179.1(7) . .
C21 C22 C23 C24 0.7(11) . .
C22 C23 C24 C25 -1.0(11) . .
C23 C24 C25 C26 0.5(10) . .
C22 C21 C26 C25 -0.5(10) . .
N4 C21 C26 C25 178.8(6) . .
C22 C21 C26 N3 -179.4(6) . .
N4 C21 C26 N3 0.0(7) . .
C24 C25 C26 C21 0.3(10) . .
C24 C25 C26 N3 178.9(6) . .
N2 C1 N1 C7 -1.5(8) . .
N2 C1 N1 Pd 175.9(5) . .
C2 C7 N1 C1 1.1(8) . .
C6 C7 N1 C1 -176.4(7) . .
C2 C7 N1 Pd -176.5(5) . .
C6 C7 N1 Pd 6.0(11) . .
N3 Pd N1 C1 173.3(17) 3_666 .
Cl1 Pd N1 C1 54.5(6) . .
Cl2 Pd N1 C1 -117.4(6) . .
N3 Pd N1 C7 -10(2) 3_666 .
Cl1 Pd N1 C7 -128.5(5) . .
Cl2 Pd N1 C7 59.5(5) . .
N1 C1 N2 C2 1.3(8) . .
N1 C1 N2 C8 -179.7(7) . .
C7 C2 N2 C1 -0.5(7) . .
C3 C2 N2 C1 -179.8(7) . .
C7 C2 N2 C8 -179.6(6) . .
C3 C2 N2 C8 1.1(12) . .
C9 C8 N2 C1 27.4(10) . .
C9 C8 N2 C2 -153.7(6) . .
N4 C20 N3 C26 -0.1(8) . .
N4 C20 N3 Pd 179.9(5) . 3_666
C21 C26 N3 C20 0.1(7) . .
C25 C26 N3 C20 -178.7(7) . .
C21 C26 N3 Pd -179.9(5) . 3_666
C25 C26 N3 Pd 1.4(10) . 3_666
N3 C20 N4 C21 0.1(8) . .
N3 C20 N4 C19 176.3(7) . .
C26 C21 N4 C20 0.0(7) . .
C22 C21 N4 C20 179.3(7) . .
C26 C21 N4 C19 -176.4(7) . .
C22 C21 N4 C19 2.9(12) . .
C12 C19 N4 C20 29.8(11) . .
C12 C19 N4 C21 -154.6(7) . .
