#------------------------------------------------------------------------------
#$Date: 2016-03-25 16:26:56 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179970 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/64/7026446.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7026446
loop_
_publ_author_name
'Ishida, Shintaro'
'Ito, Masayasu'
'Horiuchi, Hiroaki'
'Hiratsuka, Hiroshi'
'Shiraishi, Soshi'
'Kyushin, Soichiro'
_publ_section_title
;
 Synthesis and properties of
 5,10,15,20-tetrakis[4-(alkoxysilyl)phenyl]porphyrins: an application of
 selective deprotection of benzaldehyde diethyl acetals in the presence of
 alkoxysilyl groups.
;
_journal_issue                   39
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9421
_journal_page_last               9426
_journal_paper_doi               10.1039/c0dt00427h
_journal_volume                  39
_journal_year                    2010
_chemical_formula_sum            'C64 H78 N4 O8 Si4'
_chemical_formula_weight         1143.66
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 109.8959(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   12.1499(9)
_cell_length_b                   15.7100(10)
_cell_length_c                   17.0267(13)
_cell_measurement_reflns_used    13666
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      27.8764
_cell_measurement_theta_min      6.4363
_cell_volume                     3056.0(4)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 0.976
_diffrn_measured_fraction_theta_max 0.976
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0300
_diffrn_reflns_av_sigmaI/netI    0.0431
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            16293
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         6.44
_exptl_absorpt_coefficient_mu    0.155
_exptl_absorpt_correction_T_max  0.9697
_exptl_absorpt_correction_T_min  0.9479
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   multi-scan
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.243
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       platelet
_exptl_crystal_F_000             1220
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.457
_refine_diff_density_min         -0.406
_refine_diff_density_rms         0.054
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.187
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     367
_refine_ls_number_reflns         5855
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.187
_refine_ls_R_factor_all          0.0624
_refine_ls_R_factor_gt           0.0607
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0210P)²+3.9496P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1208
_refine_ls_wR_factor_ref         0.1217
_reflns_number_gt                5738
_reflns_number_total             5855
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c0dt00427h.txt
_cod_data_source_block           it01a
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7026446
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
N1 N 0.44634(15) 0.06778(11) 0.38931(11) 0.0128(4) Uani 1 1 d .
H1 H 0.4687 0.0403 0.4372 0.015 Uiso 1 1 calc R
C1 C 0.35546(18) 0.12415(13) 0.36227(13) 0.0135(4) Uani 1 1 d .
C2 C 0.34811(19) 0.15584(14) 0.28085(14) 0.0158(4) Uani 1 1 d .
H2 H 0.2926 0.1955 0.2477 0.019 Uiso 1 1 calc R
C3 C 0.43554(19) 0.11812(14) 0.26077(14) 0.0157(4) Uani 1 1 d .
H3 H 0.4533 0.1272 0.2112 0.019 Uiso 1 1 calc R
C4 C 0.49640(18) 0.06170(13) 0.32842(13) 0.0138(4) Uani 1 1 d .
C5 C 0.58972(18) 0.00864(14) 0.32984(13) 0.0139(4) Uani 1 1 d .
C6 C 0.62938(18) 0.01263(14) 0.25564(14) 0.0149(4) Uani 1 1 d .
C7 C 0.56252(19) -0.02336(15) 0.18021(14) 0.0186(5) Uani 1 1 d .
H4 H 0.4908 -0.0507 0.1753 0.022 Uiso 1 1 calc R
C8 C 0.5999(2) -0.01960(15) 0.11160(14) 0.0195(5) Uani 1 1 d .
H5 H 0.5530 -0.0448 0.0604 0.023 Uiso 1 1 calc R
C9 C 0.70474(19) 0.02025(14) 0.11590(14) 0.0167(4) Uani 1 1 d .
C10 C 0.7709(2) 0.05665(15) 0.19253(15) 0.0195(5) Uani 1 1 d .
H6 H 0.8424 0.0845 0.1976 0.023 Uiso 1 1 calc R
C11 C 0.7341(2) 0.05287(15) 0.26129(15) 0.0189(5) Uani 1 1 d .
