#------------------------------------------------------------------------------
#$Date: 2016-03-25 16:28:01 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179971 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/65/7026516.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7026516
loop_
_publ_author_name
'Ali, Shoaib'
'Muryn, Christopher A.'
'Tuna, Floriana'
'Winpenny, Richard E. P.'
_publ_section_title
;
 Synthesis and structural and magnetic characterisation of cobalt(ii)
 complexes of mixed phosphonate-antimonate ligands.
;
_journal_issue                   40
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9588
_journal_page_last               9597
_journal_paper_doi               10.1039/c0dt00482k
_journal_volume                  39
_journal_year                    2010
_chemical_formula_sum            'C94 H82 Cl5 Co4 N8 O27 P6 Sb5'
_chemical_formula_weight         2963.22
_chemical_name_systematic
;
?
;
_space_group_IT_number           96
_symmetry_cell_setting           tetragonal
_symmetry_space_group_name_Hall  'P 4nw 2abw'
_symmetry_space_group_name_H-M   'P 43 21 2'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.8698(7)
_cell_length_b                   16.8698(7)
_cell_length_c                   40.0183(12)
_cell_measurement_reflns_used    22749
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      27.5902
_cell_measurement_theta_min      2.7133
_cell_volume                     11388.8(8)
_computing_cell_refinement
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.4 (release 27-04-2006 CrysAlis171 .NET)
(compiled Apr 27 2007,17:53:11)
;
_computing_data_collection
;
CrysAlis CCD, Oxford Diffraction Ltd.,
Version 1.171.32.4 (release 27-04-2006 CrysAlis171 .NET)
(compiled Apr 27 2007,17:53:11)
;
_computing_data_reduction
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.4 (release 27-04-2006 CrysAlis171 .NET)
(compiled Apr 27 2007,17:53:11)
;
_computing_molecular_graphics    'SHELXL-97 (Sheldrick, 1997)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 8.3367
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Oxford Diffraction XCalibur 2'
_diffrn_measurement_method       'phi and omega'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1096
_diffrn_reflns_av_sigmaI/netI    0.0428
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       49
_diffrn_reflns_limit_l_min       -49
_diffrn_reflns_number            102156
_diffrn_reflns_theta_full        26.43
_diffrn_reflns_theta_max         26.43
_diffrn_reflns_theta_min         2.70
_exptl_absorpt_coefficient_mu    2.007
_exptl_absorpt_correction_T_max  0.6896
_exptl_absorpt_correction_T_min  0.5006
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.32.4 (release 27-04-2006 CrysAlis171 .NET)
(compiled Apr 27 2007,17:53:11)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.728
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             5824
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.20
_refine_diff_density_max         3.875
_refine_diff_density_min         -2.077
_refine_diff_density_rms         0.274
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.13(5)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.292
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     655
_refine_ls_number_reflns         11687
_refine_ls_number_restraints     339
_refine_ls_restrained_S_all      1.273
_refine_ls_R_factor_all          0.1087
_refine_ls_R_factor_gt           0.1080
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0000P)²+454.8685P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2119
_refine_ls_wR_factor_ref         0.2123
_reflns_number_gt                11544
_reflns_number_total             11687
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c0dt00482k.txt
_cod_data_source_block           orepw844p43212
_cod_database_code               7026516
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y+1/2, x+1/2, z+3/4'
'-x, -y, z+1/2'
'y+1/2, -x+1/2, z+1/4'
'x+1/2, -y+1/2, -z+1/4'
'y, x, -z'
'-x+1/2, y+1/2, -z+3/4'
'-y, -x, -z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Sb1 Sb 0.14947(6) 0.12639(5) 0.21599(2) 0.0110(2) Uani 1 1 d .
Sb2 Sb 0.14943(6) 0.11676(5) 0.29078(2) 0.0121(2) Uani 1 1 d .
Sb3 Sb 0.00650(5) -0.00650(5) 0.2500 0.0098(2) Uani 1 2 d S
P1 P 0.2622(2) -0.0087(2) 0.18411(9) 0.0154(8) Uani 1 1 d .
P2 P 0.2622(2) -0.0278(2) 0.31713(9) 0.0155(8) Uani 1 1 d .
P3 P 0.2874(2) 0.2151(2) 0.25546(9) 0.0172(8) Uani 1 1 d .
Co1 Co 0.08818(12) -0.08189(12) 0.19325(4) 0.0119(4) Uani 1 1 d .
Co2 Co 0.34199(12) 0.04310(12) 0.25148(5) 0.0177(4) Uani 1 1 d .
N1 N 0.0541(8) -0.0517(8) 0.1443(3) 0.017(2) Uani 1 1 d .
N2 N 0.0588(16) 0.178(2) 0.0478(8) 0.102(11) Uani 1 1 d .
N3 N 0.3196(11) 0.2737(17) 0.1096(4) 0.071(8) Uani 1 1 d .
N4 N 0.4661(7) 0.0246(8) 0.2520(3) 0.020(3) Uani 1 1 d .
C1 C 0.1033(12) 0.1992(11) 0.1787(4) 0.0291(16) Uani 1 1 d U
C2 C 0.1541(12) 0.2191(11) 0.1516(4) 0.0293(16) Uani 1 1 d U
H2 H 0.2051 0.1957 0.1498 0.035 Uiso 1 1 calc R
