Crystallography Open Database

Information card for entry 7012476

Preview

Coordinates	7012476.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C40 H25 Au O10 Os3 P2
Calculated formula	C40 H25 Au O10 Os3 P2
SMILES	[Os]123([Os]([Os]1(C#[O])(C#[O])(C#[O])C#[O])([Au]2[P](c1ccccc1)(c1ccccc1)c1ccccc1)([P]3(c1ccccc1)c1ccccc1)(C#[O])(C#[O])C#[O])(C#[O])(C#[O])C#[O]
Title of publication	Reaction of metallophosphanide anions with MLnX (X = halide) species as a simple route to heterometallic transition metal complexes
Authors of publication	Birte Ahrens; Jacqueline M. Cole; Jonathan P. Hickey; James N. Martin; Martin J. Mays; Paul R. Raithby; Simon J. Teat; Anthony D. Woods
Journal of publication	Dalton Trans.
Year of publication	2003
Journal issue	7
Pages of publication	1389 - 1395
a	10.032 ± 0.0002 Å
b	13.904 ± 0.0002 Å
c	16.43 ± 0.0004 Å
α	94.671 ± 0.001°
β	103.779 ± 0.001°
γ	111.127 ± 0.001°
Cell volume	2040.47 ± 0.07 Å³
Cell temperature	180 ± 2 K
Ambient diffraction temperature	180 ± 2 K
Number of distinct elements	6
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0368
Residual factor for significantly intense reflections	0.0333
Weighted residual factors for significantly intense reflections	0.0857
Weighted residual factors for all reflections included in the refinement	0.088
Goodness-of-fit parameter for all reflections included in the refinement	1.067
Diffraction radiation wavelength	0.7107 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
179828 (current)	2016-03-25	cif/7/01/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/01/24.	7012476.cif
120443	2014-07-15	Adding 17924 DOIs guessed from source file names.	7012476.cif
35909	2012-02-26	cif/7/: reorganising range 7 into a prefix-directory tree.	7012476.cif
5312	2011-01-03	cif/ Adding files, updated with the 'cif_fix_enum' program and the cif_core.dic dictionary. The enumerator values were fixed, mostly incorrect case, but also some values that had extra underscores, dashes or spaces. Unfortunately, 22 had non-ASCII characters with the 8-th bit set, and these got incorrectly interpreted as latin1 characters and converted to their UTF8 equivalents by Perl. To fix the structures, however, they need to be redeposited from the original files with the new CIFParser/cif_filter version.	7012476.cif
3896	2010-12-08	cif/7/ Adding CIFs with data from Dalton-Trans-2004-2000/.	7012476.cif