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Information card for entry 7024277
Preview
| Coordinates | 7024277.cif |
|---|---|
| Original paper (by DOI) | HTML |
| External links | PubChem |
| Formula | C35 H60 Ge N4 Si2 |
|---|---|
| Calculated formula | C35 H60 Ge N4 Si2 |
| SMILES | [Ge]1(N(c2c(cccc2C(C)C)C(C)C)C(=C)C=C(N1c1c(cccc1C(C)C)C(C)C)C)(N[Si](C)(C)C)N[Si](C)(C)C |
| Title of publication | Reactivity of germanium(II) hydride with nitrous oxide, trimethylsilyl azide, ketones, and alkynes and the reaction of a methyl analogue with trimethylsilyl diazomethane. |
| Authors of publication | Jana, Anukul; Roesky, Herbert W.; Schulzke, Carola |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2010 |
| Journal volume | 39 |
| Journal issue | 1 |
| Pages of publication | 132 - 138 |
| a | 10.389 ± 0.002 Å |
| b | 32.555 ± 0.007 Å |
| c | 12.216 ± 0.002 Å |
| α | 90° |
| β | 112.28 ± 0.03° |
| γ | 90° |
| Cell volume | 3823.2 ± 1.5 Å3 |
| Cell temperature | 133 ± 2 K |
| Ambient diffraction temperature | 133 ± 2 K |
| Number of distinct elements | 5 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/n 1 |
| Hall space group symbol | -P 2yn |
| Residual factor for all reflections | 0.0373 |
| Residual factor for significantly intense reflections | 0.0304 |
| Weighted residual factors for significantly intense reflections | 0.0725 |
| Weighted residual factors for all reflections included in the refinement | 0.0748 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.033 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 301848 (current) | 2025-08-21 | Add cross-references to PubChem compounds in COD range 7/02/ Each referenced PubChem compound corresponds to the full crystal structure. |
7024277.cif |
| 179947 | 2016-03-25 | cif/7/02/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/02/42. |
7024277.cif |
| 92343 | 2014-01-12 | cif/ Adding structures of 7024276, 7024277, 7024278, 7024279, 7024280 via cif-deposit CGI script. |
7024277.cif |
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Users of the data should acknowledge the original authors of the
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