Crystallography Open Database
- COD Home
- Accessing COD Data
- Add Your Data
- Documentation
Information card for entry 7036099
Preview
| Coordinates | 7036099.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Formula | C32 H76 I2 Mg2 N2 O2 Si4 |
|---|---|
| Calculated formula | C32 H76 I2 Mg2 N2 O2 Si4 |
| SMILES | C[Si](C)(C(C)(C)C)N([Mg]1([I][Mg]([I]1)(N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)[O]1CCCC1)[O]1CCCC1)[Si](C)(C)C(C)(C)C |
| Title of publication | Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes. |
| Authors of publication | Goodwin, Conrad A. P.; Smith, Alex; Ortu, Fabrizio; Vitorica-Yrezabal, Iñigo J; Mills, David P. |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2016 |
| Journal volume | 45 |
| Journal issue | 14 |
| Pages of publication | 6004 - 6014 |
| a | 31.4565 ± 0.0018 Å |
| b | 10.5855 ± 0.0005 Å |
| c | 14.2235 ± 0.0007 Å |
| α | 90° |
| β | 105.608 ± 0.005° |
| γ | 90° |
| Cell volume | 4561.5 ± 0.4 Å3 |
| Cell temperature | 120 ± 2 K |
| Ambient diffraction temperature | 120 ± 2 K |
| Number of distinct elements | 7 |
| Space group number | 15 |
| Hermann-Mauguin space group symbol | C 1 2/c 1 |
| Hall space group symbol | -C 2yc |
| Residual factor for all reflections | 0.0654 |
| Residual factor for significantly intense reflections | 0.0496 |
| Weighted residual factors for significantly intense reflections | 0.1271 |
| Weighted residual factors for all reflections included in the refinement | 0.1389 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.066 |
| Diffraction radiation probe | x-ray |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 181728 (current) | 2016-04-05 | cif/ Updating files of 7036089, 7036090, 7036091, 7036092, 7036093, 7036094, 7036095, 7036096, 7036097, 7036098, 7036099, 7036100 Original log message: Adding full bibliography for 7036089--7036100.cif. |
7036099.cif |
| 152957 | 2015-08-06 | cif/ Adding structures of 7036089, 7036090, 7036091, 7036092, 7036093, 7036094, 7036095, 7036096, 7036097, 7036098, 7036099, 7036100 via cif-deposit CGI script. |
7036099.cif |
All data in the COD and the database itself are dedicated to the
public domain and licensed under the
CC0
License
.
Users of the data should acknowledge the original authors of the
structural data.