H7 H 0.7808 0.0779 0.3126 0.023 Uiso 1 1 calc R
Si1 Si 0.75439(5) 0.02537(4) 0.02363(4) 0.01768(16) Uani 1 1 d .
C12 C 0.7292(2) -0.07582(16) -0.03463(15) 0.0239(5) Uani 1 1 d .
H8 H 0.7483 -0.0687 -0.0857 0.036 Uiso 1 1 calc R
H9 H 0.6469 -0.0923 -0.0493 0.036 Uiso 1 1 calc R
H10 H 0.7791 -0.1202 0.0002 0.036 Uiso 1 1 calc R
O1 O 0.68035(15) 0.09678(11) -0.04372(10) 0.0236(4) Uani 1 1 d .
C13 C 0.6590(3) 0.18116(18) -0.02117(19) 0.0357(6) Uani 1 1 d .
H11 H 0.7275 0.2016 0.0257 0.043 Uiso 1 1 calc R
H12 H 0.5901 0.1813 -0.0026 0.043 Uiso 1 1 calc R
C14 C 0.6376(4) 0.2381(2) -0.0939(2) 0.0682(12) Uani 1 1 d .
H13 H 0.7079 0.2408 -0.1097 0.102 Uiso 1 1 calc R
H14 H 0.6186 0.2953 -0.0794 0.102 Uiso 1 1 calc R
H15 H 0.5720 0.2161 -0.1409 0.102 Uiso 1 1 calc R
O2 O 0.89227(14) 0.05128(11) 0.06196(11) 0.0256(4) Uani 1 1 d .
C15 C 0.9564(2) 0.10977(18) 0.02976(18) 0.0313(6) Uani 1 1 d .
H16 H 0.9025 0.1394 -0.0197 0.038 Uiso 1 1 calc R
H17 H 1.0152 0.0786 0.0124 0.038 Uiso 1 1 calc R
C16 C 1.0163(3) 0.1732(2) 0.0959(2) 0.0438(8) Uani 1 1 d .
H18 H 0.9577 0.2038 0.1129 0.066 Uiso 1 1 calc R
H19 H 1.0597 0.2138 0.0740 0.066 Uiso 1 1 calc R
H20 H 1.0707 0.1436 0.1443 0.066 Uiso 1 1 calc R
C17 C 0.64874(18) -0.04726(14) 0.39376(14) 0.0144(4) Uani 1 1 d .
C18 C 0.73952(19) -0.10516(15) 0.39131(14) 0.0185(5) Uani 1 1 d .
H21 H 0.7679 -0.1124 0.3462 0.022 Uiso 1 1 calc R
C19 C 0.77702(19) -0.14733(15) 0.46513(14) 0.0190(5) Uani 1 1 d .
H22 H 0.8370 -0.1892 0.4814 0.023 Uiso 1 1 calc R
C20 C 0.70934(18) -0.11707(14) 0.51449(14) 0.0146(4) Uani 1 1 d .
N2 N 0.63138(15) -0.05709(11) 0.46914(11) 0.0139(4) Uani 1 1 d .
C21 C 0.71974(18) -0.14690(13) 0.59422(13) 0.0139(4) Uani 1 1 d .
C22 C 0.81905(18) -0.20568(14) 0.63632(13) 0.0147(4) Uani 1 1 d .
C23 C 0.93402(19) -0.17650(15) 0.65806(15) 0.0194(5) Uani 1 1 d .
H23 H 0.9487 -0.1198 0.6448 0.023 Uiso 1 1 calc R
C24 C 1.0271(2) -0.22984(15) 0.69898(15) 0.0208(5) Uani 1 1 d .
H24 H 1.1048 -0.2090 0.7129 0.025 Uiso 1 1 calc R
C25 C 1.0091(2) -0.31349(14) 0.72019(14) 0.0182(5) Uani 1 1 d .
C26 C 0.8931(2) -0.34173(14) 0.69693(15) 0.0201(5) Uani 1 1 d .