C3 C 0.1279(12) 0.2737(11) 0.1274(4) 0.0294(16) Uani 1 1 d U
H3 H 0.1602 0.2852 0.1086 0.035 Uiso 1 1 calc R
C4 C 0.0565(12) 0.3098(11) 0.1310(4) 0.0294(16) Uani 1 1 d U
C5 C 0.0068(12) 0.2893(11) 0.1578(4) 0.0294(16) Uani 1 1 d U
H5 H -0.0444 0.3123 0.1594 0.035 Uiso 1 1 calc R
C6 C 0.0319(12) 0.2356(11) 0.1818(4) 0.0292(16) Uani 1 1 d U
H6 H -0.0010 0.2243 0.2005 0.035 Uiso 1 1 calc R
C7 C 0.0965(7) 0.1739(7) 0.33122(18) 0.0261(16) Uani 1 1 d GU
C8 C 0.0298(7) 0.2205(7) 0.32586(16) 0.0263(16) Uani 1 1 d GU
H8 H 0.0103 0.2282 0.3038 0.032 Uiso 1 1 calc R
C9 C -0.0085(6) 0.2559(7) 0.3527(2) 0.0265(16) Uani 1 1 d GU
H9 H -0.0542 0.2878 0.3491 0.032 Uiso 1 1 calc R
C10 C 0.0199(7) 0.2447(7) 0.38500(18) 0.0265(16) Uani 1 1 d GU
C11 C 0.0867(7) 0.1981(7) 0.39037(16) 0.0263(16) Uani 1 1 d GU
H11 H 0.1061 0.1905 0.4124 0.032 Uiso 1 1 calc R
C12 C 0.1250(6) 0.1627(7) 0.3635(2) 0.0262(16) Uani 1 1 d GU
H12 H 0.1706 0.1309 0.3671 0.031 Uiso 1 1 calc R
C13 C -0.0817(9) 0.0817(9) 0.2500 0.029(2) Uani 1 2 d SU
C14 C -0.1140(11) 0.1080(11) 0.2194(4) 0.029(2) Uani 1 1 d U
H14 H -0.0961 0.0854 0.1990 0.035 Uiso 1 1 calc R
C15 C -0.1708(11) 0.1659(11) 0.2190(4) 0.029(2) Uani 1 1 d U
H15 H -0.1918 0.1844 0.1984 0.035 Uiso 1 1 calc R
C16 C -0.1983(10) 0.1983(10) 0.2500 0.030(2) Uani 1 2 d SU
C17 C 0.2943(11) -0.0251(12) 0.1419(4) 0.0295(17) Uani 1 1 d U
C18 C 0.3404(12) 0.0299(12) 0.1252(4) 0.0297(17) Uani 1 1 d U
H18 H 0.3586 0.0760 0.1365 0.036 Uiso 1 1 calc R
C19 C 0.3602(11) 0.0177(12) 0.0920(4) 0.0299(17) Uani 1 1 d U
H19 H 0.3940 0.0544 0.0810 0.036 Uiso 1 1 calc R
C20 C 0.3321(11) -0.0453(11) 0.0750(4) 0.0299(17) Uani 1 1 d U
H20 H 0.3454 -0.0512 0.0521 0.036 Uiso 1 1 calc R
C21 C 0.2862(11) -0.0996(12) 0.0896(4) 0.0297(17) Uani 1 1 d U
H21 H 0.2660 -0.1432 0.0772 0.036 Uiso 1 1 calc R
C22 C 0.2684(11) -0.0906(12) 0.1240(4) 0.0296(17) Uani 1 1 d U
H22 H 0.2381 -0.1302 0.1350 0.036 Uiso 1 1 calc R
C23 C 0.3072(11) -0.0423(12) 0.3579(4) 0.0282(16) Uani 1 1 d U
C24 C 0.3022(11) -0.1179(12) 0.3732(4) 0.0282(16) Uani 1 1 d U
H24 H 0.2784 -0.1610 0.3617 0.034 Uiso 1 1 calc R
C25 C 0.3328(10) -0.1284(11) 0.4055(4) 0.0283(16) Uani 1 1 d U
H25 H 0.3269 -0.1775 0.4168 0.034 Uiso 1 1 calc R
C26 C 0.3718(11) -0.0654(11) 0.4206(4) 0.0283(16) Uani 1 1 d U
H26 H 0.3931 -0.0722 0.4424 0.034 Uiso 1 1 calc R
C27 C 0.3805(11) 0.0059(11) 0.4051(4) 0.0284(16) Uani 1 1 d U
H27 H 0.4090 0.0476 0.4155 0.034 Uiso 1 1 calc R
C28 C 0.3464(11) 0.0170(11) 0.3730(4) 0.0283(16) Uani 1 1 d U
H28 H 0.3513 0.0669 0.3622 0.034 Uiso 1 1 calc R
C29 C 0.3200(15) 0.3153(12) 0.2561(5) 0.048(2) Uani 1 1 d U
C30 C 0.3975(14) 0.3378(11) 0.2508(5) 0.048(2) Uani 1 1 d U
H30 H 0.4375 0.2986 0.2484 0.057 Uiso 1 1 calc R
C31 C 0.4175(15) 0.4184(12) 0.2491(5) 0.048(2) Uani 1 1 d U
H31 H 0.4712 0.4339 0.2461 0.057 Uiso 1 1 calc R
C32 C 0.3596(14) 0.4744(12) 0.2518(5) 0.048(2) Uani 1 1 d U
H32 H 0.3732 0.5290 0.2507 0.057 Uiso 1 1 calc R
C33 C 0.2810(15) 0.4525(12) 0.2562(5) 0.048(2) Uani 1 1 d U
H33 H 0.2405 0.4916 0.2571 0.057 Uiso 1 1 calc R
C34 C 0.2629(16) 0.3759(12) 0.2591(5) 0.048(2) Uani 1 1 d U
H34 H 0.2094 0.3616 0.2634 0.057 Uiso 1 1 calc R
C35 C 0.0133(12) 0.0166(12) 0.1393(4) 0.0347(19) Uani 1 1 d U
H35 H 0.0051 0.0511 0.1577 0.042 Uiso 1 1 calc R
C36 C -0.0163(12) 0.0375(12) 0.1088(4) 0.0349(19) Uani 1 1 d U
H36 H -0.0426 0.0867 0.1057 0.042 Uiso 1 1 calc R
C37 C -0.0072(12) -0.0142(11) 0.0828(4) 0.0350(19) Uani 1 1 d U
H37 H -0.0291 -0.0024 0.0615 0.042 Uiso 1 1 calc R
C38 C 0.0344(12) -0.0844(12) 0.0878(5) 0.0348(19) Uani 1 1 d U
H38 H 0.0428 -0.1208 0.0700 0.042 Uiso 1 1 calc R
C39 C 0.0622(12) -0.0990(12) 0.1186(4) 0.0347(19) Uani 1 1 d U
H39 H 0.0900 -0.1473 0.1220 0.042 Uiso 1 1 calc R
C40 C 0.5017(12) -0.0323(13) 0.2714(5) 0.035(2) Uani 1 1 d U
H40 H 0.4685 -0.0641 0.2851 0.042 Uiso 1 1 calc R
C41 C 0.5836(12) -0.0468(13) 0.2725(5) 0.035(2) Uani 1 1 d U
H41 H 0.6058 -0.0868 0.2863 0.042 Uiso 1 1 calc R
C42 C 0.6301(11) 0.0008(12) 0.2522(5) 0.035(2) Uani 1 1 d U
H42 H 0.6861 -0.0053 0.2521 0.042 Uiso 1 1 calc R
C43 C 0.5952(12) 0.0564(13) 0.2322(5) 0.035(2) Uani 1 1 d U
H43 H 0.6258 0.0864 0.2168 0.042 Uiso 1 1 calc R
C44 C 0.5136(12) 0.0680(13) 0.2350(5) 0.035(2) Uani 1 1 d U
H44 H 0.4914 0.1118 0.2234 0.042 Uiso 1 1 calc R
C45 C 0.3699(14) 0.2768(18) 0.1709(5) 0.060(5) Uani 1 1 d U
H45A H 0.3319 0.2478 0.1848 0.091 Uiso 1 1 calc R
H45B H 0.3741 0.3316 0.1788 0.091 Uiso 1 1 calc R
H45C H 0.4219 0.2511 0.1723 0.091 Uiso 1 1 calc R
C46 C 0.3429(15) 0.2765(18) 0.1364(5) 0.060(5) Uani 1 1 d U
C47 C 0.1798(18) 0.103(2) 0.0711(9) 0.084(7) Uani 1 1 d U
H47A H 0.1988 0.0674 0.0533 0.126 Uiso 1 1 calc R
H47B H 0.1662 0.0710 0.0909 0.126 Uiso 1 1 calc R
H47C H 0.2215 0.1406 0.0769 0.126 Uiso 1 1 calc R
C48 C 0.1122(18) 0.144(2) 0.0600(9) 0.084(7) Uani 1 1 d U
O1 O 0.2063(6) -0.0746(6) 0.1934(3) 0.016(2) Uani 1 1 d .
O2 O 0.2204(7) 0.0738(7) 0.1820(2) 0.019(2) Uani 1 1 d .
O3 O 0.3347(6) -0.0041(7) 0.2065(3) 0.018(2) Uani 1 1 d .
O4 O 0.3575(6) 0.1599(6) 0.2536(3) 0.023(2) Uani 1 1 d .
