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Information card for entry 2018293
Preview
| Coordinates | 2018293.cif |
|---|---|
| Structure factors | 2018293.hkl |
| Original IUCr paper | HTML |
| Chemical name | (dimethylamine‒dimethylaminoborane‒borane- κ^2^<i>H</i>,<i>H</i>')dihydridobis(triisopropylphosphane- κ<i>P</i>)rhodium(III) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate |
|---|---|
| Formula | C54 H74 B3 F24 N2 P2 Rh |
| Calculated formula | C54 H74 B3 F24 N2 P2 Rh |
| Title of publication | A rhodium(III) complex of the linear diborazine H~3~B·NMe~2~BH~2~·NMe~2~H: an intermediate in the dehydrocoupling of H~3~B·NMe~2~H |
| Authors of publication | Chaplin, Adrian B.; Weller, Andrew S. |
| Journal of publication | Acta Crystallographica Section C |
| Year of publication | 2011 |
| Journal volume | 67 |
| Journal issue | 11 |
| Pages of publication | m355 - m358 |
| a | 12.8309 ± 0.0002 Å |
| b | 14.0813 ± 0.0002 Å |
| c | 19.1638 ± 0.0003 Å |
| α | 73.0175 ± 0.0006° |
| β | 76.4127 ± 0.0005° |
| γ | 86.6877 ± 0.0006° |
| Cell volume | 3218.56 ± 0.09 Å3 |
| Cell temperature | 150 ± 2 K |
| Ambient diffraction temperature | 150 ± 2 K |
| Number of distinct elements | 7 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.0612 |
| Residual factor for significantly intense reflections | 0.0472 |
| Weighted residual factors for significantly intense reflections | 0.1192 |
| Weighted residual factors for all reflections included in the refinement | 0.1293 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.015 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | Yes |
| Revision | Date | Message | Files |
|---|---|---|---|
| 180851 (current) | 2016-04-02 | cif/2/01/ (antanas@echidna) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 2/01/82. |
2018293.cif 2018293.hkl |
| 176760 | 2016-02-20 | cif/2/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 2/01. |
2018293.cif 2018293.hkl |
| 125873 | 2014-10-25 | cod/ (saulius@koala.ibt.lt) Adding DOIs to 1887 Acta Cryst. CIFs, their DOIs fetched using ACCE codes. |
2018293.cif 2018293.hkl |
| 88064 | 2013-08-29 | Adding _cod_database_fobs_code data item to all COD CIFs that have Fobs deposited and did not have this data item yet. | 2018293.cif 2018293.hkl |
| 31968 | 2012-01-03 | hkl/ Adding automatically assigned IUCr Fobs data for the rest of the year 2001 structures. |
2018293.cif 2018293.hkl |
| 31074 | 2011-12-12 | ../uploads/cif-deposit/cod/cif Adding structures of 2018293 via cif-deposit CGI script. |
2018293.cif |
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Users of the data should acknowledge the original authors of the
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