Crystallography Open Database

Information card for entry 4309433

Preview

Coordinates	4309433.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C36 H34 Cl4 N8 O Rh2
Calculated formula	C36 H34 Cl4 N8 O Rh2
SMILES	[Rh]12(Cl)(Cl)(c3ccccc3N=[N]1c1ccccc1[NH2]2)[NH2]c1ccccc1.O
Title of publication	Reactions of 2-(Arylazo) Aniline with RhCl3: Synthesis and Structure of New Cyclometalated Complexes of Rh(III) and Recognition of RhCl3 Assisted Azo (NN) Cleavage
Authors of publication	Jahar lal Pratihar; Nilkamal Maiti; Surajit Chattopadhyay
Journal of publication	Inorganic Chemistry
Year of publication	2005
Journal volume	44
Pages of publication	6111 - 6114
a	12.251 ± 0.012 Å
b	12.438 ± 0.012 Å
c	13.836 ± 0.013 Å
α	91.21 ± 0.02°
β	98.51 ± 0.02°
γ	101.85 ± 0.03°
Cell volume	2038 ± 3 Å³
Cell temperature	273 ± 2 K
Ambient diffraction temperature	273 ± 2 K
Number of distinct elements	6
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0698
Residual factor for significantly intense reflections	0.0396
Weighted residual factors for significantly intense reflections	0.0901
Weighted residual factors for all reflections included in the refinement	0.1025
Goodness-of-fit parameter for all reflections included in the refinement	1.021
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
179132 (current)	2016-03-23	cif/4/30/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/30/94.	4309433.cif
120081	2014-07-12	Adding DOIs to range 4/30 structures.	4309433.cif
34330	2012-02-24	cif/4/ Reorganising CIF range 4 into a prefix tree.	4309433.cif
1526	2010-09-26	cif/4/ Adding new CIFs from Inorg. Chem. 2005 deposited via Web deposition site to the COD test database (and transferede to the main COD database after renaming).	4309433.cif