Crystallography Open Database

Information card for entry 4078108

Preview

Coordinates	4078108.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C52 H88 Cl2 O2 P2 Ru4 S2
Calculated formula	C50 H72 Cl2 O3.5 P2 Ru4 S2
Title of publication	Synthesis and Reactivity of Hybrid Phosphido- and Hydrosulfido-Bridged Diruthenium Complexes: Transformations into Diruthenium and Tetraruthenium Complexes Bridged by Phosphido and Sulfido Ligands
Authors of publication	Miyake, Yoshihiro; Moriyama, Taichi; Tanabe, Yoshiaki; Endo, Satoshi; Nishibayashi, Yoshiaki
Journal of publication	Organometallics
Year of publication	2012
Journal volume	31
Journal issue	8
Pages of publication	3292
a	13.9721 ± 0.0008 Å
b	17.8282 ± 0.0013 Å
c	22.6549 ± 0.0013 Å
α	90°
β	97.032 ± 0.0016°
γ	90°
Cell volume	5600.8 ± 0.6 Å³
Cell temperature	173 K
Ambient diffraction temperature	173 K
Number of distinct elements	7
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Residual factor for significantly intense reflections	0.0494
Weighted residual factors for all reflections included in the refinement	0.1522
Goodness-of-fit parameter for all reflections included in the refinement	1
Diffraction radiation wavelength	0.71075 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
178670 (current)	2016-03-21	cif/4/07/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/07/81.	4078108.cif
91935	2013-12-29	cod/ (saulius@koala.ibt.lt) Adding DOIs that could be assigned unambiguously to the rest of COD CIFs.	4078108.cif
57710	2012-05-18	cif/ Adding structures of 4078107, 4078108, 4078109, 4078110, 4078111, 4078112 via cif-deposit CGI script.	4078108.cif