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Information card for entry 7005807
Preview
| Coordinates | 7005807.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Common name | (Trihapto-2-methyl-allyl)-bis(diisopropyl-allyl-phosphino)- nickel (ii) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate |
|---|---|
| Chemical name | (Trihapto-2-methyl-allyl)-bis(diisopropyl-allyl-phosphino)-nickel (II) tetrakis{3,5-bis(trifluoromethyl)phenyl}borate |
| Formula | C54 H57 B F24 Ni P2 |
| Calculated formula | C54 H57 B F24 Ni P2 |
| Title of publication | Oligomerization and regioselective hydrosilylation of styrenes catalyzed by cationic allyl nickel complexes bearing allylphosphine ligands. |
| Authors of publication | Hyder, Iqbal; Jiménez-Tenorio, Manuel; Puerta, M. Carmen; Valerga, Pedro |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2007 |
| Journal issue | 28 |
| Pages of publication | 3000 - 3009 |
| a | 12.799 ± 0.003 Å |
| b | 11.98 ± 0.002 Å |
| c | 37.938 ± 0.008 Å |
| α | 90° |
| β | 99.13 ± 0.03° |
| γ | 90° |
| Cell volume | 5743 ± 2 Å3 |
| Cell temperature | 100 ± 2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.086 |
| Residual factor for significantly intense reflections | 0.077 |
| Weighted residual factors for significantly intense reflections | 0.154 |
| Weighted residual factors for all reflections included in the refinement | 0.1594 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.07 |
| Diffraction radiation probe | x-ray |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 179762 (current) | 2016-03-25 | cif/7/00/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/00/58. |
7005807.cif |
| 120443 | 2014-07-15 | Adding 17924 DOIs guessed from source file names. | 7005807.cif |
| 35909 | 2012-02-26 | cif/7/: reorganising range 7 into a prefix-directory tree. | 7005807.cif |
| 1186 | 2010-06-03 | Adding CIFs from Chem-Comm-2010_20-22/ and Dalton-Trans-2007/ processing. | 7005807.cif |
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