O5 O 0.2369(6) 0.2101(6) 0.2233(2) 0.015(2) Uani 1 1 d .
O6 O 0.2361(6) 0.2041(6) 0.2873(2) 0.018(2) Uani 1 1 d .
O7 O 0.0712(6) 0.0394(6) 0.2128(2) 0.016(2) Uani 1 1 d .
O8 O 0.2071(6) 0.0687(5) 0.2522(3) 0.0132(19) Uiso 1 1 d .
O9 O 0.0916(6) 0.1712(6) 0.2548(2) 0.016(2) Uani 1 1 d .
O10 O 0.0701(6) 0.0298(6) 0.2892(2) 0.010(2) Uani 1 1 d .
O11 O 0.3264(7) -0.0241(7) 0.2914(3) 0.022(3) Uani 1 1 d .
O12 O 0.2216(6) 0.0551(6) 0.3216(3) 0.017(2) Uiso 1 1 d .
O13 O 0.2025(7) -0.0920(7) 0.3116(3) 0.025(3) Uani 1 1 d .
O14 O 0.0931(6) -0.0931(6) 0.2500 0.019(3) Uani 1 2 d S
Cl1 Cl 0.0263(3) 0.3809(4) 0.10234(15) 0.0550(16) Uani 1 1 d .
Cl2 Cl -0.2698(3) 0.2698(3) 0.2500 0.095(4) Uani 1 2 d S
Cl3 Cl -0.0295(5) 0.2877(5) 0.41831(14) 0.068(2) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O7 Sb1 O9 90.2(4) . .
O7 Sb1 O8 90.6(4) . .
O9 Sb1 O8 81.8(4) . .
O7 Sb1 O2 91.5(4) . .
O9 Sb1 O2 170.8(4) . .
O8 Sb1 O2 89.2(4) . .
O7 Sb1 O5 173.8(4) . .
O9 Sb1 O5 88.8(4) . .
O8 Sb1 O5 83.2(4) . .
O2 Sb1 O5 88.5(4) . .
O7 Sb1 C1 98.1(6) . .
O9 Sb1 C1 98.8(6) . .
O8 Sb1 C1 171.3(6) . .
O2 Sb1 C1 89.9(6) . .
O5 Sb1 C1 88.0(6) . .
O7 Sb1 Sb2 91.4(3) . .
O9 Sb1 Sb2 40.4(3) . .
O8 Sb1 Sb2 41.4(3) . .
O2 Sb1 Sb2 130.5(3) . .
O5 Sb1 Sb2 84.0(3) . .
C1 Sb1 Sb2 138.3(5) . .
O9 Sb2 O10 89.3(4) . .
O9 Sb2 O8 82.3(4) . .
O10 Sb2 O8 90.2(4) . .
O9 Sb2 O12 170.3(4) . .
O10 Sb2 O12 92.6(4) . .
O8 Sb2 O12 88.2(4) . .
O9 Sb2 O6 88.3(4) . .
O10 Sb2 O6 173.9(4) . .
O8 Sb2 O6 83.9(4) . .
O12 Sb2 O6 88.9(4) . .
O9 Sb2 C7 98.1(4) . .
O10 Sb2 C7 94.4(4) . .
O8 Sb2 C7 175.3(5) . .
O12 Sb2 C7 91.3(4) . .
O6 Sb2 C7 91.4(4) . .
O9 Sb2 Sb1 40.9(3) . .
O10 Sb2 Sb1 90.5(3) . .
O8 Sb2 Sb1 41.4(3) . .
O12 Sb2 Sb1 129.5(3) . .
O6 Sb2 Sb1 84.0(3) . .
C7 Sb2 Sb1 138.6(3) . .
O10 Sb3 O10 161.2(6) . 8
O10 Sb3 O7 99.9(4) . .
O10 Sb3 O7 77.9(4) 8 .
O10 Sb3 O7 77.9(4) . 8
O10 Sb3 O7 99.9(4) 8 8
O7 Sb3 O7 167.2(7) . 8
O10 Sb3 O14 80.6(3) . .
O10 Sb3 O14 80.6(3) 8 .
O7 Sb3 O14 83.6(3) . .
O7 Sb3 O14 83.6(3) 8 .
O10 Sb3 C13 99.4(3) . .
O10 Sb3 C13 99.4(3) 8 .
O7 Sb3 C13 96.4(3) . .
O7 Sb3 C13 96.4(3) 8 .
O14 Sb3 C13 180.000(1) . .
O10 Sb3 Co1 46.0(3) . 8
O10 Sb3 Co1 119.1(3) 8 8
O7 Sb3 Co1 121.3(3) . 8
O7 Sb3 Co1 48.6(3) 8 8
O14 Sb3 Co1 50.50(4) . 8
C13 Sb3 Co1 129.50(4) . 8
O10 Sb3 Co1 119.1(3) . .
O10 Sb3 Co1 46.0(3) 8 .
O7 Sb3 Co1 48.6(3) . .
O7 Sb3 Co1 121.3(3) 8 .
O14 Sb3 Co1 50.49(4) . .
C13 Sb3 Co1 129.51(4) . .
Co1 Sb3 Co1 100.99(8) 8 .
O1 P1 O3 113.4(6) . .
O1 P1 O2 112.8(6) . .
O3 P1 O2 110.4(6) . .
O1 P1 C17 107.9(8) . .
O3 P1 C17 108.7(8) . .
O2 P1 C17 102.9(8) . .
O11 P2 O13 114.6(7) . .
O11 P2 O12 110.9(7) . .
O13 P2 O12 111.6(7) . .
O11 P2 C23 108.7(8) . .
O13 P2 C23 108.5(8) . .
O12 P2 C23 101.6(7) . .
O4 P3 O5 111.0(6) . .
O4 P3 O6 113.8(6) . .
O5 P3 O6 111.7(6) . .
O4 P3 C29 110.2(10) . .
O5 P3 C29 103.5(8) . .
O6 P3 C29 106.0(8) . .
O1 Co1 O13 91.7(4) . 8
O1 Co1 N1 105.1(5) . .
O13 Co1 N1 99.3(5) 8 .
O1 Co1 O10 158.6(4) . 8
O13 Co1 O10 98.9(4) 8 8
N1 Co1 O10 91.6(4) . 8
O1 Co1 O7 94.1(4) . .
O13 Co1 O7 163.6(4) 8 .
N1 Co1 O7 94.0(4) . .
O10 Co1 O7 71.0(3) 8 .
O1 Co1 O14 88.1(4) . .
O13 Co1 O14 90.6(4) 8 .
N1 Co1 O14 163.2(5) . .
O10 Co1 O14 73.3(4) 8 .
O7 Co1 O14 74.3(4) . .
O1 Co1 Sb3 116.0(3) . .
O13 Co1 Sb3 121.2(3) 8 .
N1 Co1 Sb3 119.1(3) . .
O10 Co1 Sb3 42.7(3) 8 .
O7 Co1 Sb3 42.8(2) . .
O14 Co1 Sb3 44.4(3) . .
O3 Co2 O11 119.9(5) . .
O3 Co2 O4 116.6(5) . .
O11 Co2 O4 123.4(5) . .
O3 Co2 N4 90.6(5) . .
O11 Co2 N4 92.3(5) . .
O4 Co2 N4 90.9(5) . .
O3 Co2 O8 91.5(4) . .
