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Information card for entry 4309488
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| Coordinates | 4309488.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Common name | Mg-TMEDA-NHSi(iPr)3 |
|---|---|
| Formula | C24 H60 Mg N4 Si2 |
| Calculated formula | C24 H60 Mg N4 Si2 |
| SMILES | [Si](C(C)C)(C(C)C)(C(C)C)N[Mg]1(N[Si](C(C)C)(C(C)C)C(C)C)[N](C)(C)CC[N]1(C)C |
| Title of publication | Ligand Exchange Reaction Between an Alkylzinc Primary Amide and a Dialkylmagnesium Compound: Crystal Structures of [(thf)MeMg-μ-N(H)SiiPr3]2 and (tmeda)Mg[N(H)SiiPr3]2 |
| Authors of publication | Matthias Westerhausen; Tobias Bollwein; Nikolaos Makropoulos; Holger Piotrowski |
| Journal of publication | Inorganic Chemistry |
| Year of publication | 2005 |
| Journal volume | 44 |
| Pages of publication | 6439 - 6444 |
| a | 15.93 ± 0.0012 Å |
| b | 10.2952 ± 0.0006 Å |
| c | 19.9613 ± 0.0015 Å |
| α | 90° |
| β | 102.449 ± 0.009° |
| γ | 90° |
| Cell volume | 3196.7 ± 0.4 Å3 |
| Cell temperature | 200 ± 3 K |
| Ambient diffraction temperature | 200 ± 3 K |
| Number of distinct elements | 5 |
| Space group number | 15 |
| Hermann-Mauguin space group symbol | C 1 2/c 1 |
| Hall space group symbol | -C 2yc |
| Residual factor for all reflections | 0.0638 |
| Residual factor for significantly intense reflections | 0.0461 |
| Weighted residual factors for significantly intense reflections | 0.1207 |
| Weighted residual factors for all reflections included in the refinement | 0.1282 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.02 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 179132 (current) | 2016-03-23 | cif/4/30/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/30/94. |
4309488.cif |
| 120081 | 2014-07-12 | Adding DOIs to range 4/30 structures. | 4309488.cif |
| 34330 | 2012-02-24 | cif/4/ Reorganising CIF range 4 into a prefix tree. |
4309488.cif |
| 1526 | 2010-09-26 | cif/4/ Adding new CIFs from Inorg. Chem. 2005 deposited via Web deposition site to the COD test database (and transferede to the main COD database after renaming). |
4309488.cif |
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Users of the data should acknowledge the original authors of the
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