Crystallography Open Database

Information card for entry 4074103

Preview

Coordinates	4074103.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C34 H53 O1.5 P2 Ru
Calculated formula	C34 H41 O1.52 P2 Ru
Title of publication	Unprecedented Formation of μ-Vinylidene Complexes from Phospharuthenocene and Acyl Chloride via Activation of the CO Double Bond
Authors of publication	Ogasawara, Masamichi; Sakamoto, Takeshi; Ito, Azumi; Ge, Yonghui; Nakajima, Kiyohiko; Takahashi, Tamotsu; Hayashi, Tamio
Journal of publication	Organometallics
Year of publication	2007
Journal volume	26
Journal issue	27
Pages of publication	6698
a	11.897 ± 0.003 Å
b	16.879 ± 0.004 Å
c	17.761 ± 0.006 Å
α	90°
β	90.759 ± 0.013°
γ	90°
Cell volume	3566.3 ± 1.7 Å³
Cell temperature	298.1 K
Number of distinct elements	5
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/a 1
Hall space group symbol	-P 2yab
Residual factor for significantly intense reflections	0.0615
Weighted residual factors for all reflections included in the refinement	0.2074
Goodness-of-fit parameter for all reflections included in the refinement	0.994
Diffraction radiation wavelength	0.71075 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
176467 (current)	2016-02-16	cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 4.	4074103.cif
120075	2014-07-11	Adding DOIs to range 4/07 structures.	4074103.cif
47256	2012-03-23	cif/4/ Distributing the new range 4 CIFs into their appropriate prefixed subdirectories.	4074103.cif
46743	2012-03-21	../uploads/cif-deposit/cod/cif Adding structures of 4074101, 4074102, 4074103 via cif-deposit CGI script.	4074103.cif