O11 Co2 O8 88.0(4) . .
O4 Co2 O8 86.8(4) . .
N4 Co2 O8 177.4(5) . .
C39 N1 C35 117.1(14) . .
C39 N1 Co1 123.8(11) . .
C35 N1 Co1 118.7(10) . .
C44 N4 C40 115.2(16) . .
C44 N4 Co2 122.0(13) . .
C40 N4 Co2 122.7(12) . .
C6 C1 C2 119.9(16) . .
C6 C1 Sb1 122.2(13) . .
C2 C1 Sb1 117.3(14) . .
C3 C2 C1 119.2(18) . .
C3 C2 H2 120.4 . .
C1 C2 H2 120.4 . .
C4 C3 C2 120.1(17) . .
C4 C3 H3 120.0 . .
C2 C3 H3 120.0 . .
C3 C4 C5 119.9(16) . .
C3 C4 Cl1 120.1(14) . .
C5 C4 Cl1 120.0(15) . .
C6 C5 C4 120.5(18) . .
C6 C5 H5 119.7 . .
C4 C5 H5 119.7 . .
C1 C6 C5 120.1(17) . .
C1 C6 H6 119.9 . .
C5 C6 H6 119.9 . .
C8 C7 C12 120.0 . .
C8 C7 Sb2 119.2(5) . .
C12 C7 Sb2 120.7(5) . .
C7 C8 C9 120.0 . .
C7 C8 H8 120.0 . .
C9 C8 H8 120.0 . .
C10 C9 C8 120.0 . .
C10 C9 H9 120.0 . .
C8 C9 H9 120.0 . .
C9 C10 C11 120.0 . .
C9 C10 Cl3 119.5(6) . .
C11 C10 Cl3 120.5(6) . .
C12 C11 C10 120.0 . .
C12 C11 H11 120.0 . .
C10 C11 H11 120.0 . .
C11 C12 C7 120.0 . .
C11 C12 H12 120.0 . .
C7 C12 H12 120.0 . .
C14 C13 C14 121(2) . 8
C14 C13 Sb3 119.7(10) . .
C14 C13 Sb3 119.7(10) 8 .
C15 C14 C13 120.4(17) . .
C15 C14 H14 119.8 . .
C13 C14 H14 119.8 . .
C14 C15 C16 119.1(17) . .
C14 C15 H15 120.4 . .
C16 C15 H15 120.4 . .
C15 C16 C15 120(2) 8 .
C15 C16 Cl2 119.9(10) 8 .
C15 C16 Cl2 119.9(10) . .
C18 C17 C22 117.4(16) . .
C18 C17 P1 121.5(14) . .
C22 C17 P1 120.9(15) . .
C17 C18 C19 119.9(18) . .
C17 C18 H18 120.0 . .
C19 C18 H18 120.0 . .
C20 C19 C18 121.1(19) . .
C20 C19 H19 119.5 . .
C18 C19 H19 119.5 . .
C21 C20 C19 121.7(16) . .
C21 C20 H20 119.1 . .
C19 C20 H20 119.1 . .
C20 C21 C22 118.3(18) . .
C20 C21 H21 120.9 . .
C22 C21 H21 120.9 . .
C17 C22 C21 121.4(19) . .
C17 C22 H22 119.3 . .
C21 C22 H22 119.3 . .
C28 C23 C24 120.3(16) . .
C28 C23 P2 120.7(14) . .
C24 C23 P2 119.0(13) . .
C25 C24 C23 119.4(17) . .
C25 C24 H24 120.3 . .
C23 C24 H24 120.3 . .
C26 C25 C24 118.5(17) . .
C26 C25 H25 120.7 . .
C24 C25 H25 120.7 . .
C27 C26 C25 122.0(16) . .
C27 C26 H26 119.0 . .
C25 C26 H26 119.0 . .
C26 C27 C28 119.1(17) . .
C26 C27 H27 120.5 . .
C28 C27 H27 120.5 . .
C23 C28 C27 120.6(17) . .
C23 C28 H28 119.7 . .
C27 C28 H28 119.7 . .
C30 C29 C34 117.6(18) . .
C30 C29 P3 124(2) . .
C34 C29 P3 118.6(17) . .
C29 C30 C31 120(2) . .
C29 C30 H30 119.9 . .
C31 C30 H30 119.9 . .
C32 C31 C30 120(2) . .
C32 C31 H31 120.2 . .
C30 C31 H31 120.2 . .
C31 C32 C33 120.7(19) . .
C31 C32 H32 119.7 . .
C33 C32 H32 119.7 . .
C34 C33 C32 119(2) . .
C34 C33 H33 120.4 . .
C32 C33 H33 120.4 . .
C33 C34 C29 123(2) . .
C33 C34 H34 118.7 . .
C29 C34 H34 118.7 . .
N1 C35 C36 122.5(17) . .
N1 C35 H35 118.8 . .
C36 C35 H35 118.8 . .
C35 C36 C37 118.3(18) . .
C35 C36 H36 120.8 . .
C37 C36 H36 120.8 . .
C36 C37 C38 119.3(16) . .
C36 C37 H37 120.3 . .
C38 C37 H37 120.3 . .
C39 C38 C37 117.7(18) . .
C39 C38 H38 121.2 . .
C37 C38 H38 121.2 . .
N1 C39 C38 125.1(19) . .
N1 C39 H39 117.5 . .
C38 C39 H39 117.5 . .
N4 C40 C41 124.7(19) . .
N4 C40 H40 117.6 . .
C41 C40 H40 117.6 . .
C42 C41 C40 116.1(19) . .
C42 C41 H41 122.0 . .
C40 C41 H41 122.0 . .
C43 C42 C41 119.8(18) . .
C43 C42 H42 120.1 . .
C41 C42 H42 120.1 . .
C42 C43 C44 118(2) . .
C42 C43 H43 120.8 . .
C44 C43 H43 120.8 . .
N4 C44 C43 125(2) . .
N4 C44 H44 117.3 . .
C43 C44 H44 117.3 . .
C46 C45 H45A 109.5 . .
C46 C45 H45B 109.5 . .
H45A C45 H45B 109.5 . .
C46 C45 H45C 109.5 . .
H45A C45 H45C 109.5 . .
H45B C45 H45C 109.5 . .
N3 C46 C45 177(3) . .
C48 C47 H47A 109.5 . .
C48 C47 H47B 109.5 . .
H47A C47 H47B 109.5 . .
C48 C47 H47C 109.5 . .
H47A C47 H47C 109.5 . .
H47B C47 H47C 109.5 . .
N2 C48 C47 174(4) . .
P1 O1 Co1 132.1(7) . .
P1 O2 Sb1 128.6(6) . .
P1 O3 Co2 127.6(7) . .
P3 O4 Co2 120.8(6) . .
P3 O5 Sb1 123.4(6) . .
P3 O6 Sb2 122.1(6) . .
Sb1 O7 Sb3 127.1(5) . .
Sb1 O7 Co1 128.6(5) . .
Sb3 O7 Co1 88.6(4) . .
Sb2 O8 Sb1 97.2(4) . .
Sb2 O8 Co2 124.4(5) . .
Sb1 O8 Co2 124.0(5) . .
Sb2 O9 Sb1 98.7(4) . .
Sb2 O10 Sb3 127.8(5) . .
