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Information card for entry 4122107
Preview
| Coordinates | 4122107.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C48 B F40 Sb |
|---|---|
| Calculated formula | C48 B F40 Sb |
| SMILES | c1(c(c(F)c(c(c1F)F)F)F)[Sb+](c1c(c(c(c(c1F)F)F)F)F)(c1c(c(c(c(c1F)F)F)F)F)c1c(c(c(c(c1F)F)F)F)F.Fc1c([B-](c2c(c(F)c(F)c(F)c2F)F)(c2c(c(F)c(F)c(F)c2F)F)c2c(c(F)c(F)c(F)c2F)F)c(c(F)c(c1F)F)F |
| Title of publication | [Sb(C6F5)4][B(C6F5)4]: An Air Stable, Lewis Acidic Stibonium Salt That Activates Strong Element-Fluorine Bonds. |
| Authors of publication | Pan, Baofei; Gabbaï, François P |
| Journal of publication | Journal of the American Chemical Society |
| Year of publication | 2014 |
| Journal volume | 136 |
| Journal issue | 27 |
| Pages of publication | 9564 - 9567 |
| a | 16.836 ± 0.003 Å |
| b | 16.836 ± 0.003 Å |
| c | 8.201 ± 0.003 Å |
| α | 90° |
| β | 90° |
| γ | 90° |
| Cell volume | 2324.6 ± 1 Å3 |
| Cell temperature | 110 ± 2 K |
| Ambient diffraction temperature | 110 ± 2 K |
| Number of distinct elements | 4 |
| Space group number | 82 |
| Hermann-Mauguin space group symbol | I -4 |
| Hall space group symbol | I -4 |
| Residual factor for all reflections | 0.0279 |
| Residual factor for significantly intense reflections | 0.0259 |
| Weighted residual factors for significantly intense reflections | 0.0583 |
| Weighted residual factors for all reflections included in the refinement | 0.0598 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.015 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 264242 (current) | 2021-04-16 | cif/4 Fixing some Z values and formulae |
4122107.cif |
| 176467 | 2016-02-16 | cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 4. |
4122107.cif |
| 130086 | 2015-01-23 | cod/ (robertas@burundukas) The 'cif_fix_values' program was applied to CIFs that have generated the validation messages containing tag '_exptl_crystal_density_meas'. 16946 CIFs had a values that were perceived as 'not measured' and they were changed to '?'. The total of 17089 CIFs was changed. Those that were not corrected by 'cif_fix_values' were reformatted by the parser (e.g. a doi tag was moved to another place). The processing command was: mysql -u cod_reader -h www.crystallography.net cod -e \ 'select distinct codid from validation \ where message like \ "%tag%_exptl_crystal_density_meas'\''%"' -NB \ | xargs -i sh -c 'cif_fix_values {} \ | cif_filter --add-cif-header {} \ | sponge {}' |
4122107.cif |
| 121261 | 2014-08-05 | cif/ Updating files of 4122105, 4122106, 4122107 Original log message: Adding full bibliography for 4122105--4122107.cif. |
4122107.cif |
| 118248 | 2014-06-28 | cif/ Adding structures of 4122105, 4122106, 4122107 via cif-deposit CGI script. |
4122107.cif |
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Users of the data should acknowledge the original authors of the
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