H25 H 0.8779 -0.3985 0.7096 0.024 Uiso 1 1 calc R
C27 C 0.80002(19) -0.28886(14) 0.65579(15) 0.0181(5) Uani 1 1 d .
H26 H 0.7223 -0.3099 0.6408 0.022 Uiso 1 1 calc R
Si2 Si 1.13354(5) -0.38490(4) 0.77717(4) 0.01952(16) Uani 1 1 d .
C28 C 1.1791(2) -0.45530(17) 0.70744(17) 0.0304(6) Uani 1 1 d .
H27 H 1.2165 -0.4214 0.6752 0.046 Uiso 1 1 calc R
H28 H 1.1103 -0.4843 0.6692 0.046 Uiso 1 1 calc R
H29 H 1.2347 -0.4976 0.7408 0.046 Uiso 1 1 calc R
O3 O 1.23660(14) -0.31880(11) 0.82794(12) 0.0281(4) Uani 1 1 d .
C29 C 1.3578(2) -0.34056(18) 0.86790(19) 0.0312(6) Uani 1 1 d .
H30 H 1.3737 -0.3969 0.8480 0.037 Uiso 1 1 calc R
H31 H 1.3762 -0.3438 0.9291 0.037 Uiso 1 1 calc R
C30 C 1.4330(2) -0.2746(2) 0.8480(2) 0.0389(7) Uani 1 1 d .
H32 H 1.4207 -0.2758 0.7881 0.058 Uiso 1 1 calc R
H33 H 1.5154 -0.2864 0.8796 0.058 Uiso 1 1 calc R
H34 H 1.4122 -0.2182 0.8634 0.058 Uiso 1 1 calc R
O4 O 1.09334(16) -0.44849(11) 0.83867(11) 0.0267(4) Uani 1 1 d .
C31 C 1.0366(3) -0.42213(18) 0.89565(18) 0.0336(6) Uani 1 1 d .
H35 H 0.9841 -0.4682 0.9011 0.040 Uiso 1 1 calc R
H36 H 0.9878 -0.3715 0.8727 0.040 Uiso 1 1 calc R
C32 C 1.1211(3) -0.4013(3) 0.9796(2) 0.0499(9) Uani 1 1 d .
H37 H 1.1709 -0.4508 1.0020 0.075 Uiso 1 1 calc R
H38 H 1.0782 -0.3861 1.0170 0.075 Uiso 1 1 calc R
H39 H 1.1698 -0.3531 0.9750 0.075 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 N1 C4 107.79(17) . .
C1 N1 H1 126.1 . .
C4 N1 H1 126.1 . .
N1 C1 C21 125.67(19) . 3_656
N1 C1 C2 108.96(18) . .
C21 C1 C2 125.4(2) 3_656 .
C3 C2 C1 107.02(19) . .
C3 C2 H2 126.5 . .
C1 C2 H2 126.5 . .
C2 C3 C4 107.43(19) . .
C2 C3 H3 126.3 . .
C4 C3 H3 126.3 . .
N1 C4 C5 126.34(19) . .
N1 C4 C3 108.79(18) . .
C5 C4 C3 124.86(19) . .
C17 C5 C4 125.97(19) . .
C17 C5 C6 117.22(18) . .
C4 C5 C6 116.81(19) . .
C7 C6 C11 118.84(19) . .
C7 C6 C5 120.60(19) . .
C11 C6 C5 120.6(2) . .
C6 C7 C8 120.3(2) . .
C6 C7 H4 119.8 . .
C8 C7 H4 119.8 . .
C7 C8 C9 121.8(2) . .
C7 C8 H5 119.1 . .
C9 C8 H5 119.1 . .
C8 C9 C10 117.1(2) . .
C8 C9 Si1 121.64(17) . .
C10 C9 Si1 121.29(16) . .
C11 C10 C9 121.4(2) . .
C11 C10 H6 119.3 . .
C9 C10 H6 119.3 . .
C10 C11 C6 120.6(2) . .
C10 C11 H7 119.7 . .
C6 C11 H7 119.7 . .
O2 Si1 O1 110.75(9) . .
O2 Si1 C12 112.99(11) . .
O1 Si1 C12 105.25(11) . .