Sb2 O10 Co1 128.3(5) . 8
Sb3 O10 Co1 91.3(4) . 8
P2 O11 Co2 132.5(7) . .
P2 O12 Sb2 130.8(6) . .
P2 O13 Co1 131.4(8) . 8
Sb3 O14 Co1 85.1(3) . .
Sb3 O14 Co1 85.1(3) . 8
Co1 O14 Co1 170.3(7) . 8
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sb1 O7 1.977(10) .
Sb1 O9 1.984(9) .
Sb1 O8 2.000(10) .
Sb1 O2 2.017(11) .
Sb1 O5 2.063(9) .
Sb1 C1 2.086(17) .
Sb1 Sb2 2.9975(11) .
Sb2 O9 1.966(10) .
Sb2 O10 1.986(9) .
Sb2 O8 1.997(10) .
Sb2 O12 2.021(11) .
Sb2 O6 2.080(10) .
Sb2 C7 2.085(6) .
Sb3 O10 1.998(10) .
Sb3 O10 1.998(10) 8
Sb3 O7 2.002(9) .
Sb3 O7 2.002(9) 8
Sb3 O14 2.067(14) .
Sb3 C13 2.11(2) .
Sb3 Co1 2.9452(19) 8
Sb3 Co1 2.9452(19) .
P1 O1 1.504(11) .
P1 O3 1.518(11) .
P1 O2 1.562(13) .
P1 C17 1.794(17) .
P2 O11 1.494(12) .
P2 O13 1.495(12) .
P2 O12 1.568(11) .
P2 C23 1.815(17) .
P3 O4 1.507(12) .
P3 O5 1.545(10) .
P3 O6 1.553(11) .
P3 C29 1.778(18) .
Co1 O1 1.996(11) .
Co1 O13 2.046(12) 8
Co1 N1 2.105(12) .
Co1 O10 2.120(10) 8
Co1 O7 2.210(11) .
Co1 O14 2.281(2) .
Co2 O3 1.972(11) .
Co2 O11 1.978(11) .
Co2 O4 1.989(11) .
Co2 N4 2.117(12) .
Co2 O8 2.316(9) .
N1 C39 1.31(2) .
N1 C35 1.36(2) .
N2 C48 1.17(4) .
N3 C46 1.14(3) .
N4 C44 1.28(2) .
N4 C40 1.37(2) .
C1 C6 1.36(3) .
C1 C2 1.42(2) .
C2 C3 1.41(2) .
C2 H2 0.9500 .
C3 C4 1.36(3) .
C3 H3 0.9500 .
C4 C5 1.40(2) .
C4 Cl1 1.736(18) .
C5 C6 1.39(2) .
C5 H5 0.9500 .
C6 H6 0.9500 .
C7 C8 1.3900 .
C7 C12 1.3900 .
C8 C9 1.3900 .
C8 H8 0.9500 .
C9 C10 1.3900 .
C9 H9 0.9500 .
C10 C11 1.3900 .
C10 Cl3 1.731(8) .
C11 C12 1.3900 .
C11 H11 0.9500 .
C12 H12 0.9500 .
C13 C14 1.411(19) .
C13 C14 1.411(19) 8
C14 C15 1.37(2) .
C14 H14 0.9500 .
C15 C16 1.43(2) .
C15 H15 0.9500 .
C16 C15 1.43(2) 8
C16 Cl2 1.70(2) .
C17 C18 1.38(3) .
C17 C22 1.39(3) .
C18 C19 1.39(2) .
C18 H18 0.9500 .
C19 C20 1.35(3) .
C19 H19 0.9500 .
C20 C21 1.33(3) .
C20 H20 0.9500 .
C21 C22 1.42(2) .
C21 H21 0.9500 .
C22 H22 0.9500 .
C23 C28 1.34(3) .
C23 C24 1.42(3) .
C24 C25 1.40(2) .
C24 H24 0.9500 .
C25 C26 1.39(2) .
C25 H25 0.9500 .
C26 C27 1.36(3) .
C26 H26 0.9500 .
C27 C28 1.42(2) .
C27 H27 0.9500 .
C28 H28 0.9500 .
C29 C30 1.38(3) .
C29 C34 1.41(4) .
C30 C31 1.40(2) .
C30 H30 0.9500 .
C31 C32 1.36(3) .
C31 H31 0.9500 .
C32 C33 1.39(3) .
C32 H32 0.9500 .
C33 C34 1.33(3) .
C33 H33 0.9500 .
C34 H34 0.9500 .
C35 C36 1.36(2) .
C35 H35 0.9500 .
C36 C37 1.37(2) .
C36 H36 0.9500 .
C37 C38 1.39(3) .
C37 H37 0.9500 .
C38 C39 1.34(2) .
C38 H38 0.9500 .
C39 H39 0.9500 .
C40 C41 1.40(3) .
C40 H40 0.9500 .
C41 C42 1.39(3) .
C41 H41 0.9500 .
C42 C43 1.37(3) .
C42 H42 0.9500 .
C43 C44 1.40(3) .
C43 H43 0.9500 .
C44 H44 0.9500 .
C45 C46 1.45(3) .
C45 H45A 0.9800 .
C45 H45B 0.9800 .
C45 H45C 0.9800 .
C47 C48 1.41(4) .
C47 H47A 0.9800 .
C47 H47B 0.9800 .
C47 H47C 0.9800 .
O10 Co1 2.120(10) 8
O13 Co1 2.046(12) 8
O14 Co1 2.281(2) 8
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O7 Sb1 Sb2 O9 -88.8(6) . .
O8 Sb1 Sb2 O9 -178.1(6) . .
O2 Sb1 Sb2 O9 178.1(6) . .
O5 Sb1 Sb2 O9 95.3(6) . .
C1 Sb1 Sb2 O9 15.1(10) . .
O7 Sb1 Sb2 O10 -0.4(5) . .
O9 Sb1 Sb2 O10 88.3(6) . .
O8 Sb1 Sb2 O10 -89.8(5) . .
O2 Sb1 Sb2 O10 -93.6(5) . .
O5 Sb1 Sb2 O10 -176.4(4) . .
C1 Sb1 Sb2 O10 103.4(9) . .
O7 Sb1 Sb2 O8 89.3(5) . .
O9 Sb1 Sb2 O8 178.1(6) . .
O2 Sb1 Sb2 O8 -3.8(6) . .
O5 Sb1 Sb2 O8 -86.6(5) . .
C1 Sb1 Sb2 O8 -166.8(9) . .
O7 Sb1 Sb2 O12 93.3(5) . .
O9 Sb1 Sb2 O12 -178.0(6) . .
O8 Sb1 Sb2 O12 4.0(6) . .
O2 Sb1 Sb2 O12 0.1(6) . .
O5 Sb1 Sb2 O12 -82.7(5) . .
C1 Sb1 Sb2 O12 -162.8(9) . .
O7 Sb1 Sb2 O6 176.9(5) . .
O9 Sb1 Sb2 O6 -94.3(6) . .
O8 Sb1 Sb2 O6 87.6(5) . .
O2 Sb1 Sb2 O6 83.8(5) . .
O5 Sb1 Sb2 O6 1.0(5) . .
C1 Sb1 Sb2 O6 -79.2(9) . .
O7 Sb1 Sb2 C7 -97.8(6) . .
O9 Sb1 Sb2 C7 -9.0(7) . .
O8 Sb1 Sb2 C7 172.9(7) . .
