Crystallography Open Database

Information card for entry 7011747

Preview

Coordinates	7011747.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C10 H30 Al Cl2 N Sn3
Calculated formula	C10 H30 Al Cl2 N Sn3
SMILES	[Sn]([N]([Sn](C)(C)C)([Sn](C)(C)C)[Al](Cl)(Cl)C)(C)(C)C
Title of publication	Lewis base properties of tris(trimethylstannyl)amine: unusually short M‒N bonds of the adduct compounds [X3M·N(SnMe3)3] (X = Cl, Br; M = Al, Ga, In) and [Cl2(CH3)M·N(SnMe3)3] (M = Al, Ga)
Authors of publication	Q. m. Cheng; O. Stark; K. Merz; M. Winter; R. A. Fischer
Journal of publication	J. Chem. Soc., Dalton Trans.
Year of publication	2002
Journal issue	14
Pages of publication	2933 - 2936
a	12.7027 ± 0.0015 Å
b	13.0934 ± 0.0015 Å
c	12.7027 ± 0.0014 Å
α	90°
β	90°
γ	90°
Cell volume	2112.7 ± 0.4 Å³
Cell temperature	203 ± 2 K
Ambient diffraction temperature	203 ± 2 K
Number of distinct elements	6
Space group number	29
Hermann-Mauguin space group symbol	P c a 21
Hall space group symbol	P 2c -2ac
Residual factor for all reflections	0.0395
Residual factor for significantly intense reflections	0.0384
Weighted residual factors for significantly intense reflections	0.1046
Weighted residual factors for all reflections included in the refinement	0.1054
Goodness-of-fit parameter for all reflections included in the refinement	1.041
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
179821 (current)	2016-03-25	cif/7/01/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/01/17.	7011747.cif
134621	2015-04-02	The 'cif_fix_values' script with an option '--fix-only-weighting-scheme' and 'cif_filter' script were run over CIF files which included an incorrect value of the data item '_refine_ls_weighting_scheme'. Read the log for more details. There were more than 18k CIF files with values to modify. Usually these incorrect values include comment with formulas, but values of this data item must be an enumerator. The script creates new data item '_refine_ls_weighting_details' to store these comments with formulas, and writes the enumerator 'calc' as a value of data item '_refine_ls_weighting_scheme'. There exists some exceptions in the script.	7011747.cif
120443	2014-07-15	Adding 17924 DOIs guessed from source file names.	7011747.cif
35909	2012-02-26	cif/7/: reorganising range 7 into a prefix-directory tree.	7011747.cif
3896	2010-12-08	cif/7/ Adding CIFs with data from Dalton-Trans-2004-2000/.	7011747.cif