Crystallography Open Database

Information card for entry 7036100

Preview

Coordinates	7036100.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C42 H94 Mg2 N2 Si4
Calculated formula	C42 H94 Mg2 N2 Si4
Title of publication	Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes.
Authors of publication	Goodwin, Conrad A. P.; Smith, Alex; Ortu, Fabrizio; Vitorica-Yrezabal, Iñigo J; Mills, David P.
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2016
Journal volume	45
Journal issue	14
Pages of publication	6004 - 6014
a	25.268 ± 0.003 Å
b	16.935 ± 0.004 Å
c	13.2403 ± 0.0017 Å
α	90°
β	117.029 ± 0.012°
γ	90°
Cell volume	5046.9 ± 1.6 Å³
Cell temperature	150.01 ± 0.1 K
Ambient diffraction temperature	150.01 ± 0.1 K
Number of distinct elements	5
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Residual factor for all reflections	0.1424
Residual factor for significantly intense reflections	0.1003
Weighted residual factors for significantly intense reflections	0.1918
Weighted residual factors for all reflections included in the refinement	0.206
Goodness-of-fit parameter for all reflections included in the refinement	1.13
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
181728 (current)	2016-04-05	cif/ Updating files of 7036089, 7036090, 7036091, 7036092, 7036093, 7036094, 7036095, 7036096, 7036097, 7036098, 7036099, 7036100 Original log message: Adding full bibliography for 7036089--7036100.cif.	7036100.cif
152957	2015-08-06	cif/ Adding structures of 7036089, 7036090, 7036091, 7036092, 7036093, 7036094, 7036095, 7036096, 7036097, 7036098, 7036099, 7036100 via cif-deposit CGI script.	7036100.cif