Crystallography Open Database

Information card for entry 7022044

7022043 << 7022044 >> 7022045

Preview

Coordinates	7022044.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C19 H33 N2 O Rh
Calculated formula	C19 H33 N2 O Rh
SMILES	[Rh]123(O)(=C4N(C(=C(N4C(C)C)C)C)C(C)C)[CH]4=[CH]1CC[CH]2=[CH]3CC4
Title of publication	Well-defined NHC-rhodium hydroxide complexes as alkene hydrosilylation and dehydrogenative silylation catalysts.
Authors of publication	Truscott, Byron J.; Slawin, Alexandra M. Z.; Nolan, Steven P.
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2013
Journal volume	42
Journal issue	1
Pages of publication	270 - 276
a	14.999 ± 0.005 Å
b	9.986 ± 0.003 Å
c	13.137 ± 0.004 Å
α	90°
β	106.884 ± 0.008°
γ	90°
Cell volume	1882.8 ± 1 Å³
Cell temperature	93 ± 2 K
Ambient diffraction temperature	93 ± 2 K
Number of distinct elements	5
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.0513
Residual factor for significantly intense reflections	0.0422
Weighted residual factors for significantly intense reflections	0.1075
Weighted residual factors for all reflections included in the refinement	0.1164
Goodness-of-fit parameter for all reflections included in the refinement	1.146
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
179925 (current)	2016-03-25	cif/7/02/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/02/20.	7022044.cif
89952	2013-11-17	cif/ Adding structures of 7022043, 7022044 via cif-deposit CGI script.	7022044.cif