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Information card for entry 4309247
Preview
| Coordinates | 4309247.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C60 H60 Cl N8 O8 Rh2 |
|---|---|
| Calculated formula | C60 H60 Cl N8 O8 Rh2 |
| SMILES | C1=[N](c2ccc(OC)cc2)[Rh]234[Rh](N1c1ccc(cc1)OC)(Cl)([N](=CN2c1ccc(OC)cc1)c1ccc(cc1)OC)(N(C=[N]3c1ccc(OC)cc1)c1ccc(cc1)OC)[N](=CN4c1ccc(OC)cc1)c1ccc(cc1)OC |
| Title of publication | Photoinduced One-Electron Reduction of Alkyl Halides by Dirhodium(II,II) Tetraformamidinates and a Related Complex with Visible Light |
| Authors of publication | Daniel A. Lutterman; Natalya N. Degtyareva; Dean H. Johnston; Judith C. Gallucci; Judith L. Eglin; Claudia Turro |
| Journal of publication | Inorganic Chemistry |
| Year of publication | 2005 |
| Journal volume | 44 |
| Pages of publication | 5388 - 5396 |
| a | 14.135 ± 0.001 Å |
| b | 14.135 ± 0.001 Å |
| c | 30.314 ± 0.004 Å |
| α | 90° |
| β | 90° |
| γ | 90° |
| Cell volume | 6056.7 ± 1 Å3 |
| Cell temperature | 200 ± 2 K |
| Ambient diffraction temperature | 200 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 130 |
| Hermann-Mauguin space group symbol | P 4/n c c :2 |
| Hall space group symbol | -P 4a 2ac |
| Residual factor for all reflections | 0.0708 |
| Residual factor for significantly intense reflections | 0.0402 |
| Weighted residual factors for significantly intense reflections | 0.1034 |
| Weighted residual factors for all reflections included in the refinement | 0.1136 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.089 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 179130 (current) | 2016-03-23 | cif/4/30/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/30/92. |
4309247.cif |
| 120081 | 2014-07-12 | Adding DOIs to range 4/30 structures. | 4309247.cif |
| 34330 | 2012-02-24 | cif/4/ Reorganising CIF range 4 into a prefix tree. |
4309247.cif |
| 1526 | 2010-09-26 | cif/4/ Adding new CIFs from Inorg. Chem. 2005 deposited via Web deposition site to the COD test database (and transferede to the main COD database after renaming). |
4309247.cif |
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