Crystallography Open Database

Information card for entry 4347922

Preview

Coordinates	4347922.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C36 H52 F4 N4 Si4 U
Calculated formula	C36 H52 F4 N4 Si4 U
SMILES	[U]12(N([Si](C)(C)C)c3c(cccc3)[F]1)(N([Si](C)(C)C)c1c(cccc1)[F]2)(N([Si](C)(C)C)c1c(cccc1)F)N([Si](C)(C)C)c1c(cccc1)F
Title of publication	Cerium(III) and Uranium(IV) Complexes of the 2-Fluorophenyl Trimethylsilyl Amide Ligand: C-F →Ln/An Interactions that Modulate the Coordination Spheres of f-Block Elements.
Authors of publication	Yin, Haolin; Carroll, Patrick J.; Schelter, Eric J.
Journal of publication	Inorganic chemistry
Year of publication	2016
Journal volume	55
Journal issue	11
Pages of publication	5684 - 5692
a	11.1338 ± 0.0004 Å
b	20.1704 ± 0.0006 Å
c	18.7326 ± 0.0006 Å
α	90°
β	103.791 ± 0.001°
γ	90°
Cell volume	4085.6 ± 0.2 Å³
Cell temperature	100 K
Ambient diffraction temperature	100 ± 1 K
Number of distinct elements	6
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.0168
Residual factor for significantly intense reflections	0.0152
Weighted residual factors for significantly intense reflections	0.0437
Weighted residual factors for all reflections included in the refinement	0.0508
Goodness-of-fit parameter for all reflections included in the refinement	1.312
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
232587 (current)	2019-11-23	cif/ Adding structures of 4347917, 4347918, 4347919, 4347920, 4347921, 4347922 via cif-deposit CGI script.	4347922.cif