Crystallography Open Database

Information card for entry 7022043

7022042 << 7022043 >> 7022044

Preview

Coordinates	7022043.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C35 H61 N2 O Rh
Calculated formula	C35 H61 N2 O Rh
SMILES	[Rh]123(O)(=C4N(C=CN4C4CCCCCCCCCCC4)C4CCCCCCCCCCC4)[CH]4=[CH]1CC[CH]2=[CH]3CC4
Title of publication	Well-defined NHC-rhodium hydroxide complexes as alkene hydrosilylation and dehydrogenative silylation catalysts.
Authors of publication	Truscott, Byron J.; Slawin, Alexandra M. Z.; Nolan, Steven P.
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2013
Journal volume	42
Journal issue	1
Pages of publication	270 - 276
a	29.075 ± 0.007 Å
b	15.582 ± 0.003 Å
c	14.62 ± 0.003 Å
α	90°
β	90°
γ	90°
Cell volume	6624 ± 2 Å³
Cell temperature	93 ± 2 K
Ambient diffraction temperature	93 ± 2 K
Number of distinct elements	5
Space group number	61
Hermann-Mauguin space group symbol	P b c a
Hall space group symbol	-P 2ac 2ab
Residual factor for all reflections	0.1134
Residual factor for significantly intense reflections	0.1109
Weighted residual factors for significantly intense reflections	0.2333
Weighted residual factors for all reflections included in the refinement	0.2345
Goodness-of-fit parameter for all reflections included in the refinement	1.331
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
179925 (current)	2016-03-25	cif/7/02/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/02/20.	7022043.cif
89952	2013-11-17	cif/ Adding structures of 7022043, 7022044 via cif-deposit CGI script.	7022043.cif