Crystallography Open Database

Information card for entry 4069924

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Structure parameters

Formula	C61 H64 Ge4 P2 Pt
Calculated formula	C61 H64 Ge4 P2 Pt
SMILES	[Pt]12([Ge]([Ge]([Ge]([Ge]1(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)[P](CC[P]2(C)C)(C)C.c1c(cccc1)C
Title of publication	Formation and Ring Expansion of Germaplatinacycles via Dehydrogenative Ge−Ge and Ge−Pt Bond-Forming Reactions
Authors of publication	Tanabe, Makoto; Hanzawa, Masaya; Ishikawa, Naoko; Osakada, Kohtaro
Journal of publication	Organometallics
Year of publication	2009
Journal volume	28
Journal issue	20
Pages of publication	6014
a	11.927 ± 0.002 Å
b	20.208 ± 0.004 Å
c	23.619 ± 0.004 Å
α	90°
β	90°
γ	90°
Cell volume	5692.7 ± 1.8 Å³
Cell temperature	113.1 K
Number of distinct elements	5
Space group number	19
Hermann-Mauguin space group symbol	P 21 21 21
Hall space group symbol	P 2ac 2ab
Residual factor for all reflections	0.0293
Residual factor for significantly intense reflections	0.0273
Weighted residual factors for significantly intense reflections	0.0479
Weighted residual factors for all reflections included in the refinement	0.0487
Goodness-of-fit parameter for all reflections included in the refinement	1.001
Diffraction radiation wavelength	0.7107 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
301829 (current)	2025-08-20	Add cross-references to PubChem compounds in COD range 4/06/ Each referenced PubChem compound corresponds to the full crystal structure.	4069924.cif
176467	2016-02-16	cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 4.	4069924.cif
91935	2013-12-29	cod/ (saulius@koala.ibt.lt) Adding DOIs that could be assigned unambiguously to the rest of COD CIFs.	4069924.cif
40512	2012-03-07	../uploads/cif-deposit/cod/cif Adding structures of 4069922, 4069923, 4069924 via cif-deposit CGI script.	4069924.cif