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Information card for entry 4309432
Preview
Coordinates | 4309432.cif |
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Original paper (by DOI) | HTML |
Formula | C24 H21 Cl2 N6 Rh |
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Calculated formula | C24 H21 Cl2 N6 Rh |
SMILES | [Rh]12(Cl)(Cl)([NH2]c3ccccc3[N]1=Nc1c2cccc1)[NH2]c1ccccc1N=Nc1ccccc1 |
Title of publication | Reactions of 2-(Arylazo) Aniline with RhCl3: Synthesis and Structure of New Cyclometalated Complexes of Rh(III) and Recognition of RhCl3 Assisted Azo (NN) Cleavage |
Authors of publication | Jahar lal Pratihar; Nilkamal Maiti; Surajit Chattopadhyay |
Journal of publication | Inorganic Chemistry |
Year of publication | 2005 |
Journal volume | 44 |
Pages of publication | 6111 - 6114 |
a | 27.216 ± 0.003 Å |
b | 10.2993 ± 0.0008 Å |
c | 20.5772 ± 0.0019 Å |
α | 90° |
β | 122.024 ± 0.004° |
γ | 90° |
Cell volume | 4890.2 ± 0.8 Å3 |
Cell temperature | 273 ± 2 K |
Ambient diffraction temperature | 273 ± 2 K |
Number of distinct elements | 5 |
Space group number | 15 |
Hermann-Mauguin space group symbol | C 1 2/c 1 |
Hall space group symbol | -C 2yc |
Residual factor for all reflections | 0.0698 |
Residual factor for significantly intense reflections | 0.0363 |
Weighted residual factors for significantly intense reflections | 0.0782 |
Weighted residual factors for all reflections included in the refinement | 0.0871 |
Goodness-of-fit parameter for all reflections included in the refinement | 0.984 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
Revision | Date | Message | Files |
---|---|---|---|
179132 (current) | 2016-03-23 | cif/4/30/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/30/94. |
4309432.cif |
120081 | 2014-07-12 | Adding DOIs to range 4/30 structures. | 4309432.cif |
34330 | 2012-02-24 | cif/4/ Reorganising CIF range 4 into a prefix tree. |
4309432.cif |
1526 | 2010-09-26 | cif/4/ Adding new CIFs from Inorg. Chem. 2005 deposited via Web deposition site to the COD test database (and transferede to the main COD database after renaming). |
4309432.cif |
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Users of the data should acknowledge the original authors of the
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