Crystallography Open Database

Information card for entry 4069923

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Structure parameters

Formula	C42 H46 Ge3 P2 Pt
Calculated formula	C42 H46 Ge3 P2 Pt
SMILES	[Pt]12([Ge]([Ge]([Ge]1(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)[P](C)(C)CC[P]2(C)C
Title of publication	Formation and Ring Expansion of Germaplatinacycles via Dehydrogenative Ge−Ge and Ge−Pt Bond-Forming Reactions
Authors of publication	Tanabe, Makoto; Hanzawa, Masaya; Ishikawa, Naoko; Osakada, Kohtaro
Journal of publication	Organometallics
Year of publication	2009
Journal volume	28
Journal issue	20
Pages of publication	6014
a	17.783 ± 0.007 Å
b	15.928 ± 0.008 Å
c	15.164 ± 0.005 Å
α	90°
β	102.04 ± 0.03°
γ	90°
Cell volume	4201 ± 3 Å³
Cell temperature	298.1 K
Number of distinct elements	5
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/n 1
Hall space group symbol	-P 2yn
Residual factor for all reflections	0.1378
Residual factor for significantly intense reflections	0.0443
Weighted residual factors for significantly intense reflections	0.1097
Weighted residual factors for all reflections included in the refinement	0.1416
Goodness-of-fit parameter for all reflections included in the refinement	1.009
Diffraction radiation wavelength	0.71069 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
301829 (current)	2025-08-20	Add cross-references to PubChem compounds in COD range 4/06/ Each referenced PubChem compound corresponds to the full crystal structure.	4069923.cif
176467	2016-02-16	cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 4.	4069923.cif
91935	2013-12-29	cod/ (saulius@koala.ibt.lt) Adding DOIs that could be assigned unambiguously to the rest of COD CIFs.	4069923.cif
40512	2012-03-07	../uploads/cif-deposit/cod/cif Adding structures of 4069922, 4069923, 4069924 via cif-deposit CGI script.	4069923.cif