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Information card for entry 7009155
Preview
| Coordinates | 7009155.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Chemical name | Tri(tert.butyl)gallium-tri(isopropyl)antimon-adduct |
|---|---|
| Formula | C21 H48 Ga Sb |
| Calculated formula | C21 H48 Ga Sb |
| SMILES | [Sb](C(C)C)(C(C)C)(C(C)C)[Ga](C(C)(C)C)(C(C)(C)C)C(C)(C)C |
| Title of publication | Synthesis and structural characterization of the first completely alkyl-substituted Ga‒Sb Lewis acid‒base adducts † |
| Authors of publication | Schulz, Stephan; Nieger, Martin |
| Journal of publication | Journal of the Chemical Society, Dalton Transactions |
| Year of publication | 2000 |
| Journal issue | 5 |
| Pages of publication | 639 |
| a | 13.6128 ± 0.0002 Å |
| b | 9.0089 ± 0.0002 Å |
| c | 20.0307 ± 0.0002 Å |
| α | 90° |
| β | 91.75 ± 0.001° |
| γ | 90° |
| Cell volume | 2455.35 ± 0.07 Å3 |
| Cell temperature | 123 ± 2 K |
| Ambient diffraction temperature | 123 ± 2 K |
| Number of distinct elements | 4 |
| Space group number | 14 |
| Hermann-Mauguin space group symbol | P 1 21/c 1 |
| Hall space group symbol | -P 2ybc |
| Residual factor for all reflections | 0.0214 |
| Residual factor for significantly intense reflections | 0.0198 |
| Weighted residual factors for significantly intense reflections | 0.0482 |
| Weighted residual factors for all reflections included in the refinement | 0.0488 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.082 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 179795 (current) | 2016-03-25 | cif/7/00/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/00/91. |
7009155.cif |
| 130086 | 2015-01-23 | cod/ (robertas@burundukas) The 'cif_fix_values' program was applied to CIFs that have generated the validation messages containing tag '_exptl_crystal_density_meas'. 16946 CIFs had a values that were perceived as 'not measured' and they were changed to '?'. The total of 17089 CIFs was changed. Those that were not corrected by 'cif_fix_values' were reformatted by the parser (e.g. a doi tag was moved to another place). The processing command was: mysql -u cod_reader -h www.crystallography.net cod -e \ 'select distinct codid from validation \ where message like \ "%tag%_exptl_crystal_density_meas'\''%"' -NB \ | xargs -i sh -c 'cif_fix_values {} \ | cif_filter --add-cif-header {} \ | sponge {}' |
7009155.cif |
| 120443 | 2014-07-15 | Adding 17924 DOIs guessed from source file names. | 7009155.cif |
| 35909 | 2012-02-26 | cif/7/: reorganising range 7 into a prefix-directory tree. | 7009155.cif |
| 3896 | 2010-12-08 | cif/7/ Adding CIFs with data from Dalton-Trans-2004-2000/. |
7009155.cif |
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Users of the data should acknowledge the original authors of the
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