Crystallography Open Database

Information card for entry 4309487

Preview

Coordinates	4309487.cif
Original paper (by DOI)	HTML

Structure parameters

Common name	Mg{(CH3)[NH(Si(iPr)3)]} * x THF
Formula	C28 H66 Mg2 N2 O2 Si2
Calculated formula	C28 H66 Mg2 N2 O2 Si2
Title of publication	Ligand Exchange Reaction Between an Alkylzinc Primary Amide and a Dialkylmagnesium Compound: Crystal Structures of [(thf)MeMg-μ-N(H)SiiPr3]2 and (tmeda)Mg[N(H)SiiPr3]2
Authors of publication	Matthias Westerhausen; Tobias Bollwein; Nikolaos Makropoulos; Holger Piotrowski
Journal of publication	Inorganic Chemistry
Year of publication	2005
Journal volume	44
Pages of publication	6439 - 6444
a	19.8237 ± 0.0016 Å
b	20.3413 ± 0.0012 Å
c	9.0722 ± 0.0006 Å
α	90°
β	95.021 ± 0.009°
γ	90°
Cell volume	3644.2 ± 0.4 Å³
Cell temperature	200 ± 3 K
Ambient diffraction temperature	200 ± 3 K
Number of distinct elements	6
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/n 1
Hall space group symbol	-P 2yn
Residual factor for all reflections	0.0581
Residual factor for significantly intense reflections	0.0439
Weighted residual factors for significantly intense reflections	0.1177
Weighted residual factors for all reflections included in the refinement	0.1235
Goodness-of-fit parameter for all reflections included in the refinement	0.994
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
179132 (current)	2016-03-23	cif/4/30/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/30/94.	4309487.cif
120081	2014-07-12	Adding DOIs to range 4/30 structures.	4309487.cif
34330	2012-02-24	cif/4/ Reorganising CIF range 4 into a prefix tree.	4309487.cif
1526	2010-09-26	cif/4/ Adding new CIFs from Inorg. Chem. 2005 deposited via Web deposition site to the COD test database (and transferede to the main COD database after renaming).	4309487.cif