Crystallography Open Database

Information card for entry 7061677

Preview

Coordinates	7061677.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C30 H66 O7 P2 Rh2 Si2
Calculated formula	C30 H66 O7 P2 Rh2 Si2
SMILES	[Rh]12345([Rh]6([P](C)(C)C)([P](C)(C)C)[O]1[Si](O[Si]([O]26)(OC(C)(C)C)OC(C)(C)C)(OC(C)(C)C)OC(C)(C)C)[CH]1=[CH]4CC[CH]5=[CH]3CC1
Title of publication	Multinuclear rhodium complexes supported by tetra-tert-butoxy disiloxide ligand: synthesis, structure, and reactivity
Authors of publication	Ishizaka, Yusuke; Matsumoto, Kazuhiro; Sato, Kazuhiko; Choi, Jun-Chul
Journal of publication	New Journal of Chemistry
Year of publication	2022
Journal volume	46
Journal issue	33
Pages of publication	16040 - 16046
a	20.3842 ± 0.0004 Å
b	11.6384 ± 0.0002 Å
c	17.9317 ± 0.0004 Å
α	90°
β	108.738 ± 0.002°
γ	90°
Cell volume	4028.63 ± 0.15 Å³
Cell temperature	293 ± 2 K
Ambient diffraction temperature	293 ± 2 K
Number of distinct elements	6
Space group number	14
Hermann-Mauguin space group symbol	P 1 21/c 1
Hall space group symbol	-P 2ybc
Residual factor for all reflections	0.0296
Residual factor for significantly intense reflections	0.0251
Weighted residual factors for significantly intense reflections	0.1032
Weighted residual factors for all reflections included in the refinement	0.1081
Goodness-of-fit parameter for all reflections included in the refinement	0.924
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
277671 (current)	2022-09-06	cif/ Updating files of 7061675, 7061676, 7061677 Original log message: Adding full bibliography for 7061675--7061677.cif.	7061677.cif
276953	2022-07-27	cif/ Adding structures of 7061675, 7061676, 7061677 via cif-deposit CGI script.	7061677.cif