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Information card for entry 4068106
Preview
| Coordinates | 4068106.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C35 H59 Cl N3 Si2 Yb |
|---|---|
| Calculated formula | C35 H59 Cl N3 Si2 Yb |
| SMILES | [Yb]1(Cl)(N([Si](C)(C)C)[Si](C)(C)C)[N](=C(C)C=C(N1c1c(cccc1C(C)C)C(C)C)C)c1c(cccc1C(C)C)C(C)C |
| Title of publication | Synthesis of Dianionic β-Diketiminate Lanthanide Amides L′LnN(SiMe3)2(THF) by Deprotonation of the β-Diketiminate Ligand L (L = {[(2,6-iPr2C6H3)NC(CH3)]2CH}−) and the Transformation with [HNEt3][BPh4] to the Cationic Samarium Amide [LSmN(SiMe3)2][BPh4] |
| Authors of publication | Liu, Peng; Zhang, Yong; Yao, Yingming; Shen, Qi |
| Journal of publication | Organometallics |
| Year of publication | 2012 |
| Journal volume | 31 |
| Journal issue | 3 |
| Pages of publication | 1017 |
| a | 17.156 ± 0.005 Å |
| b | 18.248 ± 0.005 Å |
| c | 13.096 ± 0.004 Å |
| α | 90° |
| β | 104.166 ± 0.004° |
| γ | 90° |
| Cell volume | 3975 ± 2 Å3 |
| Cell temperature | 223 ± 2 K |
| Ambient diffraction temperature | 223 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.1072 |
| Residual factor for significantly intense reflections | 0.0767 |
| Weighted residual factors for significantly intense reflections | 0.0967 |
| Weighted residual factors for all reflections included in the refinement | 0.1046 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.164 |
| Diffraction radiation wavelength | 0.71075 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 178571 (current) | 2016-03-21 | cif/4/06/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/06/81. |
4068106.cif |
| 91935 | 2013-12-29 | cod/ (saulius@koala.ibt.lt) Adding DOIs that could be assigned unambiguously to the rest of COD CIFs. |
4068106.cif |
| 38083 | 2012-03-04 | ../uploads/cif-deposit/cod/cif Adding structures of 4068101, 4068102, 4068103, 4068104, 4068105, 4068106, 4068107 via cif-deposit CGI script. |
4068106.cif |
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Users of the data should acknowledge the original authors of the
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