Crystallography Open Database

Information card for entry 1565762

Preview

Coordinates	1565762.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C18 H15 Al F28 O3 Si
Calculated formula	C18 H15 Al F28 O3 Si
Title of publication	Ga±catalyzed hydrosilylation? About the surprising system Ga+/HSiR3/olefin, proof of oxidation with subvalent Ga+ and silylium catalysis with perfluoroalkoxyaluminate anions
Authors of publication	Barthélemy, Antoine; Glootz, Kim; Scherer, Harald; Hanske, Annaleah; Krossing, Ingo
Journal of publication	Chemical Science
Year of publication	2022
Journal volume	13
Journal issue	2
Pages of publication	439 - 453
a	9.757 ± 0.005 Å
b	17.585 ± 0.01 Å
c	17.518 ± 0.009 Å
α	90°
β	90.187 ± 0.008°
γ	90°
Cell volume	3006 ± 3 Å³
Cell temperature	100 ± 2 K
Ambient diffraction temperature	100 ± 2 K
Number of distinct elements	6
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/n 1
Hall space group symbol	-P 2yn
Residual factor for all reflections	0.0524
Residual factor for significantly intense reflections	0.0366
Weighted residual factors for significantly intense reflections	0.0919
Weighted residual factors for all reflections included in the refinement	0.1017
Goodness-of-fit parameter for all reflections included in the refinement	1.034
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
272587 (current)	2022-02-04	cif/ Updating files of 1565762 Original log message: Adding full bibliography for 1565762.cif.	1565762.cif
271416	2021-12-15	cif/ Adding structures of 1565762 via cif-deposit CGI script.	1565762.cif