Crystallography Open Database

Information card for entry 7008803

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Coordinates	7008803.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C46 H98 Ce2 F6 O19 S2 Si4
Calculated formula	C49 H76 Ce2 F6 O16 S2 Si4
Title of publication	The coordination chemistry of the C1-symmetric bis(silyl)methyl ligand [CH(SiMe3){SiMe(OMe)2}]- revisited: Li/M- (M = Zn, Tl, Ce), Li4- or Ce2-methoxy-bridged alkyls.
Authors of publication	Hitchcock, Peter B.; Huang, Qigu; Lappert, Michael F.; Zhou, Meisu
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2005
Journal issue	18
Pages of publication	2988 - 2993
a	10.6698 ± 0.001 Å
b	12.9987 ± 0.0002 Å
c	13.1909 ± 0.0002 Å
α	86.761 ± 0.001°
β	80.802 ± 0.001°
γ	70.229 ± 0.001°
Cell volume	1699.5 ± 0.16 Å³
Cell temperature	173 ± 2 K
Ambient diffraction temperature	173 ± 2 K
Number of distinct elements	7
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0286
Residual factor for significantly intense reflections	0.0266
Weighted residual factors for significantly intense reflections	0.0698
Weighted residual factors for all reflections included in the refinement	0.0713
Goodness-of-fit parameter for all reflections included in the refinement	1.062
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
179792 (current)	2016-03-25	cif/7/00/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/00/88.	7008803.cif
120443	2014-07-15	Adding 17924 DOIs guessed from source file names.	7008803.cif
35909	2012-02-26	cif/7/: reorganising range 7 into a prefix-directory tree.	7008803.cif
1504	2010-09-08	cif/7/ Adding data extracted from RSC 2005 and 2006 year publications.	7008803.cif