Crystallography Open Database

Information card for entry 7021008

Preview

Coordinates	7021008.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C44 H104 Cl4 Cu4 N8 O Si4 Sn4
Calculated formula	C44 H104 Cl4 Cu4 N8 O Si4 Sn4
SMILES	[Sn]12([Cu]3([Sn]4(Cl)[N]([Cu][N]1([Si](N2C(C)(C)C)(C)C)C(C)(C)C)([Si](N4C(C)(C)C)(C)C)C(C)(C)C)[Sn]1(Cl)[N]2([Cu]4[Cu]([N]1([Si]2(C)C)C(C)(C)C)[N]1([Sn]3(Cl)[N]4([Si]1(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C)Cl.O1CCCC1
Title of publication	Heavier carbene analogues and their derivatives as κ-El, κ(2)-El,N, and κ(2)-N,N' ligands: different reactivity patterns for acyclic and cyclic diamidogermylenes and -stannylenes.
Authors of publication	West, Joseph K.; Fondong, Gregory L.; Noll, Bruce C.; Stahl, Lothar
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2013
Journal volume	42
Journal issue	11
Pages of publication	3835 - 3842
a	15.051 ± 0.002 Å
b	21.782 ± 0.003 Å
c	25.431 ± 0.003 Å
α	108.904 ± 0.002°
β	98.938 ± 0.002°
γ	91.934 ± 0.002°
Cell volume	7760.2 ± 1.7 Å³
Cell temperature	173.15 K
Ambient diffraction temperature	173.15 K
Number of distinct elements	8
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0483
Residual factor for significantly intense reflections	0.039
Weighted residual factors for significantly intense reflections	0.1014
Weighted residual factors for all reflections included in the refinement	0.1054
Goodness-of-fit parameter for all reflections included in the refinement	1.045
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
179915 (current)	2016-03-25	cif/7/02/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/02/10.	7021008.cif
75551	2013-03-10	cif/ Adding structures of 7021007, 7021008, 7021009 via cif-deposit CGI script.	7021008.cif