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Information card for entry 7005806
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| Coordinates | 7005806.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Common name | dibromo-bis(allyldiisopropylphosphine)-nickel (ii) |
|---|---|
| Chemical name | dibromo-bis(allyldiisopropylphosphine)-nickel (II) |
| Formula | C18 H38 Br2 Ni P2 |
| Calculated formula | C18 H38 Br2 Ni P2 |
| SMILES | CC(C)[P]([Ni](Br)([P](CC=C)(C(C)C)C(C)C)Br)(CC=C)C(C)C |
| Title of publication | Oligomerization and regioselective hydrosilylation of styrenes catalyzed by cationic allyl nickel complexes bearing allylphosphine ligands. |
| Authors of publication | Hyder, Iqbal; Jiménez-Tenorio, Manuel; Puerta, M. Carmen; Valerga, Pedro |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2007 |
| Journal issue | 28 |
| Pages of publication | 3000 - 3009 |
| a | 8.2979 ± 0.0017 Å |
| b | 15.238 ± 0.003 Å |
| c | 9.339 ± 0.0019 Å |
| α | 90° |
| β | 104.4 ± 0.03° |
| γ | 90° |
| Cell volume | 1143.8 ± 0.4 Å3 |
| Cell temperature | 100 ± 2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 5 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/n 1 |
| Hall space group symbol | -P 2yn |
| Residual factor for all reflections | 0.0272 |
| Residual factor for significantly intense reflections | 0.0265 |
| Weighted residual factors for significantly intense reflections | 0.0588 |
| Weighted residual factors for all reflections included in the refinement | 0.0592 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.033 |
| Diffraction radiation probe | x-ray |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 179762 (current) | 2016-03-25 | cif/7/00/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/00/58. |
7005806.cif |
| 120443 | 2014-07-15 | Adding 17924 DOIs guessed from source file names. | 7005806.cif |
| 35909 | 2012-02-26 | cif/7/: reorganising range 7 into a prefix-directory tree. | 7005806.cif |
| 1186 | 2010-06-03 | Adding CIFs from Chem-Comm-2010_20-22/ and Dalton-Trans-2007/ processing. | 7005806.cif |
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