O2 Si1 C9 104.86(10) . .
O1 Si1 C9 111.17(9) . .
C12 Si1 C9 111.96(10) . .
Si1 C12 H8 109.5 . .
Si1 C12 H9 109.5 . .
H8 C12 H9 109.5 . .
Si1 C12 H10 109.5 . .
H8 C12 H10 109.5 . .
H9 C12 H10 109.5 . .
C13 O1 Si1 123.67(16) . .
O1 C13 C14 109.5(3) . .
O1 C13 H11 109.8 . .
C14 C13 H11 109.8 . .
O1 C13 H12 109.8 . .
C14 C13 H12 109.8 . .
H11 C13 H12 108.2 . .
C13 C14 H13 109.5 . .
C13 C14 H14 109.5 . .
H13 C14 H14 109.5 . .
C13 C14 H15 109.5 . .
H13 C14 H15 109.5 . .
H14 C14 H15 109.5 . .
C15 O2 Si1 128.87(17) . .
O2 C15 C16 109.2(2) . .
O2 C15 H16 109.8 . .
C16 C15 H16 109.8 . .
O2 C15 H17 109.8 . .
C16 C15 H17 109.8 . .
H16 C15 H17 108.3 . .
C15 C16 H18 109.5 . .
C15 C16 H19 109.5 . .
H18 C16 H19 109.5 . .
C15 C16 H20 109.5 . .
H18 C16 H20 109.5 . .
H19 C16 H20 109.5 . .
N2 C17 C5 126.66(19) . .
N2 C17 C18 108.51(19) . .
C5 C17 C18 124.83(19) . .
C19 C18 C17 107.50(19) . .
C19 C18 H21 126.2 . .
C17 C18 H21 126.2 . .
C18 C19 C20 107.52(19) . .
C18 C19 H22 126.2 . .
C20 C19 H22 126.2 . .
N2 C20 C21 126.33(19) . .
N2 C20 C19 108.64(19) . .
C21 C20 C19 125.0(2) . .
C20 N2 C17 107.81(17) . .
C20 C21 C1 124.5(2) . 3_656
C20 C21 C22 117.61(18) . .
C1 C21 C22 117.92(19) 3_656 .
C27 C22 C23 118.7(2) . .
C27 C22 C21 121.59(19) . .
C23 C22 C21 119.75(19) . .
C24 C23 C22 120.4(2) . .
C24 C23 H23 119.8 . .
C22 C23 H23 119.8 . .
C23 C24 C25 121.6(2) . .
C23 C24 H24 119.2 . .
C25 C24 H24 119.2 . .
C26 C25 C24 117.1(2) . .
C26 C25 Si2 121.04(17) . .
C24 C25 Si2 121.86(17) . .
C27 C26 C25 121.5(2) . .
C27 C26 H25 119.2 . .
C25 C26 H25 119.2 . .
C26 C27 C22 120.8(2) . .
C26 C27 H26 119.6 . .
C22 C27 H26 119.6 . .
O3 Si2 O4 113.08(10) . .
O3 Si2 C28 112.32(12) . .
O4 Si2 C28 105.46(11) . .
O3 Si2 C25 103.47(10) . .
O4 Si2 C25 109.50(10) . .
C28 Si2 C25 113.20(11) . .
Si2 C28 H27 109.5 . .
Si2 C28 H28 109.5 . .
H27 C28 H28 109.5 . .
Si2 C28 H29 109.5 . .
H27 C28 H29 109.5 . .
H28 C28 H29 109.5 . .
C29 O3 Si2 125.30(16) . .
O3 C29 C30 109.6(2) . .
O3 C29 H30 109.8 . .
C30 C29 H30 109.8 . .
O3 C29 H31 109.8 . .
C30 C29 H31 109.8 . .
H30 C29 H31 108.2 . .
C29 C30 H32 109.5 . .
C29 C30 H33 109.5 . .
H32 C30 H33 109.5 . .
C29 C30 H34 109.5 . .
H32 C30 H34 109.5 . .
H33 C30 H34 109.5 . .
C31 O4 Si2 125.10(16) . .
