Crystallography Open Database
- COD Home
- Accessing COD Data
- Add Your Data
- Documentation
Information card for entry 4071065
Preview
| Coordinates | 4071065.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Common name | Me2Si(phac-Rh(COD))2 |
|---|---|
| Chemical name | Bis(1,5-cyclooctadiene)[mu-[3,3'-[dimethylsilylenebis(1,4- phenylene)]bis(2,4-pentanedionato)]dirhodium chloroform solvate |
| Formula | C42 H52 Cl6 O4 Rh2 Si |
| Calculated formula | C42 H52 Cl6 O4 Rh2 Si |
| Title of publication | Organosilicon-Based Multifunctional β-Diketones and their Rhodium and Iridium Complexes |
| Authors of publication | Pariya, Chandi; Marcos, Yoseph S.; Zhang, Yixun; Fronczek, Frank R.; Maverick, Andrew W. |
| Journal of publication | Organometallics |
| Year of publication | 2008 |
| Journal volume | 27 |
| Journal issue | 17 |
| Pages of publication | 4318 |
| a | 13.507 ± 0.001 Å |
| b | 15.562 ± 0.001 Å |
| c | 22.709 ± 0.0015 Å |
| α | 70.463 ± 0.004° |
| β | 86.892 ± 0.003° |
| γ | 87.139 ± 0.003° |
| Cell volume | 4489.3 ± 0.5 Å3 |
| Cell temperature | 100 K |
| Ambient diffraction temperature | 100 K |
| Number of distinct elements | 6 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.115 |
| Residual factor for significantly intense reflections | 0.051 |
| Weighted residual factors for significantly intense reflections | 0.1091 |
| Weighted residual factors for all reflections included in the refinement | 0.137 |
| Goodness-of-fit parameter for all reflections included in the refinement | 0.987 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 178599 (current) | 2016-03-21 | cif/4/07/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/07/10. |
4071065.cif |
| 91935 | 2013-12-29 | cod/ (saulius@koala.ibt.lt) Adding DOIs that could be assigned unambiguously to the rest of COD CIFs. |
4071065.cif |
| 47256 | 2012-03-23 | cif/4/ Distributing the new range 4 CIFs into their appropriate prefixed subdirectories. |
4071065.cif |
| 43021 | 2012-03-13 | ../uploads/cif-deposit/cod/cif Adding structures of 4071061, 4071062, 4071063, 4071064, 4071065, 4071066, 4071067 via cif-deposit CGI script. |
4071065.cif |
All data in the COD and the database itself are dedicated to the
public domain and licensed under the
CC0
License
.
Users of the data should acknowledge the original authors of the
structural data.