O2 Sb1 Sb2 C7 169.1(7) . .
O5 Sb1 Sb2 C7 86.3(6) . .
C1 Sb1 Sb2 C7 6.1(10) . .
O10 Sb3 Co1 O1 -11.0(5) . .
O10 Sb3 Co1 O1 -176.6(5) 8 .
O7 Sb3 Co1 O1 65.8(6) . .
O7 Sb3 Co1 O1 -104.4(5) 8 .
O14 Sb3 Co1 O1 -56.4(4) . .
C13 Sb3 Co1 O1 123.6(4) . .
Co1 Sb3 Co1 O1 -56.4(4) 8 .
O10 Sb3 Co1 O13 98.5(5) . 8
O10 Sb3 Co1 O13 -67.1(6) 8 8
O7 Sb3 Co1 O13 175.3(6) . 8
O7 Sb3 Co1 O13 5.1(6) 8 8
O14 Sb3 Co1 O13 53.1(4) . 8
C13 Sb3 Co1 O13 -126.9(4) . 8
Co1 Sb3 Co1 O13 53.0(4) 8 8
O10 Sb3 Co1 N1 -138.0(5) . .
O10 Sb3 Co1 N1 56.4(6) 8 .
O7 Sb3 Co1 N1 -61.2(6) . .
O7 Sb3 Co1 N1 128.6(6) 8 .
O14 Sb3 Co1 N1 176.5(5) . .
C13 Sb3 Co1 N1 -3.5(5) . .
Co1 Sb3 Co1 N1 176.5(5) 8 .
O10 Sb3 Co1 O10 165.6(5) . 8
O7 Sb3 Co1 O10 -117.6(5) . 8
O7 Sb3 Co1 O10 72.2(5) 8 8
O14 Sb3 Co1 O10 120.1(4) . 8
C13 Sb3 Co1 O10 -59.9(4) . 8
Co1 Sb3 Co1 O10 120.1(4) 8 8
O10 Sb3 Co1 O7 -76.8(5) . .
O10 Sb3 Co1 O7 117.6(5) 8 .
O7 Sb3 Co1 O7 -170.2(5) 8 .
O14 Sb3 Co1 O7 -122.3(4) . .
C13 Sb3 Co1 O7 57.7(4) . .
Co1 Sb3 Co1 O7 -122.3(4) 8 .
O10 Sb3 Co1 O14 45.4(3) . .
O10 Sb3 Co1 O14 -120.1(4) 8 .
O7 Sb3 Co1 O14 122.3(4) . .
O7 Sb3 Co1 O14 -47.9(3) 8 .
C13 Sb3 Co1 O14 180.000(1) . .
Co1 Sb3 Co1 O14 0.0 8 .
O1 Co1 N1 C39 74.8(16) . .
O13 Co1 N1 C39 -19.5(16) 8 .
O10 Co1 N1 C39 -118.8(15) 8 .
O7 Co1 N1 C39 170.2(15) . .
O14 Co1 N1 C39 -144.7(13) . .
Sb3 Co1 N1 C39 -153.2(14) . .
O1 Co1 N1 C35 -112.9(13) . .
O13 Co1 N1 C35 152.8(13) 8 .
O10 Co1 N1 C35 53.5(13) 8 .
O7 Co1 N1 C35 -17.5(13) . .
O14 Co1 N1 C35 28(2) . .
Sb3 Co1 N1 C35 19.1(14) . .
O3 Co2 N4 C44 75.1(14) . .
O11 Co2 N4 C44 -165.0(14) . .
O4 Co2 N4 C44 -41.5(14) . .
O8 Co2 N4 C44 -68(11) . .
O3 Co2 N4 C40 -107.8(13) . .
O11 Co2 N4 C40 12.2(13) . .
O4 Co2 N4 C40 135.6(13) . .
O8 Co2 N4 C40 109(11) . .
O7 Sb1 C1 C6 67.1(17) . .
O9 Sb1 C1 C6 -24.4(17) . .
O8 Sb1 C1 C6 -117(4) . .
O2 Sb1 C1 C6 158.6(17) . .
O5 Sb1 C1 C6 -112.9(17) . .
Sb2 Sb1 C1 C6 -34(2) . .
O7 Sb1 C1 C2 -121.8(14) . .
O9 Sb1 C1 C2 146.7(14) . .
O8 Sb1 C1 C2 54(5) . .
O2 Sb1 C1 C2 -30.3(14) . .
O5 Sb1 C1 C2 58.2(15) . .
Sb2 Sb1 C1 C2 136.9(12) . .
C6 C1 C2 C3 -3(3) . .
Sb1 C1 C2 C3 -174.3(14) . .
C1 C2 C3 C4 3(3) . .
C2 C3 C4 C5 -4(3) . .
C2 C3 C4 Cl1 176.8(15) . .
C3 C4 C5 C6 4(3) . .
Cl1 C4 C5 C6 -176.7(15) . .
C2 C1 C6 C5 3(3) . .
Sb1 C1 C6 C5 174.0(14) . .
C4 C5 C6 C1 -3(3) . .
O9 Sb2 C7 C8 11.2(7) . .
O10 Sb2 C7 C8 -78.7(6) . .
O8 Sb2 C7 C8 105(5) . .
O12 Sb2 C7 C8 -171.4(7) . .
O6 Sb2 C7 C8 99.7(7) . .
Sb1 Sb2 C7 C8 17.1(9) . .
O9 Sb2 C7 C12 -171.9(7) . .
O10 Sb2 C7 C12 98.2(7) . .
O8 Sb2 C7 C12 -78(5) . .
O12 Sb2 C7 C12 5.5(7) . .
O6 Sb2 C7 C12 -83.5(7) . .
Sb1 Sb2 C7 C12 -166.0(5) . .
C12 C7 C8 C9 0.0 . .
Sb2 C7 C8 C9 176.9(9) . .
C7 C8 C9 C10 0.0 . .
C8 C9 C10 C11 0.0 . .
C8 C9 C10 Cl3 -178.8(10) . .
C9 C10 C11 C12 0.0 . .
Cl3 C10 C11 C12 178.8(10) . .
C10 C11 C12 C7 0.0 . .
C8 C7 C12 C11 0.0 . .
Sb2 C7 C12 C11 -176.8(9) . .
O10 Sb3 C13 C14 146.1(10) . .
O10 Sb3 C13 C14 -33.9(10) 8 .
O7 Sb3 C13 C14 44.9(10) . .
O7 Sb3 C13 C14 -135.1(10) 8 .
O14 Sb3 C13 C14 93.3(10) . .
Co1 Sb3 C13 C14 -174.8(10) 8 .
Co1 Sb3 C13 C14 5.2(10) . .
O10 Sb3 C13 C14 -33.9(10) . 8
O10 Sb3 C13 C14 146.1(10) 8 8
O7 Sb3 C13 C14 -135.1(10) . 8
O7 Sb3 C13 C14 44.9(10) 8 8
O14 Sb3 C13 C14 -86.7(10) . 8
Co1 Sb3 C13 C14 5.2(10) 8 8
Co1 Sb3 C13 C14 -174.8(10) . 8
C14 C13 C14 C15 0.6(15) 8 .
Sb3 C13 C14 C15 -179.4(15) . .
C13 C14 C15 C16 -1(3) . .
C14 C15 C16 C15 0.6(14) . 8
C14 C15 C16 Cl2 -179.4(15) . .