O4 C31 C32 112.4(2) . .
O4 C31 H35 109.1 . .
C32 C31 H35 109.1 . .
O4 C31 H36 109.1 . .
C32 C31 H36 109.1 . .
H35 C31 H36 107.8 . .
C31 C32 H37 109.5 . .
C31 C32 H38 109.5 . .
H37 C32 H38 109.5 . .
C31 C32 H39 109.5 . .
H37 C32 H39 109.5 . .
H38 C32 H39 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
N1 C1 1.367(3) .
N1 C4 1.372(3) .
N1 H1 0.8800 .
C1 C21 1.404(3) 3_656
C1 C2 1.447(3) .
C2 C3 1.358(3) .
C2 H2 0.9500 .
C3 C4 1.442(3) .
C3 H3 0.9500 .
C4 C5 1.401(3) .
C5 C17 1.392(3) .
C5 C6 1.499(3) .
C6 C7 1.385(3) .
C6 C11 1.395(3) .
C7 C8 1.391(3) .
C7 H4 0.9500 .
C8 C9 1.399(3) .
C8 H5 0.9500 .
C9 C10 1.400(3) .
C9 Si1 1.866(2) .
C10 C11 1.389(3) .
C10 H6 0.9500 .
C11 H7 0.9500 .
Si1 O2 1.6291(17) .
Si1 O1 1.6373(18) .
Si1 C12 1.843(3) .
C12 H8 0.9800 .
C12 H9 0.9800 .
C12 H10 0.9800 .
O1 C13 1.428(3) .
C13 C14 1.478(5) .
C13 H11 0.9900 .
C13 H12 0.9900 .
C14 H13 0.9800 .
C14 H14 0.9800 .
C14 H15 0.9800 .
O2 C15 1.430(3) .
C15 C16 1.495(4) .
C15 H16 0.9900 .
C15 H17 0.9900 .
C16 H18 0.9800 .
C16 H19 0.9800 .
C16 H20 0.9800 .
C17 N2 1.378(3) .
C17 C18 1.441(3) .
C18 C19 1.355(3) .
C18 H21 0.9500 .
C19 C20 1.442(3) .
C19 H22 0.9500 .
C20 N2 1.372(3) .
C20 C21 1.401(3) .
C21 C1 1.404(3) 3_656
C21 C22 1.495(3) .
C22 C27 1.387(3) .
C22 C23 1.395(3) .
C23 C24 1.390(3) .
C23 H23 0.9500 .
C24 C25 1.400(3) .
C24 H24 0.9500 .
C25 C26 1.399(3) .
C25 Si2 1.868(2) .
C26 C27 1.386(3) .
C26 H25 0.9500 .
C27 H26 0.9500 .
Si2 O3 1.6299(19) .
Si2 O4 1.6374(18) .
Si2 C28 1.840(3) .
C28 H27 0.9800 .
C28 H28 0.9800 .
C28 H29 0.9800 .
O3 C29 1.438(3) .
C29 C30 1.495(4) .
C29 H30 0.9900 .
C29 H31 0.9900 .
C30 H32 0.9800 .
C30 H33 0.9800 .
C30 H34 0.9800 .
O4 C31 1.430(3) .
C31 C32 1.485(4) .
C31 H35 0.9900 .
C31 H36 0.9900 .
C32 H37 0.9800 .
C32 H38 0.9800 .
C32 H39 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C4 N1 C1 C21 178.7(2) . 3_656
C4 N1 C1 C2 -0.5(2) . .
N1 C1 C2 C3 -0.4(2) . .
C21 C1 C2 C3 -179.6(2) 3_656 .
C1 C2 C3 C4 1.1(2) . .
C1 N1 C4 C5 -177.7(2) . .
C1 N1 C4 C3 1.2(2) . .
C2 C3 C4 N1 -1.4(2) . .
C2 C3 C4 C5 177.5(2) . .
N1 C4 C5 C17 -0.3(4) . .
C3 C4 C5 C17 -179.0(2) . .
N1 C4 C5 C6 179.69(19) . .
C3 C4 C5 C6 1.0(3) . .
