Crystallography Open Database

Information card for entry 7011748

Preview

Coordinates	7011748.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C10 H30 Cl2 Ga N Sn3
Calculated formula	C10 H30 Cl2 Ga N Sn3
SMILES	[Sn]([N]([Sn](C)(C)C)([Sn](C)(C)C)[Ga](Cl)(Cl)C)(C)(C)C
Title of publication	Lewis base properties of tris(trimethylstannyl)amine: unusually short M‒N bonds of the adduct compounds [X3M·N(SnMe3)3] (X = Cl, Br; M = Al, Ga, In) and [Cl2(CH3)M·N(SnMe3)3] (M = Al, Ga)
Authors of publication	Q. m. Cheng; O. Stark; K. Merz; M. Winter; R. A. Fischer
Journal of publication	J. Chem. Soc., Dalton Trans.
Year of publication	2002
Journal issue	14
Pages of publication	2933 - 2936
a	12.719 ± 0.003 Å
b	13.047 ± 0.003 Å
c	12.719 ± 0.003 Å
α	90°
β	90°
γ	90°
Cell volume	2110.7 ± 0.9 Å³
Cell temperature	203 ± 2 K
Ambient diffraction temperature	203 ± 2 K
Number of distinct elements	6
Space group number	29
Hermann-Mauguin space group symbol	P c a 21
Hall space group symbol	P 2c -2ac
Residual factor for all reflections	0.0748
Residual factor for significantly intense reflections	0.0691
Weighted residual factors for significantly intense reflections	0.1869
Weighted residual factors for all reflections included in the refinement	0.1909
Goodness-of-fit parameter for all reflections included in the refinement	1.072
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
179821 (current)	2016-03-25	cif/7/01/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/01/17.	7011748.cif
134621	2015-04-02	The 'cif_fix_values' script with an option '--fix-only-weighting-scheme' and 'cif_filter' script were run over CIF files which included an incorrect value of the data item '_refine_ls_weighting_scheme'. Read the log for more details. There were more than 18k CIF files with values to modify. Usually these incorrect values include comment with formulas, but values of this data item must be an enumerator. The script creates new data item '_refine_ls_weighting_details' to store these comments with formulas, and writes the enumerator 'calc' as a value of data item '_refine_ls_weighting_scheme'. There exists some exceptions in the script.	7011748.cif
120443	2014-07-15	Adding 17924 DOIs guessed from source file names.	7011748.cif
35909	2012-02-26	cif/7/: reorganising range 7 into a prefix-directory tree.	7011748.cif
5312	2011-01-03	cif/ Adding files, updated with the 'cif_fix_enum' program and the cif_core.dic dictionary. The enumerator values were fixed, mostly incorrect case, but also some values that had extra underscores, dashes or spaces. Unfortunately, 22 had non-ASCII characters with the 8-th bit set, and these got incorrectly interpreted as latin1 characters and converted to their UTF8 equivalents by Perl. To fix the structures, however, they need to be redeposited from the original files with the new CIFParser/cif_filter version.	7011748.cif
3896	2010-12-08	cif/7/ Adding CIFs with data from Dalton-Trans-2004-2000/.	7011748.cif