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Information card for entry 1570318
Preview
| Coordinates | 1570318.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C56 H52 Cl2 Ge O2 P2 |
|---|---|
| Calculated formula | C56 H52 Cl2 Ge O2 P2 |
| SMILES | [Ge](c1ccc2c3c(ccc(P(c4ccccc4)c4ccccc4)c13)CC2)(Cl)(Cl)c1ccc2c3c(ccc(P(c4ccccc4)c4ccccc4)c13)CC2.C1CCCO1.C1OCCC1 |
| Title of publication | Intramolecular donor-stabilized tetra-coordinated germanium(iv) di-cations and their Lewis acidic properties. |
| Authors of publication | Peddi, Balakrishna; Khan, Souvik; Gonnade, Rajesh G.; Yildiz, Cem B.; Majumdar, Moumita |
| Journal of publication | Chemical science |
| Year of publication | 2023 |
| Journal volume | 14 |
| Journal issue | 47 |
| Pages of publication | 13755 - 13764 |
| a | 22.1656 ± 0.0019 Å |
| b | 10.1752 ± 0.0009 Å |
| c | 20.7492 ± 0.0017 Å |
| α | 90° |
| β | 102.393 ± 0.003° |
| γ | 90° |
| Cell volume | 4570.7 ± 0.7 Å3 |
| Cell temperature | 150 ± 2 K |
| Ambient diffraction temperature | 150 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.0413 |
| Residual factor for significantly intense reflections | 0.0379 |
| Weighted residual factors for significantly intense reflections | 0.0978 |
| Weighted residual factors for all reflections included in the refinement | 0.1007 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.043 |
| Diffraction radiation wavelength | 1.54178 Å |
| Diffraction radiation type | CuKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 288746 (current) | 2024-01-06 | cif/ Updating files of 1570312, 1570313, 1570314, 1570315, 1570316, 1570317, 1570318, 1570319, 1570320, 1570321, 1570322, 1570323, 1570324, 1570325, 1570326, 1570327 Original log message: Adding full bibliography for 1570312--1570327.cif. |
1570318.cif |
| 287656 | 2023-11-17 | cif/ Adding structures of 1570312, 1570313, 1570314, 1570315, 1570316, 1570317, 1570318, 1570319, 1570320, 1570321, 1570322, 1570323, 1570324, 1570325, 1570326, 1570327 via cif-deposit CGI script. |
1570318.cif |
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Users of the data should acknowledge the original authors of the
structural data.