C17 C5 C6 C7 106.5(2) . .
C4 C5 C6 C7 -73.5(3) . .
C17 C5 C6 C11 -73.6(3) . .
C4 C5 C6 C11 106.4(2) . .
C11 C6 C7 C8 0.3(3) . .
C5 C6 C7 C8 -179.9(2) . .
C6 C7 C8 C9 -0.2(4) . .
C7 C8 C9 C10 -0.1(3) . .
C7 C8 C9 Si1 -179.85(18) . .
C8 C9 C10 C11 0.3(3) . .
Si1 C9 C10 C11 -179.95(18) . .
C9 C10 C11 C6 -0.2(3) . .
C7 C6 C11 C10 -0.1(3) . .
C5 C6 C11 C10 -179.9(2) . .
C8 C9 Si1 O2 -164.33(18) . .
C10 C9 Si1 O2 16.0(2) . .
C8 C9 Si1 O1 75.9(2) . .
C10 C9 Si1 O1 -103.75(19) . .
C8 C9 Si1 C12 -41.5(2) . .
C10 C9 Si1 C12 138.84(19) . .
O2 Si1 O1 C13 -68.9(2) . .
C12 Si1 O1 C13 168.7(2) . .
C9 Si1 O1 C13 47.3(2) . .
Si1 O1 C13 C14 155.8(3) . .
O1 Si1 O2 C15 -18.6(2) . .
C12 Si1 O2 C15 99.2(2) . .
C9 Si1 O2 C15 -138.6(2) . .
Si1 O2 C15 C16 126.0(2) . .
C4 C5 C17 N2 -4.2(4) . .
C6 C5 C17 N2 175.8(2) . .
C4 C5 C17 C18 175.8(2) . .
C6 C5 C17 C18 -4.2(3) . .
N2 C17 C18 C19 -1.3(3) . .
C5 C17 C18 C19 178.7(2) . .
C17 C18 C19 C20 0.6(3) . .
C18 C19 C20 N2 0.3(3) . .
C18 C19 C20 C21 178.2(2) . .
C21 C20 N2 C17 -178.9(2) . .
C19 C20 N2 C17 -1.1(2) . .
C5 C17 N2 C20 -178.6(2) . .
C18 C17 N2 C20 1.4(2) . .
N2 C20 C21 C1 5.2(4) . 3_656
C19 C20 C21 C1 -172.3(2) . 3_656
N2 C20 C21 C22 -173.6(2) . .
C19 C20 C21 C22 8.8(3) . .
C20 C21 C22 C27 -116.5(2) . .
C1 C21 C22 C27 64.6(3) 3_656 .
C20 C21 C22 C23 64.5(3) . .
C1 C21 C22 C23 -114.4(2) 3_656 .
C27 C22 C23 C24 -0.5(3) . .
C21 C22 C23 C24 178.5(2) . .
C22 C23 C24 C25 -0.5(4) . .
C23 C24 C25 C26 1.2(3) . .
C23 C24 C25 Si2 -178.68(19) . .
C24 C25 C26 C27 -0.9(3) . .
Si2 C25 C26 C27 178.97(18) . .
C25 C26 C27 C22 -0.1(4) . .
C23 C22 C27 C26 0.8(3) . .
C21 C22 C27 C26 -178.2(2) . .
C26 C25 Si2 O3 -154.10(19) . .
C24 C25 Si2 O3 25.8(2) . .
C26 C25 Si2 O4 -33.3(2) . .
C24 C25 Si2 O4 146.62(19) . .
C26 C25 Si2 C28 84.1(2) . .
C24 C25 Si2 C28 -96.0(2) . .
O4 Si2 O3 C29 75.0(2) . .
C28 Si2 O3 C29 -44.2(2) . .
C25 Si2 O3 C29 -166.6(2) . .
Si2 O3 C29 C30 135.3(2) . .
O3 Si2 O4 C31 65.8(2) . .
C28 Si2 O4 C31 -171.1(2) . .
C25 Si2 O4 C31 -49.0(2) . .
Si2 O4 C31 C32 -90.2(3) . .