O1 P1 C17 C18 173.8(15) . .
O3 P1 C17 C18 -62.8(17) . .
O2 P1 C17 C18 54.3(17) . .
O1 P1 C17 C22 -1.0(18) . .
O3 P1 C17 C22 122.4(16) . .
O2 P1 C17 C22 -120.5(16) . .
C22 C17 C18 C19 -1(3) . .
P1 C17 C18 C19 -176.1(15) . .
C17 C18 C19 C20 3(3) . .
C18 C19 C20 C21 -2(3) . .
C19 C20 C21 C22 -1(3) . .
C18 C17 C22 C21 -2(3) . .
P1 C17 C22 C21 173.0(15) . .
C20 C21 C22 C17 3(3) . .
O11 P2 C23 C28 72.8(18) . .
O13 P2 C23 C28 -162.0(16) . .
O12 P2 C23 C28 -44.2(18) . .
O11 P2 C23 C24 -105.6(16) . .
O13 P2 C23 C24 19.6(18) . .
O12 P2 C23 C24 137.3(15) . .
C28 C23 C24 C25 5(3) . .
P2 C23 C24 C25 -176.3(14) . .
C23 C24 C25 C26 -4(3) . .
C24 C25 C26 C27 1(3) . .
C25 C26 C27 C28 2(3) . .
C24 C23 C28 C27 -3(3) . .
P2 C23 C28 C27 179.1(15) . .
C26 C27 C28 C23 -1(3) . .
O4 P3 C29 C30 8.4(19) . .
O5 P3 C29 C30 -110.4(17) . .
O6 P3 C29 C30 131.9(16) . .
O4 P3 C29 C34 -177.5(14) . .
O5 P3 C29 C34 63.7(16) . .
O6 P3 C29 C34 -53.9(17) . .
C34 C29 C30 C31 1(3) . .
P3 C29 C30 C31 175.1(16) . .
C29 C30 C31 C32 -2(3) . .
C30 C31 C32 C33 0(3) . .
C31 C32 C33 C34 3(3) . .
C32 C33 C34 C29 -4(3) . .
C30 C29 C34 C33 2(3) . .
P3 C29 C34 C33 -172.7(16) . .
C39 N1 C35 C36 -2(3) . .
Co1 N1 C35 C36 -174.8(15) . .
N1 C35 C36 C37 3(3) . .
C35 C36 C37 C38 -3(3) . .
C36 C37 C38 C39 2(3) . .
C35 N1 C39 C38 1(3) . .
Co1 N1 C39 C38 173.4(16) . .
C37 C38 C39 N1 -1(3) . .
C44 N4 C40 C41 -3(3) . .
Co2 N4 C40 C41 179.9(14) . .
N4 C40 C41 C42 0(3) . .
C40 C41 C42 C43 -1(3) . .
C41 C42 C43 C44 5(3) . .
C40 N4 C44 C43 7(3) . .
Co2 N4 C44 C43 -175.4(15) . .
C42 C43 C44 N4 -9(3) . .
O3 P1 O1 Co1 142.7(8) . .
O2 P1 O1 Co1 16.2(11) . .
C17 P1 O1 Co1 -96.8(10) . .
O13 Co1 O1 P1 155.1(9) 8 .
N1 Co1 O1 P1 55.0(10) . .
O10 Co1 O1 P1 -85.1(14) 8 .
O7 Co1 O1 P1 -40.3(9) . .
O14 Co1 O1 P1 -114.4(9) . .
Sb3 Co1 O1 P1 -78.8(9) . .
O1 P1 O2 Sb1 50.8(10) . .
O3 P1 O2 Sb1 -77.3(9) . .
C17 P1 O2 Sb1 166.8(9) . .
O7 Sb1 O2 P1 -61.6(8) . .
O9 Sb1 O2 P1 39(3) . .
O8 Sb1 O2 P1 29.0(8) . .
O5 Sb1 O2 P1 112.3(8) . .
C1 Sb1 O2 P1 -159.7(10) . .
Sb2 Sb1 O2 P1 31.5(10) . .
O1 P1 O3 Co2 -79.7(10) . .
O2 P1 O3 Co2 48.1(10) . .
C17 P1 O3 Co2 160.3(9) . .
O11 Co2 O3 P1 93.1(9) . .
O4 Co2 O3 P1 -82.7(9) . .
N4 Co2 O3 P1 -174.0(9) . .
O8 Co2 O3 P1 4.5(9) . .
O5 P3 O4 Co2 -64.5(8) . .
O6 P3 O4 Co2 62.5(9) . .
C29 P3 O4 Co2 -178.6(8) . .
O3 Co2 O4 P3 91.2(8) . .
O11 Co2 O4 P3 -84.4(9) . .
N4 Co2 O4 P3 -177.7(8) . .
O8 Co2 O4 P3 1.2(7) . .
O4 P3 O5 Sb1 85.1(8) . .
O6 P3 O5 Sb1 -43.0(9) . .
C29 P3 O5 Sb1 -156.7(10) . .
O7 Sb1 O5 P3 -19(4) . .
O9 Sb1 O5 P3 62.2(8) . .
O8 Sb1 O5 P3 -19.7(8) . .
O2 Sb1 O5 P3 -109.0(8) . .
C1 Sb1 O5 P3 161.0(9) . .
Sb2 Sb1 O5 P3 22.0(7) . .
O4 P3 O6 Sb2 -82.8(8) . .
O5 P3 O6 Sb2 43.9(9) . .
C29 P3 O6 Sb2 155.9(10) . .
O9 Sb2 O6 P3 -64.5(8) . .
O10 Sb2 O6 P3 2(5) . .
O8 Sb2 O6 P3 17.9(7) . .
O12 Sb2 O6 P3 106.2(8) . .
C7 Sb2 O6 P3 -162.5(8) . .
Sb1 Sb2 O6 P3 -23.7(7) . .
O9 Sb1 O7 Sb3 -27.8(7) . .
O8 Sb1 O7 Sb3 54.0(7) . .
O2 Sb1 O7 Sb3 143.2(7) . .
O5 Sb1 O7 Sb3 54(4) . .
C1 Sb1 O7 Sb3 -126.7(8) . .
Sb2 Sb1 O7 Sb3 12.6(7) . .
O9 Sb1 O7 Co1 -152.1(6) . .
O8 Sb1 O7 Co1 -70.3(6) . .
O2 Sb1 O7 Co1 18.9(7) . .
O5 Sb1 O7 Co1 -71(4) . .
C1 Sb1 O7 Co1 109.0(8) . .
Sb2 Sb1 O7 Co1 -111.6(6) . .
O10 Sb3 O7 Sb1 -19.4(7) . .
O10 Sb3 O7 Sb1 179.6(8) 8 .
O7 Sb3 O7 Sb1 -98.7(7) 8 .
O14 Sb3 O7 Sb1 -98.7(7) . .
C13 Sb3 O7 Sb1 81.3(7) . .
Co1 Sb3 O7 Sb1 -63.5(8) 8 .
Co1 Sb3 O7 Sb1 -139.7(9) . .
O10 Sb3 O7 Co1 120.3(4) . .
O10 Sb3 O7 Co1 -40.7(3) 8 .
O7 Sb3 O7 Co1 41.0(3) 8 .
O14 Sb3 O7 Co1 41.0(3) . .
C13 Sb3 O7 Co1 -139.0(3) . .
