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Information card for entry 7024699
Preview
| Coordinates | 7024699.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C150 H118 La2 N2 O9 Si4 |
|---|---|
| Calculated formula | C150 H118 La2 N2 O9 Si4 |
| SMILES | [La]1234([n]5c(c6c(O1)c([Si](c1ccccc1)(c1ccccc1)c1ccccc1)cc1ccccc61)cccc5c1c(O2)c([Si](c2ccccc2)(c2ccccc2)c2ccccc2)cc2ccccc12)([O]1CCCC1)([OH2])[La]12([n]5c(c6c(O1)c([Si](c1ccccc1)(c1ccccc1)c1ccccc1)cc1ccccc61)cccc5c1c(O2)c([Si](c2ccccc2)(c2ccccc2)c2ccccc2)cc2ccccc12)([OH2])([OH]3)[OH]4.c1ccccc1.c1ccccc1.c1ccccc1.c1ccccc1 |
| Title of publication | Group 3 metal complexes supported by tridentate pyridine- and thiophene-linked bis(naphtholate) ligands: synthesis, structure, and use in stereoselective ring-opening polymerization of racemic lactide and beta-butyrolactone. |
| Authors of publication | Grunova, Ekaterina; Kirillov, Evgueni; Roisnel, Thierry; Carpentier, Jean-François |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2010 |
| Journal volume | 39 |
| Journal issue | 29 |
| Pages of publication | 6739 - 6752 |
| a | 22.4713 ± 0.0009 Å |
| b | 29.6425 ± 0.0013 Å |
| c | 39.18 ± 0.0014 Å |
| α | 90° |
| β | 90° |
| γ | 90° |
| Cell volume | 26098 ± 1.8 Å3 |
| Cell temperature | 100 ± 2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 6 |
| Space group number | 61 |
| Hermann-Mauguin space group symbol | P c a b |
| Hall space group symbol | -P 2bc 2ac |
| Residual factor for all reflections | 0.1255 |
| Residual factor for significantly intense reflections | 0.0828 |
| Weighted residual factors for significantly intense reflections | 0.1829 |
| Weighted residual factors for all reflections included in the refinement | 0.2032 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.032 |
| Diffraction radiation probe | x-ray |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 179951 (current) | 2016-03-25 | cif/7/02/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/02/46. |
7024699.cif |
| 92639 | 2014-01-12 | cif/ Adding structures of 7024694, 7024695, 7024696, 7024697, 7024698, 7024699 via cif-deposit CGI script. |
7024699.cif |
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Users of the data should acknowledge the original authors of the
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