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Information card for entry 4069699
Preview
| Coordinates | 4069699.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C26 H29 Cl N Nb P Rh |
|---|---|
| Calculated formula | C26 H29 Cl N Nb P Rh |
| SMILES | [Nb]123456([Rh]789%10([P]1(c1ccccc1)c1ccccc1)(N2C(C)(C)C)[cH]1[cH]7[cH]8[cH]9[cH]%101)(Cl)[cH]1[cH]3[cH]4[cH]5[cH]61 |
| Title of publication | Niobium/Rhodium Bimetallic Complexes: Synthesis, Structure, and Catalytic Hydrosilylation of Acetophenone and Benzaldehyde |
| Authors of publication | Leelasubcharoen, Somying; Zhizhko, Pavel A.; Kuzmina, Lyudmila G.; Churakov, Andrei V.; Howard, Judith A. K.; Nikonov, Georgii I. |
| Journal of publication | Organometallics |
| Year of publication | 2009 |
| Journal volume | 28 |
| Journal issue | 15 |
| Pages of publication | 4500 |
| a | 9.1504 ± 0.0003 Å |
| b | 16.5399 ± 0.0006 Å |
| c | 16.5001 ± 0.0006 Å |
| α | 90° |
| β | 103.54 ± 0.001° |
| γ | 90° |
| Cell volume | 2427.83 ± 0.15 Å3 |
| Cell temperature | 150 ± 2 K |
| Ambient diffraction temperature | 150 ± 2 K |
| Number of distinct elements | 7 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/n 1 |
| Hall space group symbol | -P 2yn |
| Residual factor for all reflections | 0.0313 |
| Residual factor for significantly intense reflections | 0.0239 |
| Weighted residual factors for significantly intense reflections | 0.056 |
| Weighted residual factors for all reflections included in the refinement | 0.0586 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.05 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 178585 (current) | 2016-03-21 | cif/4/06/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/06/96. |
4069699.cif |
| 91935 | 2013-12-29 | cod/ (saulius@koala.ibt.lt) Adding DOIs that could be assigned unambiguously to the rest of COD CIFs. |
4069699.cif |
| 40398 | 2012-03-07 | ../uploads/cif-deposit/cod/cif Adding structures of 4069699, 4069700 via cif-deposit CGI script. |
4069699.cif |
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