Co1 Sb3 O7 Co1 76.2(4) 8 .
O1 Co1 O7 Sb1 14.0(7) . .
O13 Co1 O7 Sb1 124.4(15) 8 .
N1 Co1 O7 Sb1 -91.4(7) . .
O10 Co1 O7 Sb1 178.2(8) 8 .
O14 Co1 O7 Sb1 100.9(7) . .
Sb3 Co1 O7 Sb1 138.8(9) . .
O1 Co1 O7 Sb3 -124.7(4) . .
O13 Co1 O7 Sb3 -14.3(18) 8 .
N1 Co1 O7 Sb3 129.8(5) . .
O10 Co1 O7 Sb3 39.5(3) 8 .
O14 Co1 O7 Sb3 -37.9(3) . .
O9 Sb2 O8 Sb1 1.3(4) . .
O10 Sb2 O8 Sb1 90.5(4) . .
O12 Sb2 O8 Sb1 -176.9(4) . .
O6 Sb2 O8 Sb1 -87.8(4) . .
C7 Sb2 O8 Sb1 -93(5) . .
O9 Sb2 O8 Co2 141.6(6) . .
O10 Sb2 O8 Co2 -129.2(6) . .
O12 Sb2 O8 Co2 -36.7(6) . .
O6 Sb2 O8 Co2 52.5(6) . .
C7 Sb2 O8 Co2 47(5) . .
Sb1 Sb2 O8 Co2 140.3(8) . .
O7 Sb1 O8 Sb2 -91.4(4) . .
O9 Sb1 O8 Sb2 -1.3(4) . .
O2 Sb1 O8 Sb2 177.1(5) . .
O5 Sb1 O8 Sb2 88.5(4) . .
C1 Sb1 O8 Sb2 93(4) . .
O7 Sb1 O8 Co2 128.1(6) . .
O9 Sb1 O8 Co2 -141.8(6) . .
O2 Sb1 O8 Co2 36.6(6) . .
O5 Sb1 O8 Co2 -52.0(5) . .
C1 Sb1 O8 Co2 -48(4) . .
Sb2 Sb1 O8 Co2 -140.5(8) . .
O3 Co2 O8 Sb2 177.9(6) . .
O11 Co2 O8 Sb2 58.0(6) . .
O4 Co2 O8 Sb2 -65.6(6) . .
N4 Co2 O8 Sb2 -39(11) . .
O3 Co2 O8 Sb1 -52.0(6) . .
O11 Co2 O8 Sb1 -171.9(6) . .
O4 Co2 O8 Sb1 64.5(6) . .
N4 Co2 O8 Sb1 91(11) . .
O10 Sb2 O9 Sb1 -91.6(5) . .
O8 Sb2 O9 Sb1 -1.3(4) . .
O12 Sb2 O9 Sb1 9(3) . .
O6 Sb2 O9 Sb1 82.8(5) . .
C7 Sb2 O9 Sb1 174.0(5) . .
O7 Sb1 O9 Sb2 91.8(5) . .
O8 Sb1 O9 Sb2 1.3(4) . .
O2 Sb1 O9 Sb2 -9(3) . .
O5 Sb1 O9 Sb2 -82.1(5) . .
C1 Sb1 O9 Sb2 -169.9(6) . .
O9 Sb2 O10 Sb3 29.0(6) . .
O8 Sb2 O10 Sb3 -53.3(6) . .
O12 Sb2 O10 Sb3 -141.5(7) . .
O6 Sb2 O10 Sb3 -37(4) . .
C7 Sb2 O10 Sb3 127.0(6) . .
Sb1 Sb2 O10 Sb3 -11.8(6) . .
O9 Sb2 O10 Co1 159.4(6) . 8
O8 Sb2 O10 Co1 77.2(6) . 8
O12 Sb2 O10 Co1 -11.0(6) . 8
O6 Sb2 O10 Co1 93(4) . 8
C7 Sb2 O10 Co1 -102.5(6) . 8
Sb1 Sb2 O10 Co1 118.6(5) . 8
O10 Sb3 O10 Sb2 100.8(6) 8 .
O7 Sb3 O10 Sb2 19.1(7) . .
O7 Sb3 O10 Sb2 -173.8(8) 8 .
O14 Sb3 O10 Sb2 100.8(6) . .
C13 Sb3 O10 Sb2 -79.2(6) . .
Co1 Sb3 O10 Sb2 143.3(8) 8 .
Co1 Sb3 O10 Sb2 66.9(7) . .
O10 Sb3 O10 Co1 -42.6(2) 8 8
O7 Sb3 O10 Co1 -124.3(4) . 8
O7 Sb3 O10 Co1 42.8(4) 8 8
O14 Sb3 O10 Co1 -42.6(2) . 8
C13 Sb3 O10 Co1 137.4(2) . 8
Co1 Sb3 O10 Co1 -76.4(3) . 8
O13 P2 O11 Co2 98.9(11) . .
O12 P2 O11 Co2 -28.7(12) . .
C23 P2 O11 Co2 -139.6(10) . .
O3 Co2 O11 P2 -111.0(10) . .
O4 Co2 O11 P2 64.5(11) . .
N4 Co2 O11 P2 157.0(10) . .
O8 Co2 O11 P2 -20.4(10) . .
O11 P2 O12 Sb2 70.3(10) . .
O13 P2 O12 Sb2 -58.8(10) . .
C23 P2 O12 Sb2 -174.3(9) . .
O9 Sb2 O12 P2 -42(3) . .
O10 Sb2 O12 P2 58.3(9) . .
O8 Sb2 O12 P2 -31.8(9) . .
O6 Sb2 O12 P2 -115.8(9) . .
C7 Sb2 O12 P2 152.8(9) . .
Sb1 Sb2 O12 P2 -34.5(10) . .
O11 P2 O13 Co1 -123.8(10) . 8
O12 P2 O13 Co1 3.3(12) . 8
C23 P2 O13 Co1 114.5(11) . 8
O10 Sb3 O14 Co1 -140.9(3) . .
O10 Sb3 O14 Co1 39.1(3) 8 .
O7 Sb3 O14 Co1 -39.7(3) . .
O7 Sb3 O14 Co1 140.3(3) 8 .
C13 Sb3 O14 Co1 -88.11(5) . .
Co1 Sb3 O14 Co1 180.0 8 .
O10 Sb3 O14 Co1 39.1(3) . 8
O10 Sb3 O14 Co1 -140.9(3) 8 8
O7 Sb3 O14 Co1 140.3(3) . 8
O7 Sb3 O14 Co1 -39.7(3) 8 8
C13 Sb3 O14 Co1 91.89(5) . 8
Co1 Sb3 O14 Co1 180.0 . 8
O1 Co1 O14 Sb3 131.5(3) . .
O13 Co1 O14 Sb3 -136.8(3) 8 .
N1 Co1 O14 Sb3 -10.6(14) . .
O10 Co1 O14 Sb3 -37.8(3) 8 .
O7 Co1 O14 Sb3 36.7(3) . .
O1 Co1 O14 Co1 131.5(3) . 8
O13 Co1 O14 Co1 -136.8(3) 8 8
N1 Co1 O14 Co1 -10.6(14) . 8
O10 Co1 O14 Co1 -37.7(3) 8 8
O7 Co1 O14 Co1 36.7(3) . 8
Sb3 Co1 O14 Co1 0.011(5) . 8
